WO 2013/171284 A1 discloses an optical device with a nano structure comprising a plurality of cone shaped structures distributed non-periodically on the surface of the device. A method of manufacturing the nano structure comprises the steps of providing a silicon carbide or gallium nitride substrate, forming a thin film of a masking material on a surface area, treating the thin film to form nano islands, anisotropically etching the substrate and at least a part of the thin film to form a non-periodical nano structure comprising a plurality of cone shaped surface structures.
US 2013/0340824 A1 discloses a photovoltaic device with anti-reflection means on a light-receiving surface, provided by nano-structured or black silicon. This results in a gradual change from a low porosity near the bulk material to a high porosity near the ambient air.
The semiconductor device comprises a semiconductor substrate, a transition layer in or on the semiconductor substrate, and a photonic component facing the transition layer. The transition layer allows a propagation of radiation according to a refractive index and comprises a structured surface affecting the propagation of radiation according to a gradual change of the refractive index through the transition layer with changing distance from the photonic component.
In an embodiment of the semiconductor device, the transition layer comprises the same material throughout.
In a further embodiment, the photonic component is arranged outside the semiconductor substrate, and the gradual change of the refractive index is an increase with increasing distance from the photonic component, in particular an increase from a value below 1.01 to a value above 1.01.
In a further embodiment, the photonic component is arranged in the semiconductor substrate, and the gradual change of the refractive index is a decrease with increasing distance from the photonic component, in particular a decrease from a value above 1.01 to a value below 1.01.
In a further embodiment, the semiconductor substrate and the transition layer are silicon.
In a further embodiment, the surface of the transition layer is structured by protrusions or stubs growing thinner from base to top. In particular, the protrusions or stubs may have a surface in the shape of one sheet of a circular hyperboloid of two sheets.
The method of producing the semiconductor device comprises providing a transition layer, which allows propagation of radiation according to a refractive index, in or on a semiconductor substrate, arranging a photonic component facing the transition layer, and structuring a surface of the transition layer by etching such that the propagation of radiation is affected according to a gradual change of the refractive index through the transition layer with changing distance from the photonic component.
In a variant of the method, the transition layer is formed as an integral part of the semiconductor substrate, and the surface of the transition layer comprises a surface area of the semiconductor substrate, which is structured by etching.
In a further variant of the method, the transition layer is etched in silicon by an etching process that deviates in a controlled way from the formation of black silicon. The etching process may comprise reactive ion etching.
In a further variant of the method, the surface of the transition layer is structured by etching protrusions or stubs growing thinner from base to top.
In a further variant of the method, the photonic component is mounted on a carrier, and the semiconductor substrate is fastened to the carrier, so that the surface of the transition layer is arranged opposite the photonic component.
The following is a detailed description of examples of the semiconductor device and the production method in conjunction with the appended figures.
The difference between the refractive indices of two different materials generates refraction of radiation according to Snell's law and an attenuation of the amplitude of the radiation with the transition from one material to the other. These effects can be avoided or at least reduced if the refractive index is gradually changed in an intermediate region by a continuous variation of the material composition or by a sequence of different materials whose refractive indices differ only slightly, in order to adapt the conditions for the propagation of radiation between regions of different refractive indices. Instead, the effect of the different refractive indices can be mitigated by a suitable structure of the interface in such a manner that the propagation of radiation is affected according to a gradual change of the refractive index through the structured layer. The semiconductor device makes use of the latter option.
The surface 6 of the transition layer 5 is provided with a structure that generates a gradual change of the effective refractive index with the change of the distance from the photonic component 4. Thus the propagation of radiation is affected in a way similar to a gradual change of the actual refractive index of the material through which the radiation propagates. The change of the effective refractive index through the transition layer 5 depends on this surface structure. The refractive index of the material of the transition layer 5 itself is not changed. The material of the transition layer 5 can therefore be the same throughout.
The structure of the surface 6 may be produced on a nano-scale level by nanotechnology like nanoimprint lithography, for instance, which is known per se in semiconductor technology. A surface structure comprising a plurality of protrusions in the shape of cones can be generated by deep reactive ion etching into a silicon surface, for example. Whereas in a conventional etching process erroneous operation or malfunction of the equipment may result in an undesired surface comprising needle-shaped protrusions known as “black silicon” or “silicon-grass,” an appropriate adaptation of the etching parameters enables the formation of a surface structure providing a gradual change of the effective refractive index. For this purpose, silicon etching can be modified to deviate in a controlled way from the formation of black silicon, in order to produce a surface structure comprising stubs or protrusions of essentially conical shape having dimensions appropriate for a gradual change of the effective refractive index. Infrared light, for instance, can easily enter or leave bulk silicon through such a structured surface, in particular from the semiconductor substrate 2 passing the transition layer 5 into the cavity 3 of the embodiment according to
In embodiments of the semiconductor device, the photonic component 4 may comprise a passive infrared sensor, like a bolometer, or a sensor for the detection of visible light, for example. Silicon, which may be the material of the substrate 2, is transparent to infrared radiation with a wavelength in the range from 9 μm to 11 μm. Between the bulk material of the semiconductor substrate 2 and the cavity 3, the transition layer 5 provides a gradual change of the effective refractive index, which increases the light efficiency typically by up to 50%. If the recess in the semiconductor substrate 2 is produced by deep reactive ion etching, the etching of the surface structure can immediately follow on an appropriate change of the etching parameters.
In the embodiment according to
In the embodiment according to
The described semiconductor device and method of production provide a novel way for photonic devices to substitute conventional gradient-index (GRIN) layers. An important advantage is the possibility to create the layer generating the gradual change of the effective refractive index as an integral part of a semiconductor substrate by just etching the surface by an etching method that is compatible with standard processes like a CMOS process. Hence there is no need for a layer deposition or layer transfer, and production costs will not essentially be increased by the application of this method. The method can be implemented on a standard DRIE (deep reactive ion etching) equipment using a photoresist mask to structure the whole area where the structured surface is to be generated.
Number | Date | Country | Kind |
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14169491.9 | May 2014 | EP | regional |
Filing Document | Filing Date | Country | Kind |
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PCT/EP2015/058821 | 4/23/2015 | WO | 00 |