The invention disclosed and claimed herein below is also described in German Patent Application No. 10 2009 032 684, entitled “A Process for the Production of Glass Tubes Having at least one Tube End Section of Reduced Stress”, which was filed on Jul. 9, 2009 in Germany, the entire content of which is hereby expressly incorporated by reference. The aforesaid German Patent Application provides the basis for a claim of priority of invention for the invention described and claimed herein below under 35 U.S.C. 119 (a) to (d).
1. The Field of the Invention
The present invention relates in general to the improvement of the fracture strength or tensile strength of end sections of glass tubes against mechanical or thermal loads, as they typically occur in the course of further processing at the respective end section, and relates in particular to a process for the production of glass tubes with reduced stress in or at least one tube end, preferably in or at both tube ends, wherein according to a further aspect of the present invention the intention is to create a predetermined stress profile in at least one tube end section.
2. The Description of the Related Art
After being cut or cut to length from a glass tube stream, industrially produced glass tubes have a specific stress curve, such as is illustrated by way of example in
If such a tube end is used directly and without appropriate post-treatment in a glass-to-metal joint, the result due to the steep gradient between tensile stress and compressive stress at the tube end after thermal processing, e.g. on heating with glass solder, is splitting off during the cooling process due to stress induction (also referred to as “ring fracturing” of the tube end.) This leads to the complete destruction of a glass-to-metal joint such as is illustrated by way of example in
In order nevertheless to use glass tubes for glass-to-metal joints the entire glass tube is subjected according to the prior art to what is referred to as precision cooling. For this purpose the entire glass tube passes, after being severed from the glass drawing line and cooling to ambient temperature, into a separate oven in which the entire glass tube is subjected to a controlled heat treatment, i.e. a predetermined heat treatment with precisely defined heating and cooling curve.
There are cooling curves adapted to each type of glass that are supposed to bring about a reduction in the stress. The general doctrine says that for the stress relief of glass a time period of at least 15 min is required between the annealing point at a viscosity n=1013.5 Pa s and the strain point at a viscosity n=1012 Pa s to reduce the stress to such an extent that it is possible to process the glass safely (without breakage). Subsequently, the temperature of the glass item must be decreased at a rate of 2° C./min from the annealing point to the strain point. Such a precision cooling of glass tubes is therefore very time-consuming because several hours are usually needed for heating up and cooling down.
Such a precision cooling is also very costly and usually consumes a lot of energy. An annealing lehr is normally used for cooling glass or for controlling the stresses from the center of the tube towards the end of the tube. For this purpose a glass item or the glass tube is placed into the annealing lehr, passes through a predetermined cooling curve and is then removed from the lehr and packaged.
In addition, the atmosphere in conventional ovens used for precision cooling is relatively dirty with the result that the glass tubes have to be laboriously cleaned after the precision cooling, for instance if they have to be coated for a subsequent use.
One way out in order to eliminate these problems is to cut off and discard the respective tube end sections after cooling down completely to ambient temperature. However, this reduces efficiency and increases the costs of glass tube production.
U.S. Pat. No. 2,166,871 A describes a process in which a glass gob is continuously severed, in a heat-softened state, from a glass tube line (glass drawing line) and subsequently formed. Viscosities or temperatures around the working point at a viscosity n=104 Pa s are required for this purpose. The glass gob thus produced is subsequently subjected to a heat treatment that is not described in greater detail.
GB 826,270A discloses a process for severing glass tubes that is primarily used for large glass tube diameters. The glass tube, after local heating using burners, is heated until melted off by applying a very high electric voltage. Due to this very rapid local overheating, the severed glass tube must be heated up immediately after being severed to prevent stress cracks (“runners”) induced by the high temperature difference. For this purpose the still heated glass tube is placed on a transport means which moves the glass tube past heating devices provided laterally. However, in this case there is no passage through a heating region with a predetermined temperature profile, which extends in the longitudinal direction of the glass tube and in which the temperature of the glass tube is selectively and locally increased depending on a distance to the respective tube end.
It is an object of the present invention is to provide a simple and efficient process for producing glass tubes by which glass tubes with reduced stress in at least one tube end section can be produced. According to a further preferred aspect of the present invention, the intention is to induce a predetermined stress profile with reduced stress overall in at least one end of a glass tube.
