Patent Application
20190186825
This specification relates to operating industrial facilities, for example, hydrocarbon refining facilities or other industrial facilities that include operating plants that process natural gas or recover natural gas liquids.
Petroleum refining processes are chemical engineering processes used in petroleum refineries to transform raw hydrocarbons into various products, such as liquid petroleum gas (LPG), gasoline, kerosene, jet fuel, diesel oils, and fuel oils. Petroleum refineries are large industrial complexes that can include several different processing units and auxiliary facilities, such as utility units, storage tank farms, and flares. Each refinery can have its own unique arrangement and combination of refining processes, which can be determined, for example, by the refinery location, desired products, or economic considerations. The petroleum refining processes that are implemented to transform the raw hydrocarbons into products can require heating and cooling. Various process streams can exchange heat with a utility stream, such as steam, a refrigerant, or cooling water, in order to heat up, vaporize, condense, or cool down. Process integration is a technique for designing a process that can be utilized to reduce energy consumption and increase heat recovery. Increasing energy efficiency can potentially reduce utility usage and operating costs of chemical engineering processes.
This document describes technologies relating to process integration of natural gas liquid recovery systems and associated refrigeration systems.
This document includes one or more of the following units of measure with their corresponding abbreviations, as shown in Table 1:
Certain aspects of the subject matter described here can be implemented as a natural gas liquid recovery system. The natural gas liquid recovery system includes a cold box and a refrigeration system configured to receive heat through the cold box. The cold box includes a plate-fin heat exchanger including compartments. The cold box is configured to transfer heat from hot fluids in the natural gas liquid recovery system to cold fluids in the natural gas liquid recovery system. The refrigeration system includes a primary refrigerant including a first mixture of hydrocarbons. The refrigeration system includes a low pressure (LP) refrigerant separator in fluid communication with the cold box. The LP refrigerant separator is configured to receive a first portion of the primary refrigerant and configured to separate phases of the first portion of the primary refrigerant into a LP primary refrigerant liquid phase and a LP primary refrigerant vapor phase. The LP refrigerant separator is configured to provide at least a portion of the LP primary refrigerant liquid phase to the cold box. The refrigeration system includes a high pressure (HP) refrigerant separator in fluid communication with the cold box. The HP refrigerant separator is configured to receive a second portion of the primary refrigerant and configured to separate phases of the second portion of the primary refrigerant into a HP primary refrigerant liquid phase and a HP primary refrigerant vapor phase. The HP refrigerant separator is configured to provide at least a portion of the HP primary refrigerant liquid phase to the cold box. The refrigeration system includes a subcooler configured to transfer heat between the first portion of the primary refrigerant and the LP primary refrigerant vapor phase.
This, and other aspects, can include one or more of the following features.
The hot fluids can include a feed gas to the natural gas liquid recovery system. The feed gas can include a second mixture of hydrocarbons.
The primary refrigerant can include a mixture on a mole fraction basis of 61% to 69% of C3 hydrocarbon and 31% to 39% C4 hydrocarbon.
The natural gas liquid recovery system can be configured to produce a sales gas and a natural gas liquid from the feed gas. The sales gas can include at least 98.6 mol % of methane. The natural gas liquid can include at least 99.5 mol % of hydrocarbons heavier than methane.
The natural gas liquid recovery system can include a feed pump configured to send a hydrocarbon liquid to the de-methanizer column. The natural gas liquid recovery system can include a natural gas liquid pump configured to send natural gas liquid from the de-methanizer column. The natural gas liquid recovery system can include a storage system configured to hold an amount of natural gas liquid from the de-methanizer column.
The natural gas liquid recovery system can include a chill down train configured to condense at least a portion of the feed gas in at least compartment of the cold box. The chill down train can include a separator in fluid communication with the cold box. The separator can be positioned downstream of the cold box. The separator can be configured to separate the feed gas into a liquid phase and a refined gas phase.
The natural gas liquid recovery system can include a gas dehydrator positioned downstream of the chill down train. The gas dehydrator can be configured to remove water from the refined gas phase.
The gas dehydrator can include a molecular sieve.
The natural gas liquid recovery system can include a liquid dehydrator positioned downstream of the chill down train. The liquid dehydrator can be configured to remove water from the liquid phase.
The liquid dehydrator can include a bed of activated alumina.
Certain aspects of the subject matter described here can be implemented as a method for recovering natural gas liquid from a feed gas. Heat is transferred from hot fluids to cold fluids through a cold box. The cold box includes a plate-fin heat exchanger including compartments. Heat is transferred to a refrigeration system through the cold box. The refrigeration system includes a primary refrigerant comprising a first mixture of hydrocarbons, a low pressure (LP) refrigerant separator in fluid communication with the cold box, a high pressure (HP) refrigerant separator in fluid communication with the cold box, and a subcooler. A first portion of the primary refrigerant is flowed to the LP refrigerant separator. The first portion of the primary refrigerant is separated into a LP primary refrigerant liquid phase and a LP primary refrigerant vapor phase using the LP refrigerant separator. Heat is transferred from the first portion of the primary refrigerant to the LP primary refrigerant vapor phase using the subcooler. At least a portion of the LP primary refrigerant liquid phase is flowed to the cold box. A second portion of the primary refrigerant is flowed to the HP refrigerant separator. The second portion of the primary refrigerant is separated into a HP primary refrigerant liquid phase and a HP primary refrigerant vapor phase using the HP refrigerant separator. At least a portion of the HP primary refrigerant liquid phase is flowed to the cold box. At least one hydrocarbon stream originating from the feed gas is flowed to a de-methanizer column in fluid communication with the cold box. The at least one hydrocarbon stream is separated into a vapor stream and a liquid stream using the de-methanizer column. The vapor stream includes a sales gas including predominantly of methane. The liquid stream includes a natural gas liquid including predominantly of hydrocarbons heavier than methane. A gas stream is expanded through a turbo-expander in fluid communication with the de-methanizer column to produce expansion work. The expansion work is used to compress the sales gas from the de-methanizer column.
