The present invention relates to dispensers for containing and dispensing fluids and other substances, such as cosmetic products, and more particularly, to dispensers for holding multiple doses of such fluids and other substances, and that include one-way valves for hermetically sealing the substances within the dispensers, actuators for actuating pumps within the dispensers and dispensing metered doses of substances through the one-way valves, and in some embodiments, covers that are movably mounted on the dispensers for selectively covering and accessing the dispensing portions of the dispensers.
Prior art dispensers for storing and dispensing multiple doses of fluids, such as cosmetic dispensers for dispensing, for example, liquid lipstick, typically do not store the liquid lipstick or other product in a hermetically sealed storage chamber. In addition, such dispensers may be exposed to, or are applied to a user's lips or other facial surfaces that may contain dirt, germs, bacteria and/or other unwanted contaminants. Such contaminants can penetrate through the dispensing openings in the dispensers and, in turn, contaminate the bulk of the product, such as a liquid lipstick, stored within the dispensers. As a result, the contaminants can be passed from one user to another or otherwise cause unhealthy conditions with further usage of the dispensers. Further, because the products stored within the dispensers are exposed to air, the products can degrade or spoil, and/or require preservatives to prevent such degradation and/or spoilage from occurring. In some circumstances, preservatives can cause allergic and/or other undesirable or negative reactions, such as unwanted dermatological reactions.
It is an object of the present invention to overcome one or more of the above-described drawbacks and/or disadvantages of the prior art.
In accordance with one aspect, the present invention is directed to a dispenser for dispensing a substance comprises a body defining a variable-volume storage chamber for storing the substance, such as a liquid lipstick, concealer, or other cosmetic or cosmeceutical product. A dispensing portion of the dispenser is connected with the body and defines a compression chamber or bore coupled in fluid communication with the storage chamber for receiving substance therefrom. A piston is received within the bore and an outlet aperture is coupled in fluid communication with the bore. A one-way valve including an axially-extending valve seat and an axially-extending flexible valve cover is seated on the valve seat and defines a normally-closed, axially-extending seam between the valve cover and valve seat forming a fluid-tight seal therebetween. The flexible valve cover is movable relative to the valve seat, and the seam is connectable in fluid communication with the outlet aperture to allow the passage of a predetermined amount of substance pumped by the piston through the seam and out of the dispenser. An actuator is drivingly connected to at least one of the piston and the bore for moving at least one of the piston and the bore relative to the other and dispensing a predetermined amount of substance within the bore through the outlet aperture.
In some embodiments of the present invention, at least one cover extends adjacent to and covers the dispensing portion, and is movably mounted with respect to the dispensing portion between a closed position covering the dispensing portion and an open position exposing the dispensing portion.
In some embodiments of the present invention, the flexible valve cover is responsive to a flow of substance in the outlet aperture exceeding a valve opening pressure to move between (i) a normally-closed condition, and (ii) an open condition wherein portions of the valve cover axially spaced relative to each other substantially sequentially move substantially radially relative to the valve seat to allow the passage substance through the seam and out of the dispenser.
Also in a currently preferred embodiment of the present invention, the substance is a cosmetic, such as a liquid lipstick or a concealer, and the dispensing portion includes an applicator surface defining a contour substantially conforming to a facial contour for facilitating application of the cosmetic thereto.
In some embodiments of the present invention, the dispenser comprises a flexible bladder mounted within the body and defining the storage chamber between the bladder and body. The dispenser also includes a spring for biasing the piston and, preferably, the spring is formed integral with the bladder. In one embodiment of the present invention, the spring is formed by a substantially dome-shaped portion of the bladder.
In one such embodiment of the present invention, the bladder defines a first axially-extending, annular surface, and the body defines a second axially-extending, annular surface facing the first surface of the bladder and forming the storage chamber therebetween. The first surface of the bladder is movable radially inwardly and away from the second surface of the body to expand the storage chamber and receive substance therein. In addition, the first surface of the bladder is movable radially outwardly toward the second surface of the body upon dispensing substance therefrom. Also in this embodiment, a cap is coupled to the body and defines an aperture therethrough. The piston is received through the aperture and at least one of the piston and cap is movable relative to the other between a first position with the piston spaced away from the outlet aperture and defining a compression chamber therebetween, and a second position with the piston located adjacent to the outlet aperture for dispensing a predetermined amount of substance within the compression chamber through the outlet aperture.
