Polishing head for pressurized delivery of slurry

Information

  • Patent Grant
  • 6648734
  • Patent Number
    6,648,734
  • Date Filed
    Thursday, August 30, 2001
    23 years ago
  • Date Issued
    Tuesday, November 18, 2003
    20 years ago
Abstract
The present invention provides a polishing head, for use with a polishing apparatus. In one embodiment, the polishing head includes a carrier head assembly, and a retaining ring having a surface positionable adjacent a polishing pad and couplable to the carrier head assembly and configured to retain a semiconductor wafer therein, the retaining ring having a slurry conduit located therethrough to provide a flow of slurry to the polishing pad.
Description




TECHNICAL FIELD OF THE INVENTION




The present invention is directed, in general, to the polishing of semiconductor wafers and, more specifically, to a polishing head for delivering slurry, a polishing system employing the polishing head and a method manufacturing an integrated circuit incorporating the polishing head or the polishing system.




BACKGROUND OF THE INVENTION




In the fabrication of semiconductor components, the various devices are formed in layers upon an underlying substrate, such as silicon. In such semiconductor components, it is desirable that all layers, including insulating layers, have a smooth surface topography, since it is difficult to lithographically image and pattern layers applied to rough surfaces. Conventional chemical/mechanical polishing (CMP) has been developed for providing smooth semiconductor topographies. Typically, a given semiconductor wafer may be polished several times, such as upon completion of each metal layer.




The CMP process involves holding, and optionally rotating, a thin, reasonably flat, semiconductor wafer, held in a carrier head having a retainer ring, against a rotating polishing pad. The wafer may be repositioned radially within a set range as the polishing pad is rotated across the surface of the wafer. The polishing surface, which conventionally includes a polyurethane material affixed to a platen, is wetted by a chemical slurry, under controlled chemical, solid contents, pressure, and temperature conditions. The chemical slurry contains selected chemicals that etch or oxidize selected surfaces of the wafer during the CMP process in preparation for their removal.




Additionally, the slurry contains a polishing agent, such as alumina or silica, that is used as the abrasive material for the mechanical removal of the semiconductor material. The combination of chemical and mechanical removal of material during the polishing process results in superior planarization of the polished surface of the semiconductor wafer. In this process it is important to remove a sufficient amount of material to provide a smooth surface, without removing an excessive amount of underlying materials. To this end, proper slurry distribution during the polishing process is imperative. Accurate material removal is particularly important in today's submicron technologies where the layers between device and metal levels are constantly getting thinner.




In addition to proper slurry distribution during planarizing, some CMP systems are also directed to controlling the profile of polishing pads so as to control the “edge effect” of wafers being polished. Edge effect includes the non-uniform material removal from the edge, versus the center, of semiconductor wafers caused by a flexing in the CMP polishing pad near the wafer edge. As edge effect becomes more predominant, edge exclusion, which is the inability to print and fabricate dies along the edge of the wafer, typically increases. To combat this edge effect, conventional CMP systems attempt to press the retainer ring surrounding the wafer down into the polishing pad. By pressing the retainer ring into the polishing pad, pad deformation occurs under the retainer ring rather than under the edge of the wafer. As a result, edge effect of a semiconductor wafer may be significantly reduced or even eliminated.




Unfortunately, although substantially addressing the problem of edge effect, the prior art techniques introduce other problems. Specifically, to press the retainer ring down into the polishing pad, complex and costly pneumatic or hydraulic systems must be constructed to properly maneuver the retainer ring without damaging the wafer or the polishing pad. In addition, pressing the retainer ring against an abrasive polishing pad eventually wears the ring to the point of needing replacement. Moreover, since the retainer ring surrounds the outer edge of the wafer, pressing the ring into the polishing pad may significantly prevent the distribution of slurry to the wafer surface.




Accordingly, what is needed in the art is a apparatus and method for delivering slurry during a polishing operation that does not suffer from the deficiencies found in the prior art.




SUMMARY OF THE INVENTION




To address the above-discussed deficiencies of the prior art, the present invention provides a polishing head, for use with a polishing apparatus. In one embodiment, the polishing head includes a carrier head assembly, and a retaining ring having a surface positionable adjacent a polishing pad and couplable to the carrier head assembly and configured to retain a semiconductor wafer therein, the retaining ring having a slurry conduit located therethrough to provide a flow of slurry to the polishing pad.




