Claims
- 1. Substantially spherical porous beads of an aromatic polyether ketone resin, which have all of the following characteristics:(1) said porous beads have an average particle diameter of 50 to 5,000 μm, (2) said porous beads have a porosity of 40 to 99%, (3) said porous beads have continuous pores in a three-dimensional network, (4) said porous beads are smooth, (5) said porous beads are skinless, and (6) said porous beads have fibrils constituting the matrix of said porous beads having the three dimensional pore structure, wherein ratio of the average thickness of the fibrils at a peripheral portion of the beads to the average thickness of the fibrils at an inner portion of the beads is 1.1 or more.
- 2. The porous beads according to claim 1, wherein said aromatic polyether ketone resin is a thermoplastic, crystalline polymer having a glass transition temperature of at least 130° C.
- 3. A method for producing porous beads, which comprises:(a) mixing, while heating, an aromatic polyether ketone resin with a solvent capable of dissolving said resin to thereby obtain a resin solution; (b) dispersing said resin solution in a liquid dispersion medium which is incapable of dissolving said resin and is non-miscible with said solvent, to thereby obtain a dispersion having said resin solution dispersed therein in the form of globules; (c) cooling said dispersion while maintaining the dispersed form of said resin solution in said liquid dispersion medium, to thereby solidify the resin in said resin solution; and (d) separating the solidified resin from a mixture of said solvent and said liquid dispersion medium, thereby obtaining substantially spherical porous beads of said aromatic polyether ketone resin.
- 4. The method according to claim 3, wherein said mixing of said resin with said solvent in step (a) is performed at a temperature of 200° C. or higher.
- 5. The method according to claim 3 or 4, wherein said solvent consists essentially of carbon, hydrogen and oxygen atoms.
- 6. The method according to claim 3 or 4, wherein said resin solution is used without an additional component other than said resin and said solvent.
- 7. The porous beads according to claim 1, wherein said ratio of the average thickness of the fibrils at a peripheral portion of the beads to the average thickness of the fibrils at an inner portion of the beads is 1.2 or more.
- 8. The porous beads according to claim 1, wherein said ratio of the average thickness of the fibrils at a peripheral portion of the beads to the average thickness of the fibrils at an inner portion of the beads is 1.3 or more.
- 9. The porous beads according to claim 1, wherein the surface smoothness of said porous beads is not more than 1%, wherein said surface smoothness is defined by the following formula:S=H/D×100 wherein S represents the surface smoothness (%), H represents the height (μm) of projections present on the surface of the beads, and D represents the diameter (μm) of the beads.
- 10. The porous beads according to claim 1, wherein said aromatic polyether ketone resin is a homopolymer comprising any one of the recurring units selected from the group consisting of a polyether ketone (PEK) unit, a polyether ether ketone (PEEK) unit, a polyether ketone ketone (PEKK) unit, a polyether ether ketone ketone (PEEKK) unit and a polyether ketone ether ketone ketone (PEKEKK) respectively represented by the following formulae (2) to (6):
- 11. The porous beads according to claim 1, wherein said aromatic polyether ketone resin is a homopolymer comprising any one of the recurring units selected from the group consisting of a polyether ketone (PEK) unit and a polyether ether ketone (PEEK) unit respectively represented by formulae (2) and (3):
Priority Claims (1)
Number |
Date |
Country |
Kind |
11-325302 |
Nov 1999 |
JP |
|
Parent Case Info
This application is the national phase under 35 U.S.C. §371 of PCT International Application No. PCT/JP00/08074 which has an International filing date of Nov. 16, 2000, which designated the United States of America.
PCT Information
Filing Document |
Filing Date |
Country |
Kind |
PCT/JP00/08074 |
|
WO |
00 |
Publishing Document |
Publishing Date |
Country |
Kind |
WO01/36522 |
5/25/2001 |
WO |
A |
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