In a process according to the present invention the glass tube is severed or cut from a glass tube line (hereinafter also glass drawing line) with a predetermined length in a still heated condition (while still being at a temperature well above room temperature), normally at a relatively high temperature, and is subsequently transported through a heating region that extends in the longitudinal direction of the glass tube and in which at least one tube end section, preferably both tube end sections, but not the entire glass tube, is/are subjected to a selective local heat treatment that is designed so that the stresses in the respective tube end section can be reduced suitably, in particular by adaptation to the desired application in each case. This local heat treatment that according to the invention relates preferably only and exclusively to the region of the transformation range (glass transition temperature) Tg [° C.] or to viscosities of approximately n=1013 dPa s to approximately n=1014.5 dPa s (annealing point/strain point) after the production of a tube and being severed from the glass stream, may be carried out relatively quickly with respect to time. Test series of the inventor have shown that a local heat treatment lasting only a few minutes, sometimes considerably less than 2 minutes in length, is basically adequate to sufficiently reduce the stresses. According to the invention it is no longer necessary to adhere to a temperature gradient of 2° C./min for cooling down from the upper temperature to the strain point. As a result it is possible to reduce the energy expenditure and time expenditure considerably by comparison with precision cooling.
The process according to the present invention thus avoids the time-consuming and costly precision cooling, which is necessary in conventional processes according to the prior art, by a selective local heat treatment of the at least one tube end section in the heating region, wherein the stress profile, which results at the end regions of the symmetric glass body (e.g. tube, rod et cetera) in the course of its production, is selectively varied by means of the local heat treatment.
Moreover, according to the invention, additional expenditure for interim storage of glass tubes that have already cooled is also unnecessary. Elaborate test series of the inventor have also shown that contaminations of the glass tubes due to the atmosphere in the precision cooling oven can be significantly reduced according to the process according to the invention with the result that it is basically possible to dispense with further laborious cleaning of the glass tube surface prior to any subsequent use, e.g. for coating.
According to the invention, in particular it is no longer necessary to subject the entire glass tube to a controlled cooling process using an annealing lehr or similar. Rather a selective and specific local heat treatment of only the respective tube end sections is perfectly adequate for subsequent processing.
For this purpose the selective local heat treatment preferably may start at the interface between tensile stress and compressive stress or in their immediate vicinity, that is at the or close to the first passage through zero of the stress curve of an untreated glass tube according to
According to a further embodiment, the glass tube when cut to size is transported further in a predetermined direction that is different from the direction in which the glass tube line is drawn from the upstream glass tube production plant, for example at right angles thereto, whereby the respective tube end section passes through a predetermined temperature profile for local heat treatment. This temperature profile can be varied locally and/or with respect to time during the local heat treatment in the longitudinal direction of the glass tube.
According to a preferred embodiment, the local temperature profile at the tube ends, when viewed in the longitudinal direction of the glass tube, includes a temperature maximum with a predetermined drop in temperature on both sides of the temperature maximum such that the temperature profile is usually symmetrical. The resulting temperature profile at the end of the heating path is produced by the local shift in the maxima due to moving the glass tube along the heating device.
According to further embodiments, it is possible however, when viewed in the longitudinal direction of the glass tube, also to provide two or a plurality of such temperature maxima. Such a temperature maximum may be implemented in a simple manner by a heating device that is disposed in the glass tube transport path at a predetermined distance from the respective glass tube end and at a predetermined distance from the surface of the glass tube, for example by means of one or a plurality of elongated gas burners, in particular a gas flame burner, or also by means of one or a plurality of electrical resistance heaters. A variation of the temperature profile with respect to time may be implemented in a simple manner by varying the energy supply to such a heating device.
According to a further embodiment, the temperature of the glass tube after being cut to length from the glass tube line up to passing through the predetermined temperature profile referred to previously does not fall below 200° C., preferably not below 300° C. which means that the energy expenditure for heating the tube ends can be further minimized.
For varying the temperature profile in the longitudinal direction of the glass tube with respect to time, it is possible according to a further embodiment to arrange a plurality of heating devices, viewed in the glass tube's direction of transport, i.e. preferably perpendicular or virtually perpendicular to the longitudinal direction of the glass tube, distributed along a curve at predetermined distances (spacings) from one another. Here the distance of the curve to the respective tube end viewed in the direction of transport may decrease continuously or alternatively, according to a less preferred embodiment, may basically also increase whereby the curve intersects the direction of glass tube transport at an acute angle in at least one place. The plurality of heating devices ensures local temperature maxima at various positions when viewed in the longitudinal direction of the glass tube. Since the glass tube is transported in a predetermined direction during the heat treatment, the respective temperature maximum thus passes continuously through the respective tube end section, when viewed in the longitudinal direction of the glass tube, and a resulting temperature profile arises together with cooling down which begins at the starting point. It is thus possible to influence the stress profile even more specifically. With sufficiently high temperatures at the tube end, this can still be used for fusing the cut edge (known as glazing).
