This disclosure relates generally to cutting elements for earth-boring tools and related earth-boring tools and methods. More specifically, disclosed embodiments relate to techniques for producing a polished chamfer of a polycrystalline diamond cutting element exhibiting a low surface roughness and substantially free of surface defects and earth-boring tools incorporating such cutting elements.
Earth boring tools for forming wellbores in subterranean earth formations may include a plurality of cutting elements secured to a body. For example, fixed cutter earth boring rotary drill bits (also referred to as “drag bits”) include a plurality of cutting elements that are fixedly attached to a bit body of the drill bit. Similarly, roller cone earth boring rotary drill bits include cones that are mounted on bearing pins extending from legs of a bit body such that each cone is capable of rotating about the bearing pin on which the cone is mounted. A plurality of cutting elements may be mounted to each cone of the drill bit.
The cutting elements used in earth boring tools often include polycrystalline diamond compact (often referred to as “PDC”) cutters, which are cutting elements that include a polycrystalline diamond (PCD) material. Such polycrystalline diamond cutting elements are formed by sintering and bonding together relatively small diamond grains or crystals under conditions of high pressure and high temperature, typically in the presence of a catalyst (typically including a Group VIII element, such as cobalt, iron, or nickel, or an alloy or mixture having such elements), to form a layer of polycrystalline diamond material on a cutting element substrate. These processes are often referred to as high-pressure/high-temperature (or “HPHT”) processes. Catalyst material is mixed with the diamond grains to reduce the amount of oxidation of diamond by oxygen and carbon dioxide during an HPHT process and to promote diamond to diamond bonding.
The cutting element substrate may include a cermet material (i.e., a ceramic metal composite material) such as cobalt cemented tungsten carbide. In such instances, the cobalt (or other catalyst material) in the cutting element substrate may be drawn into the diamond grains or crystals during sintering and serve as a catalyst material for forming a diamond table from the diamond grains or crystals. In other methods, powdered catalyst material may be mixed with the diamond grains or crystals prior to sintering the grains or crystals together in an HPHT process.
Upon formation of a diamond table using an HPHT process, catalyst material may remain in interstitial spaces between the grains or crystals of diamond in the resulting polycrystalline diamond table. The presence of the catalyst material in the diamond table may contribute to thermal damage in the diamond table when the cutting element is heated during use, due to friction at the contact point between the cutting element and the formation.
Conventional PDC fabrication relies on the catalyst alloy that sweeps through the compacted diamond feed during HPHT synthesis. Traditional catalyst alloys are cobalt based with varying amounts of nickel, tungsten, and chromium to facilitate diamond intergrowth between the compacted diamond material. However, in addition to facilitating the formation of diamond to diamond bonds during HPHT sintering, these alloys also undesirably facilitate the formation of graphite from diamond during drilling. Formation of graphite in the PCD material can rupture diamond necking regions (i.e., grain boundaries) due to an approximate 57% volumetric expansion during the transformation. This phase transformation is known as “back conversion” or “reverse graphitization,” and typically occurs at temperatures exceeding 900° C., near cutting element cutting edge temperatures experienced during drilling applications. This mechanism, coupled with mismatch of the coefficients of thermal expansion of the metallic phase and diamond as temperatures exceed 600° C. is believed to account for a significant part of degradation of the general performance criteria known as “thermal stability.” From experimental wear conditions, “back conversion” appears to dominate impairment of the thermal stability of a PCD, promoting premature degradation of the cutting edge and performance.
To reduce problems associated with different rates of thermal expansion and with back conversion in polycrystalline diamond cutting elements, so called “thermally stable” polycrystalline diamond (TSD) cutting elements have been developed. A TSD cutting element may be formed by leaching the catalyst material (e.g., cobalt) out from interstitial spaces between the diamond grains in the diamond table using, for example, an acid. Substantially all of the catalyst material may be removed from the diamond table, or only a portion may be removed. TSD cutting elements in which substantially all catalyst material has been leached from the diamond table have been reported to be thermally stable up to temperatures of about 1,200° C. It has also been established, however, that fully leached diamond tables are relatively more brittle and vulnerable to shear, compressive, and tensile stresses than are non-leached diamond tables. In an effort to provide cutting elements having diamond tables that are more thermally stable relative to non-leached diamond tables, but that are also relatively less brittle and vulnerable to shear, compressive, and tensile stresses relative to fully leached diamond tables, cutting elements have been provided that include a diamond table in which only at least a portion of the catalyst material has been leached from the diamond table.
Some embodiments of the present disclosure include a method of forming a cutting element. The method may include leaching at least a portion of a diamond table of the cutting element and, subsequent to leaching the diamond table of the cutting element, forming a chamfer on a leached portion of the diamond table of the cutting element proximate an interface between a cutting surface of the diamond table and an outer side surface of the diamond table.
