This application is based upon and claims the benefit of priority of the prior Japanese Patent Application No. 2018-089347, filed on May 7, 2018, the entire content of which is incorporated herein by reference.
This application relates to a plating apparatus and especially relates to an electroplating apparatus.
Conventionally, wiring has been formed on fine grooves for wiring, holes, or resist openings provided on surfaces of a substrate such as a semiconductor wafer, and bumps (protruding electrode) electrically connected to electrodes of a package or similar component has been formed on the surface of the substrate. As such method for forming these wiring and bump, a method such as an electroplating method, a deposition method, a printing method, and a ball bump method has been known. In accordance with increase in the number of I/Os of a semiconductor chip and decrease in pitch, the electroplating method that allows miniaturization and provides comparatively stable performance has been often used.
When the electroplating is performed on the substrate such as the semiconductor wafer, an anode sometimes has a shape similar to that of the substrate as a plating object to arrange the anode and the substrate in parallel in an electrolyte. For example, when the substrate as the plating object is circular, the anode may be configured circular having a similar size. When the substrate as the plating object is quadrangular, a quadrangular anode having a similar size may be used as the anode.
When the wiring or the bump is formed in the electroplating method, a seed layer (power feed layer) having a low electrical resistance is formed on a surface of a barrier metal provided on the grooves for wiring, the holes, or the resist openings on the substrate. A plating film grows on a surface of this seed layer. Recently, in accordance with the miniaturization of the wiring and the bump, the seed layer having a thinner film thickness has been used. As the film thickness of the seed layer thins, an electrical resistance (sheet resistance) of the seed layer increases.
Generally, the substrate to be plated has an electric contact on its peripheral edge portion. In view of this, a current corresponding to a combined resistance of an electric resistance value of a plating solution and an electric resistance value of the seed layer from a center portion of the substrate to the electric contact flows through the center portion of the substrate. Meanwhile, a current approximately corresponding to the electric resistance value of the plating solution flows through the peripheral edge portion (near the electric contact) of the substrate. That is, the current is less likely to flow through the center portion of the substrate by the electric resistance value of the seed layer from the center portion of the substrate to the electric contact. This phenomenon that the current concentrates on the peripheral edge portion of the substrate is referred to as a terminal effect.
The thinner the film thickness of the seed layer of the substrate is, the larger the electric resistance value of the seed layer from the center portion of the substrate to the electric contact is. In view of this, the thinner the film thickness of the seed layer of the substrate is, the more significant the terminal effect in the plating is. As a result, a plating rate in the center portion of the substrate decreases, the film thickness of the plating film in the center portion of the substrate becomes thinner than that of the plating film in the peripheral edge portion of the substrate, and an in-plane uniformity of the film thickness decreases.
To suppress the decrease in the in-plane uniformity of the film thickness due to the terminal effect, it is necessary to adjust an electric field applied to the substrate. For example, a plating apparatus that installs a regulating plate, which adjusts an electric potential distribution between an anode and a substrate, between the anode and the substrate has been known (see PTL 1).
PTL 1: Japanese Unexamined Patent Application Publication No. 2017-115171
As described above, when the regulating plate is arranged between the anode and the substrate to reduce the terminal effect, a space to arrange the regulating plate is needed between the anode and the substrate. Generally, the larger a distance between the anode and the substrate is, the smaller an influence of the terminal effect is. Therefore, when the electroplating is performed by arranging a tabular anode having a size similar to that of the substrate as the plating object parallel to the substrate, considering the reduction of the terminal effect, there is a constant limitation to decrease the distance between the anode and the substrate. The larger the distance between the substrate and the anode is, the larger a volume of a plating tank on which they are arranged is and the larger a size of the plating apparatus is. The larger the plating tank is, the larger a necessary amount of the plating solution is and the larger a running cost of the plating apparatus is.
One object of this application is to provide a plating apparatus that reduces a terminal effect. One object of this application is to reduce the terminal effect while decreasing a distance between a substrate and an anode.