This, and other aspects, can include one or more of the following features.
The hot fluids can include the feed gas including a second mixture of hydrocarbons.
The primary refrigerant can include a mixture on a mole fraction basis of 61% to 69% of C3 hydrocarbon and 31% to 39% C4 hydrocarbon.
The sales gas including predominantly of methane can include at least 98.6 mol % of methane. The natural gas liquid including predominantly of hydrocarbons heavier than methane can include at least 99.5 mol % of hydrocarbons heavier than methane.
A hydrocarbon liquid can be sent to the de-methanizer column using a feed pump. Natural gas liquid can be sent from the de-methanizer column using a natural gas liquid pump. An amount of natural gas liquid from the de-methanizer column can be stored in a storage system.
A fluid can be flowed from the cold box to a separator of a chill down train.
At least a portion of the feed gas can be condensed in at least one compartment of the cold box. The feed gas can be separated into a liquid phase and a refined gas phase using the separator.
Water can be removed from the refined gas phase using a gas dehydrator including a molecular sieve.
Water can be removed from the liquid phase using a liquid dehydrator including a bed of activated alumina.
Certain aspects of the subject matter described here can be implemented as a system. The system includes a cold box including compartments. Each of the compartments includes one or more thermal passes. The system includes one or more hot process streams. Each of the one or more hot process streams flow through one or more of the compartments. The system includes one or more cold process streams. Each of the one or more cold process streams flow through one or more of the compartments. The system includes one or more hot refrigerant streams. Each of the one or more hot refrigerant streams flow through one or more of the compartments. The system includes one or more cold refrigerant streams. Each of the one or more cold refrigerant streams flow through one or more of the compartments. In each of the one or more thermal passes of each of the compartments, one of the one or more hot process streams transfers heat to at least one of the one or more cold process streams or the one or more cold refrigerant streams. One of the one or more cold refrigerant streams is the only stream that flows through only one of the compartments. For each of the compartments, a number of potential passes is equal to a product of A) a total number of hot process streams and hot refrigerant streams flowing through the respective compartment and B) a total number of cold process streams and cold refrigerant streams flowing through the respective compartment. For at least one of the compartments, a number of thermal passes is less than the number of potential passes of the respective compartment.
This, and other aspects, can include one or more of the following features.
The one or more cold refrigerant streams can include a first cold refrigerant stream and a second cold refrigerant stream. The first cold refrigerant stream, the second cold refrigerant stream, and the one or more hot refrigerant streams can have compositions different from each other.
At least one of the one or more hot refrigerant streams can transfer heat to the first cold refrigerant stream.
A total number of compartments can be 16. A total number of thermal passes of the plurality of compartments of the cold box can be 46. A total number of potential passes of the plurality of compartments of the cold box can be 63.
For seven of the plurality of compartments, the number of thermal passes can be less than the number of potential passes of the respective compartment.
For at least one of the seven compartments, the number of thermal passes can be at least one fewer than the number of potential passes of the respective compartment.
For at least one of the seven compartments, the number of thermal passes can be at least two fewer than the number of potential passes of the respective compartment.
At least one of the compartments having the number of thermal passes that is at least one fewer than the number of potential passes of the respective compartment can be adjacent to one of the compartments having the number of thermal passes that is at least two fewer than the number of potential passes of the respective compartment. All of the cold process streams and cold refrigerant streams that flow through one of the adjacent compartments can also flow through the other of the adjacent compartments.
For at least one of the seven compartments, the number of thermal passes can be at least four fewer than the number of potential passes of the respective compartment.
At least one of the compartments having the number of thermal passes that is at least two fewer than the number of potential passes of the respective compartment can be adjacent to one of the compartments having the number of thermal passes that is at least four fewer than the number of potential passes of the respective compartment.
All of the hot process streams and cold refrigerant streams that flow through one of the adjacent compartments can also flow through the other of the adjacent compartments.
All of the cold process streams and cold refrigerant streams that flow through one of the adjacent compartments can also flow through the other of the adjacent compartments.
All of the hot process streams, cold process streams, and cold refrigerant streams that flow through one of the adjacent compartments can also flow through the other of the adjacent compartments.
All of the hot process streams, hot refrigerant streams, and cold refrigerant streams that flow through one of the adjacent compartments can also flow through the other of the adjacent compartments.
The details of one or more implementations of the subject matter described in this specification are set forth in the accompanying drawings and the detailed description. Other features, aspects, and advantages of the subject matter will become apparent from the description, the drawings, and the claims.
NGL Recovery System
Gas processing plants can purify raw natural gas or crude oil production associated gases (or both) by removing common contaminants such as water, carbon dioxide, and hydrogen sulfide. Some of the contaminants have economic value and can be processed, sold, or both. Once the contaminants have been removed, the natural gas (or feed gas) can be cooled, compressed, and fractionated in the liquid recovery and sales gas compression section of a gas processing plant. Upon the separation of methane gas, which is useful as sales gas for houses and power generation, the remaining hydrocarbon mixture in liquid phase is called natural gas liquids (NGL). The NGL can be fractionated in a separate plant or sometimes in the same gas processing plant into ethane, propane and heavier hydrocarbons for several versatile uses in chemical and petrochemical processes as well as transportation industries.
The liquid recovery section of a gas processing plant includes one or more chill-down trains—three, for example—to cool and dehydrate the feed gas and a de-methanizer column to separate the methane gas from the heavier hydrocarbons in the feed gas such as ethane, propane, and butane. The liquid recovery section can optionally include a turbo-expander. The residue gas from the liquid recovery section includes the separated methane gas from the de-methanizer and is the final, purified sales gas which is pipelined to the market.
