This invention relates to a system and method for stabilizing the pressure of a gas source as well as recycling the gas thereof to a downstream system.
Pressure control is widely used in industrial processes or machineries. It affects the quality and productivity of production and is an important factor in triggering reaction in chemical production processes.
An On-line Analyzer paired with a Sample Conditioning System is commonly used for quality control in production lines of petrochemical, food, biotech, and drug industries. The Sample Conditioning System dictates the performance of the On-line Analyzer. It must ensure that the gas flowing into the On-line Analyzer is stable in pressure, temperature and flow.
Usually gas flowing into the On-line Analyzer from the Sample Conditioning System has environmental temperature and pressure. Gas discharged from the On-line Analyzer usually cannot flow back into the production pipeline by itself but rather needs to be pumped back to production or to a recycler. The layout is shown in
a) 201: Gas source to be pressure-controlled.
b) 202: Sample Conditioning System: a processing system that works with, and is in front of, the On-line Analyzer.
c) 203: On-line Analyzer: an analyzer that takes gas inflow from the Sample Conditioning System and continuously analyzes it.
d) 204: Pump.
e) 101: High Pressure Recovery Tank: for recycling gas.
If the pressure of the recycling tank at the output end of the On-line Analyzer is not stable in pressure, it will cause the gas pressure inside the On-line Analyzer to be unstable. As a result, the reading of the On-line Analyzer will fluctuate abruptly. Therefore, system designers are forced to discharge the analyzed gas into the atmosphere as shown in
a) 201: same with 201 in
b) 202: same with 202 in
c) 203: same with 203 in
d) 301: Atmosphere.
Another technology in stabilizing gas pressure and recycling gas is shown in
a) 701 Limit Switch A: a directionless switch for stopping the operation of gas pumping.
b) 702 Tripper Rod: a rigid rod which moves with the wire to a particular position to trigger a Limit Switch.
c) 703 Limit Switch B: a directionless switch for starting the operation of gas pumping.
d) 704 Counterweight: to balance the weight of the Floating Top via the Pulley Set.
e) 705 Pulley: to support the wires and make it easy for the wires to move and change the direction of the force applied.
f) 706 Pulley: same with 705.
g) 707 Floating Top: working together with the Pulley Set and the Counterweight such that when gas flows into the Bucket and raises the Floating Top, the accommodating volume of the Bucket increases without changing the pressure inside the Bucket.
h) 708 Bucket: for accommodating continuous gas inflow.
i) 201 Gas source: source of the gas which needs to be pressure-controlled.
j) 300 Booster Device: capable of drawing in gas from one end, pressurizing the gas, and discharging the gas from the other end.
k) 101: High-Pressure Recovery Tank.
The Bucket has a double-layered shell with high-density silicon oil filled in between the layers so that there is no space between the sides of Floating Top and the shell of the Bucket. The weight of the Floating Top is balanced by counterweights. When gas enters the Bucket, the Floating Top rises and the Tripper Rod declines. When the Tripper Rod touches the Limit Switch B, the Booster Device is started and the gas inside the Bucket is drawn out. Then the Floating Top goes down, causing the Tripper Rod to rise, until the Tripper Rod touches Limit Switch A and the Booster Device stops.
When gas flows into the Bucket, the inertia to raise the Floating Top must be overcome. Also, when the Booster Device is started by the Limit Switch B and ready to pump gas to the High Pressure Recovery Tank, there is the issue of the unstable pressure at the output end causing unstable suction volume. The Floating Top cannot swiftly move to balance the quick changes of gas flow due to its inertia of mass.
This design cannot satisfy the requirement of a stable On-line Analyzer when the pressure fluctuation is large in the recycler, or when the flow volume fluctuation is large at the source. Also, the components are exposed to the atmosphere all the time, the change of characteristics of the material on the surface would make the balance mechanism deteriorate.
