Patent Grant
10300516
This application is a national stage application under 35 U.S.C. 371 and claims the benefit of PCT Application No. PCT/BR2014/000250 having an international filing date of Jul. 23, 2014, which designated the United States, which PCT application claimed the benefit of Brazilian Patent Application No. BR 10 2013 021663 1 filed Aug. 23, 2013, the disclosures of which are incorporated herein by reference.
The present invention relates to a process for producing a multilayer pipe from at least one inner pipe and one outer pipe by means of at least one mechanical forming step. The pipes produced by this method typically have a corrosion-resistant layer, which enables their use in highly corrosive environments.
Multilayer pipes, such as pipes having a metallurgical bond (also known as “clad pipes”) and pipes having a mechanical bond (also known as “lined pipes”), as well as their processes of manufacturing are object of current industrial development, said multilayer pipes being mainly used in the oil industry wherein there may be strong mechanical stress and highly corrosive environments. Sometimes, the internally circulating fluid may also promote a chemical attack to the pipe, requiring the use of corrosion-resistant alloys (CRA).
According to the definition provided in the standards DNV-OS-F101 and API 5LD, a clad pipe consists of an external pipe having a corrosion-resistant inner layer where the bond between these materials is metallurgical. According to the definition provided in the standards DNV OS F101 and API 5LD, a lined pipe consists of an external pipe having a corrosion-resistant inner layer, where the bond between these materials is mechanical. The clad pipes may optionally be manufactured from lined pipes.
The prior art contains several processes for manufacturing clad pipes, generally including a material preparation step, an optional layer step and a cladding step. Two well-known processes used in industrial scale for large production batches are cladding by rolling and overlay welding. In the cladding process by sheet rolling, the sheet rolling of two different materials is made simultaneously, said process originating one single clad sheet. This sheet is then treated, formed and welded longitudinally originating the seam clad pipe.
In the cladding process by overlay welding, the materials are joined by deposition of fillet welds throughout the inner pipe surface. The material used in the fillet weld is normally a corrosion-resistant alloy. The weld deposition process enables a metallurgical bond between the internal and external materials of the seamless clad pipe.
Another process for manufacturing a seamless clad pipe is described in document GB2085330. The clad pipe is formed by at least two metal layers comprising a cold drawing step to obtain a good mechanical bond of the layers, resulting in a lined pipe in which preferably the ends are welded so as to prevent intrusion of air between the pipes. The drawing carried out is thus not sufficient to ensure the quality of the product. A step of hot forming in which the lined pipe is heated, preferably in a furnace is also carried out, and preferably a nickel intermediate layer is disposed to prevent diffusion of carbon. However, this additional layer increases the cost of the product.
The hot forming step disclosed in prior-art document GB2085330 comprises hot pressing or rolling of the outer pipe, but the document does not describe how this hot forming step is performed. Pressing normally requires the manufacture of a special die having fixed pipe-making dimensions. The manufacture of this die and the pressing operation are feasible alternatives only in special applications due to the cost and the impossibility of producing pipes with different sizes.
Document U.S. Pat. No. 3,598,156 discloses a bimetal tubing comprising an intermediate iron or steel layer and two copper layers at the inner and outer surfaces of the pipe. An embodiment of the bimetal tubing contains a cold mechanical expansion step followed by heating between 950° C. and 1050° C. with a high frequency inductor, to obtain the metallurgical bond between the intermediate layer and the outer and inner pipes. The metallurgical bond occurs due to the melting of the intermediate layer; however, no additional pipe forming step is performed. To perform the expansion, a tapered mandrel is used, which is fixed to rod, and the pipe is longitudinally moved along the mandrel, when pulled by the drawing carriage. A second bimetal tubing embodiment exhibits in its manufacturing process a codrawing step followed by heating by electromagnetic induction.
For the bimetal tubing of document U.S. Pat. No. 3,598,156 to be produced in a single cold-forming step, an initial step is required to prepare the material, consisting in galvanizing the intermediate layer, that is, a layer of low-melting point Zn, Pb, Ag, Al needs to be deposited which, when heated, performs a metallurgical bond with the iron or steel pipe without joining the outer and inner layers.
None of the prior-art processes discloses the production of a lined or clad pipe from at least two metal pipes using only one forming step, without the need for additional thermal treatment or forming steps, so as to obtain the multilayer pipe with the desired quality. Similarly, no prior-art reference discloses the production of said multilayer pipes from seamless pipes, and none of the prior art documents discloses a seamless clad pipe.