In some embodiments of the present invention, the dispenser further comprises a substantially annular piston slidably received within the body and forming a substantially fluid-tight seal therebetween. The variable-volume storage chamber is formed between the substantially annular piston and the other piston, and the substantially annular piston is movable toward the other piston upon dispensing a dosage from the storage chamber to reduce the volume of the storage chamber in an amount approximately equal to the volume of the dose dispensed.
In some embodiments of the present invention, the dispenser further comprises a filling tube received within the body, and a second one-way valve coupled in fluid communication between the filling tube and the variable volume storage chamber. The second one-way valve preferably includes an axially-extending valve seat and an axially-extending flexible valve cover seated on the valve seat and defining a normally-closed, axially-extending seam therebetween forming a fluid-tight seal between the valve cover and valve seat. The flexible valve cover is movable relative to the valve seat, and the seam is connectable in fluid communication with variable-volume storage chamber to permit the passage of substance through the seam and into the storage chamber.
In accordance with another aspect, the present invention is directed to a method for storing and dispensing a substance with a dispenser. The dispenser includes a variable-volume storage chamber, a dispensing valve including an annular, axially-extending valve seat, and an annular, axially-extending flexible valve cover overlying the valve seat and forming an axially-extending valve seam therebetween, and a pump coupled in fluid communication between the variable-volume storage chamber and the valve seam. The method comprises the following steps:
(i) storing substance in the variable-volume storage chamber;
(ii) normally sealing the dispensing valve along the annular, axially-extending valve seam and preventing both the dispensing of substance below a threshold pressure through the valve seam, and external contamination of the substance in the variable-volume storage chamber through the valve seam;
(iii) manually actuating the pump to pressurize a metered dose of substance to a pressure greater than the threshold pressure and, in turn, substantially sequentially opening the valve seam in an axial direction thereof to allow the passage of substance at a pressure greater than the threshold pressure through the valve seam and out of the dispenser; and
(iv) decreasing the volume of the variable-volume storage chamber in an amount approximately equal to the volume of the dosage of substance dispensed.
In accordance with another aspect, the method further comprises the step of providing a filling tube mounted within a body portion of the dispenser, and a second one-way valve coupled in fluid communication between the filling tube and variable-volume storage chamber. The second one-way valve includes an axially-extending valve seat and an axially-extending flexible valve cover seated on the valve seat and defining a normally-closed, axially-extending seam therebetween forming a fluid-tight seal between the valve cover and valve seat. In accordance with this aspect, the method further comprises the steps of (i) inserting a filling member into the filling tube, (ii) pumping substance through the filling tube and into the seam of the second one-way valve at sufficient pressure to substantially radially move the flexible valve cover relative to the valve seat and, in turn, introduce the substance through the seam and into the variable-volume storage chamber, (iii) terminating pumping substance into the seam, (iv) allowing the valve cover to return to its normally-closed position, and (v) hermetically sealing the substance within the variable-volume storage chamber
One advantage of the present invention is that the dispenser can store multiple doses of substances, such as liquid lipsticks, concealers, or other cosmetic or cosmeceutical products, in a hermetically sealed, sterile condition throughout the shelf life and usage of the dispenser. Further, currently preferred embodiments of the dispenser can provide metered doses of the liquid lipstick, concealer, or other substance with a simple, one-handed actuation motion.
Other objects and advantages of the present invention will become apparent in view of the following detailed description of the currently preferred embodiments and the accompanying drawings.
