The present invention generally relates to ammunition casings. More particularly, the present invention relates to an ammunition casing that is made with a polymer instead of a metal.
Review of existing patent literature reveals over 200 patents issued for various aspects of producing polymer casings. Investigation of the details of some of these patents indicates that most or all of them relay on conventional injection molding as means of manufacture but require multipiece construction with multiple components because regions of the typical munitions cross section consists of necked down and tapered regions that will be impossible to injection mold due to the severe undercuts.
Review of these patents and associated claims leads to some common limitations. All are multi-piece casing designs due to the inherent difficulties in traditional injection molding. This requires some non-trivial means of attachment between the various pieces. Metal injection molding is claimed (MIM) with the same considerations and limitations as above. Many polymer base resins are claimed but no reference to carbon nanotube additives or graphene platelet additives was found. Alternative projectile retention mechanisms are claimed, typically using molded in surface textures to increase surface friction. No mention can be found accommodating the inherent visco-elastic behavior of polymers under long term tension load, such as stress relaxation or creep. These phenomena conspire to the effect of loosening the projectile fit to the polymer casing over time.
Accordingly, there is a need for an improved casing utilizing polymers and not metals. The present invention fulfills these needs and provides other related advantages.
In an exemplary embodiment of the present invention, a method of manufacturing a casing (11) for an ammunition cartridge (10) is disclosed. The method comprises the steps of: providing an injection mold (22); using the injection mold, injection molding a polymer forming the casing into a first state (11a); wherein the casing in the first state is generally cylindrically shaped (35) along a longitudinal axis (36), the casing extending from a base (37) to a distal end (33) with a blind hole (38) formed therein, the blind hole comprising a primer retention feature (20) disposed at the base and leading into a flash hole (15), wherein the flash hole extends along a neck (38) of the casing to the distal end; placing an insulator (23) and/or reflector (24) around at least a portion of the casing separating the base from the neck; using a heater (25), directly heating the neck of the casing while not directly heating the base of the casing, the casing now in a second state (11b); inserting a stretch rod (27) into the blind hole and stretching the neck from a first length (41) to a second length (42), the casing now in a third state (11c); providing a blow mold cavity (28, 29, 30); inserting the casing in the third state into the blow mold cavity; pressurizing the blind hole with an air pressure causing the neck of the casing to be blow molded into a fourth state (11d), wherein the neck of the casing now comprises at least one undercut (18) circumferentially disposed about the longitudinal axis of the casing; and removing at least a portion (45) of the distal end of the casing, the casing now being in a fifth state (11e).
In other embodiments, the entirety of the casing in the fifth state may be made from the polymer, wherein the polymer is a single material.
The flash hole may be a smaller diameter in comparison to the primer retention feature when the casing is in the first state.
The injection mold (22) may comprise a first mold (22a), a second mold (22b) and a pull mold (22c), where the first mold and the second mold are configured to cooperatively form an outside surface (39) of the casing in the first state, wherein the first and second molds are configured to be separated moving apart from one another, and including a pull mold (22c) that is configured to form an inside surface (40) of the primer retention feature and flash hole, wherein the pull mold separates in a direction perpendicular to the first and second molds.
The blow mold cavity may comprise a first blow mold (28) and a second blow mold (29), wherein the first and second blow molds are configured to cooperatively form an inside surface (43) that matches an outside surface (44) of the casing in the fourth state.
The heater may be an infrared heater or hot air heater.
The polymer may comprise a base resin of polypropylene, polyethylene, high density polyethylene or acetal.
The polymer may comprise an additive of carbon nanotubes and graphene platelets in a percentage by weight of 0.01 to 30 percent.
The polymer may comprise a base resin of nylon, ABS, PET, polyamides, PEEK, general co-polymers, general homo-polymers.
The polymer may comprise an additive of fiberglass filled materials and/or Talc filled materials.
The polymer may not comprise PEEK.
The blow mold cavity may include at least one annular rib (34) configured to form a cannelure (19) into the fourth state of the casing.