Thus, the objectives of the present invention are to provide a process for producing multilayer pipes from seamless pipes in a more economical manner, substantially reducing the efforts in the process by expansion, while ensuring the final quality of the multilayer pipes.
The objectives of the invention are achieved by a process for producing a multilayer pipe by expansion, wherein the multilayer pipe comprises at least one external layer made from an outer pipe of metallic material and an internal layer made from an inner pipe of metallic material, the inner pipe having an elastic return smaller than the elastic return of outer pipe when both are deformed, and an external diameter smaller than the internal diameter of the outer pipe; said process comprising:
a mounting step of the pipes, wherein the inner pipe is inserted inside the outer pipe;
at least one mechanical expansion step, comprising providing a relative movement between a mandrel and the mounted pipes in the longitudinal direction, with the mandrel being located internally in the inner pipe, wherein at least part of the mandrel has a greater external diameter than the internal diameter of the inner pipe.
Before the mounting step between the pipes, a chemical preparation step is preferably performed in the following sequence:
acid pickling of at least the inner surface of the inner pipe;
neutralizing and washing of the at least the inner surface of the inner pipe; applying lubricant on the inner surface of the inner pipe.
The step of applying lubricant may comprise applying a reactive oil based lubricant or a combination of oxalate and reactive soap.
Preferably, before the mounting step between the pipes, a shot-blasting step is performed on the inner surface of the outer pipe and on the outer surface of the inner pipe.
Alternatively, after the mounting step between the pipes, a positioning step is carried out, in which the outer and inner pipes mounted together are arranged with one end supported on an expansion die and are secured in relation to the expansion bench.
Alternatively, after the mounting step between pipes, a heating step is performed by induction of the outer and inner pipes, synchronizedly with a mechanical expansion step. In this case, before the step of mounting the pipes, a step of lubrifying at least the inner surface of the inner pipe with a lubricant preferably based on a mixture of water and graphite is performed. The process may comprise after at least one mechanical expansion step, a heating by induction step of the inner and outer pipes, synchronizedly with at least one additional hot mechanical expansion step. Alternatively, in the heating step, an electromagnetic induction coil is disposed externally to the outer and inner pipes and moves longitudinally relative to the outer and inner pipes, synchronizedly with the displacement of the mandrel. Alternatively, in the at least one mechanical expansion step, the mandrel is moved longitudinally and internally in the inner pipe while the outer pipe and the inner pipe are held at a fixed position.
In the heating step, alternatively a heating device is disposed internally to the outer and inner pipes and moves longitudinally relative to the outer and inner pipes together with the rod of the mandrel.
The process may further comprise, after the expansion step, a step of bending the multilayer pipe.
The mandrel preferably has the shape of a truncated cone, whose minimum diameter is smaller than the internal diameter of the inner pipe and the maximum diameter is greater than the internal diameter of the inner pipe, causing an adequate elastic deformation of the external pipe during the extrusion process.
After the mounting step, a step of welding the ends of both pipes together and generating a vacuum between the inner and outer pipes may be performed.
During the mechanical expansion step, a step of applying a flux of an inert gas between the inner and outer pipes may be performed.
The objectives of the invention are also achieved by a multilayer pipe, comprising at least one external layer made from an outer pipe of metallic material and an internal layer made from an inner pipe of metallic material, the inner pipe having an elastic return smaller than the elastic return presented by the outer pipe when both are deformed, and an external diameter smaller than the internal diameter of the outer pipe, the multilayer pipe being produced by the previously described process.
The outer pipe may consist of a carbon manganese steel alloy and the inner pipe may be made of a corrosion-resistant alloy.
The inner pipe may be made of a material comprising at least one of carbon steel, low alloy steel, high alloy steel, stainless steel, nickel base alloy, titanium base alloy, cobalt base alloy, copper base alloy, tin base alloy and zirconium base alloy. The outer and inner pipes are preferably seamless pipes.
The multilayer pipe may comprise at least one intermediate layer of metallic material disposed between the outer and inner pipes. The intermediate layer of metallic material may have a melting point lower than the melting points of the outer and inner pipes. The intermediate layer may comprises nickel (Ni) or zirconium (Zn). Alternatively, the multilayer pipe may comprise a layer of corrosion-resistant alloy disposed externally to the outer pipe formed of a second outer pipe having an internal diameter larger than the external diameter of the underlying pipe. This second outer pipe preferably has a yield strength greater than the yield strength of the underlying outer pipe.