According to one embodiment, a plating apparatus is provided. The plating apparatus includes a substrate holder that holds a substrate as a plating object, an electric contact disposed on the substrate holder to apply a current to a substrate, and a plurality of anodes arranged to face the substrate holder. Each of the plurality of anodes has a long and thin shape. Each of the plurality of anodes is arranged such that a longitudinal direction of the anode is parallel to a surface of the substrate held onto the substrate holder and such that at least one end in the longitudinal direction of each of the anodes faces the electric contact of the substrate holder.
The following describes embodiments of a plating apparatus according to the present invention with the attached drawings. In the attached drawings, identical or similar reference numerals are attached to identical or similar components, and overlapping description regarding the identical or similar components may be omitted in the description of the respective embodiments. Features shown in the respective embodiments are applicable to other embodiments in so far as they are consistent with one another.
The loading/unloading unit 101 includes two cassette tables 125 and a substrate removal/mounting mechanism 129. The cassette table 125 includes a cassette 125a that houses a substrate. The substrate removal/mounting mechanism 129 is configured to mount/remove the substrate on/from the substrate holder (not illustrated). A stocker 130 to house the substrate holder is disposed at the proximity of (for example, under) the substrate removal/mounting mechanism 129. In the center of these units 125, 129, and 130, a substrate conveying device 127 formed of a robot for conveyance that conveys the substrate between these units is arranged. The substrate conveying device 127 is configured to run with a running mechanism 128.
The cleaning unit 120 includes a cleaning device 120a that cleans and dries the substrate after the plating process. The substrate conveying device 127 is configured to convey the substrate after the plating process to the cleaning device 120a and take out the cleaned and dried substrate from the cleaning device 120a.
The preprocessing/postprocessing unit 102A includes a pre-wet tank 132, a pre-soak tank 133, a pre-rinse tank 134, a blow tank 135, and a rinse tank 136. In the pre-wet tank 132, the substrate is immersed in a pure water. In the pre-soak tank 133, an oxide film on a surface of a conducting layer such as a seed layer formed on a surface of the substrate is removed by etching. In the pre-rinse tank 134, the substrate after pre-soak is cleaned with a cleaning liquid (for example, pure water) together with the substrate holder. In the blow tank 135, liquid draining of the substrate after cleaning is performed. In the rinse tank 136, the substrate after plating is cleaned with the cleaning liquid together with the substrate holder. The pre-wet tank 132, the pre-soak tank 133, the pre-rinse tank 134, the blow tank 135, and the rinse tank 136 are arranged in this order.
The plating processing unit 102B includes a plurality of plating tanks 139 including an overflow tank 138. Each plating tank 139 internally houses one substrate and immerses the substrate in a plating solution internally held to perform plating such as copper plating on the surface of the substrate. Here, a type of the plating solution is not especially limited, and various plating solutions are used as usage.
The plating apparatus 100 includes a substrate holder conveyance device 137 positioned lateral to these respective devices. The substrate holder conveyance device 137 employs, for example, a linear motor system to convey the substrate holder between these respective devices together with the substrate. This substrate holder conveyance device 137 is configured to convey the substrate holder between the substrate removal/mounting mechanism 129, the pre-wet tank 132, the pre-soak tank 133, the pre-rinse tank 134, the blow tank 135, the rinse tank 136, and the plating tank 139.
The plating tank 139 houses a substrate holder 11 holding a substrate S1. The substrate holder 11 is arranged in the plating tank 139 such that the substrate S1 is immersed in the plating solution Q in a vertical state. An anode 62 held onto an anode holder 60 is arranged on a position facing the substrate S1 in the plating tank 139. Detailed structure and arrangement of the anode 62 according to the embodiment will be described later, but a plurality of anodes 62 having elongate shapes are arranged on the anode holder 60. A regulation plate 64 projecting in a direction to the substrate S1 is mounted on a front surface side (a side facing the substrate S1) of the anode holder 60. The regulation plate 64 is disposed to surround a whole peripheral area of the plurality of anodes 62. The regulation plate 64 is formed of a dielectric material. The regulation plate 64 adjusts a direction of the electric field between the anode 62 and the substrate S1. The regulation plate 64 may be fixed to the anode holder 60 or may be configured simply attachable to and removable from the anode holder 60 with a mounting member such as a screw. The substrate S1 is electrically connected to the anode 62 via a plating power supply 144. Applying the current between the substrate S1 and the anode 62 forms a plating film (for example, a copper film) on a surface of the substrate S1.