In another exemplary embodiment of the present invention, a method of manufacturing a casing (11) for an ammunition cartridge (10) is disclosed. The method comprises the steps of: providing an injection mold (22); using the injection mold, injection molding a polymer forming the casing into a first state (11a); wherein the casing in the first state is generally cylindrically shaped (35) along a longitudinal axis (36), the casing extending from a base (37) to a distal end (33) with a blind hole (38) formed therein; either: a) during the injection molding of the polymer, forming the blind hole comprising a primer retention feature (20) disposed at the base and leading into a flash hole (15), wherein the flash hole extends along a neck (38) of the casing to the distal end; or b) machining the primer retention feature and/or the flash hole; inserting a stretch rod (27) into the blind hole and stretching the neck from a first length (41) to a second length (42), the casing now in a third state (11c); providing a blow mold cavity (28, 29, 30); inserting the casing in the third state into the blow mold cavity; pressurizing the blind hole with an air pressure causing the neck of the casing to be blow molded into a fourth state (11d), wherein the neck of the casing now comprises at least one undercut (18) circumferentially disposed about the longitudinal axis of the casing; and removing at least a portion (45) of the distal end of the casing, the casing now being in a fifth state (11e).
While the casing is in the first state, the method may include the step of placing an insulator (23) and/or reflector (24) around at least a portion of the casing separating the base from the neck, and while using a heater (25), directly heating the neck of the casing while not directly heating the base of the casing, the casing now in a second state (11b).
The entirety of the casing in the fifth state may be made from the polymer, wherein the polymer is a single material.
The method of manufacturing the ammunition cartridge may utilizing the casing disclosed and may now include the step of disposing a primer (12) inside the primer retention feature, adding a propellant (14) inside the casing and disposing a projectile in the distal end of the casing.
Another exemplary embodiment of the present invention is a method of manufacturing a casing (11) for an ammunition cartridge (10). The method comprises the steps of: providing an injection mold (55, 56, 57, 58); using the injection mold, injection molding a first polymer forming a first part (52) of a casing, wherein the first part of the casing is generally cylindrically shaped (35) along a longitudinal axis (36) and includes a stepped end (54) forming a first part (53) of a mechanical connection; removing a portion (57, 58) of the injection mold exposing the stepped end of the first part of the casing; disposing an additional mold (59, 60, 61) about the stepped end of the casing; using the additional mold, injection molding a second polymer forming a second part (62) of the casing, wherein the second part includes a second stepped end (63) forming a second part (64) of the mechanical connection; wherein the first and second stepped ends are mechanically locked together; providing a thermal swagging tool (68, 69); and using the thermal swagging tool, forming a conical tapered region (70) along an end (71) of the first part of the casing opposite the mechanical connection.
The first polymer and second polymer may not be the same material type.
The second polymer may comprise ceramic or metal powder additives and the first polymer does not comprise ceramic or metal powder additives.
Other features and advantages of the present invention will become apparent from the following more detailed description, when taken in conjunction with the accompanying drawings, which illustrate, by way of example, the principles of the invention.
The accompanying drawings illustrate the invention. In such drawings:
Often, people mistakenly refer to an ammunition cartridge as a bullet, yet the bullet is typically just one of four parts that form the ammunition cartridge.
The Casing: A bullet's casing is the metal shell that encases the bullet's propellant. It is usually made of brass, although steel or aluminum casings are also used. The casing also holds the bullet's primer, which ignites the propellant and causes the bullet to be fired from the gun. When a bullet is fired, the casing is ejected from the gun along with the spent primer. The casing can then be reloaded with a new primer and propellant and reused. When the primer explodes after being struck by the firing pin, the small explosion travels through the flash hole to then ignite the propellent inside the casing.
The Primer: A primer in a bullet is a small explosive charge that serves to ignite the powder in the cartridge. It is located at the base of the cartridge and is usually made of a material that is readily ignitable by heat or friction. When the trigger of a firearm is pulled, the firing pin strikes the primer, causing it to detonate. The resulting explosion ignites the powder within the cartridge, propelling the bullet out of the barrel. In order for a primer to function properly, it must be of the correct size and type for the particular caliber of ammunition being used. Additionally, the primer must be seated correctly in order to ensure reliable ignition. Improperly seated primers can cause misfires, which can be dangerous.
The Projectile: The projectile is the part of the bullet that actually strikes the target. It is usually made of lead 16, although other materials such as steel or copper can also be used. The lead 16 may also have a metal jacket 17. The projectile is seated on top of the propellant within the cartridge. When the primer is detonated, the resulting explosion ignites the propellant and propels the projectile out of the barrel. The projectile continues to travel forward until it strikes the target or runs out of kinetic energy.
The Propellant: Gunpowder, also known as black powder, is a type of explosive that is used in bullets. It consists of a mixture of sulfur, charcoal and potassium nitrate. When gunpowder is ignited, it rapidly expands and produces a large volume of gas. This gas is what propels the bullet out of the barrel. Gunpowder is very sensitive to heat and friction, so it must be carefully handled in order to avoid accidental detonation.