The present invention will be further described in more details based on one example of execution represented in the drawings. The figures show:
As illustrated in
When only cold expansion is performed, the multilayer pipes produced by this process are lined pipes, so that the at least two metal pipes are attached together only by a mechanical bond. When hot expansion is performed, a metallurgical bond is formed between the at least two pipes in at least a portion of their interface.
The multilayer pipe produced by this process may be a clad pipe, when the bonding between the layers forming the multilayer pipe meets the minimum requirements of norms ASTM A578 and API 5LD, that is, any non-clad area on the surface of the pipe may not exceed a diameter of 25 mm inside a scanned area of a 225 by 225 mm square centered on an indication of a discontinuity. Moreover, the pipe should not have any non-clad area within a distance of 100 mm from the pipe end. According to the present invention, the clad pipe may be manufactured by the process according to the invention with up to 100% cladding between the outer pipe 10 and the inner pipe 20.
In the aspect of the invention shown in
The inner pipe 20 has an external diameter smaller than the internal diameter of the outer pipe 10, as may be seen at the bottom of the diagram in
The inner pipe 20 and the outer pipe 10 are preferably seamless, so as to prevent the multilayer pipe produced from having seams on its surface. Thus, the multilayer pipes having at least a cladded part and/or the lined pipes produced by the process according to the invention are also seamless. In alternative embodiments of the invention, the outer pipe 10 may be a seamless pipe, and the inner pipe 20 may be a welded seam pipe. However, other types of seam pipes may be used within the scope of the present invention. The multilayer pipe may also be manufactured from three or more pipes, one being disposed inside the other and subjected to mechanical expansion forming which is described herein.
Then, if needed, the outer pipe 10 and the inner pipe 20 are measured and cut in length, which may vary according to the resources and tools available, such as the length of the rod and the capacity of the expansion bench.
Then, the process according to the invention preferably comprises the steps of chemical preparation 32 of the pipes, which leads to cleaner surfaces and facilitates the expansion step, contributing to a better performance, because they reduce friction between the pipe and the expansion mandrel. Chemical preparation is particularly applied to the inner surface of the inner pipe 20, which will be in contact with the mandrel 2 during expansion. This complete chemical preparation may also be applied to both the internal surface of the inner pipe and the external surface of the outer pipe, since after this step, no protection is required for the pipe surfaces, and it also improves the final quality of the pipe.
Initially, acid pickling of at least the inner surface of the inner pipe 20 is performed to remove oxides and impurities. Preferably, also the surfaces of the interface of the tubes (outer surface of the inner tube and inner surface of the outer tube) are also subjected to acid pickling, in order to achieve better surface quality and better connection between them. However, when the step of acid pickling is performed by submerging the tubes in an acid solution for practical reasons, then both surfaces of both tubes may be subjected to this step.
Then, at least the inner surface of the inner pipe 20 is neutralized and washed to receive a deposit of lubricant. Also for practical reasons, the steps of neutralizing and washing the tubes may be performed on both surfaces of both tubes.
The lubricant is usually applied to the inner surface of the inner pipe. In general, the lubricant may be soap, mineral oils and other lubricants capable of achieving lower friction conditions, depending on the other process variables, such as the force of the expansion carriage 6, deformation applied, geometry of the tools.
According to one embodiment of the invention, an oxalate layer may be applied before the deposition of the lubricant. This oxalate layer reacts with the metal inner surface of the inner pipe, creating the conditions for applying a reactive lubricant on the same, which is responsible for the decreased friction between the expansion tool and the pipe during its passage through the pipe. Thus, other materials may be applied to the pipes at this step, as long as they also provide a good connection between the pipe and the lubricant. When the oxalate layer is applied, preferably the deposited lubricant used is reactive soap. Alternatively, a reactive oil may be used as the lubricant. In this case, usually there is no need to apply oxalate before applying the lubricant. Also according to an advantageous embodiment of the invention, a step of shot-blasting 33 the inner surface 33 of the outer pipe 10 and the outer surface of the inner pipe 20 is performed which will be mechanically connected together by the expansion process. These surfaces are preferably blasted in order to increase their roughness and optimize the contact force between the materials, thus improving the mechanical bonding between the pipes. The shot-blasting is preferably carried out with steel shots, due to the similarity with the material to be blasted and lower cost, but other types of shots may also be used.