Additional embodiments include a method of forming a cutting element. The method may include leaching at least a portion of a diamond table and, subsequent to leaching the diamond table, polishing an interface between a cutting surface of the diamond table and an outer side surface of the diamond table to form a chamfer on the diamond table.
Some embodiments of the disclosure include a method of forming an earth-boring tool. The method may include forming a cutting element. Forming the cutting element may include leaching a diamond table of the cutting element and, subsequent to leaching the diamond table of the cutting element, forming a chamfer on the diamond table of the cutting element at an interface between a cutting surface of the diamond table and an outer side surface of the diamond table. The method may also include securing the cutting element to a body of the earth-boring tool.
For a detailed understanding of the present disclosure, reference should be made to the following detailed description, taken in conjunction with the accompanying drawings, in which like elements have generally been designated with like numerals, and wherein:
The illustrations presented herein are not actual views of any particular cutting elements or earth-boring tools, but are merely idealized representations that are employed to describe example embodiments of the present disclosure. Additionally, elements common between figures may retain the same numerical designation.
As used herein, the term “particle” means and includes any coherent volume of solid matter having an average dimension of about 500 μm or less. Grains (i.e., crystals) and coated grains are types of particles.
As used herein, the term “hard material” means and includes any material having a Knoop hardness value of about 3,000 Kgf/mm2 (29,420 MPa) or more. Hard materials include, for example, diamond and cubic boron nitride.
As used herein, the term “polycrystalline hard material” means and includes any material comprising a plurality of grains or crystals of the material that are bonded directly together by inter-granular bonds. The crystal structures of the individual grains of polycrystalline hard material may be randomly oriented in space within the polycrystalline hard material.
As used herein, the term “polycrystalline compact” means and includes any structure comprising a polycrystalline hard material comprising inter-granular bonds formed by a process that involves application of pressure (e.g., compaction) to the precursor material or materials used to form the polycrystalline hard material.
Thus, as used herein, the term “leached,” when used in relation to a volume of polycrystalline hard material (e.g., a polycrystalline diamond table), means that the volume or at least a region of the volume does not include catalyst material in interstitial spaces between inter-bonded diamond grains, regardless of whether or not catalyst material was removed from that region (by a leaching process or any other removal process). Similarly, as used herein the term “leaching” means and includes removal of a catalyst material from interstitial spaces between inter-bonded diamond grains of a polycrystalline diamond table by any technique, without limitation to acid leaching.
As used herein, the term “earth-boring tool” means and includes any type of bit or tool used for drilling during the formation or enlargement of a wellbore and includes, for example, rotary drill bits, percussion bits, core bits, eccentric bits, bi-center bits, reamers, mills, drag bits, roller-cone bits, hybrid bits, and other drilling bits and tools known in the art.
As used herein, any relational term, such as “first,” “second,” “front,” “back,” etc., is used for clarity and convenience in understanding the disclosure and accompanying drawings, and does not connote or depend on any specific preference or order, except where the context clearly indicates otherwise.
As used herein, the terms “comprising,” “including,” “containing,” “characterized by,” and grammatical equivalents thereof are inclusive or open-ended terms that do not exclude additional, un-recited elements or method steps, but also include the more restrictive terms “consisting of” “consisting essentially of” and grammatical equivalents thereof.
As used herein, the term “may” with respect to a material, structure, feature, or method act indicates that such is contemplated for use in implementation of an embodiment of the disclosure, and such term is used in preference to the more restrictive term “is” so as to avoid any implication that other compatible materials, structures, features, and methods usable in combination therewith should or must be excluded.
As used herein, the term “configured” refers to a size, shape, material composition, and arrangement of one or more of at least one structure and at least one apparatus facilitating operation of one or more of the structure and the apparatus in a predetermined way.
As used herein, the singular forms following “a,” “an,” and “the” are intended to include the plural forms as well, unless the context clearly indicates otherwise.
As used herein, the term “and/or” includes any and all combinations of one or more of the associated listed items.
As used herein, the term “substantially” in reference to a given parameter, property, or condition means and includes to a degree that one skilled in the art would understand that the given parameter, property, or condition is met with a small degree of variance, such as within acceptable manufacturing tolerances. For example, a parameter that is substantially met may be at least about 90% met, at least about 95% met, or even at least about 99% met.
As used herein, the term “about” used in reference to a given parameter is inclusive of the stated value and has the meaning dictated by the context (e.g., it includes the degree of error associated with measurement of the given parameter).