A paddle 145, which is reciprocated parallel to the surface of the substrate S1 to stir the plating solution Q, is arranged between the substrate S1 and the anode 62. The paddle 145 stirs the plating solution Q to allow sufficient copper ions to be uniformly supplied to the surface of the substrate S1.
The substrate holder 11 holds the polygonal substrate S1 such that a surface to be plated of the polygonal substrate S1 illustrated in
In the embodiment in the drawing, the plurality of anodes 62 are elongate and arranged on the anode holder main body 61 such that their longitudinal directions are parallel to one another. In a state where the anode holder 60 and the substrate holder 11 are arranged on the plating tank 139, the longitudinal direction of the anode 62 will be parallel to the surface of the substrate S1.
The anode 62 can be formed of various materials corresponding to a purpose of the plating process. In one embodiment, the anode 62 can be an insoluble anode. In one embodiment, the anode 62 can be formed of an alloy containing titanium and platinum or an alloy containing titanium and iridium oxide. In one embodiment, the anode 62 can be formed as a solid member. In one embodiment, the anode 62 may be formed hollow such that thin metallic plates are stuck one another. The anode 62 may be a soluble anode such as phosphorus-containing copper having a surface on which coating has been performed so as not to change the dimensions in the x direction and they direction.
As illustrated in
In the embodiment of the plating apparatus that uses the plurality of elongate anodes 62 as described above, the direction and a magnitude of the electric field formed between the anode 62 and the substrate S1 are different depending on the shape, the number, and the arrangement of the used anodes 62. Therefore, the direction and the magnitude of the electric field formed between the anode 62 and the substrate S1 can be adjusted by the shape, the number, and the arrangement of the used anodes 62. Especially, arranging the end of the anode 62 having thin end to face the electric contact 17 of the substrate S1 can undergo reduced influence of the terminal effect. As described above, the current at the proximity of the electric contact of the substrate as the plating object is larger than that on the center portion of the substrate. Arranging the end of the anode 62 having the thin end to face the electric contact 17 of the substrate S1 decreases a projected area of the anode 62 on the substrate S1 near the end of the anode 62, that is, at the proximity of the electric contact 17 of the substrate S1, when the substrate S1 is viewed from the anode 62. Therefore, compared with a case that uses an anode having a constant width without thinly forming its end, the current flowing at the proximity of the electric contact 17 of the substrate S1 can be decreased, and as a result, the influence of the terminal effect can be canceled. In the above-described embodiment, the shape of the anode 62 can decrease the influence of the terminal effect. Thus, the distance between the anode and the substrate S1 can be made smaller than ever before. Making the distance between the anode and the substrate S1 small can make the plating tank small and can make the necessary amount of the plating solution smaller than ever before. In the above-described embodiment, the shape of the anode 62 can decrease the influence of the terminal effect. Thus, it is not necessary to arrange a regulating plate between the anode and the substrate as in a conventional method. However, the present invention does not eliminate the use of the regulating plate.
The above-described embodiment has describes the plating apparatus that uses the substrate holder 11 and the anode 62 to perform the plating process on the polygonal substrate S1. However, an anode having the same or like features is also applicable to a plating apparatus for performing the plating process on a circular substrate.
In the embodiment illustrated in
As illustrated in
The substrate holder 11 and the anode 62 for performing the plating process on the circular substrate S1, which have been described with
The anode holder 60 according to the embodiment illustrated in
From the above-described embodiments, at least the following technical ideas are obtained.
According to a configuration 1, a plating apparatus is provided. The plating apparatus includes a substrate holder for holding a substrate as a plating object, an electric contact disposed on the substrate holder to apply a current to a substrate, and a plurality of anodes arranged to face the substrate holder. Each of the plurality of anodes has a long and thin shape. Each of the plurality of anodes is arranged such that a longitudinal direction of the anode is parallel to a surface of the substrate held onto the substrate holder and such that at least one end in the longitudinal direction of each of the anodes faces the electric contact of the substrate holder.