The steps of chemical treatment and shot-blasting respectively contribute to facilitate the process for producing pipes and improve the quality of the final product, but are not essential in the process of the invention.
The inner pipe 20 is then inserted inside the outer pipe 10 in a stage of initial mounting 34 between the pipes 10, 20, so that they can be expanded together. This mounting step may be done automatically or manually, in which case the fit between the pipes must provide sufficient clearance.
According to alternative embodiments of the invention, after the pipes are mounted together, the process may comprise additional steps intended to eliminate or minimize the presence of oxygen between the inner and outer pipes, in order to avoid a formation of oxides in this interface, and thereby providing a better connection between the pipes.
One possibility is to weld the ends of both pipes together and to generate a vacuum between the inner and outer pipes. The vacuum may be generated, for example, through a hole and a vacuum pump. Thereby the oxygen would be eliminated from between the pipes.
Another possibility would be to apply a flux of an inert gas between the inner and outer pipes during the cold expansion step or the hot expansion step, but without the need of welding the pipes ends, in order to assure that the gas remaining between them is not oxygen. Then, the outer pipe 10 and the inner pipe 20 mounted together are subjected to at least one mechanical expansion step 36. In this step (both in case of hot and cold expansion, as will be explained below), a relative movement is provided between the mandrel 2 and the mounted pipes in the longitudinal direction, with the mandrel being positioned internally in the inner pipe 20.
In this step, according to one embodiment of the invention, a mandrel 2 is moved longitudinally within the inner pipe 20, while both inner pipe 20 and the outer pipe 10 are held in a fixed position. For the expansion of these pipes, it is necessary that the external diameter of the mandrel 2 is greater than the internal diameter of the inner pipe 10, as illustrated in
The maximum diameter of expansion die opening 4 is smaller than the nominal diameter of the inner pipe 20. Thus, the outer 10 pipe and the inner pipe 20 mounted together have their axial movements restricted, remaining fixed throughout the mechanical expansion step. An expansion die support 5 secures the expansion die 4 to the expansion bench.
The mandrel 2 has a shape of a truncated cone, and its smaller end has a diameter smaller than the internal diameter of the inner pipe. Thus, the smaller end of the mandrel 2 can be inserted into the one end of the assembly of the inner pipe 20 and outer pipe 10, so that the mandrel is then moved longitudinally within the pipes. The larger portion of the mandrel 2 has a diameter greater than the internal diameter of the inner pipe 10, in order to achieve the expansion of the pipes, causing an adequate elastic deformation of the external pipe during the extrusion process. The mechanical expansion step occurs with the passage with interference of mandrel 2 along the length of the inner pipe 20 and the outer pipe 10 mounted together, moving longitudinally with respect to the expansion die support 5. A force of the expansion carriage 6 is applied onto a rod 3 fixed to the mandrel 2, being responsible for this movement. A multilayer pipe 1 is obtained after mechanical expansion. Thus, the mandrel will cause deformation on the wall thickness of the inner pipe, and the expansion of inner pipe will cause deformation on the wall thickness of the outer pipe.
The cold expansion step is preferably performed 1 to 10 times, at a speed varying from 0.2-20.0 m/min and at room temperature. The deformation applied to the inner pipe varies from 0.1-20.0% and the deformation applied to the outer pipe also varies from 0.1-20.0%.
This mechanical expansion step shown in the process of the present invention has the advantage of reducing the effort required by the expansion carriage, since the outer pipe 10 and the inner pipe 20 mounted together remain fixed throughout the process and only rod 3 moves, and the inertia of rod 3 and mandrel 2 is much lower than inertia of the assembly of the outer pipe 10 and the inner pipe 20 or the final multilayer pipe 1. This reduction in effort results in a reduction of energy consumption of the expansion bench and of the process as a whole.
In the stress-strain engineering diagram shown in
The mechanical bond between the outer pipe 10 and the inner pipe 20 constituting the lined pipe 1 according to an example of the product of the invention can be seen in
As can be noticed, the process according to the present invention is capable of producing lined pipes with mechanical bond between the outer pipe and the inner pipe only by cold expansion without the need for heating the pipes. The process of the present invention may comprise more than one step of mechanical expansion, depending on the end product that is desired. Several steps of cold expansion may be carried out, or a combination of cold expansion followed by hot expansion, or only hot expansion.