As explained earlier, the casing is typically made of metal. However, the inventors of the present application have developed a casing that is manufactured from a polymer. The invention described herein utilizes an injection-stretch blow molding process to mold severely undercut 18 regions while maintaining thin wall sections with high dimensional consistency in a single piece casing, similar to the single piece casing 11 shown in
Review of the prior art for polymer casing design and production yields more than 200 existing patents. Most of these patents ignore the difficulties of injection molding polymer munition casings with necked or severely undercut regions. Several of the patents do attempt to accommodate the necked (i.e., undercut 18) region of the casing with a two-stage operation, where the first stage molds a straight wall axisymmetric cylinder and the second stage uses a thermoforming operation to produce the reduced diameter neck. Other approaches use a multi-piece casing design to eliminate the severe undercuts. Additionally, an insert molding operation is sometimes contemplated to overmold a metallic primer insert, but this is not really a single piece ammunition casing. Neither of the approaches is suitable for high volume production of a molded component with attendant precision thin walls. Also, various schemes have been proposed to help retain the projectile to the casing with sufficient retention force, where the typical annual retaining rib feature results in yet another undercut confounding molding. Alternatives such as molding high grip texture and other similar approaches show up in the patent literature. Additionally, the use of materials in the patent filings reviewed show no specific reference to high strength additives, such as graphene platelets or carbon nanotubes.
The present invention teaches that the optimal solution for low-cost production of consumer grade polymer munitions lies with a combination of advanced material additives in a commodity base resin, combined with a high-speed manufacturing process of molding severe undercuts with precision thin walls resulting in a single, one-piece casing with consistent wall thicknesses.
The mechanical requirements of the molded polymer casing are extremely challenging. High resistance to heat and pressure waves are needed at very high strain rates, and the ammunition casing must resist these forces and then successfully eject from the chamber without jamming. This is contrasted with the need for low cost which can rule out traditional polymer solutions, for example PEEK with 40% carbon fiber fill which ranges to $40/lbs for raw resin.
The use of high-tech additives with commodity resin is therefore an attractive alternative. Examples would be a base resin of polypropylene, high density polyethylene, or acetal with multiwalled carbon nanotubes or graphene platelets as an additive. The use of carbon nanotubes can increase tensile strength of the base polymer by roughly 150%.
A rough weight estimate of a 7.62 sized casing (no primer cap and no projectile) molded from neat PP would be on the order of 0.86 grams to 1.0 gram. Carbon nanotubes are approximately $2-$4/gram depending on the source, with a typical let down ratio of 1% over the base resin. At $1.10/lb for virgin PP, we have the following raw material estimates: $0.02 for the base resin and $0.04 for the nanotube additive=$0.06 total for raw materials.
If another base resin such as HDPE is substituted, we might expect the cost to go higher, perhaps by another $0.02 per unit. The base resin will be chosen on which has better dispersion properties for the carbon nanotubes.
Due to the severe undercuts preventing a simple open and shut injection molding cycle, some means must be considered which can accommodate the undercuts. For example, the dimensional undercut 18 on the 7.62 mm casing as shown in
Research on various manufacturing processes indicates that using injection stretch blow molding may be a breakthrough process for axisymmetric cylindrical shapes such as the 7.62 mm casing. Other than the ease of molding undercuts, an additional and significant benefit is the bi-axial orientation of the material during stretch forming. Research data shows tensile strength increasing more than 200% during the process of stretching the parison. (The term parison as used herein refers to an unshaped mass of molten material before it is molded into its final form.) Introducing the air blow additionally orients to the radial direction and increases hoop strength performance by as much as 500%.
This method has been used most typically by packaging manufacturers for plastic container production and is fairly common in the United States. The inventors can find no record of this method ever being used with carbon nanotube additives nor with regard to ammunition casings. Using this method, thin walls are also (relatively) easily maintained to nominal wall sections of 0.007″-0.010″ with good consistency and the annular projectile capture features are easily molded.
When using polymer molded casings, retention of the projectile (before firing) is an important consideration. The interface between the outer diameter (OD) of the projectile and the inner diameter (ID) of the casing constitutes a precision fit and tolerances must be held tightly. The interface between the two components provides an initial gas seal as well as a means of mechanical attachment. The fit must be tight enough to prevent any dislodging of the projectile during normal transit, handling and recoil, and not too tight as to adversely influence the firing event.