In
As shown typically in
As shown in
As indicated above, the dispensing nozzle 24 includes a relatively rigid valve seat 26 and a flexible valve cover 28 mounted over the valve seat and defining the axially elongated, annular seam or interface 30 therebetween. As shown in
The dispensing portion 16 is formed integral with the body 12 and is formed of a relatively rigid material defining therein the axially elongated bore 18. The piston assembly 22 is slidably received within the bore 18 and the piston tip 58 is formed on the free end thereof. The dosage or compression chamber 60 is formed between the piston tip 58 and the stop surface 62 formed on the axially inner side of the valve seat 26. An annular fluid conduit 64 extends axially between the piston body 22 and the bore 18 and, when the piston is located in the rest position as shown in
The bore 18 defines a reduced cross-sectional portion 66 that cooperates with the piston tip 58 to define the volume of the dosage chamber 60 and thus the dosage volume of the dispenser. The axial extent of the reduced portion 66 defines a compression zone within which the fluid or other substance is compressed by the piston 22 and, in turn, forced through the dispensing nozzle 24. Thus, as shown best in
In the rest position (
As may be recognized by those of ordinary skill in the pertinent art based on the teachings herein, the shape and materials of construction are only exemplary, and numerous other shapes and/or materials of construction equally may be employed. For example, if desired, the piston tip may be formed of a resilient material that is attached to the end of the piston assembly. However, one advantage of the integral, relatively hard plastic piston as shown in
As shown in
As may be recognized by those of ordinary skill in the pertinent art based on the teachings herein, the construction of many aspects of the dispenser 10, including aspects of the body, flexible bladder, pump or piston, and nozzle, may be the same as or similar to that described in co-pending U.S. Pat. No. 6,761,286 entitled “Fluid Dispenser Having a Housing and Flexible Inner Bladder”; and/or U.S. patent application Ser. No. 10/691,270, filed Oct. 21, 2003, entitled “Ophthalmic Dispenser and Associated Method”, and/or U.S. patent application Ser. No. 10/519,691, entitled “One-way Actuation Release Mechanism for a System for Applying Medicament⇄, filed Apr. 10, 2003 as a reissue of U.S. Pat. No. 6,213,982, and/or U.S. provisional application Ser. No. 60/519,961, filed Nov. 14, 2003, entitled “Delivery Device and Method of Delivery”, filed Nov. 14, 2003; and/or U.S. provisional application Ser. No. 60/582,225, filed Jun. 23, 2004, entitled “Delivery Device with Compliance Monitor and Method”; each of which is assigned to the Assignee of the present invention, and is hereby expressly incorporated by reference as part of the present disclosure.
As shown in
As shown in
The dispenser 10 is filled by slidably receiving a probe (not shown) within the fill conduit 56 such that the tip of the probe is located at the base of the fill conduit and adjacent to the inlet 92 to the filling valve 83. Then, fluid, such as a liquid lipstick or other cosmetic or cosmeceutical product, is introduced through the probe, through the inlet apertures 92 and valve interface or seam 86 of the filling valve 83, and into the storage chamber 14. The fluid is introduced through the probe at a pressure greater than the valve opening pressure of the filling valve 83 to open the valve and allow the fluid to flow therethrough. As the storage chamber 14 is filled with fluid, the bladder 40 correspondingly collapses to allow the variable volume chamber 14 to correspondingly expand and receive the fluid. Once the storage chamber 14 is filled with fluid, the probe is removed from the fill conduit 56, and the flexible valve cover 84 seals against the valve seat 80 to hermetically seal the fluid within the dispenser. The filling cannula or probe, and other aspects of the filling apparatus and method for filling the dispensers of the present invention may be the same as or similar to that disclosed in U.S. patent application Ser. No. 10/843,902, filed May 12, 2004, entitled “Dispenser and Apparatus and Method for Filling a Dispenser”, which is assigned to the Assignee of the present invention and is hereby expressly incorporated by reference as part of the present disclosure.
The bladder 40 (including the integral valve member 83 and dome-shaped spring 81) is preferably made of an elastomeric material that is relatively soft in comparison to the body 12 and valve seat 80 of the piston assembly. For example, the bladder 12 may be made of a polymeric material, such as one of the materials sold under the trademarks Kraton™ or Santoprene™ (e.g., Santoprene 8211-35), or a vulcanized rubber or other polymeric material. However, as may be recognized by those of ordinary skill in the pertinent art based on the teachings herein, these materials are only exemplary, and numerous other materials that are currently, or later become known for performing the functions of the bladder and/or valve member equally may be used.
As shown in
As may be recognized by those of ordinary skill in the pertinent art based on the teachings herein, the spring 81 may take any of numerous different shapes and/or configurations, or may be formed of any of numerous different materials, that are currently, or later become known for performing the function of the spring as described herein. For example, the spring may define a shape other than a dome shape, or may not be formed integral with the bladder or the valve member. For example, the spring could take the form of a coil or other type of spring, that may be made of metal, plastic, or any of numerous other materials, for biasing the piston assembly as described herein. Also, the shape and/or material of construction of the spring may be selected to control the spring force applied to the piston assembly. One advantage of the substantially dome-shaped configuration, however, is that the dome shape imparts lateral (or radial) and axial forces to the piston assembly 22 to facilitate maintaining sufficient force to drive the piston from the fully-actuated to the rest position throughout the shelf-life and usage of the dispenser 10. Yet another advantage of the illustrated embodiment of the present invention is that by forming the spring integral with the base portion of the bladder, a separate part that otherwise would be required to bias the piston assembly, is eliminated.