The embodiment of the invention in which the process carries out the hot expansion of the pipe is shown in
In the cases of hot mechanical expansion, the steps involved in the chemical preparation described above are replaced by a step of applying a lubricant in order to reduce the friction resulting from contact of the tubular element with the expansion die and with the mandrel. The lubricant used is preferably based on a mixture of water and graphite, or any lubricant for high-temperature processes, like the hex-α-BN. This lubricant has the advantage that it does not modify the surface chemical composition of the pipes. The lubricant may be applied by submerging the tube therein, spraying, painting or any other process assuring that a layer of lubricant is formed in the inner surface of the inner tube.
In one embodiment of the invention, heating is carried out by means of an electromagnetic induction coil. The electromagnetic induction coil is disposed externally to the outer pipe 10 and the inner pipe 20 mounted together and moves longitudinally relative to the outer and inner pipes, synchronizedly with the displacement of the mandrel 2, while the pipes are held in a fixed position. If the pipes are fixed on an expansion bench, the coil will move longitudinally also in relation to the expansion die. The mounted pipes enter the coil at ambient temperature, and after being subjected to a magnetic field, are heated by Joule effect (electric current circulating in the steel constituting the pipes) reaching a minimum temperature of 900° C. at the exit of the coil.
Alternatively, in an embodiment not shown in the drawings, the pipes are heated by an internal heating device, which moves inside the pipe with the rod 3 of the mandrel promoting heating from the inner surface of the inner pipe. This internal heating device may also be a coil or another heating device. The internal heating depends on the dinamic heating conditions of the material during the expansion step.
According to another alternative of the invention, the mandrel and the heating device, such as the heating coil, are maintained in a fixed position in series, and the pipes are displaced through them, passing first through the heating device, and then through the mandrel.
At the end of this hot expansion step a clad pipe is obtained, which has a metallurgical bond between the outer pipe 10 and the inner pipe 20, as can be seen in
The hot expansion step is preferably performed 1 to 5 times, at a speed varying from 0.1-5.0 m/min and at a temperature varying from 800-1300° C.
The use of an electromagnetic induction coil for heating of the pipe is advantageous because it allows for rapid and homogenous heating of the pipe by means of dynamic control of the coil power parameters, traction force and speed of the mandrel, which are variable during the process. Furthermore, heating with this coil simultaneously with the expansion step provides higher heating rates than those obtained by other heating means. These high heating rates prevent a possible grain growth, which might occur during a conventional heating if the material is exposed for a long time at high temperatures.
Another advantage of induction heating accomplished in the present invention is that the electromagnetic induction coil is easy to install on the line, and this movable coil eliminates the need for handling hot pipes and moving the equipments, which has a direct impact on safety. Moreover, the induction heating eliminates the need to burn fuel gas for heating the pipes in furnaces, and thus eliminates the need for treating potentially polluting emissions.
In an alternative embodiment of the invention, when hot expansion is performed, the process comprises a step of applying at least one intermediate layer of metallic material to the interface between the outer pipe 10 and the inner pipe 20. This intermediate layer of metallic material may have a melting point lower than the melting point of the metallic materials constituting the outer pipe 10 and the inner pipe 20, but it is not a component necessary to ensure metallurgical bonding between the pipes. The application of the intermediate layer of material must be done before the mounting step between the outer pipe 10 and the inner pipe 20.
The intermediate layer of metallic material may also be formed of a material that has affinity with the metallic materials of the outer pipe 10 and inner pipe 20 in order to avoid the formation of deleterious phases that consequently may weaken the interface between materials. The intermediate layer may consist of nickel (Ni), zirconium (Zn) or other metals or metal alloys. The application of an intermediate layer of the material may be through painting, galvanizing, electroplating, not limited to these application forms.
After hot expansion, a step of bending the multilayer pipe may also be performed, not shown in the drawings. This bending may be performed cold, hot or by folds, not being limited to these methods.
In one embodiment of the manufacturing process, comprising a cold forming step followed by a hot forming step, the cold-formed pipes, called lined pipes, serve as raw material for the manufacture of hot-formed pipes, which are multilayer pipes having at least a cladded part. Obtaining a good mechanical bond during the cold stage helps to ensure a good cladding during the hot forming step.
In alternative embodiments of the invention, when hot expansion is performed, a multilayer pipe of the lined type may be initially used, obtained by other known process for the production of lined pipes. Alternatively, one can carry out only the hot expansion step, without the need for a previous cold forming step.