The present invention provides a system and method for pressure stabilization of a gas source. It comprises a pressure stabilizer divided into a receiving chamber and a pressure chamber by a flexible membrane, a booster device, a gas divider, and a control driver that can sense movement of the flexible membrane and control the gas divider accordingly. A pressure pilot is used to set the desired pressure of the pressure chamber. The pressure of the receiving chamber will stabilize to be the same with that of the pressure chamber regardless of the gas flow or pressure change at the gas source or the pressure fluctuation in the downstream system. The gas passing the system can eventually be recycled without harming the environment.
The present invention is a Proactive Pressure Stabilizing System (“PPSS”) and the method thereof. It comprises a Pressure Stabilizer, a Booster Device, a Gas Divider, and a Control Driver.
The present invention can be laid out using one of the two ways shown in
Explanations of
a) 101 High Pressure Recovery Tank: for recycling pressurized gas.
b) 102 Control Driver: a mechanism that senses the movement or shape change of the Flexible Membrane and controls the Divider Controller of the Gas Divider accordingly. It can be implemented using either a mechanical structure, like a rigid rod, or an electronic signal transmission.
c) 200 Pressure Stabilizer: divided into a Receiving Chamber and a Pressure Chamber by the Flexible Membrane.
d) 2001 Receiving Chamber Gas Outlet.
e) 2002 Receiving Chamber Source Inlet: for channeling the gas source into the Receiving Chamber.
f) 2003 Receiving Chamber: for accepting continuous gas inflow.
g) 2004 Flexible Membrane: a piece of flexible material that can sense and balance the pressure from both contacting sides.
h) 2005 Pressure Pilot: for channeling in a particular pressure to the Pressure Chamber.
i) 2006 Pressure Chamber: for accepting gas of a particular pressure which must remain constant when the volume of the Pressure Chamber changes.
j) 300 Booster Device: a pump; drawing in gas from one side and discharging the gas from the other side after pressurizing the gas.
k) 3001 Booster Inlet: inlet end of the Booster Device.
l) 3002 Booster Outlet: outlet end of the Booster Device.
m) 400 Gas Divider: for controlling and adjusting, using its Divider Controller, the portion of gas outflow or the amount of gas being drawn out.
n) 4001 Divider Gas Inlet: gas inlet of the Gas Divider.
o) 4002 Divider Controller: an adjustment mechanism for the gas flow, using either a mechanic apparatus, for example, a rotor, or an electronic control to adjust the amount or portion of the gas flowing out or being drawn out from the Gas Divider.
p) 4003 Divider Gas Outlet: gas outlet of the Gas Divider.
A Flexible Membrane divides the inside of the Pressure Stabilizer into two independent chambers: the Receiving Chamber and the Pressure Chamber. The Receiving Chamber continuously accepts gas inflow. Via the natural extension or shape change of the Flexible Membrane, the pressure in the Receiving Chamber is kept the same with the particular pressure fed to the Pressure Chamber. The best material for the Flexible Membrane should be light, thin, soft, or creased. If creased, the extension of the Flexible Membrane is actually crease-unfolding, rather than extending the material to induce an opposite tension which would be exerted on the Receiving Chamber and would change the pressure of the Receiving Chamber. Light, thin and soft material can also reduce the delay effect caused by inertial mass and allow the Flexible Membrane to extend, move left/right or up/down without overcoming the extra force needed by inertial mass that would change the inner pressure of the Receiving Chamber. The material must be suitable for the characteristics of the gas inflow. If possible, it should be inactive to the gas inflow. For example, Teflon, PP, metal foil, PU, Viton, PE, Carbon, Ryton, Silicon can be used.