For conventional metallic (both ferrous and non-ferrous) casings, one of two retention methods are typically used: a) an interference fit; and b) a crimped interface. The interference fit relies on close tolerances between the two components, as well as a slight elastic deformation of the casing during insertion of the projectile, where the resulting hoop stress (neck tension) and frictional contact provide the necessary retention forces. The crimping process typically uses a cannelure 19 formed on the projectile and a roll crimp tool is used to plastically deform (swage) the casing into the cannelure, retaining the projectile with a positive mechanical connection. The cannelure is the groove around the cylinder of a bullet.
In a similar fashion to projectile retention, a smaller pocket (i.e., the primer cap pocket 20) is molded in the casing for an interference fit with an industry standard primer cap which will be pressed into place in a counterbored recess. In addition, a gas vent (i.e., flash hole) is allowed at the bottom of the primer counterbore through into the main chamber. This is formed by a core pin in the mold. Another version may require a non-standard primer cap OD to mate with the slightly larger ID of the molded casing necessitated by the stretch pin opening.
The invention can be described as consisting of several key attributes:
The '318 provisional application listed the caliber and munition types that are claimed under this concept for rifle cartridges and also listed the caliber and munition types for piston cartridges. Accordingly, the present invention can be applied to any casing.
The '318 provisional application showed and taught the basics of a generalized injection stretch blow molding process predominantly used to manufacture thin-walled containers. The process of the present invention differs in several ways as will now be explained in more detail.
Alternatively, the casing 11a could be molded without the primer retention feature and flash hole. The casing 11a would be very thick absent the blind hole disposed therein. Then, in a machining step, the primer retention feature and flash hole could be precision machined.
All of the steps described herein can be performed with robotic tooling such that the casing moves quickly from each stage without the need for human handling. This speeds production time while keeping the hot parts of the casing hot as needed during the stretching and blow molding stages.
The injection stretch blow molding process inherently supports many different kinds of projectile crimp configurations that can be difficult or impossible to achieve with conventional polymer injection molding, such as cannelure crimping, taper crimping and/or roll crimping.
Casing shapes and rim configurations supported by the invention include: necked down of “bottle shaped” designs; straight wall, cylindrical casings; tapered casing designs; belted rim designs; semi-rimmed designs; rim designs; rimless designs; and/or rebated designs.
Molding of an annular internal rib integral with the casing to mate with a typical projectile cannelure, providing positive mechanical retention between the two components, reducing the effects of visco-elastic behavior (creep).
One piece molding of a typical “bottle shaped” cartridge casing. One piece manufacturing as taught above results in a single piece polymer ammunition casing, meaning the material is the same material throughout and is free from fasteners, adhesives, bonds and the like. It means the material is continuous and uninterrupted with breaks, cuts or assembly joints.
The invention described herein now teaches a two-shot injection molding process to mold a single piece casing utilizing two entirely different materials. A low-cost commodity resin with high performance additives may be used for the shoulder walls of the casing. Then, a second material may be co-molded in a two-shot molding machine that contains a high-performance engineering resin with either ceramic or metal powder additives to increase localized thermal performance to result in a single piece casing.
A singular challenge for polymer-based munition casings is the requirement to use resins that can withstand the extremely high temperatures and pressure waves resulting from the firing event. The ceramic/metal matrix second shot provides this performance. Review of prior art for polymer casing design and production yields more than 200 existing patents. Most of these patents ignore the difficulties of injection molding polymer munition casings with necked, or severely undercut regions. Several of the patents do attempt to accommodate the necked (undercut) region of the 7.62 mm casing with a two-stage operation, the first stage molds. A straight wall axisymmetric cylinder, the second stage uses a thermoforming operation to produce the reduced diameter neck. Other approaches use a multi-piece casing design to eliminate the severe undercuts.
Also, various schemes have been proposed to help retain the projectile to the casing with sufficient retention force, the typical annual retaining rib feature results in yet another undercut confounding molding. Alternatives such as molding high grip texture and other similar approaches show up in the patent literature. Additionally, the use of materials in the patent filings reviewed show no specific reference to high strength additives, such as graphene platelets or carbon nanotubes. The optimal solution for low-cost production of consumer grade polymer munitions lies with a combination of advanced material additives in a commodity base resin, combined with a high-speed manufacturing process of molding severe undercuts with precision thin walls resulting in a single, one-piece casing with consistent wall thicknesses.