The polycrystalline hard material 105 may have exposed surfaces, such as a cutting face 121, a side surface 123, and a chamfer 109. The cutting face 121 may be substantially planar, or may have any other selected shape. The side surface 123 may be substantially cylindrical, or any other selected shape. For example, in some embodiments, the side surface 123 may include a plurality of planar surfaces circumscribing the cutting element 100. The shape and angle of the chamfer 109 may be selected to improve performance of the cutting element 100.
Furthermore, as is described in greater detail below, the polycrystalline hard material 105 may include a leached material. For example, at least a portion of the polycrystalline hard material 105 may be substantially free of a catalyst material. Moreover, as is discussed in greater detail below, the chamfer 109 may be formed post any leaching processes.
For example, leaching the polycrystalline hard material 105 may include leaching the catalyst material out from interstitial spaces between inter bonded diamond crystals in the polycrystalline hard material 105 using leaching agent such as, for example, an acid or combination of acids (e.g., aqua regia). A substantial amount of the catalyst material may be removed from the polycrystalline hard material 105, or catalyst material may be removed from only a portion thereof. Thermally stable polycrystalline hard materials in which substantially all catalyst materials have been leached out from the polycrystalline hard materials may be thermally stable up to temperatures of about twelve hundred degrees Celsius (1,200° C.). In view of the foregoing, the polycrystalline hard material 105 may be leached via any conventional process.
The method 200 may further include forming a chamfer 109 on the volume of polycrystalline hard material 105 subsequent to leaching the volume of polycrystalline hard material 105, as shown in act 204 of
In some embodiments, the air nozzle 304 may be spaced apart from the polishing element 302 and may be offset from the polishing element 302. For example, the air nozzle 304 may be offset from a center plane 306 centered between lateral sides of the polishing element 302 (e.g., lateral side surfaces of the polishing wheel). As a result, when a part being polished is removed from contact with the polishing element 302, a polished portion of the part may be exposed to airflow from the air nozzle 304. In additional embodiments, the air nozzle 304 may be aligned with the polishing element 302. For example, the air nozzle 304 may be centered on the center plane 306 centered between the lateral sides of the polishing element 302. As a result, the polishing element 302 may be at least partially cooled during polishing processes.
In some embodiments, the polishing element 302 may include a polishing and/or grinding wheel. For example, the polishing element 302 may include a resin bonded, diamond wheel having a grit size of D220 per 3M specification. The air nozzle 304 may include a tube coupled to an air source (e.g., a compressor) and having an opening for directing airflow. The air nozzle 304 may be configured to provide airflow resulting from air pressure within a range of between about 2.0 psi and about 8.0 psi. For example, the air nozzle 304 may be configured to provide airflow resulting from air pressure of about 5.0 psi.
Referring still to
In some embodiments, the polishing element 302 may be rotated at a rotations-per-minute (RPM) within a range of between about 2200 RPM and about 3200 RPM. For example, in some embodiments, the polishing element 302 may be rotated at about 2800 RPM. In other embodiments, the polishing element 302 may be rotated at about 2400 RPM. In some embodiments, the collet and the polycrystalline hard material 105 may also be rotated during polishing/grinding processes. For example, the collet and the polycrystalline hard material 105 may be rotated within a range of about 300 RPM and 700 RPM. For instance, the collet and the polycrystalline hard material 105 may be rotated at about 575 RPM.
In some embodiments, while forming the chamfer 109, the polycrystalline hard material 105 may be polished/ground until at least a portion of the diamond particles within the polycrystalline hard material 105 are overheated and graphitized. Subsequently, at least the polished/grinded portion the polycrystalline hard material 105 may be subjected to airflow from the air nozzle 304 to at least substantially remove the graphitized diamond particles. In some embodiments, the polycrystalline hard material 105 may be subjected to airflow from the air nozzle 304 for a time period within a range of between about 0.1 seconds and about 2.0 second. For example, the polycrystalline hard material 105 may be subjected to airflow from the air nozzle 304 for about 0.5 seconds prior to being returned to the polishing element 302. Furthermore, the acts of polishing/grinding the polycrystalline hard material 105 and removing graphitized diamond particles (i.e., graphite) via airflow may be repeated until the chamfer 109 is formed.
In some embodiments, forming the chamfer 109 on the polycrystalline hard material 105 may include a dry polishing process. In other words, forming the chamfer 109 on the polycrystalline hard material 105 may not include using a liquid coolant.
Referring still to
In experiments performed by the inventors, it was determined that providing airflow directly onto the part being polished yielded smoother surfaces (e.g., lower roughness averages) in comparison to providing airflow directly onto the polishing element 302.
Referring to
Referring still to
Embodiments of the present disclosure further include:
Embodiment 1. A method of forming a cutting element, the method comprising: leaching at least a portion of a diamond table of the cutting element; and subsequent to leaching the diamond table of the cutting element, forming a chamfer on a leached portion of the diamond table of the cutting element proximate an interface between a cutting surface of the diamond table and an outer side surface of the diamond table.