In the embodiment of the invention in which a cold-forming step is performed followed by a hot-forming step, the process preferably comprises a step of preparing the multilayer pipe carried out after the cold expansion step and before the hot expansion step.
At this stage of preparing the multilayer pipe, the bond between the lined pipe materials may be verified and the multilayer pipe produced by cold expansion may be straightened and the pipe dimensions may be calibrated. The steps of straightening of the pipes and calibration of the pipe dimensions may preferably be performed through cold-co-drawing, which provides a better dimensioning and improves the surface quality of the pipes.
If necessary, a lubricant is applied to the inner surface of the multilayer pipe, which will come again in contact with the mandrel in the additional mechanical expansion step.
When the process of the present invention uses seamless pipes as a raw material for the multilayer pipe, there is no need for a welding process to obtain a pipe, which is usually employed when the pipe is produced from another form of sheet metal. Thus, the multilayer pipes of the present invention preferably are seamless, featuring homogeneous materials in any radial section. However, in principle, the process also applies to longitudinally welded pipes.
The process according to the invention may further comprise heat treatment steps after the hot expansion steps, with the purpose of adjusting material properties. These heat treatment steps depend on the mechanical, metallurgical and corrosion properties of the clad pipe 1 that may need adjustment. Some materials may lose some of their mechanical, metallurgical and corrosion properties during the production steps. These additional thermal treatments may, therefore, be performed, in order to restore the mechanical and metallurgical properties of the pipe, for example, when the pipes 10 and 20 are made of X65 steel and Inconel®. In preferred embodiments of the invention, in the heat treatment step, the multilayer pipe having at least a portion of metallurgical bond is subjected to a cooling or a quenching and tempering step, which contributes to adjusting the mechanical, metallurgical and corrosion properties of the pipe.
The process of the present invention may also comprise a verifying step of the metallurgical bond between the pipes, for confirmation that cladding occurred. The verification may be destructively by cutting a section of the pipe, for example, at intervals of 90° to verify whether in all of these pieces the outer and inner pipes remain attached. Verification can also be non-destructively, through inspection by Ultrassonic testing, analysis of the microstructure, cross sectional analysis of the interface, SEM/EDX or GDOES testing, among others, to check if a metallurgical clad was obtained at least in a part of the pipe produced by the process according to the invention.
The process according to the present invention has a much higher performance when compared with the processes of the prior art, since it does not require any displacement of the pipe or of the inner and outer pipes within the manufacturing installations other than the expansion equipment itself. And in view of the simplicity of the process and the reduced number of steps, it is possible to produce a high amount of lined and/or clad pipes within a small period, with an estimated productivity higher than 100 m/h.
The present invention also relates to the multilayer pipes obtained by the process according to the present invention. The multilayer pipes 1 are manufactured from at least one outer pipe 10 of metallic material and one inner pipe 20 of metallic material, wherein the inner pipe 20 has a smaller elastic return than the elastic return shown by the outer pipe 10 when both are deformed. Since these pipes are usually used in environments related to the oil industry, which are highly corrosive and subjected to strong mechanical stress, the outer pipe 10 is preferably made of metallic material composed of a carbon manganese steel alloy to provide the required mechanical strength to the multilayer pipe. The inner pipe 20 is preferably made of metallic material resistant to corrosion.
According to one embodiment of the invention, the outer pipe 10 may have the following chemical composition:
C≤0.30
Mn≤1.40
P≤0.030
S≤0.030
Cu≤0.5
Cr≤0.5
Ni≤0.5
Mo≤0.15
Nb+V+Ti≤0.15
and the following mechanical properties before and after the process according to the invention (YS=yield strength and UTS=tensile strength):
360 MPa<YS<830 MPa
455 MPa<UTS<935 MPa
minimum elongation εmin=15%.
The corrosion-resistant alloy of the inner pipe comprises at least one of the materials among carbon steel, low alloy steel, high alloy steel, stainless steel, nickel base alloy, titanium base alloy, cobalt base alloy, copper base alloy, tin base alloy and zirconium base alloy, not being limited to the abovementioned materials. The corrosion level of the corrosion-resistant alloys according to the invention are tested in environment levels I-VII of the International Standard NACE MR0175, wherein the precise corrosion level in each case will depend on the internal material thereof.