The mechanical requirements of the molded polymer casing are extremely challenging. High resistance to heat and pressure waves are needed at very high strain rates, and the ammunition casing must resist these forces and then successfully eject from the chamber without jamming. This is contrasted with the need for low cost which can rule out traditional polymer solutions, for example PEEK with 40% carbon fiber fill which ranges to $40/pound for raw resin.
In this embodiment this is solved using two separate materials, the low-cost commodity resin with carbon additives for the main casing and a high-performance ceramic metal/matrix material that molds the much smaller primer end of the casing, where most of the force and thermal effects are concentrated.
A rough weight estimate of a 7.62 mm sized casing (no primer cap and no projectile) molded from neat PP would be on the order of 0.86 gram to 1.0 gram. Carbon nanotubes are approximately $2-$4/gram depending on the source, with a typical let down ratio of 1% over the base resin. At $1.10/pound for virgin PP, we have the following raw material estimates: $0.02 for the base resin and $0.04 for the nanotube additive=$0.06 total for raw materials.
The cost for the ceramic/metal matrix polymer is much higher, however the amount of resin used is quite small as the total approximate volume is less than the main casing. The total approximate volume of the 7.62 mm cartridge casing is about 1049 mm3, while the primer region using the ceramic metal matrix is about ¼ the total volume, or about 237 mm3.
Accommodation of the high thermal conditions and high frequency shock loads are managed in a manufacturing process that combines the two discrete materials into a singular monolithic molding. There are at least two methods to accomplish two-shot molding; (a) using a two barrel/two screw molding press with each barrel dedicated to a specific material, the press machinery then rotates the mold 180 degrees to result in two entirely separate but simultaneous molding operations in the same machine; or (b) using two separate molds and two separate molding machines, and manually transferring the molded part from the first stage to the second.
When using polymer molded casings, retention of the projectile is an important consideration. The interface between the OD of the projectile and the ID of the casing constitutes a precision fit, and tolerances must be held tightly. The interface between the two components provides an initial gas seal as well as a means of mechanical attachment. The fit must be tight enough to prevent any dislodging of the projectile during normal transit, handling, and recoil, and not too tight as to adversely influence the firing event.
For conventional metallic (both ferrous and non-ferrous) casings, one of two retention methods are typically used: (a) interference fit; and (b) a crimped interface. The interference fit relies on close tolerances between the two components, as well as a slight elastic deformation of the casing during insertion of the projectile. The resulting hoop stress (neck tension) and frictional contact provide the necessary retention forces. The crimping process typically uses a cannelure formed on the projectile, and a roll crimp tool is used to plastically deform (swage) the casing into the cannelure, retaining the projectile with a positive mechanical connection.
In a similar fashion to the projectile retention, a smaller pocket is molded for an interference fit with an industry standard primer cap which will be pressed into place in a counterbored recess. In addition, a gas vent is allowed at the bottom of the primer counterbore through into the main chamber. This is formed by a core pin in the mold.
Review of these patents and associated claims leads to some common limitations. All are multi-piece casing designs due to the inherent difficulties in traditional injection molding. This requires some non-trivial means of attachment between the various pieces. Metal Injection Molding (MIM) is claimed with the same considerations and limitations as above. Many polymer base resins are claimed but no reference to carbon nanotube additives or graphene platelet additives was found. Alternative projectile retention mechanisms are claimed, typically using molded in surface textures to increase surface friction. No mention can be found accommodating the inherent visco-elastic behavior of polymers under long term tension load, such as stress relaxation or creep. These phenomena conspire to the effect of loosening the projectile fit to the polymer casing over time.
The invention can be described as consisting of several key attributes:
The present invention can be manufactured in a generalized two-shot injection molding process. The final casing merges two disparate polymers with different material properties into a single component in a simultaneous molding process. Every mold cycle may fill each of the cavities with the respective material where cavity one is always empty and a new part is molded of the commodity resin, and simultaneously, cavity 2 over-molds this substrate with the ceramic/metal matrix material. For example, The cavity 1 position may molded with material 1. This side of the molding press has a dedicated screw barrel for material 1, which is the substrate or main cavity casing. The cavity 2 position may rotate 180 degrees and places the now complete cavity 1 molded component under the screw barrel for cavity 2. This contains a dedicated screw barrel with the ceramic/metal matrix polymer. The shot then over-molds the substrate casing and produces a semi-finished part. The completed two-part molding then constitutes a single component which is ejected into a collection hopper for post processing.
