Printhead with multiple ink feeding channels

Abstract
A thermal ink jet printhead (40) for the emission of droplets of ink on a print medium (46) comprises a reservoir (103) containing ink (142), a die (61), a slot (102) engraved in said die (61) and a plurality of ejectors (73), each of which in turn comprises a chamber (74), a resistor (27) and a nozzle (56), each of said chambers (74) being put in fluid communication with said slot (102) through a plurality of elementary ducts (72) lying on a different plane from the bottom (67) of said chamber (74).
Description




TECHNICAL FIELD




This invention relates to a printhead used in equipment for forming, through successive scanning operations, black and colour images on a print medium, usually though not exclusively a sheet of paper, by means of the thermal type ink jet technology, and in particular to the head actuating assembly and the associated manufacturing process.




BACKGROUND ART




Depicted in

FIG. 1

is an ink jet colour printer on which the main parts are labelled as follows: a fixed structure


41


, a scanning carriage


42


, an encoder


44


and, by way of example, printheads


40


which may be either monochromatic or colour, and variable in number.




The printer may be a stand-alone product, or be part of a photocopier, of a “plotter”, of a facsimile machine, of a machine for the reproduction of photographs and the like. The printing is effected on a physical medium


46


, normally consisting of a sheet of paper, or a sheet of plastic, fabric or similar.




Also shown in

FIG. 1

are the axes of reference:




x axis: horizontal, i.e. parallel to the scanning direction of the carriage


42


; y axis: vertical, i.e. parallel to the direction of motion of the medium


46


during the line feed function; z axis: perpendicular to the x and y axes, i.e. substantially parallel to the direction of emission of the droplets of ink.




The composition and general mode of operation of a printhead according to the thermal type technology, and of the “top-shooter” type in particular, i.e. those that emit the ink droplets in a direction perpendicular to the actuating assembly, are already widely known in the sector art, and will not therefore be discussed in detail herein, this description instead dwelling more fully on some only of the features of the heads and the manufacturing process, of relevance for the purposes of understanding this invention.




The current technological trend in ink jet printheads is to produce a large number of nozzles per head (≧300), a definition of more than 600 dpi (dpi=“dots per inch”), a high working frequency (≧10 kHz) and smaller droplets (≦10 pl) than those produced in earlier technologies.




Requirements such as these are especially important in colour printhead manufacture and make it necessary to produce actuators and hydraulic circuits of increasingly smaller dimensions, greater levels of precision, narrow assembly tolerances. It is important in particular to ensure that the volume and speed of the droplets subsequently emitted are as constant as possible, and that no “satellite” droplets are formed as these, with a trajectory generally different from the main droplets, are distributed randomly near the edges of the graphic symbols, reducing their sharpness.





FIG. 2

shows an enlarged axonometric view of an actuating assembly


111


of an ink jet printhead according to the known art, made of a die


100


of semiconductor material (usually Silicon), on the upper face of which resistors


27


have been made for emission of the droplets of ink, driving circuits


62


for driving the resistors


27


, soldering pads


77


for connecting the head to an electronic controller not shown in the figure, and which bears a pass-through slot


102


through which the ink flows from a reservoir not shown in the figure. Around the upper edge of the slot


102


a basin


76


has been made, the characteristics and functions of which are as described in detail in Italian patent application TO 98A 000562. Affixed to the upper face of the die is a layer


105


of photopolymer having, usually though not exclusively, a thickness less than or equal to 25 μm in which, by means of known photolithographic techniques, a plurality of ducts


53


and a plurality of chambers


57


positioned locally to the resistors


27


have been made. Stuck on the photopolymer


105


is a nozzle plate


106


, generally made of a plate of gold-plated nickel or kapton, of thickness less than or equal to 50 μm, bearing a plurality of nozzles


56


, each nozzle


56


being in correspondence with a chamber


57


. In the current technology, the nozzles


56


have a diameter D of between 10 and 60 μm, while their centres are usually spaced apart by a pitch A of {fraction (1/300)}


th


or {fraction (1/600)}


th


of an inch (84.6 μm or 42.3 μm). Generally, though not always, the nozzles


56


are arranged in two rows parallel to the y axis, staggered one from the other by a distance B=A/2, in order to double the resolution of the image in the direction parallel to the y axis; the resolution thus becomes {fraction (1/600)}


th


or {fraction (1/1200)}


th


of an inch (42.3 μm or 21.2 μm). The x, y and z axes, already defined in

FIG. 1

, are also shown in FIG.