The selection of the material of the inner pipe 20 and the outer pipe 10 should preferably observe the criterion of the outer pipe having a higher yield strength compared to the inner pipe, said criterion being important to ensure a good mechanical bond.
In an alternative embodiment of the invention, the multilayer pipe comprises at least one intermediate layer of metallic material disposed between the outer pipe 10 and the inner pipe 20, which has a melting point lower than the melting points of the metallic materials constituting the outer pipe 10 and the inner pipe 20 and has affinity for the metallic materials of the outer pipe 10 and the inner pipe 20 to avoid the formation of deleterious phases. This intermediate layer may be applied through painting, galvanizing, electroplating, not being limited to these application forms.
In an alternative embodiment of the invention, the multilayer pipe further comprises a layer of corrosion-resistant alloy disposed externally to the outer pipe. This layer of material resistant to external corrosion consists of a second outer pipe having an internal diameter greater than the external diameter of the underlying pipe 10. Preferably, the layer of material resistant to external corrosion has a yield strength greater than the yield strength of the outer pipe 10. Thus, in the pipe manufacturing process of the present invention, this outer pipe of material resistant to corrosion is also subjected to cold or hot expansion and is attached by a mechanical or metallurgical bond, depending on the expansion performed.
The clad pipe produced according to the invention meets the minimum requirements of norms ASTM A578 and API 5LD as described above, and may achieve up to 100% cladding between the outer pipe 10 and the inner pipe 20.
The dimensions of the multilayer lined or clad pipe produced by the process of the present invention will depend on the application thereof. According to one embodiment of the present invention, the pipes may have an external diameter dext varying from 50.80 mm<dext<355.6 mm, and a wall width WT varying from 5.0 mm<WT<30.0 mm, wherein the minimum wall thickness of the pipe of the corrosion resistant alloy for linepipe applications is WTminCRA=2.50 mm.
The total deformation values of the final pipe when compared to the initially assembled pipes before the production process according to the invention are the following:
External diameter deformation: 0.1 to 20%
Wall thickness deformation: 0.1 to 40%. The process for producing multilayer pipes, object of the present invention, differs from the prior art because it produces lined pipes by mechanical cold-forming in an economical manner, substantially reducing the effort in the expansion process.
The multilayer pipe obtained by the present invention also has the advantage of being a preferably seamless pipe, which gives the product a higher degree of isotropy and less risk of failure in weld sections.
In the production of clad pipes using hot expansion, the present process differs from the prior art for dispensing with the steps of welding, post heating and finishing by pressing, rolling or other methods of mechanical forming aiming to improve the dimensional quality and the mechanical strength of the final product.
The lined or clad pipes obtained by the process according to the present invention have properties that meet international standards for lined and clad pipes. However, the process provides a simpler implementation and reduced cost when compared to other processes of the prior art.
The example described above represents a preferred embodiment; however, it should be understood that the scope of the present invention encompasses other possible variations, and is limited only by the content of the appended claims, which include all possible equivalents.
| Number | Date | Country | Kind |
|---|---|---|---|
| 1020130216631 | Aug 2013 | BR | national |
| Filing Document | Filing Date | Country | Kind |
|---|---|---|---|
| PCT/BR2014/000250 | 7/23/2014 | WO | 00 |
| Publishing Document | Publishing Date | Country | Kind |
|---|---|---|---|
| WO2014/169367 | 10/23/2014 | WO | A |
| Number | Name | Date | Kind |
|---|---|---|---|
| 3126625 | Laing | Mar 1964 | A |
| 3156042 | Reed | Nov 1964 | A |
| 3481762 | Streicher | Dec 1969 | A |
| 3863328 | Arntz | Feb 1975 | A |
| 3983042 | Jain | Sep 1976 | A |
| 5097585 | Klemm | Mar 1992 | A |
| 20070132228 | Montague | Jun 2007 | A1 |
| Number | Date | Country |
|---|---|---|
| 10 2010 04446 | Mar 2012 | DE |
| S61 283415 | Dec 1986 | JP |
| WO 2004103603 | Dec 2004 | WO |
| Entry |
|---|
| English Translation JPS61283415 Mori. |
| International Search Report prepared by the European Patent Office on Oct. 9, 2014, for International Application No. PCT/BR2014/000250. |
| Written Opinion prepared by the European Patent Office on Oct. 9, 2014, for International Application No. PCT/BR2014/000250. |
| Number | Date | Country | |
|---|---|---|---|
| 20160207086 A1 | Jul 2016 | US |