According to a configuration 2, in the plating apparatus according to the configuration 1, each of the plurality of anodes has an end in the longitudinal direction, and the anode is formed thinner near the end compared with another part of the anode.
According to a configuration 3, in the plating apparatus according to the configuration 2, each of the plurality of anodes includes a tapered portion whose width decreases toward the end and a constant-width portion having a constant width, and the tapered portion is configured attachable to and removable from the constant-width portion.
According to a configuration 4, in the plating apparatus according to any one configuration of the configuration 1 to the configuration 3, each of the plurality of anodes has an approximately rectangular cross-section when each of the plurality of anodes is cut out in a planar surface perpendicular to the longitudinal direction.
According to a configuration 5, in the plating apparatus according to any one configuration of the configuration 1 to the configuration 4, the substrate holder is configured to hold a quadrangular substrate, and the electric contact is configured to contact opposed two sides of a quadrangular substrate. The plurality of anodes are arranged such that the longitudinal direction of the anode is perpendicular to the two sides that contact the electric contact, when a substrate is viewed from a side of the anode.
According to a configuration 6, in the plating apparatus according to any one configuration of the configuration 1 to the configuration 4, the substrate holder is configured to hold a circular substrate, and the electric contact is configured to contact an outer peripheral portion of a circular substrate. The plurality of anodes are arranged such that the end in the longitudinal direction of the anode faces the outer peripheral portion that contacts the electric contact, when a substrate is viewed from a side of the anode.
According to a configuration 7, in the plating apparatus according to any one configuration of the configuration 1 to the configuration 6, in each of the plurality of anodes, when a dimension parallel to a direction perpendicular to a surface of a substrate is defined as a height H and a dimension in a direction perpendicular to the longitudinal direction and a height direction is defined as a width W, the anode includes a tapered portion where the width W decreases toward the end and a constant-width portion having a constant width W2, the tapered portion and the constant-width portion have an identical height H, and when a width of the end of the tapered portion is defined as W1, a condition of W1<W2<H is satisfied.
According to a configuration 8, in the plating apparatus according to any one configuration of the configuration 1 to the configuration 6, in each of the plurality of anodes, when a dimension parallel to a direction perpendicular to a surface of a substrate is defined as a height H and a dimension in a direction perpendicular to the longitudinal direction and a height direction is defined as a width W, the anode includes a tapered portion where the width W decreases toward the end and a constant-width portion having a constant width W2, the tapered portion and the constant-width portion have an identical height H, and when a width of the end of the tapered portion is defined as W1, a condition of 2×W1<W2≤10×W1 and 10×W1<H≤30×W1 is satisfied.
According to a configuration 9, in the plating apparatus according to any one configuration of the configuration 1 to the configuration 8, each of the plurality of anodes is an insoluble anode and contains an alloy containing titanium and platinum or an alloy containing titanium and iridium oxide.
According to a configuration 10, in the plating apparatus according to any one configuration of the configuration 1 to the configuration 9, the plating apparatus includes an anode holder configured to hold the plurality of anodes. The anode holder includes a nozzle for spouting a plating solution.
11 . . . substrate holder
13 . . . arm portion
14 . . . pedestal
15 . . . connector portion
17 . . . electric contact
60 . . . anode holder
61 . . . anode holder main body
62 . . . anode
62
a . . . constant-width portion
62
b . . . tapered portion
63 . . . arm portion
64 . . . regulation plate
65 . . . connector portion
66 . . . pedestal
69 . . . nozzle
100 . . . plating apparatus
138 . . . overflow tank
139 . . . plating tank
144 . . . power supply
145 . . . paddle
S1 . . . substrate
Q . . . plating solution
Number | Date | Country | Kind |
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JP2018-089347 | May 2018 | JP | national |
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Number | Date | Country |
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2017-115171 | Jun 2017 | JP |
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Number | Date | Country | |
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20190338438 A1 | Nov 2019 | US |