Claims
- 1. Method for preparing an emulsion having grains rich in silver bromide in the presence of gelatin as a protective colloid in a reaction vessel wherein a yield of more than 250 g, expressed as amount of silver nitrate, equivalent with the amount of precipitated silver halide per liter of reaction vessel mixture is attained, wherein at least 70% of a total projected area of all grains is provided by {111} tabular grains having an average aspect ratio of more than 2:1 and an average thickness of from 0.05 up to 0.30 .mu.m and wherein a ratio by number of hexagonal tabular grains to triangular tabular crystals present is more than 10:1, said method comprising following steps:
- preparing in a reaction vessel a gelatinous dispersion medium containing an initial amount of gelatin corresponding with less than 50% of a total amount of gelatin used in the said method, said initial amount of gelatin having an average methionine content of less than 30 .mu.moles per mole and said dispersion medium having a volume of less than 2 liter per 500 g, expressed as amount of silver nitrate, equivalent with the amount of precipitated silver halide;
- precipitating therein silver halide crystal nuclei by double-jet precipitation of an aqueous silver nitrate and an aqueous solution comprising halide ions, wherein less than 10% by weight of a total amount of silver nitrate used is consumed;
- adding to said reaction vessel gelatin in an amount of more than 50% of a total amount of gelatin used in the said method;
- growing said silver halide crystal nuclei by further precipitation of silver halide by means of double-jet precipitation of an aqueous silver nitrate solution and an aqueous solution comprising halide ions, wherein more than 90% by weight of a total amount of silver nitrate is consumed; and
- concentrating by ultrafiltration the said reaction mixture volume in the said reaction vessel obtained during precipitation growth steps.
- 2. Method according to claim 1, wherein said tabular {111} grains rich in silver bromide are composed of silver bromide, silver bromoiodide, silver bromochloride or silver bromochloroiodide.
- 3. Method according to claim 2, wherein in said silver bromoiodide or silver bromochloroiodide iodide is present in an amount of up to 3 mole %.
- 4. Method according to claim 2, wherein iodide is provided by means of an iodide releasing agent.
- 5. Method according to claim 1, wherein an average thickness of the said tabular {111} grains is from 0.05 up to 0.20 .mu.m.
- 6. Method according to claim 1, wherein adding to said reaction vessel gelatin differing from the said initial amount of gelatin is in an amount of more than 80% by weight of total amount of gelatin used, wherein said gelatin differing from said initial amount of gelatin contains methionine in an amount of more than 30 .mu.moles per gram.
- 7. Gelatinous emulsion prepared according to the method of claim 1, wherein said emulsion has silver bromide, silver bromoiodide, silver bromochloride or silver bromochloroiodide grains and wherein at least 70% of the total projected area of all grains is provided by tabular {111} grains having an average aspect ratio of more than 2:1 and an average thickness of from 0.05 to 0.30 .mu.m and wherein a ratio by number of hexagonal tabular grains to triangular tabular grains is more than 10:1.
- 8. Gelatinous emulsion according to claim 7, wherein a ratio by number of hexagonal tabular grains to triangular tabular grains is more than 20:1.
- 9. Photographic material comprising a support and on one or on both sides thereof one or more light-sensitive silver halide emulsion layer(s) coated from a gelatinous emulsion according to claim 7.
- 10. Photographic material according to claim 9, wherein said photographic material is a single-side or double-side coated radiographic material.
Priority Claims (1)
Number |
Date |
Country |
Kind |
97203313 |
Oct 1997 |
EPX |
|
Parent Case Info
This application claims the benefit of U.S. Provisional Application Ser. No. 60/070,498 filed Jan. 5, 1998.
US Referenced Citations (2)
Number |
Name |
Date |
Kind |
5567580 |
Fenton et al. |
Oct 1996 |
|
5723278 |
Jagannathan et al. |
Mar 1998 |
|
Foreign Referenced Citations (1)
Number |
Date |
Country |
0 697 618 A1 |
Feb 1996 |
EPX |