In another aspect, the present invention provides a polishing system. In one embodiment, the polishing system includes a retaining ring having a surface positionable adjacent a polishing pad and couplable to a carrier head assembly and configured to retain a semiconductor wafer therein, the retaining ring having a slurry conduit formed therein to provide a flow of slurry to the polishing pad. In addition, the polishing system includes a pump configured to deliver the flow of slurry under pressure through the slurry conduit to a surface of the polishing pad.




In yet another aspect, the present invention provides a method of manufacturing an integrated circuit. In an exemplary embodiment, the method includes forming an integrated circuit layer over a semiconductor wafer, and polishing the integrated circuit layer. During the polishing, the method includes flowing a pressurized slurry through a slurry conduit located within a retaining ring of a carrier head assembly and against a surface of a polishing pad, the pressurized slurry causing a surface of the polishing pad located under the retaining ring to deform in a direction away from said retaining ring.




The foregoing has outlined preferred and alternative features of the present invention so that those skilled in the art may better understand the detailed description of the invention that follows. Additional features of the invention will be described hereinafter that form the subject of the claims of the invention. Those skilled in the art should appreciate that they can readily use the disclosed conception and specific embodiment as a basis for designing or modifying other structures for carrying out the same purposes of the present invention. Those skilled in the art should also realize that such equivalent constructions do not depart from the spirit and scope of the invention in its broadest form.











BRIEF DESCRIPTION OF THE DRAWINGS




For a more complete understanding of the present invention, reference is now made to the following detailed description taken in conjunction with the accompanying FIGUREs. It is emphasized that various features may not be drawn to scale. In fact, the dimensions of various features may be arbitrarily increased or reduced for clarity of discussion. Reference is now made to the following descriptions taken in conjunction with the accompanying drawings, in which:





FIG. 1

illustrates a sectional view of one embodiment of a polishing apparatus manufactured according to the principles of the present invention;





FIG. 2

illustrates a close-up, sectional view of the retaining ring shown in

FIG. 1

;





FIG. 3

illustrates a CMP system for planarizing a semiconductor wafer which may provide an environment for a polishing apparatus manufactured according to the principles of the present invention; and





FIG. 4

illustrates a sectional view of a conventional integrated circuit (IC), which may be formed using the polishing system of the present invention.











DETAILED DESCRIPTION




Referring initially to

FIG. 1

, illustrated is a sectional view of one embodiment of a polishing head


100


manufactured according to the principles of the present invention. As shown, the polishing head


100


includes a carrier head assembly


110


. A semiconductor wafer


120


is positioned against a face of the carrier head assembly


110


, and may be secured to the carrier head assembly


110


using negative pressure (vacuum), adhesive or other conventional technique.




Coupled to the carrier head assembly


110


is a retaining ring


130


manufactured according to the principles of the present invention. The retaining ring


130


may be formed integrally with the carrier head assembly


110


, and is in part used to retain the wafer


120


therein during a polishing operation. Alternatively, the retaining ring


130


may be removably couplable to the carrier head assembly


110


. Having an annular shape, the retaining ring


130


is configured to retain the semiconductor wafer


120


within an inside diameter of the retaining ring


130


. By retaining it therein, the retaining ring


130


prevents the wafer


120


from excessive movement during a polishing operation. Those skilled in the art understand the importance of securely holding the wafer


120


during polishing so as to prevent any damage thereto. Located within the retaining ring


130


are slurry conduits


170


, manufactured in accordance with the principles of the present invention.




During a polishing operation, such as a CMP process, the carrier head assembly


110


presses the wafer


120


against an abrasive surface of a polishing pad


140


, typically formed from polyurethane. The CMP process may be employed to polish, for instance, an integrated circuit layer of the wafer


120


. As used herein, the term “integrated circuit layer” includes any layer of a semiconductor wafer forming a part of an integrated circuit. Those skilled in the art will understand the principles of the present invention described herein may be used to polish any type of integrated circuit layer.