Preferably, the curve is a straight line along which the heating devices are distributed at uniform distances (spacings) from one another, in which case the temperature maximum builds up at constant transport speed with constant speed in the longitudinal direction of the glass tube. Basically, however, different distances may also be provided between the individual heating devices or groups of heating devices.
The curve extends here in the longitudinal direction of the glass tube, preferably across a respective heating region in which the stresses are supposed to be decreased in a predetermined manner by means of the selective (specific) local heat treatment. As explained above, this heating region includes at least the stress curve's first passage through zero according to
According to a further embodiment, the respective heating region at the at least one tube end section is shielded against the outside environment so that external influences, for example temperature changes or air flows, have no effect on the specific local heat treatment at the respective tube end section. For this purpose, the heating region may, for example, be formed as a box-shaped heating region that is shielded against the outside environment by appropriate walls, for example of a refractory material, for the purposes of insulation. When using individual gas burners or gas-heated burner strips, it is expedient to arrange the heating devices underneath the glass tube, thus the respective tube end section is locally heat-treated by the heat rising from the heating devices. The heat rising out of a heating region shielded in such a manner advisably discharges through an exhaust vent or similar which is formed above the glass tube. The heat from the respective heating region can be discharged through it so that the temperature conditions, in particular the temperature profile, may also be varied appropriately with respect to time in the respective heating regions. At the same time, the vent's cross-section may also be varied appropriately, for example to vary time constants for changing the temperature conditions.
According to a further embodiment, the glass tube is rotated at least in the region of the respective heating device at a predetermined angular speed that is preferably steady in order to ensure an even more uniform local heat treatment around the circumference of the tube.
According to a further embodiment, slipping of the glass tube in its longitudinal direction on transport during the selective local heat treatment is prevented, that is the position of the respective tube end, when viewed in the longitudinal direction of the glass tube, does not vary. Therefore the temperature profile may be specified even more accurately. Furthermore this prevents variations from tube to tube. For this purpose, the transport device for transporting the glass tube in the predetermined direction may have appropriate limiting means, limit stops for example, or an active open-loop or closed-loop control may be provided to fix the glass tube's position.
Elaborate test series of the inventor have also shown in particular that subsequent precision cooling or severing of the tube end is not necessary if it is possible to reduce the tensile stress in the respective tube end section, particularly in the region between 7 and 20 mm distant from the respective tube end, to below 4.5 MPa which can be achieved by appropriate selection of the temperature conditions during the selective (specific) local heat treatment.
According to a further aspect of the present invention, a predetermined stress profile is induced in the respective tube end section. For this purpose, the stress profile of a glass tube produced previously is measured using a suitable measuring apparatus and the parameters of the local heat treatment, in particular the temperature profile and its time-related and/or local variation, is selectively modified, that is to say controlled (open or closed loop), in such a manner that the desired predetermined stress profile can be achieved for glass tubes that are locally heat-treated with the appropriately modified temperature conditions.
Preferably, the glass tube produced according to the present invention is used for glass-to-metal joints, in particular for those in which a glass solder is used for joining a tube end to a metal end cap, or also for applications of glass tubes in photovoltaics, for example for elongated photovoltaic cells such as are described for example in US 2007/0215195 A1, the contents of which are explicitly incorporated herein by way of reference for the purposes of disclosure.
The invention will be described in the following in an exemplary manner and with reference to the associated drawing, from which will ensue further features, advantages and objects to be achieved, in which:
a is a stress profile at the end of a glass tube after being severed from the glass tube line, the glass tube being produced using a conventional production process without subsequent heat treatment;
b is a stress profile of a glass tube that has been subjected to subsequent precision cooling according to the prior art;
a is a glass tube end section in a glass tube that is produced using a process according to the invention;
b is a glass-to-metal joint for the glass tube according to
Identical reference numerals in the figures indicate identical elements or element groups or those having substantially the same technical effect.