2


.





FIG. 3

is an axonometric enlargement of two chambers


57


, adjacent and communicating with the slot


102


through the basin


76


and the ducts


53


made in the layer of photopolymer


105


. Normally the ducts


53


have a length l and a rectangular cross-section having a depth a and a width b. The chambers


57


have a depth d, substantially equal to the depth a of the ducts


53


.




A section of an ejector


55


can be seen in

FIG. 4

, where the following are shown, in addition to the items already mentioned: a reservoir


103


containing ink


142


, a droplet


51


of ink, a vapour bubble


65


, a meniscus


54


in correspondence with the surface of separation between the ink and the air, an external edge


66


and arrows


52


which indicate the prevalent direction of motion of the ink.




To describe the operation of an ejector for a thermal type ink jet printhead, an electrical analogy is used, for which the following equivalences are established:


















V = electrical voltage in volt




equivalent to: pressure in N/m


2


;






I = current in A




equivalent to: flow rate m


3


/s;






R = resistance in ohm




equivalent to: hydraulic resistance in







N/m


2


/m


3


/s = N s/m


5


;






L = Inductance in henry




equivalent to the ratio between the mass of







the column of liquid that fills the duct and







the square of the section of the duct; this







ratio is called “hydraulic inertance”, and







is measured in kg/m


4


;






C = capacitance in farad




equivalent to: hydraulic compliance







in m


3


/N/m


2


= m


5


/N.














In the equivalent diagram of

FIG. 5

the bubble is represented as a variable capacitance C


b


. There is a front leg


70


, equivalent to the whole formed by the chamber


57


, the nozzle


56


, the meniscus


54


and the droplet


51


, and a rear leg


71


, which represents the section of the hydraulic circuit between the chamber


57


and the reservoir


103


.




The front leg


70


comprises a fixed impedance L


f


, R


f


corresponding substantially to the chamber


57


, a variable impedance L


u


, R


u


corresponding substantially to the nozzle


56


, and a deviator T which, during the step in which the droplet


51


is formed, inserts a variable resistance R


g


substantially corresponding to the droplet, whereas, during the steps of withdrawal of the meniscus


54


, of filling of the nozzle, of subsequent oscillation and damping of the meniscus, inserts a capacitance C


m


substantially corresponding to the meniscus itself.




Ejection of the ink takes places in accordance with the following steps:




a) The electronic control circuit


62


supplies energy to the resistor


27


, so as to produce local boiling of the ink with formation of the bubble


65


of steam in expansion. During this step, in the equivalent electric circuit of

FIG. 5

the variable resistance R


g


is inserted. The bubble


65


generates two opposing flows: I


p


(to the reservoir


103


) and I


a


(to the nozzle


56


).




b) The electronic circuit


62


terminates the delivery of energy to the resistor


27


, the vapour condenses, the bubble


65


collapses, the droplet


51


detaches itself, the meniscus


54


withdraws emptying the nozzle


56


. The two opposing flows I


p


and I


a


remain. In this step, in the equivalent circuit of

FIG. 5

the capacitance C


m


corresponding to the meniscus


54


is inserted.




c) The bubble


65


has disappeared, the meniscus


54


demonstrates its capillarity and goes back towards the outer edge


66


of the nozzle


56


sucking new ink


142


into the nozzle


56


. Its return completed, the meniscus


54


remains attached to the outer edge


66


by oscillating and behaving like a vibrating membrane. In the equivalent electric circuit of

FIG. 5

the capacitance C


m


is still inserted. During this step the equivalent circuit of the ejector


55


is simplified as sketched in

FIG. 6

, where C


m


represents the capacitance of the meniscus, while R and L represent respectively the sum of all the resistances and of all the inductances present between the meniscus


54


and the reservoir


103


. In addition, the flows I


p


and I


a


converge into a single flow i.




To obtain an optimal operation of the ejector


55


, it is necessary for the meniscus


54


, at the end of the step c), to reach the idle state rapidly and without oscillating. In this way the ink


142


does not wet the outer surface of the nozzle plate


106


, thereby avoiding alterations of speed and volume of the following droplets.




For a given nozzle


56


the parameters L


u


, R


u


and C


m


, belonging to the front hydraulic part


70


of the ejector


55


, are set and therefore, to obtain the values of R and L according to the criteria set down below, it is possible to act only on the design of the rear hydraulic part


71


.