The liquid recovery process can be heavily heat integrated in order to achieve a desired energy efficiency associated with the system. Heat integration can be achieved by matching relatively hot streams to relatively cold streams in the process in order to recover available heat from the process. The transfer of heat can be achieved in individual heat exchangers—shell-and-tube, for example—located in several areas of the liquid recovery section of the gas processing plant, or in a cold box, where multiple relatively hot streams provide heat to multiple relatively cold streams in a single unit.
In some implementations, the liquid recovery system can include a cold box, a first chill down separator, a second chill down separator, a third chill down separator, a feed gas dehydrator, a liquid dehydrator feed pump, a de-methanizer feed coalescer, a liquid dehydrator, a de-methanizer, and a de-methanizer bottom pump. The liquid recovery system can optionally include a de-methanizer reboiler pump.
The first chill down separator is a vessel that can operate as a 3-phase separator to separate the feed gas into water, liquid hydrocarbon, and vapor hydrocarbon streams. The second chill down separator and third chill down separator are vessels that can separate feed gas into liquid and vapor phases. The feed gas dehydrator is a vessel and can include internals to remove water from the feed gas. In some implementations, the feed gas dehydrator includes a molecular sieve bed. The liquid dehydrator feed pump can pressurize the liquid hydrocarbon stream from the first chill down separator and can send fluid to the de-methanizer feed coalescer, which is a vessel that can remove entrained water carried over in the liquid hydrocarbon stream past the first chill down separator. The liquid dehydrator is a vessel and can include internals to remove any remaining water in the liquid hydrocarbon stream. In some implementations, the liquid dehydrator includes a bed of activated alumina. The de-methanizer is a vessel and can include internal components, for example, trays or packing, and can effectively serve as a distillation tower to boil off methane gas. The de-methanizer bottom pump can pressurize the liquid from the bottom of the de-methanizer and can send fluid to storage, for example, tanks or spheres. The de-methanizer reboiler pump can pressurize the liquid from the bottom of the de-methanizer and can send fluid to a heat source, for example, a typical heat exchanger or a cold box.
Liquid recovery systems can optionally include auxiliary and variant equipment such as additional heat exchangers and vessels. The transport of vapor, liquid, and vapor-liquid mixtures within, to, and from the liquid recovery system can be achieved using various piping, pump, and valve configurations. In this disclosure, “approximately” means a deviation or allowance of up to 10%, and any variation from a mentioned value is within the tolerance limits of any machinery used to manufacture the part.
Cold Box
A cold box is a multi-stream, plate-fin heat exchanger. For example, in some aspects, a cold box is a plate-fin heat exchanger with multiple (for example, more than two) inlets and a corresponding number of multiple (for example, more than two) outlets. Each inlet receives a flow of a fluid (for example, a liquid) and each outlet outputs a flow of a fluid (for example, a liquid). Plate-fin heat exchangers utilize plates and finned chambers to transfer heat between fluids. The fins of such heat exchangers can increase the surface area to volume ratio, thereby increasing effective heat transfer area. Plate-fin heat exchangers can therefore be relatively compact in comparison to other typical heat exchangers that exchange heat between two or more fluid flows (for example, shell-and-tube).
A plate-fin cold box can include multiple compartments that segment the exchanger into multiple sections. Fluid streams can enter and exit the cold box, traversing the cold box through the one or more compartments that together make up the cold box.
In traversing a particular compartment, one or more hot fluids traversing the compartment communicates heat to one or more cold streams traversing the compartment, thereby “passing” heat from the hot fluid(s) to the cold fluid(s). In the context of this disclosure, a “pass” refers to the transfer of heat from a hot stream to a cold stream within a compartment. One may think of the total amount of heat passing from a particular hot stream to a particular cold stream as a singular “thermal pass”. Although the configuration of any given compartment may have one or more “physical passes”, that is, a number of times the fluid physically traverses the compartment from a first end (where the fluid enters the compartment) to another end (where the fluid exits the compartment) to effect the “thermal pass”, the physical configuration of the compartment is not the focus of this disclosure.
Each cold box and each compartment within the cold box can include one or more thermal passes. Each compartment can be viewed as its own individual heat exchanger with the series of compartments in fluid communication with one another making up the totality of the cold box. Therefore, the number of heat exchanges for the cold box is the sum of the number of thermal passes that occur in each compartment. The number of thermal passes in each compartment potentially is the product of the number of hot fluids entering and exiting the compartment times the number of cold fluids entering and exiting the compartment.
A simple version of a cold box can serve an example for determining the number of potential passes for a cold box. For example, a cold box comprising three compartments has two hot fluids (hot 1 and hot 2) and three cold fluids (cold 1, cold 2, and cold 3) entering and exiting the cold box. Hot 1 and cold 1 traverse the cold box between the first compartment and the third compartment, hot 2 and cold 2 traverse the cold box between the second and third compartment, and cold 3 traverses the cold box between the first and second compartment. Using this example, the first compartment has two thermal passes: hot 1 passes thermal energy to cold 1 and cold 3; the second compartment has six passes: hot 1 passes heat to cold 1, cold 2, and cold 3, and hot 2 also passes heat to cold 1, cold 2, and cold 3; and the third compartment has four passes: hot 1 passes heat to cold 1 and cold 2, and hot 2 also passes heat to cold 1 and cold 2. Therefore, on a compartment basis, the number of thermal passes that can be present in the example cold box is the sum of the individual products of each compartment (2, 6 and 4), or 12 thermal passes. This is the maximum number of thermal passes that can be present in the example cold box based upon its configuration of entries and exits from the various compartments. The determination assumes that all the hot streams and all the cold streams in each compartment are in thermal communication with each other.
In some implementations of the systems, methods, and cold boxes, the number of thermal passes is equal to or less than the maximum number of potential passes for a cold box. In some such instances, a hot stream and a cold stream may traverse a compartment (and therefore be counted as a potential pass using the compartment basis method); however, heat from the hot stream is not transferred to the cold stream. In such an instance, the number of thermal passes for such a compartment would be less than the number of potential passes. As well, the number of thermal passes for such a cold box would be less than the number of potential passes.