The polishing pad


140


is mounted on a polishing platen


150


, which is rotated during the polishing operation. In addition, the carrier head assembly


110


may also be rotated during the polishing operation if desired. As the carrier head assembly


110


presses the wafer


120


against the polishing pad


140


, a slurry delivery system (not illustrated) forces a flow of slurry through slurry conduits


170


formed in the retaining ring


130


. In an advantageous embodiment, the carrier head assembly


110


includes a carrier head slurry conduit (not illustrated) couplable to the slurry conduits


170


of the retaining ring


130


. In such an embodiment, the slurry flows through the carrier head slurry conduit to the slurry conduits


170


in the retaining ring


130


.




By pressurizing the slurry and forcing it through the slurry conduits


170


with a slurry pump, the polishing head of the present invention causes pad deformations


160


to occur directly beneath the retaining ring


130


. By deforming the polishing pad


140


under the retaining ring


130


rather than under the edge of the wafer


120


, the present invention substantially prevents the problem of edge effect on the wafer


120


. Moreover, by creating the pad deformations


160


with the pressurized flow of slurry, the surface of the retaining ring


130


positionable adjacent the polishing pad


140


is prevented from physically contacting the polishing pad


140


during the polishing operation. Those skilled in the art understand the benefits of preventing such contact, as discussed in greater detail below.




Turning now to

FIG. 2

, illustrated is a close-up, sectional view of the retaining ring


130


shown in FIG.


1


. Also illustrated are the semiconductor wafer


120


and the polishing pad


140


discussed above. Now shown in detail are the slurry conduits


170


for passing a flow of slurry (one flow is designated


210


) through. As the flow of slurry


210


is forced through the slurry conduits


170


, the pressure of the slurry


210


exiting the bottom face of the retaining ring


130


creates the pad deformation


160


described above.




In accordance with principles discussed herein, by creating the pad deformation


160


under the retaining ring


130


rather than under the wafer


120


, a polishing head of the present invention substantially prevents detrimental edge effect at an edge


220


of the wafer


120


. More specifically, when the flow of slurry


210


creates the pad deformation


160


, corners (one of which is designated


230


) of the polishing pad


140


are formed around the indention. Such a corner


230


would likely be the cause of edge effect on the wafer


120


if the pad deformation were formed under the wafer edge


220


rather than the retaining ring


130


. As such, in a preferred embodiment, the slurry conduits


170


are located within the retaining ring


130


a sufficient distance from the wafer


120


so as not to inadvertently cause an edge effect under the edge


220


of the wafer


120


.




In addition, a pressure of the flow of slurry


210


delivered by a slurry pump (not illustrated) may be selected such that although pad corners


230


are still formed, the polishing pad


140


is kept away a sufficient distance so as not to contact the retaining ring


130


. As mentioned above, by preventing the retaining ring


130


from contacting the polishing pad


140


, a less complex polishing head is provided and the life of the retaining ring


130


, as well as the polishing pad


140


, may be significantly extended. Moreover, by preventing contact between the retaining ring


130


and the polishing pad


140


, excess vibration in the carrier head assembly


110


may also be reduced. In an advantageous embodiment, the pressure provided by the slurry pump ranges from about 7 psi to about 30 psi. Of course, other pressures may be used, perhaps based on the desired distance the polishing pad


140


is to be kept away from the retaining ring


130


. For example, specific mechanical properties of the material comprising the polishing pad


140


may affect the slurry delivery pressure needed to achieve the desired pad deflection. In addition, characteristics of the slurry itself, such as viscosity and tendency to agglomerate, may also affect the delivery pressure to be applied.




In another embodiment, the flow rate at which the flow of slurry


210


is expelled through the slurry conduits


220


ranges from about 200 ml/minute to about 700 ml/minute. Those skilled in the art understand that other flow rates may be employed, perhaps depending on the amount of polishing desired, without departing from the broad scope of the present invention. In addition, the type of slurry used during the polishing operation may affect the flow rate of slurry


210


. Of course, a polishing head manufactured according to the principles discussed herein may accommodate any type of slurry, and may be employed in any type of polishing operation.




Another advantage provided by the present invention is a better flow of slurry to the wafer


120


. In typical prior art slurry delivery systems, when the retaining ring


130


is pressed against the polishing pad


140


during a polishing operation, the contact between the retaining ring


130


and the polishing pad


140


may significantly prevent the flow of slurry


210


to the wafer


120


. Those skilled in the art understand that an adequate amount of slurry


210


at the interface between the polishing pad


140


and the wafer


120


is essential for accurate planarization. The polishing head of the present invention recognizes and addresses this problem. For instance, by preventing the polishing pad


140


from contacting the retaining ring


130


, a space between the two remains that allows slurry


210


to pass from outside the retaining ring


130


to the wafer


120


held on the inside where the slurry


210


is needed the most.