The expression in function of the time i, which represents the flow, is given by the known relation:









i
=



V
m

L

*
t
*




-
t


2

τ








(
1
)













where V


m


represents the pressure generated by the meniscus


54


, which is negative during the filling step, and τ is the time constant, measured in seconds, of the RLC circuit of

FIG. 6

, equal to the ratio L/R.




For maximum speed in filling of the nozzle


56


, the flow i must be rendered maximal, and for this to happen L and τ must be rendered minimal.




Also, for the meniscus


54


to reach the idle state rapidly without oscillating, the equivalent circuit of

FIG. 6

must be “critical damping” type, and must for this purpose satisfy the known relation:









R
=

2
*


L

C
m








(
2
)













For a duct


53


of length l, the section of which has sides a and b with a>>b, the following known relations apply:









R



12
*
ρ
*
υ
*
l



b
3

*
a






(
3
)






L



ρ
*
l


b
*
a






(
4
)






τ
=


L
R

=


b
2


12
*
υ







(
5
)













where ρ is the density of the ink in kg/m


3


, ν is the viscosity of the ink in m


2


/s, and all lengths are measured in metres.




The time constant τ is a function of the width b, while it is independent of both the depth a and the length l.




It is possible to determine a value of b which gives values R and L such as to produce the critical damping, according to the expression (2). However the same value of b, substituted in (5), provides a value of τ which limits the flow i, according to the relation (1), and accordingly limits the emission frequency of the droplets. Moreover, it is not possible to modify either depth a or length l at will, as these parameters are subject to other technological and functional constraints, not described as they are not essential for the understanding of this invention.




To increase the emission frequency of the droplets, it is necessary to make the time constant τ much shorter than that obtained in the known art, while at the same time satisfying the critical damping condition: this problem is solved in this invention by making a plurality of N ducts in parallel, as will be seen in detail in the description of the preferred embodiment.




Some further drawbacks with the chambers


57


according to the known art are now mentioned, which have three continuous lateral walls and a fourth wall interrupted by the duct


53


of non-negligible width. In this situation the bubble


65


collapses prevalently in the direction of the resistor


27


underneath, which is thus subjected to greater wear on account of the known phenomenon of cavitation. In addition, the collapse of the bubble is dissymmetrical as it is attracted to the wall opposite the duct


53


: this cause a dissymmetry in the motion of the meniscus


54


, with a resulting deviation of the terminal part of the droplet


51


and the formation of satellite droplets having a different direction from the droplet


51


.




In this invention the duct


53


is substituted by N ducts placed in parallel and communicating with the chamber through the lower or upper wall, and consequently the four lateral walls of the chamber are continuous and symmetrical.




In U.S. Pat. No. 5,666,143 a solution is described in which the ink is brought to the chamber along multiple ducts, but these do not suffice to solve the problems reported.




DISCLOSURE OF THE INVENTION




The object of this invention is to render the emission frequency of the droplets of ink maximal by making the time constant τ of the ejector as short as possible, while at the same time satisfying the condition of critical damping of the meniscus.




Another object is to increase the degrees of freedom of the design of the ejector, by having the additional parameter consisting of the number N of elementary ducts in parallel.




A further object is to increase the life span of the resistor by making a chamber with four continuous walls, which promotes symmetrical collapse of the bubble in the direction of these walls and not towards resistor: this lowers the harmful effects of cavitation during collapse of the bubble.




Another object is to avoid the formation of satellite droplets by achieving a symmetrical movement of the meniscus made possible by the chamber with four continuous walls.




Yet another object is to filter the ink of any impurities that may be present.




These and other objects, characteristics and advantages of the invention will be apparent from the description that follows of a preferred embodiment, provided purely by way of an illustrative, non-restrictive example, with reference to the accompanying drawings.











BRIEF DESCRIPTION OF THE DRAWINGS




FIG.


1


—is an axonometric view of an ink jet printer;




FIG.


2


—is an enlarged view of an actuating assembly made according to the known art;




FIG.


3


—represents two emission chambers, according to the known art;




FIG.


4


—represents a sectioned view of one ejector of the head, according to the known art;




FIG.


5


—represents an equivalent electrical diagram of the hydraulic circuit of an ejector of the head;




FIG.


6


—represents a simplified equivalent wiring diagram of the hydraulic circuit of an ejector of the head;




FIG.


7


—represents an axonometric view of a portion of the actuating assembly of the head, made according to this invention;




FIG.