Overall, the Booster Device adds pressure to the gas so that it can flow to the downstream system, usually a High Pressure Recovery Tank in practice, unless the downstream system has a pump-like function and is negative in pressure relative to the Receiving Chamber. Devices like Booster Pump, Bellow Pump, Diaphragm Pump, Ejector (Aspirator, Eductor), Gear Pump, and Compressor can be candidates for the Booster Device. In fact, any form of pumping device available in the market will do, as long as their physical property and the material are suitable for the application. Because the pump volume of the Booster Device will decrease as the pressure of the downstream increases, the principle of choosing the Booster Device is that, under the maximum possible downstream pressure, the pump volume of the Booster Device has to be greater than the maximum possible gas inflow at the Receiving Chamber.
The Gas Divider has a gas inlet, a gas outlet and a Divider Controller that adjusts the gas flowing out or being drawn out of the Gas Divider. The Divider Controller is driven by the Control Driver which can sense the movement or shape-change of the Flexible Membrane. Either or both of the Divider Controller and the Control Driver can be implemented mechanically or electronically. Various implementations will be discussed later.
No matter how the flow or pressure of the gas flowing into the Receiving Chamber fluctuates, or how the pressure in the downstream system changes, the pressure of the Receiving Chamber will converge to be the same as that of the Pressure Chamber. The mass flow of the gas being pumped to the downstream system, High Pressure Recovery Tank for an example, after being automatically adjusted by the Divider Controller, will be “synchronized in change” with the mass flow of the gas flowing into the Receiving Chamber. Here, “synchronized in change” means that when the mass flow of the gas inflow changes, the mass flow being drawn out will, because of the extension or movement of the Flexible Membrane, change the pressurized flow into the High Pressure Recovery Tank until its mass flow is equivalent to the mass flow of the gas inflow. The time needed for the “synchronization” depends on the volume of the Pressure Stabilizer and the degree the mass flow of the gas inflow fluctuates.
With the Positive Type layout shown in
In the Positive Type layout, if the Divider Gas Outlet is fully closed by the Divider Controller, some booster devices, by their design, could be overheated or their moving components could be latched and damaged because of the lack of gas exhaust. This can be solved by adding a reflux opening to the Gas Divider and redirect the gas back to the Receiving Chamber. If no such concern exists for the booster device used, reflux is not needed. The connections are shown in
a) 101 same with 101 in
b) 200 same with 200 in
c) 2001 same with 2001 in
d) 2002 same with 2002 in
e) 2003 same with 2003 in
f) 2004 same with 2004 in
g) 2005 same with 2005 in
h) 2006 same with 2006 in
i) 2007 Receiving Chamber Reflux Inlet: for receiving the gas reflux.
j) 300 same with 300 in
k) 3001 same with 3001 in
l) 3002 same with 3002 in
m) 400 same with 400 in
n) 4001 same with 4001 in
o) 4002 same with 4002 in
p) 4003 same with 4003 in
q) 4004 Gas Reflux: an outlet for channeling gas in the Gas Divider back to the Pressure Stabilizer.
In
In the Positive Type layout, because the pressure at the output end of the Booster Device is higher, the Divider Gas Outlet and the Gas Reflux need to overcome a greater resistance due to higher pressure when opening from the completely-closed state. If a mechanical Control Driver, for example, a rod, is used, the rod would need to be long enough to have enough total torque to drive the Divider Controller. To prevent leaking of pressurized gas, the gap inside the Divider Controller for moving or rotating needs to be reduced. However, too small or too tight of a gap would not produce enough rotation torque and make it necessary for the Flexible Membrane to be paired with a longer rod so that the torque pushing the Divider Controller can be amplified and the precision of pressure control can be raised. If electronic adjustment signal is used in the Control Driver/Divider Controller set, the above consideration is not necessary.