The completed molding may then be loaded into a vibratory bowl feeder and fed into a projectile assembly station, which is designed to insert and swage the projectile into the co-molded casing. The rotary assembly station is organized into two main functions; first fixturing the model component in a rotating fixture nest, then using an induction heater to soften the plastic, swaging the neck down to the final tapered size while imparting the annual containment rib to capture the projectile, then pressing the projectile into the necked down diameter for permanent retention established when the casing cools down.
Design Variations Covered Under this Invention:
Some materials do not fuse together well, mainly due to large differences in the melt front temperatures, in these cases mechanical interlocks are added to insure a tight bond between the two shots.
Cartridge shapes and rim configurations supported by the invention include: necked down of “bottle shaped” designs; straight wall, cylindrical cartridges; tapered cartridge designs; belted rim designs; semi-rimmed designs; rim designs; rimless designs; and/or rebated designs.
Thermoforming of an annular internal rib integral with the casing to mate with a typical projectile cannelure, providing positive mechanical retention between the two components, reducing the effects of visco-elastic behavior (creep).
One piece molding of a typical “bottle shaped” cartridge casing, intermingling materials with high thermal performance with low cost commodity resins for the main casing.
Although several embodiments have been described in detail for purposes of illustration, various modifications may be made to each without departing from the scope and spirit of the invention. Accordingly, the invention is not to be limited, except as by the appended claims.
This non-provisional application claims priority to provisional application 63/364,318 filed on May 6, 2022, the entire contents of which are fully incorporated herein with this reference.
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244810 | Jan 1966 | AT |
364284 | Oct 1981 | AT |
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1092440 | Dec 1980 | CA |
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2749624 | Sep 2018 | CA |
199812 | Sep 1938 | CH |
238162 | Jun 1945 | CH |
458996 | Jun 1968 | CH |
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34858 | Feb 2021 | CZ |
1 016 162 | Sep 1957 | DE |
1 831 833 | May 1961 | DE |
1115158 | Oct 1961 | DE |
1 961 307 | Jun 1971 | DE |
2 131 339 | Jan 1973 | DE |
2 548 599 | May 1977 | DE |
2 705 235 | Aug 1978 | DE |
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4 229 559 | Dec 2000 | DE |
10 2018 218 423 | Apr 2020 | DE |
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826 622 | Apr 1938 | FR |
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17 442 | Dec 1916 | GB |
507 651 | Jun 1939 | GB |
560 315 | Mar 1944 | GB |
627 624 | Aug 1949 | GB |
672 706 | May 1952 | GB |
732 633 | Jun 1955 | GB |
754 650 | Aug 1956 | GB |
765502 | Jan 1957 | GB |
769 753 | Mar 1957 | GB |
858 560 | Jan 1961 | GB |
875 240 | Aug 1961 | GB |
875 241 | Aug 1961 | GB |
988 596 | Apr 1965 | GB |
1 015 516 | Jan 1966 | GB |
1 096 658 | Dec 1967 | GB |
1 142 467 | Feb 1969 | GB |
1 175 305 | Dec 1969 | GB |
1 203 216 | Aug 1970 | GB |
2 530 908 | Apr 2016 | GB |
2 571 951 | Sep 2019 | GB |
251399 | Apr 2018 | IL |
274334 | Jun 2020 | IL |
948467 | May 1973 | IT |
UB20154648 | Apr 2017 | IT |
201800000000 | Jun 2020 | IT |
6337176 | Jun 2018 | JP |
910005021 | Mar 1991 | KR |
0153289 | Dec 1998 | KR |
10-1295318 | Aug 2013 | KR |
10-2016-0127349 | Nov 2016 | KR |
2 734 603 | Oct 2020 | RU |
420 288 | Sep 1981 | SE |
950203 | Aug 1982 | SU |
9513516 | May 1995 | WO |
2007014024 | Jan 2007 | WO |
2008091245 | Jul 2008 | WO |
2012172406 | Dec 2012 | WO |
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2020244773 | Dec 2020 | WO |
WO-2023215622 | Nov 2023 | WO |
Entry |
---|
International Search Report in PCT/US2023/021267 (Year: 2023). |
Written Opinion in PCT/US2023/021267 (Year: 2023). |
Number | Date | Country | |
---|---|---|---|
20230358515 A1 | Nov 2023 | US |
Number | Date | Country | |
---|---|---|---|
63364318 | May 2022 | US |