As shown in
As shown, the applicator surface defines a curvilinear contour to substantially conform to the contour an application surface, such as facial tissue. In the illustrated embodiment, the contour is defined by a radius “R” dimensioned to comformably contact a user's lips for purposes of applying a metered dose of liquid lipstick thereto. However, as may be recognized by those of ordinary skill in the pertinent art based on the teachings herein, this specific shape of the applicator surface may take any of numerous different such shapes that are currently or later become known for performing the function of the applicator surface as described herein. For example, the applicator surface may take any of a variety of different forms designed to substantially conformably contact a user's eyelids, eyebrows, eyelashes, cheeks, toenails, fingernails, etc.
As shown typically in
As shown in
In the operation of the dispenser 10, a user may grasp the dispenser in one hand and flip open the covers 36, 38 as shown, for example, in
One advantage of the currently preferred embodiments of the present invention, is that once a metered dosage is dispensed, the piston tip 58 returns to its rest position, as shown typically in
In
In the operation of the dispenser 110, a user may grasp the dispenser in one hand and remove the cover 136 with either hand. Then, the user may axially depress with the index finger or other preferred digit of the same hand the manually engageable portion 194 of the actuator 132 to dispense a metered dose of liquid lipstick, or other substance contained within the dispenser, onto the applicator surface 208. If desired, the user may depress the actuator 132 with a finger of the hand not holding the dispenser; however, one advantage of the currently preferred embodiments of the present invention, is that the dispenser may be held and actuated with the same hand. In order to apply the metered dosage of liquid lipstick or other substance contained within the dispenser to the lips (e.g., for lip applications, the dispenser may alternatively contain a lip balm or other substance that may be applied to a person's lips), the user may hold with the other hand the cover 136 and position and look into the mirror 212 of the cover to view the dispensing tip and/or lip surfaces and, in turn, apply the applicator surface 208 containing the substance thereon to the lips. Upon contacting the desired lip surface with the applicator surface 208, the applicator surface substantially conformably contacts the lip surface and facilitates uniformly applying the substance in a film-like manner thereto. The user may then move the applicator surface 108 along the lip surface, with or without the assistance of the mirror 212, to uniformly spread the liquid lipstick or other substance thereon. As additional liquid lipstick or other substance is required to cover additional surface portions of the lips, the user may then axially depress the actuator 132 in the same manner as described above and repeat the application until the liquid lipstick or other substance is suitably applied.
In
In this embodiment, as described in the above-mentioned co-pending patent application, a plurality of threads are formed on an upper guide portion of the piston which engage partial threads formed on the inner wall of the upper portion of the body 312A. The threads on the upper guide portion of the piston define a plurality of regions in which the thread diameter gradually increases, beginning from a diameter that corresponds to the diameter of the partial threads on the inner wall of the upper portion of the body 312A, to a diameter that is greater than the diameter of the partial threads. The largest diameter threads on the piston have a smaller diameter than the diameter or corresponding dimension of the body 312A between the partial threads.
As the actuator 332 and the piston connected thereto are rotated, as indicated by the arrow 406, the larger diameter threads on the piston are progressively engaged by the partial threads on the inner wall of the upper portion of the body 312A. This causes the upper portion of the body 312A to expand slightly. As the largest diameter threads on the piston disengage from the partial threads on the body 312A and enter the area between the partial threads, the body 312A rapidly returns to its original shape. When the larger diameter threads are located in the area between the partial threads, the piston assembly is locked in position until a sufficient rotational force is applied to the piston assembly to cause the larger diameter threads to engage the partial threads on the inner wall of the body 312A. By establishing the thread pitch as disclosed in the above-mentioned co-pending patent application, the distance of travel of the piston for each rotation of the piston through the threaded portions can be precisely controlled, resulting in delivery of a pre-determined amount of the substances for each incremental rotation of the piston.
In the operation of the dispenser 310, a user may grasp the dispenser in one hand and flip open the covers 336, 338 as shown, for example, in
In
In the illustrated embodiment, the plunger 440 is made of a relatively resilient plastic material, such as one of the plastics sold under the trademark Santoprene™ (e.g., Santoprene 8211-35 (shore 35 hardness) or 8211-55 (shore 55 hardness)). In addition, the valve cover 428 and dome spring 481 also are made of a relatively resilient plastic, such as one of the plastics sold under the trademark Santoprene™ (e.g., Santoprene 8211-35 (shore 35 hardness)). As may be recognized by those of ordinary skill in the pertinent art based on the teachings herein, these materials are only exemplary, and may be changed as desired or otherwise required by a particular application. For example, in applications requiring low sorption, the plunger and dispenser body may be formed of a relatively low sorptive material, such as a relatively hard plastic, including one or more of the plastics sold under the trademark Topaz.