With the Negative Type layout, because the inlet end of the Booster Device is lower in pressure than the outlet end, the aforementioned flow resistance needed to overcome is relatively smaller. The leaking issue can be solved more easily, and the stability and precision of pressure control is easier to increase. Likewise, using electronic adjustment signal for control would void this consideration.
a) 400: same with 400 in
b) 4001: same with 4001 in
c) 4002: Rotor, as an example of the Divider Controller. It has three connected channels: R1, R2 and R3 as shown. R1 is for gas inflow, R2 is for gas outflow, and R3 is for gas reflux.
d) 4003: same with 4003 in
e) 4004: same with 4004 in
f) 1101 Rod, as an example of the Control Driver. It's connected to the Flexible Membrane, moves and rotates the Rotor 4002 tracking the Flexible Membrane's extension or shape change.
a) Status A: Divider Gas Inlet and R1 are completely pass-through, Divider Gas Outlet and R2 are completely closed, and Gas Reflux and R3 are completely pass-through. Therefore Divider Gas Inlet and Gas Reflux are completely pass-through.
b) Status B: Divider Gas Inlet and R1 are completely pass-through, Divider Gas Outlet and R2 are partially pass-through, and Gas Reflux and R3 are partially pass-through. Therefore Divider Gas Inlet is partially pass-through at the same time with Divider Gas Outlet and Gas Reflux.
c) Status C: Divider Gas Inlet and R1 are completely pass-through, Divider Gas Outlet and R2 are completely pass-through, and Gas Reflux and R3 are completely closed. Therefore Divider Gas Inlet and Divider Gas Outlet are completely pass-through.
The above example uses basic lever mechanism and let the rod attached to the Rotor follow the extension and shape change of the Flexible Membrane to achieve the torque needed for rotation. It won't exert force on the Flexible Membrane significantly, and won't cause pressure difference between the Receiving Chamber and the Pressure Chamber.
a) 901 Rear Plate.
b) 902 Gas Reflux: for channeling gas back to the Receiving Chamber.
c) 903 Gas Divider.
d) 904 Divider Gas Outlet.
e) 905 Divider Gas Inlet.
f) 906 Right Plate
g) 907 R2 Exit: gas from Divider Gas Inlet flows to the R2 channel via the R1 channel and then flows to the Divider Gas Outlet using this exit.
h) 908 R3 Exit: gas from the Divider Gas Inlet flows to the R3 channel via the R1 channel and then flows to Gas Reflux using this exit.
i) 909 Divider Controller implemented by a Rotor.
j) 901 Front Plate.
k) 911 Control Driver implemented by a Rod.
a) 1001 Rotor Seat: for affixing the Rotor.
b) 1002 Bearing: a component helping the Rotor rotates.
c) 1003 Divider Controller implemented with a Rotor.
d) 1004 Divider Gas Inlet.
e) 1005 Gas Divider Body.
f) 1006 Body Seat of the Gas Divider: for installing and seating the body of the Gas Divider.
g) 1007 Divider Gas Outlet.
h) 1008 Rod Socket: a socket for installing the Rod.
a) 200: same with 200 in
b) 2001: same with 2001 in
c) 2002: same with 2002 in
d) 2003: same with 2003 in
e) 2004: same with 2004 in
f) 2005: same with 2005 in
g) 2006: same with 2006 in
h) 2007: same with 2007 in
i) 400: same with 400 in
j) 4001: same with 4001 in
k) 4002: same with 4002 in
l) 4003: same with 4003 in
m) 4004: same with 4004 in
n) 1101: same with 1101 in
In
a) 200: same with 200 in
b) 2001: same with 2001 in
c) 2002: same with 2002 in
d) 2003: same with 2003 in
e) 2004: same with 2004 in
f) 2005: same with 2005 in
g) 2006: same with 2006 in
h) 2007: same with 2007 in
i) 400: same with 400 in
j) 4001: same with 4001 in
k) 4002: same with 4002 in
l) 4003: same with 4003 in
m) 4004: same with 4004 in
n) 1101: same with 1101 in
In
a) 200: same with 200 in
b) 2001: same with 2001 in
c) 2002: same with 2002 in
d) 2003: same with 2003 in
e) 2004: same with 2004 in
f) 2005: same with 2005 in
g) 2006: same with 2006 in
h) 400: same with 400 in
i) 4001: same with 4001 in
j) 4002: same with 4002 in
k) 4003: same with 4003 in
l) 4004: same with 4004 in
m) 1101: same with 1101 in
In
Explanation of
a) 200: same with 200 in
b) 2001: same with 2001 in
c) 2002: same with 2002 in
d) 2003: same with 2003 in
e) 2004: same with 2004 in
f) 2005: same with 2005 in
g) 2006: same with 2006 in
h) 1501: an electronic Gas Divider.