8


—represents an axonometric view of the emission chamber, according to a different visual angle from that of

FIG. 7

;




FIG.


9


—represents a section according to the plane AA, shown in

FIG. 7

;




FIG.


10


—illustrates the flow of the process for manufacture of the actuating assembly of

FIG. 7

;




FIG.


11


—represents a section view of the actuating assembly, at the start of the manufacturing process;




FIGS. from


12


to


14


—represent the actuating assembly as it is during later steps of the manufacturing process;




FIG.


15


—illustrates the flow of the manufacturing process of an actuating assembly according to a second embodiment;




FIG.


16


—represents an enlarged view of an actuating assembly, according to a third embodiment;




FIG.


17


—represents a section view and a view of the lower face of the actuating assembly, according to the third embodiment;




FIG.


18


—represents section view and a view of the lower face of the actuating assembly, according to a fourth embodiment;




FIG.


19


—represents an enlarged view of the actuating assembly, according to a fifth embodiment;




FIG.


20


—represents a section view of the actuating assembly, according to the fifth embodiment.











DESCRIPTION OF THE PREFERRED EMBODIMENT





FIG. 7

illustrates a portion of the actuator for printhead, monochromatic or colour, comprising an ejector


73


according to the invention. For simplicity's sake, the other parts of the head, being already known and not concerning the invention, are not depicted. The following are shown in the figure:




a portion of a die


61


;




a substrate


140


of Silicon P belonging to the die


61


;




a slot


102


cut into the substrate


140


;




the basin


76


, having depth c;




a layer


107


of photopolymer, according to the invention;




a chamber


74


according to the invention, made in the layer


107


of photopolymer, having depth d;




a bottom


67


of the chamber


74


;




lateral walls


68


of the chamber


74


;




the resistor


27


on the bottom


67


of the chamber


74


;




elementary ducts


72


according to the invention, which convey the ink


142


from the basin


76


to the chamber


74


, each having depth ƒ, width g and length l.





FIG. 8

illustrates the chamber


74


from a different visual angle, indicated by the reference axes, which shows the outlet of the elementary ducts


72


in the chamber


74


. The ducts


72


are located under the layer


107


of photopolymer, and are therefore at a lower level than the bottom


67


of the chamber


74


: in this way, a tank


63


is made which hydraulically connects the ducts


72


with the chamber


74


.





FIG. 9

shows the ejector


73


sectioned according to a plane AA, indicated in

FIGS. 7 and 8

.




According to a construction variant of the preferred embodiment, the basin


76


is missing, and the ducts


72


face directly on to the slot


102


.




A method is now described for calculating the correct number N of elementary ducts


72


.




The time constant τ is a function of the width g of each single duct


72


, whereas it is independent of the number N of ducts in parallel, as indicated by the following relation, analogous to (5):









τ
=


L
R

=


g
2


12
*
υ







(
6
)













It is therefore possible to obtain as short a time constant τ as possible by selecting the smallest value of g possible, compatibly with technological feasibility.




Conversely, if we assign τ a predetermined value, we obtain:








g


={square root over (12*ν*τ)}  (7)






In practice, the width g according to this invention is, though not exclusively, between 3 and 15 μm.




Having thus determined the geometrical dimensions of a single duct


72


, we obtain values R′ and L′ of resistance and inductance equivalent to each duct


72


by means of the following relations, similar to (3) and (4):










R





12
*
ρ
*
υ
*
l



g
3

*
f






(
8
)







L





ρ
*
l


g
*
f






(
9
)













The total resistance R and total inductance L of the equivalent circuit with the plurality of ducts


72


in parallel are calculated using the known formula for impedances in parallel, and are:








R=R′/N


  (10)










L=L′/N


  (11)






It is now possible to obtain the value of N by substituting the expressions (10) and (11) in (2), which becomes:











R


N

=

2
*



L



N
*

C
m









(
12
)













and which allows us to obtain









N
=



(

R


)

2

*


C
m


4


L









(
13
)













The value thus obtained for N is generally not an integer, and must be rounded to the nearest whole number: this causes a slight deviation from the condition of critical damping, which may be recovered with a slight variation of the length l of the elementary duct


72


.




The manufacturing process of an ejector


73


for a monochromatic or colour ink jet printhead


40


according to the invention is effected according to the steps indicated in the flow diagram of FIG.


10


.

FIGS. 11

to


14


represent the ejector


73


in successive stages of the work.