Furthermore, prior art slurry delivery systems apply slurry to a polishing pad at the center of the pad, or at least typically at a point distal from a wafer being polished. In contrast, the polishing head of the present invention applies the slurry


210


to the polishing pad


140


through the retaining ring


130


, immediately adjacent the edge


220


of the wafer


120


. By delivering the slurry


210


so close to the wafer


120


, a polishing head constructed according to the present invention again assures the slurry


210


is delivered where it is needed the most. Moreover, with the slurry


210


now being delivered where it is more likely needed, the present invention allows for a more efficient amount of slurry


210


to be used during the polishing operation. Of course, the present invention may include embodiments where the delivery system described herein is combined with such prior art systems, to further ensure the proper delivery of slurry throughout a polishing operation. Yet another advantage provided by the present invention is an improved rate of moistening the polishing pad


140


prior to polishing the wafer


120


. It is common practice to thoroughly wet a polishing pad before polishing a wafer so as to insure a more uniform planarization of a wafer. With the pressurized slurry delivery of the polishing head discussed herein, wetting of the polishing pad


140


may occur in an shorter amount of time, rendering the polishing operation more efficient.




In one embodiment, the slurry conduits


170


may be formed in the retaining ring


130


so as to make an angle normal (perpendicular) with the surface of the retaining ring


130


positionable adjacent the polishing pad


140


. Such a configuration would provide a vertically downward pressure on the polishing pad


140


by the pressurized flow of slurry


210


exiting the slurry conduits


170


. In an alternative embodiment, where the retainer ring


130


includes multiple slurry conduits


170


at varying distances from the edge


220


of the wafer


120


, an outer conduit


240


(illustrated in broken line in

FIG. 2

) may make an abnormal angle θ with this surface of the retaining ring


130


. In such an embodiment, the outer conduit


240


may carry pressurized water or other cleaning solution, rather than slurry


210


. Having the abnormal angle θ, the cleaning solution in such an embodiment may be sprayed at the polishing surface of the polishing pad


140


so as to clear debris, polishing residue or other particles from in front of the retaining ring


130


as it moves across the polishing pad


140


during a polishing operation. As a result, more accurate planarization of the wafer


120


may be accomplished by removing harmful particles before they can detrimentally impact the polishing process.




Looking now at

FIG. 3

, illustrated is a polishing system


300


which may provide an environment for a slurry delivery system


301


incorporating a polishing head manufactured according to the principles of the present invention. The polishing system


300


includes a polishing pad


310


for polishing a semiconductor substrate


330


and a polishing platen


305


on which the polishing pad


310


is securely mounted. The polishing system


300


further includes a drive motor


315


coupled to a drive shaft


320


. The drive shaft


320


, in turn, is coupled to the polishing platen


305


. During a polishing operation, the drive motor


315


is used to turn the drive shaft


320


, thereby rotating the polishing platen


305


and polishing pad


310


about a first axis A


1


.




The polishing system


300


still further includes a carrier head assembly


325


. Mounted to the carrier head assembly


325


is the substrate


330


, which may be a semiconductor wafer, that has been selected for polishing. During the polishing process, a downward force


335


is applied to the carrier head assembly


325


, causing the carrier head assembly


325


to press the substrate


330


against the polishing pad


310


, as the polishing pad


310


is rotated. Typically, the carrier head assembly


325


may also be rotated using another motor during the polishing operation about a second axis A


2


.




In accordance with the principles described herein, a retaining ring


340


surrounding the substrate


330


and mounted to the carrier head assembly


325


is not pressed into the polishing pad


310


. Instead, the slurry delivery system


301


is used to cause deformations in the polishing pad


310


underneath the retaining ring


340


, rather than underneath the substrate


330


, in order to prevent edge effect. The slurry delivery system


301


includes a slurry pump


350


having a supply tank


355


. As illustrated, the slurry pump


350


may be located near the polishing pad


310


and used to pressurize slurry held in the supply tank


355


. In addition, the slurry delivery system


301


includes a slurry delivery conduit


360


, coupled to carrier head slurry conduits


345


formed within the carrier head assembly


325


. The carrier head slurry conduits


345


are coupled to slurry conduits (not separately designated) in the retaining ring


340


to provide a flow of slurry therethrough.