An annular, tapered gap 449 is formed between the cap 446 and adjacent wall of the body 412 to facilitate inserting the cap into the body and snapping or otherwise fixedly securing the lobe 478 of the cap into the corresponding annular groove of the body. In this embodiment, the fill tube 454 is captured between the biasing force of the dome spring 481 and the actuator 432, and therefore there is no need to fixedly secure the actuator to the fill tube.
Another difference of the dispenser 410 in comparison to the dispenser 110 described above, is that the dome spring 481 is formed integral with the valve cover 484, but not with a corresponding bladder. Rather, the dispenser 410 includes the plunger 440 for forming the variable-volume storage chamber 414 in lieu of the flexible bladder described above. As can be seen, when the piston 454 is depressed inwardly to dispense a metered dose, the dome spring 481 deforms both axially and radially inwardly. Then, when the piston (or actuator) is released, the resiliency of the dome spring 481 drives the piston outwardly and into the rest position, as shown typically in
Also in this embodiment, the piston 422 is formed separately from the fill tube 454 and is then fixedly secured to the fill tube. The piston 422 defines an axially-extending shaft 423 that is received within the inner end of the fill tube 454 to form the piston/fill tube assembly. The piston shaft 423 defines one or more first annular or other protuberances 485 received within corresponding annular or other grooves or recesses formed in the dome spring 481 to fixedly secure the dome spring to the piston, and one or more second annular or other protuberances 487 received within corresponding annular or other grooves or recesses formed in the fill tube 454 to fixedly secure the piston to the fill tube.
The valve assembly 424 of the dispenser 410 further includes a tamper-resistant ring 425 received within a corresponding annular groove formed in the base of the visco-elastic valve cover 428 to fixedly secure the valve cover to the valve seat. One advantage of the tamper-resistant ring 425 is that it prevents anyone from removing the valve cover and tampering with the contents of the dispenser without damaging the tamper-resistant ring.
As can be seen, the dispenser 410 defines a more narrow and elongated configuration than the dispenser 110 described above. As may be recognized by those of ordinary skill in the pertinent art based on the teachings herein, the dispensers of the invention may take any of numerous different shapes, configurations and/or sizes.
In
As may be recognized by those of ordinary skill in the pertinent art based on the teachings herein, numerous changes and modifications may be made to the above-described and other embodiments of the present invention without departing from the spirit of the invention as defined in the claims. For example, the components of the dispensers may be made of any of numerous different materials that are currently or later become known for performing the function(s) of each such component. Similarly, the components of the dispensers may take any of numerous different shapes and/or configurations. Also, the dispensers may be used to dispense any of numerous different types of fluids or other substances for any of numerous different applications, including, for example, cosmetic, dermatological, or other pharmaceutical, cosmeceutical and/or OTC applications. Further, the filling machines used to fill the dispensers of the present invention may take any of numerous different configurations that are currently known, or that later become known for filling the dispensers. For example, the filling machines may have any of numerous different mechanisms for sterilizing, feeding, evacuating and/or filling the dispensers. Further, the filling valve need not be formed through the bladder or otherwise as shown, but may extend through the body or otherwise may be coupled in fluid communication with the storage chamber to evacuate and/or fill the storage chamber. Alternatively, the dispenser may include one valve for evacuating the interior of the dispenser and another valve for filling the storage chamber of the dispenser. Still further, the piston and/or dispensing valve each may take a configuration that is different than that disclosed herein. In another embodiment, the dispenser may include a needle penetrable and laser resealable stopper coupled in fluid communication with the variable-volume storage chamber for needle filling the storage chamber through the resealable stopper and then laser resealing the needle hole in the stopper as disclosed in the following patents and co-pending patent applications that are assigned to the Assignee of the present invention and are hereby expressly incorporated by reference as part of the present disclosure: U.S. Pat. No. 6,604,561, entitled “Medicament Vial Having a Heat-Sealable Cap, and Apparatus and Method for Filling the Vial”; U.S. Pat. No. 6,684,916, entitled “Medicament Vial Having a Heat-Sealable Cap, and Apparatus and Method for Filling the Vial”; U.S. patent application Ser. No. 10/694,364, filed Oct. 27, 2003, entitled “Medicament Vial Having a Heat-Sealable Cap, and Apparatus and Method for Filling the Vial”; U.S. patent application Ser. No. 10/766,172, filed Jan. 28, 2004, entitled “Medicament Vial Having a Heat-Sealable Cap, and Apparatus and Method for Filling the Vial”; and U.S. patent application Ser. No. 10/600,525, filed Jun. 19, 2003, entitled “Sterile Filling Machine Having Needle Filling within E-Beam Chamber”. Accordingly, this detailed description of currently preferred embodiments is to be taken in an illustrative, as opposed to a limiting sense.