In the step


201


, by means of a known process, a wafer is made available containing a plurality of dice completed solely in the control circuits


62


and in the resistors


27


. Visible in

FIG. 11

is a section of a portion of a die


61


in which an ejector will be made. The following are indicated:




a portion of the die


61


;




the substrate


140


of Silicon P belonging to the die


61


;




a LOCOS insulating layer


35


Of SiO


2


;




a BPSG “interlayer”


33


;




the resistor


27


;




a layer


30


Of Si


3


N


4


and SiC for protection of the resistors;




a conducting layer


26


, made of a layer of Tantalum covered by a layer of Gold.




In the step


202


, a photoresist is laid over the entire surface of the wafer.




In the step


203


, development is effected of the photoresist, by means of a first mask not depicted in any of the figures, of the geometry of the elementary ducts


72


, of the basin


76


and of the tank


63


.




In the step


204


, dry etching (Tegol) is performed of the LOCOS+BPSG+Si


3


N


4


until the substrate


140


of Silicon is uncovered in the areas defined by the first mask in the previous step


203


.




In the step


205


, the elementary ducts


72


, the basin


76


and the tank


63


are etched into the Silicon using “dry” technology in the STS plant, with arrangements known to those acquainted with the sector art. Geometry of the etching is defined by the photoresist already developed in the step


203


according to the design of the first mask, reinforced by the layer of LOCOS+BPSG +Si


3


N


4


beneath. Referring back to

FIG. 7

, depth ƒ of the channels is less than depth c of the basin


76


due to the different etching speed resultant on the different width of the etching front. If, as a non-restricting example, we assume ƒ=10 μm, g=5 μm and a basin width of 300 μm we obtain a depth c of the basin equal to approximately 20 μm. In general, the depth ƒ is prevalently but not exclusively between 10 and 100 μm. At this stage of the work, the ejector is as shown in FIG.


12


.




In the step


212


, the photoresist is removed and the wafer cleaned.




In the step


213


, the layer


107


, consisting of negative photopolymer, is laminated on the entire surface of the wafer.




In the step


214


, the layer


107


is developed according to the geometry of a second mask, non depicted in any of the figures, with the purpose of obtaining the chamber


74


, the plan of which includes the resistor


27


and the tank


63


, and uncovering the basin


76


, as illustrated in

FIG. 13

, where the dashed area represents the remaining photopolymer.




In the step


215


, the areas of the resistors


27


and of the soldering pads


77


are protected using a material that may be removed with water.




In the step


216


, the pass-through slot


102


is made by way of, for example, a sand blasting process. At this stage of the work, the zone of the ejector is as shown in FIG.


14


.




In the step


217


, the usual completion and finishing operations are carried out, known to those acquainted with the sector art.




Second Embodiment




The principle of the invention is also applicable in cases where the basin


76


is made with a ratio between the depth c and the depth ƒ of the elementary ducts


72


and of the tank


63


that is greater than what it would be naturally on account of the different etching speeds. As a non-restricting example, for the basin


76


a depth c of between 20 and 100 μm may be selected, and for the ducts


72


and the tank


63


a depth ƒ of between 5 and 20 μm. The production process is modified according to the flow diagram of

FIG. 15

, in which the following steps are inserted after the step


204


.




In the step


205


′, elementary ducts


72


and the tank


63


are etched into the Silicon with “dry” technology on the STS plant. The depth ƒ of the etching is prevalently but not exclusively limited to between 5 and 20 μm. In this stage, the basin


76


may or may not be etched, depending on the design of the first mask.




In the step


206


, the photoresist previously laid in the step


202


and developed in the


203


is removed.




In the step


207


, lamination is performed of a “dry film” type photoresist over the entire surface of the wafer, which in this way covers and protects the area occupied by the ducts


72


and the tank


63


.




In the step


210


, development is effected of the second photoresist, by means of a third mask not depicted in any of the figures, so as to leave uncovered only the area of the basin


76


.




In the step


211


, a further etching is made in the Silicon, this time of the basin


76


, using “dry” technology in the STS plant. The depth of this etching is in this way greater than that which would be obtained by the step


205


′ alone, and prevalently but not exclusively between 20 and 100 μm.




Once this step is completed, the process continues to step


212


, as already described for the preferred embodiment.