Using the prior example but with a modification, this can be demonstrated. With the stipulation to the example cold box that there is a mitigation technique or device that inhibits the transfer of thermal energy in the second compartment from hot 2 to cold 2, the number of thermal passes for second compartment is no longer six; it is now five. With such a reduction, the total thermal passes for the cold box is now eleven, not twelve, as previously determined.
In some implementations, a compartment may have fewer thermal passes than the number of potential passes. In some implementations, the number of thermal passes in a compartment may be fewer than the number of potential passes by one, two, three, four, five, or more. In some implementations, the number of thermal passes in a cold box may have fewer than the number of potential passes for the cold box.
The cold box can be fabricated in horizontal or vertical configurations to facilitate transportation and installation. The implementation of cold boxes can also potentially reduce heat transfer area, which in turn reduces required plot space in field installations. The cold box, in certain implementations, includes a thermal design for the plate-fin heat exchanger to handle a majority of the hot streams to be cooled and the cold streams to be heated in the liquid recovery process, thus allowing for cost avoidance associated with interconnecting piping, which would be required for a system utilizing multiple, individual heat exchangers that each include only two inlets and two outlets.
In certain implementations, the cold box includes alloys that allow for low temperature service. An example of such an alloy is aluminum alloy, brazed aluminum, copper, or brass. Aluminum alloys can be used in low temperature service (less than −100° F., for example) and can be relatively lighter than other alloys, potentially resulting in reduced equipment weight. The cold box can handle single-phase liquid, single-phase gaseous, vaporizing, and condensing streams in the liquid recovery process. The cold box can include multiple compartments, for example, ten compartments, to transfer heat between streams. The cold box can be specifically designed for the required thermal and hydraulic performance of a liquid recovery system, and the hot process streams, cold process streams, and refrigerant streams can be reasonably considered as clean fluids that do not contain contaminants that can cause fouling or erosion, such as debris, heavy oils, asphalt components, and polymers. The cold box can be installed within a containment with interconnecting piping, vessels, valves, and instrumentation, all included as a packaged unit, skid, or module. In certain implementations, the cold box can be supplied with insulation.
Chill Down Trains
The feed gas travels through at least one chill down train, each train including cooling and liquid-vapor separation, to cool the feed gas and facilitate the separation of light hydrocarbons from heavier hydrocarbons. For example, the feed gas travels through three chill down trains. Feed gas at a temperature in a range of approximately 130° F. to 170° F. flows to the cold box which cools the feed gas down to a temperature in a range of approximately 70° F. to 95° F. A portion of the feed gas condenses through the cold box, and the multi-phase fluid enters a first chill down separator that separates feed gas into three phases: hydrocarbon feed gas, condensed hydrocarbon liquid, and water. Water can flow to storage, such as a process water recovery drum where the water can be used, for example, as make-up in a gas treating unit. In subsequent chill down trains, the separator can separate a fluid into two phases: hydrocarbon gas and hydrocarbon liquid. As the feed gas travels through each chill down train, the feed gas can be refined. In other words, as the feed gas is cooled down in a chill down train, the heavier components in the gas can condense while the lighter components can remain in the gas. Therefore, the gas exiting the separator can have a lower molecular weight than the gas entering the chill down train.
Condensed hydrocarbons from the first chill down train, also referred to as first chill down liquid, is pumped from the first chill down separator by one or more liquid dehydrator feed pumps. In certain implementations, the liquid can have enough available pressure to be passed downstream with a valve instead of using a pump to pressurize the liquid. First chill down liquid travels through a de-methanizer feed coalescer to remove any free water entrained in the first chill down liquid to avoid damage to downstream equipment, for example, a liquid dehydrator. Removed water can flow to storage, such as a condensate surge drum. Remaining first chill down liquid can be sent to one or more liquid dehydrators, for example, a pair of liquid dehydrators, in order further remove water and any hydrates that may be present in the liquid.
Hydrates are crystalline substances formed by associated molecules of hydrogen and water, having a crystalline structure. Accumulation of hydrates in a gas pipeline can choke (and in some cases, completely block) piping and cause damage to the system. Dehydration aims for the depression of the dew point of water to less than the minimum temperature that can be expected in the gas pipeline. Gas dehydration can be categorized as absorption (dehydration by liquid media) and adsorption (dehydration by solid media). Glycol dehydration is a liquid-based desiccant system for the removal of water from natural gas and NGLs. In cases where large gas volumes are transported, glycol dehydration can be an efficient and economical way to prevent hydrate formation in the gas pipeline.
Drying in the liquid dehydrators can include passing the liquid through, for example, a bed of activated alumina oxide or bauxite with 50% to 60% aluminum oxide (Al2O3) content. In some implementations, the absorption capacity of the bauxite is 4.0% to 6.5% of its own mass. Utilizing bauxite can reduce the dew point of water in the dehydrated gas down to approximately −65° C. Some advantages of bauxite in gas dehydration are small space requirements, simple design, low installation costs, and simple sorbent regeneration. Alumina has a strong affinity for water at the conditions of the first chill down liquid.