i) 1502: an electronic Divider Controller.
j) 1503: Proximity Sensor: a non-contacting sensor that can sense the distance of objects and output a signal of corresponding strength.
The force needed for the movement of the Divider Controller cannot be exerted on the Flexible Membrane to trigger the inner pressure change of the Receiving Chamber. In the above-discussed Rod and Rotor example, the Divider Controller needs to have a very smooth contacting surface for the rotation or movement, and the gap in between needs to be small enough not to cause any leak during operation. It's advantageous that the Rod has as many contacting points as possible with the surface of the Flexible Membrane. The more the contacting points, the larger the sum of torque induced. In order to let the Rod maintain the contacting points when the Flexible Membrane extends or changes shape, a belt loop-like structure can be used across the surface of the Flexible Membrane so that the Rod can go through the loops and move freely on the surface of the Flexible Membrane. Alternatively the Rod can be adhered to the surface of the Flexible Membrane. When the Flexible Membrane changes shape, it conveys the amount of shape change to the rod. The torque produced by the summation of the minor force at each close-contact point between the Rod and the Flexible Membrane pushes the Rod and turns the Rotor. The longer the Rod is, the larger the torque is. The larger the area of the Flexible Membrane is, the larger the allowed extension can be, and in turn, the greater the instant volume change can be tolerated.
a) 200: same with 200 in
b) 2001: same with 2001 in
c) 2002: same with 2002 in
d) 2003: same with 2003 in
e) 2004: same with 2004 in
f) 2005: same with 2005 in
g) 2006: same with 2006 in
h) 400: same with 400 in
i) 4001: same with 4001 in
j) 4002: same with 4002 in
k) 4003: same with 4003 in
l) 4004: same with 4004 in
m) 1101: same with 1101 in
a) 200: same with 200 in
b) 2001: same with 2001 in
c) 2002: same with 2002 in
d) 2003: same with 2003 in
e) 2004: same with 2004 in
f) 2005: same with 2005 in
g) 2006: same with 2006 in
h) 400: same with 400 in
i) 4002: same with 4002 in
j) 1101: same with 1101 in
k) 1801 Divider Controller implemented by a Rotor: the rotation of the Rotor triggers a corresponding signal.
l) 1802 Signal Transmitter: transmits signal reflecting the position of the Rotor.
In the case where a Rod is used for the Control Driver, to increase the precision of pressure control, and to better sense the pressure difference between the Receiving Chamber and the Pressure Chamber, we can extend the length of the Rod to increase the pressure control sensitivity. If implemented electronically, we can raise the sensitivity of the component that senses the position of the Flexible Membrane, or use an optical sensor of higher resolution. Moreover, we can enlarge the ratio of the Receiving Chamber volume over the gas inflowing rate. The larger the volume of the Pressure Stabilizer is, the lower the ratio of the inflow gas molecules relative to the Pressure Stabilizer volume is, and the smaller the pressure change is. That is, the larger the Pressure Stabilizer volume, the larger the tolerable bursts of flow rate change. Enlarging the volume of the Pressure Stabilizer usually also means enlarging the area of the Flexible Membrane and its allowed degree of extension, and the Pressure Stabilizer's higher toleration of instant inflow rate change.