In accordance with the present invention, slurry is delivered from a slurry pump


350


to the carrier head slurry conduits


345


, passing through a mandrel


365


holding the carrier head assembly


325


. The slurry then passes from the carrier head slurry conduits


345


to the slurry conduits in the retaining ring


340


. The slurry pump


350


pressurizes the flow of slurry such that the slurry is expelled from a surface of the retaining ring


340


adjacent the polishing pad


310


with enough force to deform portions of the polishing pad


310


located under the retaining ring


340


away from the retaining ring


340


. In this manner, edge effect on the substrate


330


may be substantially prevented without contacting the retaining ring


340


against the abrasive polishing pad


310


. Of course, those skilled in the art understand a polishing system


300


constructed according to the principles of the present invention may include a greater or lesser number of components, or perhaps variations of the components illustrated in

FIG. 3

, while remaining within the scope of the present invention.




By providing a slurry delivery system, and a polishing apparatus incorporating such a system, that produces a pressurize flow of slurry from a retaining ring surrounding a wafer to substantially prevent edge effect of a wafer, the present invention provides several benefits over the prior art. For instance, as discussed above, the present invention may provide a better flow of slurry to the interface between a polishing pad and the wafer than previously found in the art. Those skilled in the art understand that slurry is needed most at the interface between the two. Moreover, since a system according to the present invention applies slurry immediately adjacent the edge of the wafer, less slurry may be used during a polishing operation. Also, the life of a retaining ring, as well as a polishing pad, may be significantly extended by preventing the retaining ring from contacting the polishing pad, since the flow slurry prevents direct frictional contact between the two. Moreover, a delivery system according to the present invention may be employed in almost any apparatus used to polish substrates, while retaining benefits such as those described above. As discussed above, those skilled in the art understand the risk of edge exclusion of dies, as well as other defects, that may occur if edge effect on a semiconductor wafer is not reduced or eliminated.




Turning finally to

FIG. 4

, illustrated is a sectional view of a conventional integrated circuit (IC)


400


, which may be formed using the polishing system of the present invention. The IC


400


may include active devices, such as transistors, used to form CMOS devices, BiCMOS devices, Bipolar devices, or other types of active devices. The IC


400


may further include passive devices such as inductors or resistors, or it may also include optical devices or optoelectronic devices. Those skilled in the art are familiar with these various types of device and their manufacture.




In the embodiment illustrated in

FIG. 4

, components of the conventional IC


400


include transistors


410


, having gate oxide layers


460


, formed on a semiconductor wafer. The transistors


410


may be metal-oxide semiconductor field effect transistors


410


(MOSFETs), however other types of transistors are within the scope of the present invention. Interlevel dielectric layers


420


are then shown deposited over the transistors


410


.




The polishing system of the present invention may be used to polish any or all of the layers of the IC


400


, including the interlevel dielectric layers


420


, in accordance with the principles described above. Interconnect structures


430


are formed in the interlevel dielectric layers


420


to form interconnections between the various components therein to form an operative integrated circuit. In addition, the interconnect structures


430


also connect the transistors


410


to other areas or components of the IC


400


. Those skilled in the art understand how to connect these various devices together to form an operative integrated circuit. Also illustrated are conventionally formed tubs


440


,


445


, source regions


450


, and drain regions


455


.




Of course, use of the polishing system of the present invention is not limited to the manufacture of the particular IC


400


illustrated in FIG.


4


. In fact, the present invention is broad enough to encompass the manufacture of any type of integrated circuit formed on a semiconductor wafer which would benefit from polishing performed in accordance with the present invention. In addition, the present invention is broad enough to encompass integrated circuits having greater or fewer components than illustrated in the IC


400


of FIG.


4


. Beneficially, each time the present invention is employed to form part or all of the IC


400


, manufacturing costs may be eliminated from the entire manufacturing process, as discussed in detail above.




Although the present invention has been described in detail, those skilled in the art should understand that they can make various changes, substitutions and alterations herein without departing from the spirit and scope of the invention in its broadest form.