Liquid sorbents can be used to dehydrate gas. Desirable qualities of suitable liquid sorbents include high solubility in water, economic viability, and resistance to corrosion. If the sorbent is regenerated, it is desirable for the sorbent to be regenerated easily and for the sorbent to have low viscosity. A few examples of suitable sorbents include diethylene glycol (DEG), triethylene glycol (TEG), and ethylene glycol (MEG). Glycol dehydration can be categorized as absorption or injection schemes. With glycol dehydration in absorption schemes, the glycol concentration can be, for example, approximately 96% to 99% with small losses of glycol. The economic efficiency of glycol dehydration in absorption schemes depends heavily on sorbent losses. In order to reduce sorbent loss, a desired temperature of the desorber (that is, dehydrator) can be strictly maintained to separate water from the gas. Additives can be utilized to prevent potential foaming across the gas-absorbent contact area. With glycol dehydration in injection schemes, the dew point of water can be decreased as the gas is cooled. In such cases, the gas is dehydrated, and condensate also drops out of the cooled gas. Utilization of liquid sorbents for dehydration allows for continuous operation (in contrast to batch or semi-batch operation) and can result in reduced capital and operating costs in comparison to solid sorbents, reduced pressure differentials across the dehydration system in comparison to solid sorbents, and avoidance of the potential poisoning that can occur with solid sorbents.
A hygroscopic ionic liquid (such as methanesulfonate, CH3O3S−) can be utilized for gas dehydration. Some ionic liquids can be regenerated with air, and in some cases, the drying capacity of gas utilizing an ionic liquid system can be more than double the capacity of a glycol dehydration system.
Two liquid dehydrators can be installed in parallel: one liquid dehydrator in operation and the other in regeneration of alumina. Once the alumina in one liquid dehydrator is saturated, the liquid dehydrator can be taken off-line and regenerated while the liquid passes through the other liquid dehydrator. Dehydrated first chill down liquid exits the liquid dehydrators and is sent to the de-methanizer. In certain implementations, the first chill down liquid can be sent directly to the de-methanizer from the first chill down separator. Dehydrated first chill down liquid can also pass through the cold box to be cooled further before entering the de-methanizer.
Hydrocarbon feed gas from the first chill down separator, also referred to as first chill down vapor, flows to one or more feed gas dehydrators for drying, for example, three feed gas dehydrators. The first chill down vapor can pass through the demister before entering the feed gas dehydrators. In certain implementations, two of the three gas dehydrators can be on-stream at any given time while the third gas dehydrator is on regeneration or standby. Drying in the gas dehydrators can include passing hydrocarbon gas through a molecular sieve bed. The molecular sieve has a strong affinity for water at the conditions of the hydrocarbon gas. Once the sieve in one of the gas dehydrators is saturated, that gas dehydrator is taken off-stream for regeneration while the previously off-stream gas dehydrator is placed on-stream. Dehydrated first chill down vapor exits the feed gas dehydrators and enters the cold box. In certain implementations, the first chill down vapor can be sent directly to the cold box from the first chill down separator. The cold box can cool dehydrated first chill down vapor down to a temperature in a range of approximately −30° F. to 20° F. A portion of the dehydrated first chill down vapor condenses through the cold box, and the multi-phase fluid enters the second chill down separator. The second chill down separator separates hydrocarbon liquid, also referred to as second chill down liquid, from the first chill down vapor. Second chill down liquid is sent to the de-methanizer. The second chill down liquid can pass through the cold box to be cooled before entering the de-methanizer. The second chill down liquid can optionally combine with the first chill down liquid before entering the de-methanizer.
Gas from the second chill down separator, also referred to as second chill down vapor, flows to the cold box. In certain implementations, the cold box cools the second chill down vapor down to a temperature in a range of approximately −60° F. to −40° F. In certain implementations, the cold box cools the second chill down vapor down to a temperature in a range of approximately −100° F. to −80° F. A portion of the second chill down vapor condenses through the cold box, and the multi-phase fluid enters the third chill down separator. The third chill down separator separates hydrocarbon liquid, also referred to as third chill down liquid, from the second chill down vapor. The third chill down liquid is sent to the de-methanizer.
Gas from the third chill down separator is also referred to as high pressure residue gas. In certain implementations, the high pressure residue gas passes through the cold box and heats up to a temperature in a range of approximately 120° F. to 140° F. In certain implementations, a portion of the high pressure residue gas passes through cold box and cools down to a temperature in a range of approximately −160° F. to −150° F. before entering the de-methanizer. The high pressure residue gas can be pressurized and sold as sales gas.
De-Methanizer
The de-methanizer removes methane from the hydrocarbons condensed out of the feed gas in the cold box and chill down trains. The de-methanizer receives as feed the first chill down liquid, the second chill down liquid, and the third chill down liquid. In certain implementations, an additional feed source to the de-methanizer can include several process vents, such as vent from a propane surge drum, vent from a propane condenser, vents and minimum flow lines from a de-methanizer bottom pump, and surge vent lines from NGL surge spheres. In certain implementations, an additional feed source to the de-methanizer can include high-pressure residue gas from the third chill down separator, the turbo-expander, or both.
The residue gas from the top of the de-methanizer is also referred to as overhead low pressure residue gas. In certain implementations, the overhead low pressure residue gas enters the cold box at a temperature in a range of approximately −170° F. to −150° F. In certain implementations, the overhead low pressure residue gas enters the cold box at a temperature in a range of approximately −120° F. to −100° F. and exits the cold box at a temperature in a range of approximately 20° F. to 40° F. The overhead low pressure residue gas can be pressurized and sold as sales gas.
The de-methanizer bottom pump pressurizes liquid from the bottom of the de-methanizer, also referred to as de-methanizer bottoms, and sends fluid to storage, such as NGL spheres. The de-methanizer bottoms can operate at a temperature in a range of approximately 25° F. to 75° F. The de-methanizer bottoms can optionally pass through the cold box to be heated to a temperature in a range of approximately 85° F. to 105° F. before being sent to storage. The de-methanizer bottoms can optionally pass through a heat exchanger or the cold box to be heated to a temperature in a range of approximately 65° F. to 110° F. after being sent to storage. The de-methanizer bottoms includes hydrocarbons heavier (that is, having a higher molecular weight) than methane and can be referred to as natural gas liquid. Natural gas liquid can be further fractionated into separate hydrocarbon streams, such as ethane, propane, butane, and pentane.