The present invention can be used to solve the problems of the aforementioned On-Line Analyzer/Sample Conditioning System example. It can steadily and precisely control the pressure of the Receiving Chamber so that it approximates the particular pressure of the Pressure Chamber. By changing the volume of the Pressure Stabilizer, or by changing the sensibility of the component or mechanical structure that detects the Flexible Membrane extension, the precision can be adjusted to comply with application needs. The present invention can also recycle the gas back to the production pipeline or a recycling tank without exhausting it into the atmosphere. The layout is shown in
a) 201: same with 201 in
b) 202: same with 202 in
c) 203: same with 203 in
d) 401: PPSS, the present invention.
e) 101: High Pressure Recovery Tank.
The present invention can bear the condition of an unstable gas flow or gas pressure in the upstream and unstable pressure of a High Pressure Recovery Tank in the downstream, and still keep the pressure inside the Receiving Chamber stable. It functions as the exhaust and recycler of the On-line Analyzer, and allows the On-line Analyzer to always maintain a stable analyzing condition to achieve the performance
The gas vapor recycling system at gas stations is another area the present invention can be used. The Gas Vapor Hood on the nozzle needs to have a suction volume larger than the escaping gasoline vapor to avoid leaking of gasoline vapor. When gasoline vapor is being vacuumed in, the surrounding air is also drawn in at the same time, causing the opening of the Gas Vapor Hood to have slightly negative pressure. The issues introduced in view of processing and consumer rights are:
a) The recycled gasoline vapor contains oxygen and becomes dangerously explosive.
b) The recycled gasoline vapor contains large amount of air and makes recycling not economical.
c) The suction end of Gas Vapor Hood shows slightly negative pressure, which in turn causes more gasoline to evaporate. This additional evaporated gasoline in turn is carried away by the Gas Vapor Hood. This phenomenon will continue until the gas pumping is stopped. It affects consumer's right directly.
To solve the problem, first we should know that the gasoline vapor introduced when pumping gas into a car comes from the following sources:
a) Gasoline vapor at the environmental temperature of the gas tank. Gasoline vapor pressure is a function of temperature. The environmental temperature determines the vapor pressure.
b) Gasoline vapor caused by drastic disturbance: Gasoline is energized by the pump and bursts out of the nozzle. It is formed because velocity, collision and drastic disturbance cause those gasoline molecules with high energy to escape the surface of the liquid.
c) Pushed-out gasoline vapor: adding gasoline causes the liquid level of the tank to rise and pushes gasoline vapor on the top out of the tank.
The b) and c) factors above cause mass quantity of gasoline vapor escaping the opening of the gas tank and affect the surrounding environment. The present invention can be applied to this situation as
a) 501: Automotive fuel tank.
b) 502: Gas nozzle.
c) 503: Gas Vapor Hood: a vacuuming hood surrounding the gas nozzle. When the nozzle reaches inside the automotive fuel tank, the Gas Vapor Hood will encompass the whole opening of the tank.
d) 401 PPSS: the present invention.
e) 505 Gas Recovery Device: collects recycled gasoline vapor and separates it into liquid gasoline and air.
f) 506 Gas Tank: the underground tank at the gas station.
In this application, we can fill the Pressure Chamber with small amount of gasoline that can exist in both liquid and vapor, and seal the Pressure Pilot opening. Alternatively we can connect Pressure Pilot to a pressure source with the above property so that the pressure in the Pressure Chamber is always the same with the gasoline vapor pressure of the gas tank at the environmental temperature. Before pumping gasoline, the pressure at the gasoline filling point doesn't form a pressure difference with the Receiving Chamber to push gas vapor into the Receiving Chamber. At this point, the Receiving Chamber has zero vapor inflow. The vacuumed-out vapor for recycling is also zero.
