Claims
- 1. A method for improving the dart impact strength, ductility, or dart impact strength and ductility when measured at -30.degree. C. of a composition comprising a polyetherimide resin, a siloxane-polyetherimide copolymer, and a polycarbonate resin wherein said polycarbonate resin is a branched polycarbonate resin.
- 2. The method of claim 1, wherein the composition comprises from 50 to 95 parts by weight of the polyetherimide resin, from 0.5 to 12 parts by weight of the siloxane-polyetherimide copolymer; and from 5 to 45 parts by weight of the branched polycarbonate resin.
- 3. The method of claim 1, wherein the polyetherimide resin comprises structural units of the formula: ##STR19## wherein the divalent T moiety bridges the 3,3', 3,4', 4,3', or 4,4' positions of the aryl rings of the respective aryl imide moieties of formula (I); T is --O-- or a group of the formula --O--Z--O--; Z is a divalent radical selected from the group consisting of formulae: ##STR20## wherein X is a member selected from the group consisting of divalent radicals of the formulae: ##STR21## wherein y is an integer from 1 to about 5, and q is 0 or 1; R is a divalent organic radical selected from the group consisting of: (a) aromatic hydrocarbon radicals having from 6 to about 20 carbon atoms and halogenated derivatives thereof, (b) alkylene radicals having from 2 to about 20 carbon atoms, (c) cycloalkylene radicals having from 3 to about 20 carbon atoms, and (d) divalent radicals of the general formula: ##STR22## where Q is a member selected from the group consisting of formulae: ##STR23## where y' is an integer from about 1 to about 5.
- 4. The method of claim 1, wherein the polyetherimide resin is the reaction product formed by melt polymerization of 2,2-bis[4-(3,4-dicarboxyphenoxy)phenyl]propane dianhydride with metaphenylene diamine.
- 5. The method of claim 1, wherein the branched aromatic polycarbonate resin is made by reacting a polyfunctional aromatic compound with a dihydric phenol and a carbonate precursor to form a branched polymer.
- 6. The method of claim 5, wherein the polyfunctional compound is one or more compounds selected from the group consisting of 1,1,1-tri(4-hydroxyphenyl)ethane, 1,3,5,-trihydroxy-benzene, trimellitic anhydride, trimellitic acid, trimellityl trichloride, 4-chloroformyl phthalic anhydride, pyromellitic acid, pyromellitic dianhydride, mellitic acid, mellitic anhydride, trimesic acid, benzophenonetetracarboxylic acid and benzophenonetetracarboxylic dianhydride.
- 7. The method of claim 5, wherein the dihydric phenol is one or more compounds selected from the group consisting of 2-bis-(4-hydroxyphenyl)propane, 2,2-bis(3,5-dimethyl-4-hydroxyphenyl)propane, bis(4-hydroxyphenyl) methane, 4,4-bis(4-hydroxyphenyl)heptane, 35,3',5'-tetrachloro-4,4'-dihydroxyphenyl)propane, 2,6-dihydroxy naphthalene, hydroquinone and 2,4'-dihydroxyphenyl sulfone.
- 8. The method of claim 5, wherein the carbonate precursor is one or more compounds selected from the group consisting of carbonyl halides, carbonate esters, and haloformates.
- 9. The method of claim 1, wherein the method comprises blending the polyetherimide resin, the siloxane-polyetherimide copolymer, and the branched polycarbonate resin.
- 10. The method of claim 1, wherein the siloxane-polyetherimide copolymer is the reaction product of an aromatic bis(ether anhydride) with a diamine and an aminoalkyl-terminated organosiloxane compound of the structural formula: ##STR24## wherein: R.sub.1, R.sub.2, R.sub.3 and R.sub.4 are each independently (C.sub.1 -C.sub.6)alkyl,
- a and c are each independently integers from 1 to 10, and
- b is an integer from 1 to about 40, preferably from 5 to 25.
- 11. The method of claim 10, wherein R.sub.1, R.sub.2, R.sub.3, R.sub.4 are each methyl, a and c are each 3 and b has an average value of from 9 to 20.
- 12. A method for improving the dart impact strength, ductility, or dart impact strength and ductility when measured at -30.degree. C. of a composition consisting essentially of a polyetherimide resin, a siloxane-polyetherimide copolymer, and a polycarbonate resin wherein said polycarbonate resin is a branched polycarbonate resin.
- 13. A shaped article made by molding the composition of claim 1.
Parent Case Info
This is a divisional of co-pending application Ser. No. 08/996,610 filed on Dec. 23, 1997.
US Referenced Citations (14)
Divisions (1)
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Number |
Date |
Country |
Parent |
996610 |
Dec 1997 |
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