This patent application claims priority to U.S. provisional application Ser. No. 60/488,355, filed Jul. 17, 2003, entitled “Piston-Type Dispenser with One-Way Valve for Storing and Dispensing Metered Amounts of Substances, and Pivoting Cover for Covering Dispensing Portion Thereof”, and to U.S. provisional application Ser. No. 60/539,814, filed Jan. 27, 2004, entitled “Piston-Type Dispenser with One-Way Valve for Storing and Dispensing Metered Amounts of Substances”, each of which is hereby expressly incorporated by reference as part of the present disclosure.
Number | Name | Date | Kind |
---|---|---|---|
1471091 | Bessesen | Oct 1923 | A |
2128035 | Boetel | Aug 1938 | A |
2522403 | Ross | Sep 1950 | A |
2648334 | Brown et al. | Aug 1953 | A |
2687133 | Schwarz | Aug 1954 | A |
2951584 | Bauer | Sep 1960 | A |
3123661 | Roman | Mar 1964 | A |
3353718 | McLay | Nov 1967 | A |
3356093 | Monahon | Dec 1967 | A |
3412910 | Hahn | Nov 1968 | A |
3648903 | Marchant | Mar 1972 | A |
3659749 | Schwartz | May 1972 | A |
3662753 | Tassell | May 1972 | A |
3669323 | Harker et al. | Jun 1972 | A |
3699961 | Szpur | Oct 1972 | A |
3756729 | Tufts | Sep 1973 | A |
3838689 | Cohen | Oct 1974 | A |
3921333 | Clendinning et al. | Nov 1975 | A |
3963814 | Cospen et al. | Jun 1976 | A |
3993069 | Buckles et al. | Nov 1976 | A |
4002516 | Gaborieau et al. | Jan 1977 | A |
4023607 | Jensen et al. | May 1977 | A |
4050459 | Sanchez | Sep 1977 | A |
4102476 | Loeffler | Jul 1978 | A |
4128349 | Del Bon | Dec 1978 | A |
4141474 | Nilson | Feb 1979 | A |
4185628 | Kopfer | Jan 1980 | A |
4189065 | Herold | Feb 1980 | A |
4233262 | Curto | Nov 1980 | A |
4239132 | Mueller et al. | Dec 1980 | A |
4240465 | Rader | Dec 1980 | A |
4264018 | Warren | Apr 1981 | A |
4346708 | LeVeen et al. | Aug 1982 | A |
4367739 | LeVeen et al. | Jan 1983 | A |
4420100 | Mueller | Dec 1983 | A |
4458830 | Werding | Jul 1984 | A |
4475905 | Himmelstrup | Oct 1984 | A |
4479578 | Brignola et al. | Oct 1984 | A |
4479989 | Mahal | Oct 1984 | A |
4482585 | Ohodaira et al. | Nov 1984 | A |
4493348 | Lemmons | Jan 1985 | A |
4501781 | Kushida et al. | Feb 1985 | A |
4513891 | Hain et al. | Apr 1985 | A |
4526294 | Hirschmann et al. | Jul 1985 | A |
4578295 | Jabarin | Mar 1986 | A |
4579757 | Su et al. | Apr 1986 | A |
4603066 | Jabarin | Jul 1986 | A |
4624594 | Sasaki et al. | Nov 1986 | A |
4636412 | Field | Jan 1987 | A |
4643723 | Smit | Feb 1987 | A |
4699300 | Blake | Oct 1987 | A |
4700838 | Falciani et al. | Oct 1987 | A |
4704510 | Matsui | Nov 1987 | A |
4722459 | Goncalves | Feb 1988 | A |
4737148 | Blake | Apr 1988 | A |
4739906 | LoTurco | Apr 1988 | A |
4776717 | Iizuka et al. | Oct 1988 | A |
4784652 | Wikström | Nov 1988 | A |
4842165 | Van Coney | Jun 1989 | A |
4854481 | Bohl et al. | Aug 1989 | A |
4854486 | Daley et al. | Aug 1989 | A |
4859513 | Gibbons et al. | Aug 1989 | A |
4865591 | Sams | Sep 1989 | A |
4880675 | Mehta | Nov 1989 | A |