A portion of the liquid at the bottom of the de-methanizer, also referred to as de-methanizer reboiler feed, is routed to the cold box where the liquid is partially or fully boiled and routed back to the de-methanizer. In certain implementations, the de-methanizer reboiler feed flows hydraulically based on the available liquid head at the bottom of the de-methanizer. Optionally, a de-methanizer reboiler pump can pressurize the de-methanizer reboiler feed to provide flow. In certain implementations, the de-methanizer reboiler feed operates at a temperature in a range of approximately 0° F. to 20° F. and is heated in the cold box to a temperature in a range of approximately 20° F. to 40° F. In certain implementations, the de-methanizer reboiler feed is heated in the cold box to a temperature in a range of approximately 55° F. to 75° F. One or more side streams from the de-methanizer can optionally pass through the cold box and return to the de-methanizer.
Turbo-Expander
The liquid recovery system can include a turbo-expander. The turbo-expander is an expansion turbine through which a gas can expand to produce work. The produced work can be used to drive a compressor, which can be mechanically coupled with the turbine. A portion of the high pressure residue gas from the third chill down separator can expand and cool down through the turbo-expander before entering the de-methanizer. The expansion work can be used to compress the overhead low pressure residue gas. In certain implementations, the overhead low pressure residue gas is compressed in the compression portion of the turbo-expander in order to be delivered as sales gas.
Primary Refrigeration System
The liquid recovery process typically requires cooling down to temperatures that cannot be achieved with typical water or air cooling, for example, less than 0° F. Therefore, the liquid recovery process includes a refrigeration system to provide cooling to the process. Refrigeration systems can include refrigeration loops, which involve a refrigerant cycling through evaporation, compression, condensation, and expansion. The evaporation of the refrigerant provides cooling to a process, such as liquid recovery.
The refrigeration system includes a refrigerant, a cold box, a knockout drum, a compressor, an air cooler, a water cooler, a feed drum, a throttling valve, and a separator. The refrigeration system can optionally include additional knockout drums, additional compressors, and additional separators which operate at different pressures to allow for cooling at different temperatures. The refrigeration system can optionally include one or more subcoolers. The additional subcoolers can be located upstream or downstream of the feed drum. The additional subcoolers can transfer heat between streams within the refrigeration system.
Because the refrigerant provides cooling to a process by evaporation, the refrigerant is chosen based on a desired boiling point in comparison to the lowest temperature needed in the process, while also taking into consideration re-compression of the refrigerant. The refrigerant, also referred to as the primary refrigerant, can be a mixture of various non-methane hydrocarbons, such as ethane, ethylene, propane, propylene, n-butane, i-butane, and n-pentane. A C2 hydrocarbon is a hydrocarbon that has two carbon atoms, such as ethane and ethylene. A C3 hydrocarbon is a hydrocarbon that has three carbons, such as propane and propylene. A C4 hydrocarbon is a hydrocarbon that has four carbons, such as an isomer of butane and butene. A C5 hydrocarbon is a hydrocarbon that has five carbons, such as an isomer of pentane and pentene. In certain implementations, the primary refrigerant has a composition of ethane in a range of approximately 1 mol % to 80 mol %. In certain implementations, the primary refrigerant has a composition of ethylene in a range of approximately 1 mol % to 45 mol %. In certain implementations, the primary refrigerant has a composition of propane in a range of approximately 1 mol % to 25 mol %. In certain implementations, the primary refrigerant has a composition of propylene in a range of approximately 1 mol % to 45 mol %. In certain implementations, the primary refrigerant has a composition of n-butane in a range of approximately 1 mol % to 20 mol %. In certain implementations, the primary refrigerant has a composition of i-butane in a range of approximately 2 mol % to 60 mol %. In certain implementations, the primary refrigerant has a composition of n-pentane in a range of approximately 1 mol % to 15 mol %.
The knockout vessel is a vessel located directly upstream of the compressor to knock out any liquid that may be in the stream before it is compressed because the presence of liquid may damage the compressor. The compressor is a mechanical device that increases the pressure of a gas, such as a vaporized refrigerant. In the context of the refrigeration system, the increase in pressure of a refrigerant increases the boiling point, which can allow the refrigerant to be condensed utilizing air, water, another refrigerant, or a combination of these. The air cooler, also referred to as a fin fan heat exchanger or air-cooled condenser, is a heat exchanger that utilizes a fan to flow air over a surface to cool a fluid. In the context of the refrigeration system, the air cooler provides cooling to a refrigerant after the refrigerant has been compressed. The water cooler is a heat exchanger that utilizes water to cool a fluid. In the context of the refrigeration system, the water cooler also provides cooling to a refrigerant after the refrigerant has been compressed. In certain implementations, condensing the refrigerant can be accomplished with one or more air coolers. In certain implementations, condensing the refrigerant can be accomplished with one or more water coolers. The feed drum, also referred to as a feed surge drum, is a vessel that contains a liquid level of refrigerant so that the refrigeration loop can continue to operate even if there exists some deviation in one or more areas of the loop. The throttling valve is a device that direct or controls a flow of fluid, such as a refrigerant. The refrigerant reduces in pressure as the refrigerant travels through the throttling valve. The reduction in pressure can cause the refrigerant to flash—that is, evaporate. The separator is a vessel that separates a fluid into liquid and vapor phases. The liquid portion of the refrigerant can be evaporated in a heat exchanger, for example, a cold box, to provide cooling to a system, such as a liquid recovery system.