Claims
  • 1. A method of manufacturing an integrated circuit, comprising:forming an integrated circuit layer over a semiconductor wafer; and polishing the integrated circuit layer, including: flowing a pressurized slurry through a slurry conduit located within a retaining ring of a carrier head assembly and against a surface of a polishing pad, wherein all portions of the slurry conduit located within the retaining ring make an angle normal with the surface of the retaining ring positionable adjacent the polishing pad, the pressurized slurry causing a surface of the polishing pad located under the retaining ring to deform in a direction away from the retaining ring.
  • 2. The method as recited in claim 1 wherein the flowing occurs at a flow rate ranging from about 200 ml/minute to about 700 ml/minute.
  • 3. The method as recited in claim 1 wherein the flowing includes flowing a pressurized slurry through a slurry conduit using a slurry pump.
  • 4. The method as recited in claim 3 wherein a pressure of the slurry pump ranges from about 7 psi to about 35 psi.
  • 5. The method as recited in claim 1 wherein the flowing includes flowing a pressurized slurry through a carrier head slurry conduit and through a plurality of slurry conduits located within the retaining ring.
  • 6. The method as recited in claim 5 wherein the flowing includes flowing a pressurized slurry to the carrier head slurry conduit from a slurry delivery system having a supply tank and a delivery conduit coupled to the supply tank.
  • 7. For use with a polishing apparatus, a polishing head, comprising:a carrier head assembly; and a retaining ring having a surface positionable adjacent a polishing pad and couplable to the carrier head assembly and configured to retain a semiconductor wafer therein, the retaining ring having a slurry conduit located therethrough to provide a flow of slurry to the polishing pad, wherein all portions of the slurry conduit located within the retaining ring make an angle normal with the surface of the retaining ring positionable adjacent the polishing pad.
  • 8. The polishing head as recited in claim 7 wherein the retaining ring is integrally formed with the carrier head assembly.
  • 9. The polishing head as recited in claim 7 wherein the retaining ring is removably couplable to the carrier head assembly.
  • 10. The polishing head as recited in claim 7 wherein the retainer ring includes a plurality of slurry conduits located within the retaining ring.
  • 11. The polishing head as recited in claim 10 wherein at least one of the slurry conduits is positioned at an angle abnormal with respect to the surface.
  • 12. The polishing head as recited in claim 10 wherein the carrier head assembly includes a carrier head slurry conduit that provides a flow of pressurized slurry through each of the plurality of slurry conduits in the retaining ring.
  • 13. The polishing head as recited in claim 7 wherein the carrier head assembly includes a carrier head slurry conduit that is fluidly couplable to the slurry conduit.
  • 14. A polishing system, comprising:a retaining ring having a surface positionable adjacent a polishing pad and couplable to a carrier head assembly and configured to retain a semiconductor wafer therein, the retaining ring having a slurry conduit formed therein to provide a flow of slurry to the polishing pad; wherein all portions of the slurry conduit located within the retaining ring make an angle normal with the surface of the retaining ring positionable adjacent the polishing pad; and a pump configured to deliver the flow of slurry under pressure through the slurry conduit to a surface of the polishing pad.
  • 15. The polishing system as recited in claim 14 wherein the polishing system includes a polishing head and the retaining ring forms a portion of the polishing head.
  • 16. The polishing system as recited in claim 14 wherein the polishing system further includes a polishing platen on which the polishing pad is mounted.
  • 17. The polishing system as recited in claim 16 wherein the polishing system further includes a motor, coupled to the polishing platen, configured to rotate the polishing platen during a polishing operation.
  • 18. The polishing system as recited in claim 14 wherein the polishing system further includes a motor, coupled to the carrier head assembly, configured to rotate the carrier head assembly during a polishing operation.
  • 19. The polishing head as recited in claim 14 wherein the carrier head assembly includes a carrier head slurry conduit that provides a flow of pressurized slurry to the slurry conduit in the retaining ring.
  • 20. The polishing system as recited in claim 19 further including a slurry delivery system having a supply tank and a delivery conduit, coupled to the supply tank, for delivering slurry to the carrier head slurry conduit.
US Referenced Citations (4)
Number Name Date Kind
5944593 Chiu et al. Aug 1999 A
6183350 Lin et al. Feb 2001 B1
6241582 Lin et al. Jun 2001 B1
6293850 Lin et al. Sep 2001 B1
Foreign Referenced Citations (1)
Number Date Country
1 038 636 Sep 2000 EP