4895279 | Schultz | Jan 1990 | A |
4903741 | Ibanez | Feb 1990 | A |
4910147 | Bacehowski et al. | Mar 1990 | A |
4921733 | Gibbons et al. | May 1990 | A |
4923480 | Monestere | May 1990 | A |
4936833 | Sams | Jun 1990 | A |
4949877 | Hanna et al. | Aug 1990 | A |
4962868 | Borchard | Oct 1990 | A |
4973318 | Holm et al. | Nov 1990 | A |
4978036 | Burd | Dec 1990 | A |
4981479 | Py | Jan 1991 | A |
5033647 | Smith et al. | Jul 1991 | A |
5083416 | Schneider et al. | Jan 1992 | A |
5102705 | Yammoto et al. | Apr 1992 | A |
5108007 | Smith et al. | Apr 1992 | A |
5143236 | Gueret | Sep 1992 | A |
5178300 | Haviv et al. | Jan 1993 | A |
5197638 | Wood | Mar 1993 | A |
5226568 | Newton et al. | Jul 1993 | A |
5226895 | Harris | Jul 1993 | A |
5238153 | Castillo et al. | Aug 1993 | A |
5244465 | Michel | Sep 1993 | A |
5253785 | Haber et al. | Oct 1993 | A |
5257696 | Greene | Nov 1993 | A |
5263946 | Klug | Nov 1993 | A |
5267986 | Py | Dec 1993 | A |
5277342 | Dickau et al. | Jan 1994 | A |
5290260 | Stines | Mar 1994 | A |
5318204 | Davis et al. | Jun 1994 | A |
5320256 | Wood | Jun 1994 | A |
5320845 | Py | Jun 1994 | A |
5332121 | Schmidt et al. | Jul 1994 | A |
5339972 | Crosnier et al. | Aug 1994 | A |
5360145 | Gueret | Nov 1994 | A |
5366108 | Darling | Nov 1994 | A |
5401259 | Py | Mar 1995 | A |
5416303 | Grooms et al. | May 1995 | A |
5419465 | Schroeder | May 1995 | A |
5425465 | Healy | Jun 1995 | A |
5429254 | Christine | Jul 1995 | A |
5489026 | D'Aloia | Feb 1996 | A |
5489027 | Goerigk | Feb 1996 | A |
RE35187 | Gortz | Mar 1996 | E |
5497910 | Meadows et al. | Mar 1996 | A |
D368774 | Py | Apr 1996 | S |
5545147 | Harris | Aug 1996 | A |
5556678 | Jupin et al. | Sep 1996 | A |
D374719 | Py | Oct 1996 | S |
5562960 | Sugiura et al. | Oct 1996 | A |
5564596 | Meadows et al. | Oct 1996 | A |
5565160 | Makuuchi et al. | Oct 1996 | A |
5582330 | Iba | Dec 1996 | A |
5582598 | Chanoch | Dec 1996 | A |
5591136 | Gabriel | Jan 1997 | A |
5609273 | Firestone et al. | Mar 1997 | A |
5613957 | Py | Mar 1997 | A |
5615795 | Tipps | Apr 1997 | A |
5630800 | Blank et al. | May 1997 | A |
5636930 | Holloway | Jun 1997 | A |
5641004 | Py | Jun 1997 | A |
5664704 | Meadows et al. | Sep 1997 | A |
5676267 | Slat et al. | Oct 1997 | A |
5685869 | Py | Nov 1997 | A |
5687882 | Mueller | Nov 1997 | A |
5692651 | Fuchs | Dec 1997 | A |
5702019 | Grimard | Dec 1997 | A |
5718334 | Demel | Feb 1998 | A |
5727892 | Baudin | Mar 1998 | A |
5728075 | Levander | Mar 1998 | A |
5730322 | Iba et al. | Mar 1998 | A |
5738067 | Landwehr | Apr 1998 | A |
5743441 | Baudin et al. | Apr 1998 | A |
5743889 | Sams | Apr 1998 | A |
5746728 | Py | May 1998 | A |
5755269 | Venooker et al. | May 1998 | A |
5759218 | Martin et al. | Jun 1998 | A |
5772347 | Gueret | Jun 1998 | A |
5780130 | Hansen et al. | Jul 1998 | A |
5785683 | Szapiro et al. | Jul 1998 | A |
5799837 | Firestone et al. | Sep 1998 | A |
5803311 | Fuchs | Sep 1998 | A |
5804236 | Frisk | Sep 1998 | A |