The primary refrigerant flows from the feed drum through the throttling valve and reduces in pressure to approximately 1 to 2 bar. The reduction in pressure through the valve causes the primary refrigerant to cool down to a temperature in a range of approximately −100° F. to −10° F. The reduction in pressure through the valve can also cause the primary refrigerant to flash—that is, evaporate—into a two-phase mixture. The primary refrigerant separates into liquid and vapor phases in the separator. The liquid portion of the primary refrigerant flows to the cold box. As the primary refrigerant evaporates, the primary refrigerant provides cooling to another process, such as the natural gas liquid recovery process. The evaporated primary refrigerant exits the cold box at a temperature in a range of approximately 70° F. to 160° F. The evaporated primary refrigerant can mix with the vapor portion of the primary refrigerant from the separator and enter the knockout drum operating at a pressure in a range of approximately 1 to 10 bar. The compressor raises the pressure of the primary refrigerant up to a pressure in a range of approximately 9 to 35 bar. The increase in pressure can cause the primary refrigerant temperature to rise to a temperature in a range of approximately 150° F. to 450° F. The compressor outlet vapor is condensed through the air cooler and a water cooler. In certain implementations, the primary refrigerant vapor is condensed using a multitude of air coolers or water coolers, or both in combination. The combined duty of the air cooler and water cooler can be in a range of approximately 30 to 360 MMBtu/h. The condensed primary refrigerant downstream of the coolers can have a temperature in a range of approximately 80° F. to 100° F. The primary refrigerant returns to the feed drum to continue the refrigeration cycle. In certain implementations, there can be additional throttling valves, knockout drums, compressors, and separators that handles a portion of the primary refrigerant.
Secondary Refrigeration System
In certain implementations, the refrigeration system includes an additional refrigerant loop that includes a secondary refrigerant, an evaporator, an ejector, a cooler, a throttling valve, and a circulation pump. The additional refrigerant loop can use a secondary refrigerant that is distinct from the primary refrigerant.
The secondary refrigerant can be a hydrocarbon, such as i-butane. The evaporator is a heat exchanger that provides heating to a fluid, for example, the secondary refrigerant. The ejector is a device that converts pressure energy available in a motive fluid to velocity energy, brings in a suction fluid that is at a lower pressure than the motive fluid, and discharges the mixture at an intermediate pressure without the use of rotating or moving parts. The cooler is a heat exchanger that provides cooling to a fluid, for example, the secondary refrigerant. The throttling valve causes the pressure of a fluid, for example, the secondary refrigerant, to reduce as the fluid travels through the valve. The circulation pump is a mechanical device that increases the pressure of a liquid, such as a condensed refrigerant.
This secondary refrigeration loop provides additional cooling in the condensation portion of the refrigeration loop of primary refrigerant. The secondary refrigerant can be split into two streams. One stream can be used for subcooling the primary refrigerant in the subcooler, and the other stream can be used to recover heat from the primary refrigerant in the evaporator located upstream of the air cooler in the primary refrigeration loop. The portion of secondary refrigerant for subcooling the primary refrigerant can travel through the throttling valve to bring down the operating pressure in a range of approximately 2 to 3 bar and an operating temperature in a range of approximately 40° F. to 70° F. To subcool the primary refrigerant, the secondary refrigerant receives heat from the primary refrigerant in the subcooler and heats up to a temperature in a range of approximately 45° F. to 85° F. The portion of secondary refrigerant for recovering heat from the primary refrigerant can be pressurized by the circulation pump and can have an operating pressure in a range of approximately 10 to 20 bar and an operating temperature in a range of approximately 90° F. to 110° F. The secondary refrigerant recovers heat from the primary refrigerant in the evaporator and heats up to a temperature in a range of 170° F. to 205° F. The split streams of secondary refrigerant can mix in the ejector and discharge at an intermediate pressure of approximately 4 to 6 bar and an intermediate temperature in a range of approximately 110° F. to 150° F. The secondary refrigerant can pass through the cooler, for example, a water cooler, and condense into a liquid at approximately 4 to 6 bar and 85° F. to 105° F. The cooling duty of the cooler can be in a range of approximately 60 to 130 MMBtu/h. The secondary refrigerant can split downstream of the cooler into two streams to continue the secondary refrigeration cycle.
Refrigeration systems can optionally include auxiliary and variant equipment such as additional heat exchangers and vessels. The transport of vapor, liquid, and vapor-liquid mixtures within, to, and from the refrigeration system can be achieved using various piping, pump, and valve configurations.
Flow Control System
In each of the configurations described later, process streams (also referred to as “streams”) are flowed within each unit in a gas processing plant and between units in the gas processing plant. The process streams can be flowed using one or more flow control systems implemented throughout the gas processing plant. A flow control system can include one or more flow pumps to pump the process streams, one or more flow pipes through which the process streams are flowed, and one or more valves to regulate the flow of streams through the pipes.
In some implementations, a flow control system can be operated manually. For example, an operator can set a flow rate for each pump by changing the position of a valve (open, partially open, or closed) to regulate the flow of the process streams through the pipes in the flow control system. Once the operator has set the flow rates and the valve positions for all flow control systems distributed across the gas processing plant, the flow control system can flow the streams within a unit or between units under constant flow conditions, for example, constant volumetric or mass flow rates. To change the flow conditions, the operator can manually operate the flow control system, for example, by changing the valve position.
In some implementations, a flow control system can be operated automatically. For example, the flow control system can be connected to a computer system to operate the flow control system. The computer system can include a computer-readable medium storing instructions (such as flow control instructions) executable by one or more processors to perform operations (such as flow control operations). For example, an operator can set the flow rates by setting the valve positions for all flow control systems distributed across the gas processing plant using the computer system. In such implementations, the operator can manually change the flow conditions by providing inputs through the computer system. In such implementations, the computer system can automatically (that is, without manual intervention) control one or more of the flow control systems, for example, using feedback systems implemented in one or more units and connected to the computer system. For example, a sensor (such as a pressure sensor or temperature sensor) can be connected to a pipe through which a process stream flows. The sensor can monitor and provide a flow conditions (such as a pressure or temperature) of the process stream to the computer system. In response to the flow condition deviating from a set point (such as a target pressure value or target temperature value) or exceeding a threshold (such as a threshold pressure value or threshold temperature value), the computer system can automatically perform operations. For example, if the pressure or temperature in the pipe exceeds the threshold pressure value or the threshold temperature value, respectively, the computer system can provide a signal to open a valve to relieve pressure or a signal to shut down process stream flow.