Third Embodiment




A variant in the known art consists in producing the nozzles directly on a “flat cable”, which in this way also performs the function of nozzle plate, and is represented in

FIG. 16

by means of an enlarged view of an actuating assembly


112


. According to this embodiment, the nozzle plate


106


is replaced by a flat cable with nozzles


130


, which comprises the nozzles


56


′. The following may be seen in the figure:




the die


100


, made according to the known art already illustrated in

FIG. 2

;




the layer of photopolymer


107


, made according to the preferred embodiment, which comprises the chambers


74


having the continuous lateral walls


68


;




the flat cable with nozzles


130


, made for instance of Kapton;




an upper face


113


of the flat cable with nozzles


130


;




a lower face


114


of the flat cable with nozzles


130


.





FIG. 17

presents a section of the flat cable with nozzles


130


and a view of its lower face


114


, limited to a single ejector. The elementary ducts


72


′ are made directly on the lower face


114


of the flat cable with nozzles


130


, using for instance an excimer laser.




Fourth Embodiment




This embodiment is represented in

FIG. 18

by way of a section of the flat cable with nozzles


130


and a view of the lower face


114


, limited to a single ejector. The elementary ducts


72


′ are again made directly on the lower face


114


of the flat cable with nozzles


130


, together with a chamber


74


′, using for instance an excimer laser, but the layer


107


is missing.




Fifth Embodiment




The principle of the invention is also applicable in cases where the feeding of the ink takes place on the two sides of the die, according to a variant of the known art disclosed in the U.S. Pat. No. 5,278,584.

FIG. 19

represents a die


183


with lateral feeding of the ink and a flat cable with nozzles


180


associated therewith, having an upper face


115


and a lower face


116


, produced according to said patent.





FIG. 20

represents a section view of a die with lateral feeding


183


″, of a photopolymer


107


″ in which a plurality of chambers


74


″ has been made, of a flat cable with nozzles


180


″ which present an upper face


115


and a lower face


116


. A plurality of nozzles


56


″ and elementary ducts


72


″ are made in the lower face


116


of the flat cable with nozzles


180


″, similarly to what was described in the third embodiment. The ink reaches the chamber


74


″ from the sides of the dice


183


″ through the elementary ducts


72


″.




A variant of the fifth embodiment may be obtained by also etching the chambers directly in the lower face


116


of the flat cable with nozzles


180


″ and eliminating the layer of photopolymer


107


″, similarly to what was described for the fourth embodiment.




A further variant of the fifth embodiment may be obtained by etching the elementary ducts in the silicon of the dice


183


, on a plane below the layer


107


″, similarly to what was described for the preferred embodiment. The elementary ducts face on to a depression produced by a “scribing” operation, known to those acquainted with the sector art: in this way, the cut with the diamond wheel, which separates the dice


183


, does not touch the ends of the elementary ducts directly, and thus avoids damaging them.



Claims
  • 1. Method for manufacturing a thermal ink jet printhead (40) comprising a reservoir (103) suitable for containing ink, a die (61), a slot (102) etched into said die (61) and a plurality of ejectors (73), each of which in turn comprises a chamber (74), a resistor (27) and a nozzle (56), characterized in that it comprises the steps of:(205) etching a plurality of elementary ducts (72), a tank (63) and a basin (76) fluidly connected with said slot (102); (213) covering said plurality of elementary ducts (72) and said tank (63) by means of a layer (107); and (214) producing in said layer (107) said chamber (74), fluidly connected with said plurality of elementary ducts (72) and with said tank (63).
  • 2. Method according to claim 1, characterized in that it also comprises the step of:(211) effecting a further etching of the basin (76).
Priority Claims (1)
Number Date Country Kind
AO99A0002 Dec 1999 IT
Parent Case Info

This application is a U.S. national phase application of PCT/IT00/00534, filed Dec. 19, 2000, claiming priority on Italian Application No. A099A000002, filed Dec. 27, 1999, herein incorporated by reference.

PCT Information
Filing Document Filing Date Country Kind
PCT/IT00/00534 WO 00
Publishing Document Publishing Date Country Kind
WO01/47715 7/5/2001 WO A
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Number Name Date Kind
4502060 Rankin et al. Feb 1985 A
5734399 Weber et al. Mar 1998 A
6019907 Kawamura Feb 2000 A
6117698 Atobe et al. Sep 2000 A
6162589 Chen et al. Dec 2000 A
6309054 Kawamura et al. Oct 2001 B1
6365058 Beatty et al. Apr 2002 B1
Foreign Referenced Citations (4)
Number Date Country
0549211 Jun 1993 EP
0564069 Oct 1993 EP
0678387 Oct 1995 EP
0694398 Jan 1996 EP