5816772 | Py | Oct 1998 | A |
5823397 | Gil | Oct 1998 | A |
5829901 | Brown et al. | Nov 1998 | A |
5855302 | Fisscher | Jan 1999 | A |
5860755 | Bunk | Jan 1999 | A |
5875931 | Py | Mar 1999 | A |
5876372 | Grabenkort et al. | Mar 1999 | A |
5879095 | Gueret | Mar 1999 | A |
5879336 | Brinon | Mar 1999 | A |
5899624 | Thompson | May 1999 | A |
5921989 | Deacon et al. | Jul 1999 | A |
5931386 | Jouillat | Aug 1999 | A |
5934500 | Cogger et al. | Aug 1999 | A |
5944702 | Py | Aug 1999 | A |
RE36410 | Meshberg | Nov 1999 | E |
5983905 | Patching | Nov 1999 | A |
6004298 | Levander | Dec 1999 | A |
6032101 | Freedman et al. | Feb 2000 | A |
6033384 | Py | Mar 2000 | A |
6050444 | Sugg | Apr 2000 | A |
6053370 | Ludbrook et al. | Apr 2000 | A |
6053893 | Bucher | Apr 2000 | A |
6062430 | Fuchs | May 2000 | A |
6062437 | Mascitelli | May 2000 | A |
6083201 | Skinkle | Jul 2000 | A |
6083450 | Safian | Jul 2000 | A |
6145707 | Baudin | Nov 2000 | A |
6170705 | Schneider et al. | Jan 2001 | B1 |
RE37047 | Py | Feb 2001 | E |
6186686 | Neuner et al. | Feb 2001 | B1 |
6193698 | Kirchhofer et al. | Feb 2001 | B1 |
6200047 | Holloway | Mar 2001 | B1 |
6202901 | Gerber et al. | Mar 2001 | B1 |
6234363 | Stradella | May 2001 | B1 |
6254579 | Cogger et al. | Jul 2001 | B1 |
6267768 | Deacon et al. | Jul 2001 | B1 |
6280421 | Kirchhofer et al. | Aug 2001 | B1 |
6283976 | Portney | Sep 2001 | B1 |
6290679 | Hostettler et al. | Sep 2001 | B1 |
6301767 | Granger et al. | Oct 2001 | B1 |
6306423 | Donovan et al. | Oct 2001 | B1 |
6312708 | Donovan | Nov 2001 | B1 |
6325253 | Robinson | Dec 2001 | B1 |
6338442 | De Laforcade | Jan 2002 | B1 |
6343713 | Abplanalp | Feb 2002 | B1 |
6351924 | Gustafsson et al. | Mar 2002 | B1 |
6357945 | Losier et al. | Mar 2002 | B1 |
6371129 | Le Bras-Brown et al. | Apr 2002 | B1 |
6383167 | Kirchhofer et al. | May 2002 | B2 |
6383509 | Donovan et al. | May 2002 | B1 |
6386395 | Lunghetti | May 2002 | B1 |
6419412 | Ostrowski et al. | Jul 2002 | B1 |
6428545 | Portney | Aug 2002 | B2 |
6446844 | Gross | Sep 2002 | B1 |
6450994 | Boyles et al. | Sep 2002 | B1 |
6471095 | Cann | Oct 2002 | B1 |
6485470 | Hostettler et al. | Nov 2002 | B2 |
6502725 | Alexander | Jan 2003 | B1 |
6533482 | Byun | Mar 2003 | B1 |
6581805 | Conboy et al. | Jun 2003 | B2 |
6604561 | Py | Aug 2003 | B2 |
6662977 | Gerber et al. | Dec 2003 | B2 |
6761286 | Py et al. | Jul 2004 | B2 |
20010009990 | Hostettler et al. | Jul 2001 | A1 |
20020017294 | Py | Feb 2002 | A1 |
20020071708 | Fontanet et al. | Jun 2002 | A1 |
20020074362 | Py et al. | Jun 2002 | A1 |
20030089743 | Py et al. | May 2003 | A1 |
20040112925 | Py et al. | Jun 2004 | A1 |
Number | Date | Country |
---|---|---|
0802827 | Aug 1998 | EP |
0649795 | Jun 1999 | EP |
0673852 | Feb 2000 | EP |
Number | Date | Country | |
---|---|---|---|
20050089358 A1 | Apr 2005 | US |
Number | Date | Country | |
---|---|---|---|
60488355 | Jul 2003 | US | |
60539814 | Jan 2004 | US |