Embodiment 2. The method of embodiment 1, wherein forming the chamfer on the diamond table comprises polishing the diamond table of the cutting element without a liquid coolant.
Embodiment 3. The method of any one of embodiments 1 or 2, wherein forming the chamfer on the diamond table comprises polishing the diamond table of the cutting element with a polishing wheel rotating at least 2440 RPM.
Embodiment 4. The method of any one of embodiments 1 through 3, wherein forming the chamfer on the diamond table comprises polishing the diamond table of the cutting element with a polishing wheel rotating at least 2800 RPM.
Embodiment 5. The method of any one of embodiments 1 through 4, wherein forming the chamfer on the diamond table comprises: polishing the diamond table of the cutting element until at least a portion of the diamond table graphitizes; and removing graphite from the diamond table by subjecting at least a portion of the diamond table to airflow.
Embodiment 6. The method of embodiment 6, wherein the airflow results from a pressure of at least 5.0 psi.
Embodiment 7. The method of any one of embodiments 6 or 7, wherein the graphite is removed from the diamond table while the diamond table disengaged from a polishing wheel.
Embodiment 8. The method of any one of embodiments 1 through 7, further comprising rotating the diamond table of the cutting element within a collet while forming the chamfer on the diamond table.
Embodiment 9. The method of embodiment 8, wherein the collet is rotated at at least 575 RPM while polishing the diamond table.
Embodiment 10. A method of forming a cutting element, the method comprising: leaching at least a portion of a diamond table; and subsequent to leaching the diamond table, polishing an interface between a cutting surface of the diamond table and an outer side surface of the diamond table to form a chamfer on the diamond table.
Embodiment 11. The method of embodiment 10, further comprising attaching the diamond table to a substrate.
Embodiment 12. The method of any one of embodiments 10 or 11, wherein leaching at least a portion of the diamond table comprised leaching the at least a portion via or more of hot acid leaching or vacuum leaching.
Embodiment 13. The method of any one of embodiments 10 through 12, wherein polishing the interface between the cutting surface of the diamond table and the outer side surface of the diamond table comprises polishing the diamond table of the cutting element without a liquid coolant.
Embodiment 14. The method of any one of embodiments 10 through 13, wherein polishing the interface between the cutting surface of the diamond table and the outer side surface of the diamond table comprises polishing the diamond table with a polishing wheel rotating at least 2440 RPM.
Embodiment 15. The method of any one of embodiments 10 through 14, wherein polishing the interface between the cutting surface of the diamond table and the outer side surface of the diamond table comprises polishing the diamond table with a polishing wheel rotating at least 2800 RPM.
Embodiment 16. The method of any one of embodiments 10 through 15, wherein polishing the interface between the cutting surface of the diamond table and the outer side surface of the diamond table: polishing the diamond table via a polishing wheel until at least a portion of the diamond table graphitizes; disengaging the diamond table from the polishing wheel; and while the diamond table is disengaged from the polishing wheel; subjecting the diamond table to airflow to remove graphitized portions of the diamond table.
Embodiment 17. The method of embodiment 16, further comprising: subsequent to removing the graphitized portions of the diamond table, reengaging the diamond table with the polishing wheel; polishing the diamond table via a polishing wheel until at least an additional portion of the diamond table graphitizes; disengaging the diamond table from the polishing wheel an additional time; and while the diamond table is disengaged from the polishing wheel; subjecting the diamond table to airflow to remove additional graphitized portions of the diamond table.
Embodiment 18. A method of forming an earth-boring tool, the method comprising: forming a cutting element comprising: leaching a diamond table of the cutting element; and subsequent to leaching the diamond table of the cutting element, forming a chamfer on the diamond table of the cutting element at an interface between a cutting surface of the diamond table and an outer side surface of the diamond table; and securing the cutting element to a body of the earth-boring tool.
Embodiment 19. The method of embodiment 18, wherein forming the chamfer on the diamond table comprises polishing the diamond table of the cutting element without a liquid coolant.
Embodiment 20. The method of any one of embodiments 18 or 19, wherein forming the chamfer on the diamond table comprises polishing the diamond table of the cutting element with a polishing wheel rotating within a range between about 2440 RPM and about 2800 RPM.
The embodiments of the disclosure described above and illustrated in the accompanying drawings do not limit the scope of the disclosure, which is encompassed by the scope of the appended claims and their legal equivalents. Any equivalent embodiments are within the scope of this disclosure. Indeed, various modifications of the disclosure, in addition to those shown and described herein, such as alternative useful combinations of the elements described, will become apparent to those skilled in the art from the description. Such modifications and embodiments also fall within the scope of the appended claims and equivalents.