In a process according to the invention, the glass tube after being cut to size from a glass drawing line is subsequently stress-relieved on its ends in a post-processing line. For this purpose, a selective local heat treatment is carried out at a respective end of the glass tube. According to
According to
The straight line 12 at least sweeps the region, when viewed in the longitudinal direction of the glass tube, in which the passage through zero of the stress profile of a still untreated glass tube would lie (cf.
Heating devices 13 are disposed underneath glass tubes 1 and transport device 11 so that the heat generated by them escapes upwards. Heating region L2 is preferably shielded and insulated against the outside environment by a housing of an appropriate refractory material (not illustrated), wherein one or a plurality of exhaust vents is provided above glass tube 1 in such a manner that the heat given off by heating devices 13 can escape upwards. Heating devices 13 may be long flame burners or burner strips that can deliver their heat to the end of the glass tube locally in a limited manner. These burners emit a long and relatively narrow (only a few millimeters wide) flame front which enables a very high local energy density. The long flame burners are disposed at a predetermined angle to direction of motion v. This reduces the risk of a local overheating. Basically, it is also possible to use gas burners with a porous combustion chamber, such as are disclosed for example in German patent application DE 10 2006 017 354 A1 of the applicant, the content of which is expressly incorporated in the present application by way of reference. Alternatively, it is also basically possible to use electric heating devices that are mounted above and/or below.
Heating devices 13 may be supplied with different amounts of energy to achieve a desired temperature or stress profile. For this purpose, an appropriate control device 18 is provided that can, for example, control or regulate the respective gas supply to the gas burners. The rate of motion can also be varied in direction v for specifying the desired temperature or stress profile for which purpose an appropriate open-loop or closed-loop control 17 that can also control or regulate individual transport devices (not shown) is assigned to transport device 11.
During the process, the glass tubes fixed on the post-processing line are moved, whilst rotating evenly, through the heating zone generated by the burners. By stopping the movement, glass tube 1 is prevented from slipping on the post-processing line and thus resulting in the whole tube end being heated. The rotation of glass tube 1 ensures even heating on all sides.
According to
a shows a further embodiment for a glass tube that is produced in accordance with a process according to the present invention. In region L1, i.e. approximately 2 to 10 mm away from the respective end of the tube, the compressive strength ranges between approximately 6 and 15 MPa. In region L2, i.e. in the region approximately 7 to 20 mm away from the respective end of the tube, the respective tensile stress is reduced to approximately 4.5 MPa. The position of the above-mentioned passage through zero of the stress is exemplary and in particular dependent on the tube diameter.
Glass tubes produced in such a way may be used according to the invention for glass-to-metal joints, as these are illustrated by way of example in
Such glass-to-metal joints are required in particular for applications of glass tubes in photovoltaics, such as are disclosed by way of example in US 2007/0215195 A1, the entire content of which is expressly incorporated in the present application by way of reference.
Although it was explained above that the tensile stress at or in the respective glass tube end section is reduced below 6.0 MPa, more preferably below 4.5 MPa, in particular within the afore-mentioned region at a distance between 7 millimeters and 20 millimeters away from the respective tube end, the value of the tensile stress and/or the aforementioned distance can in general also depend on the wall thickness or on the outer diameter of the glass tube so that the present invention most preferably is not delimited at all to the afore-mentioned specific parameter ranges or values. Instead, these parameter ranges or values are based on typical glass tube dimensions as they are typically employed for forming a glass-to-metal-joint for applications in photovoltaics or the exploitation of solar thermal energy.
As will become apparent to a person skilled in the art when studying the foregoing, although it was explained above that the selective local heat treatment is carried out at both ends of a glass tube in a similar manner, it may also basically be sufficient to carry out such a local heat treatment at only one end of a glass tube. The local heat treatments at both ends of the glass tube also need not be carried out identically; rather it is also possible to use different parameters for the local heat treatment. The local heat treatment at both ends of the glass tube also need not be carried out simultaneously but may also be carried out after one another locally and in respect of time.
While the invention has been illustrated and described as embodied in a process for production of glass tubes having at least one tube end section of reduced stress, it is not intended to be limited to the details shown, since various modifications and changes may be made without departing in any way from the spirit of the present invention.
Without further analysis, the foregoing will so fully reveal the gist of the present invention that others can, by applying current knowledge, readily adapt it for various applications without omitting features that, from the standpoint of prior art, fairly constitute essential characteristics of the generic or specific aspects of this invention.
What is claimed is new and is set forth in the following appended claims.
Number | Date | Country | Kind |
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10 2009 032 684.7 | Jul 2009 | DE | national |