After gasoline pumping starts, the additional “gasoline vapor caused by drastic disturbance” and the “pushed-out gasoline vapor” form a pressure that causes the pressure at the gas tank opening to be greater than that in the Receiving Chamber so that gasoline vapor flows towards the Receiving Chamber, and eventually, after being pressurized by the Booster Device, flows to a gas recovery device. The Gas Vapor Hood is designed to encompass the gas tank opening completely, and is connected to the present invention. The layout shown in
Another application of the present invention is the gas supplying system of fuel cells.
a) 601 Hydrogen Gas.
b) 602 Oxygen Gas.
c) 603 Fuel Cell, which uses hydrogen and oxygen at its two electrodes and their electro-chemical reaction for electricity generation.
d) 401 PPSS, the present invention.
e) 604 Gas/Water Separator: a device that separates gas and water.
Fuel cells generate a large amount of heat when generating electricity. The pressure of gas supply at electrodes (proportional to gas reaction density at the electrodes) must be adjusted with the temperature change of the fuel cell so that the fuel cell can achieve the maximum and the most stable performance under continuous temperature change.
Gases that are not fully reacted are discharged. The present invention can collect gas discharged by fuel cells. PPSS causes the gas discharge outlets on both electrodes and the inside of the fuel cell to form a closed system with constant pressure difference, and in turn, precisely and stably controls the reaction pressure of gas supply on both electrodes. The collected gas can be reused after being pressurized and recycled, so that the gas utilization rate can be increased. This raises the throughput of the fuel cells.
PPSS can be widely used in all kinds of devices or applications that need precise pressure control. PPSS can also do without the high-tech precision electronic controls and simply take advantage of material properties and light mechanical structure to precisely control pressure without consuming power. It also can synchronize the mass flow of the discharged gas with the mass flow of the incoming gas. This is a breakthrough in industrial design and can be used in environment protection related applications nowadays when green power is a global concern.
In practice, in order for the user to see the operations of the PPSS, a measurer or sensor of flow, pressure, temperature or any physical or chemical property can be installed in the pipeline where the gas flows into the Pressure Stabilizer, where the gas is drown out of the Pressure Stabilizer, where the gas flows back to Pressure Stabilizer, or where the gas is pumped to High Pressure Recovery Tank. These added components has no effect on pressure stabilization, however they can help the user to view the operational states, and they are also a friendly design of the operation interface.
This application claims the benefit of the U.S. Provisional Patent application No. 61/925,218 entitled “PPS-Proactive Pressure Stabilizer”, filed on Jan. 8, 2014, and US62030671 entitled “PPSS-Proactive Pressure Stabilizing System”, filed on Jul. 30, 2014.
Filing Document | Filing Date | Country | Kind |
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PCT/US2015/010077 | 1/3/2015 | WO | 00 |
Publishing Document | Publishing Date | Country | Kind |
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WO2015/105734 | 7/16/2015 | WO | A |
Number | Name | Date | Kind |
---|---|---|---|
337461 | Truesdell | Mar 1886 | A |
1622151 | Joyce | Mar 1927 | A |
2816561 | Krueger | Dec 1957 | A |
3223116 | Criddle | Dec 1965 | A |
4798521 | Schmidt | Jan 1989 | A |
5239492 | Hartwig | Aug 1993 | A |
5758686 | Ohtsuka | Jun 1998 | A |
6418956 | Bloom | Jul 2002 | B1 |
9110475 | Simpson | Aug 2015 | B2 |
9261086 | Takai | Feb 2016 | B2 |
20080000531 | Robb | Jan 2008 | A1 |
20090107562 | Wang | Apr 2009 | A1 |
20090308337 | Imhof | Dec 2009 | A1 |
20110185772 | Ruthven | Aug 2011 | A1 |
20130014560 | Wei | Jan 2013 | A1 |
Number | Date | Country |
---|---|---|
M331043 | Apr 2008 | TW |
201016297 | May 2010 | TW |
Number | Date | Country | |
---|---|---|---|
20160313746 A1 | Oct 2016 | US |
Number | Date | Country | |
---|---|---|---|
61925218 | Jan 2014 | US | |
62030671 | Jul 2014 | US |