In some implementations, the techniques described here can be implemented using a cold box that integrates heat exchange across various process streams and refrigerant streams in a gas processing plant, and is presented to enable any person skilled in the art to make and use the disclosed subject matter in the context of one or more particular implementations. Various modifications, alterations, and permutations of the disclosed implementations can be made and will be readily apparent to those or ordinary skill in the art, and the general principles defined may be applied to other implementations and applications, without departing from scope of the disclosure. In some instances, details unnecessary to obtain an understanding of the described subject matter may be omitted so as to not obscure one or more described implementations with unnecessary detail and inasmuch as such details are within the skill of one of ordinary skill in the art. The present disclosure is not intended to be limited to the described or illustrated implementations, but to be accorded the widest scope consistent with the described principles and features.
The subject matter described in this specification can be implemented in particular implementations, so as to realize one or more of the following advantages. A cold box can reduce the total heat transfer area required for the NGL recovery process and can replace multiple heat exchangers, thereby reducing the required amount of plot space and material costs. The refrigeration system can use less power associated with compressing the refrigerant streams in comparison to conventional refrigeration systems, thereby reducing operating costs. Using a mixed hydrocarbon refrigerant can potentially reduce the number of refrigeration cycles (in comparison to a refrigeration system that uses multiple cycles of single component refrigerants), thereby reducing the amount of equipment in the refrigeration system. Process intensification of both the NGL recovery system and the refrigeration system can result in reduced maintenance, operation, and spare parts costs. Other advantages will be apparent to those of ordinary skill in the art.
Referring to
Condensed hydrocarbons 105, also referred to as first chill down liquid 105, can be pumped from the first chill down separator 102 by one or more liquid dehydrator feed pumps 110. In certain implementations, first chill down liquid 105 can be pumped through a de-methanizer feed coalescer (not shown) to remove any free water entrained in the first chill down liquid 105. In such implementations, any removed water can flow to storage, such as a condensate surge drum. First chill down liquid 105 can optionally flow to one or more liquid dehydrators, for example, a pair of liquid dehydrators (not shown). First chill down liquid 105 can flow to a de-methanizer 150. In some implementations, the first chill down liquid 105 can flow through the cold box 199 and be cooled before entering the de-methanizer 150.
Hydrocarbon feed gas 103 from the first chill down separator 102, also referred to as first chill down vapor 103, can flow to one or more feed gas dehydrators 108 for drying, for example, three feed gas dehydrators. The first chill down vapor 103 can flow through a demister (not shown) before entering the feed gas dehydrators 108. Dehydrated first chill down vapor 115 exits the feed gas dehydrators 108 and can enter the cold box 199. The cold box 199 can cool dehydrated first chill down vapor 115. A portion of the dehydrated first chill down vapor 115 can condense through the cold box 199, and the multi-phase fluid enters a second chill down separator 104. The second chill down separator 104 can separate hydrocarbon liquid 117, also referred to as second chill down liquid 117, from the gas 119. The second chill down liquid 117 can flow to the de-methanizer 150. In certain implementations, the second chill down liquid 117 can flow through the cold box 199 and be cooled before entering the de-methanizer 150. The second chill down liquid 117 can optionally mix with the first chill down liquid 105 before entering the de-methanizer 150.
Gas 119 from the second chill down separator 104, also referred to as second chill down vapor 119, can flow to the cold box 199. The cold box 199 can cool the second chill down vapor 119. A portion of the second chill down vapor 119 can condense through the cold box 199, and the multi-phase fluid enters a third chill down separator 106. The third chill down separator 106 can separate hydrocarbon liquid 121, also referred to as third chill down liquid 121, from the gas 123. The third chill down liquid 121 can flow to the de-methanizer 150.
Gas 123 from the third chill down separator 106 is also referred to as high pressure (HP) residue gas 123. The HP residue gas 123 can be divided into various portions, for example, a first portion 123a and a second portion 123b. The first portion 123a of the HP residue gas 123 can flow through the cold box 199 and be cooled (and condensed into a liquid) before entering the de-methanizer 150. The second portion 123b of the HP residue gas 123 can flow to a turbo-expander 156. The second portion 123b of the HP residue gas 123 can expand as it flows through the turbo-expander 156 and by doing so, generate work. After expansion, the second portion 123b of the HP residue gas 123 can enter the de-methanizer 150.
The de-methanizer 150 can receive as feed the first chill down liquid 105, the second chill down liquid 117, the third chill down liquid 121, and the first portion 123a of the HP residue gas 123. An additional feed source to the de-methanizer 150 can include several process vents, such as vent from a propane surge drum, vent from a propane condenser, vents and minimum flow lines from a de-methanizer bottom pump, and surge vent lines from NGL surge spheres. Residue gas from the top of the de-methanizer 150 is also referred to as overhead low pressure (LP) residue gas 153. The overhead LP residue gas 153 can be heated as the overhead LP residue gas 153 flows through the cold box 199. Using the work generated from the expansion of the HP residue gas 123, the turbo-expander 156 can pressurize the overhead LP residue gas 153. The now-pressurized overhead LP residue gas 153 can be sold as sales gas. The sales gas can be predominantly made up of methane (for example, at least 98.6 mol % of methane).
A de-methanizer bottom pump 152 can pressurize liquid 151 from the bottom of the de-methanizer 150, also referred to as de-methanizer bottoms 151. The de-methanizer bottoms 151 can be sent to storage, such as an NGL sphere. The de-methanizer bottoms 151 can also be referred to as natural gas liquid and can be predominantly made up of hydrocarbons heavier than methane (for example, at least 99.5 mol % of hydrocarbons heavier than methane).
A portion of the liquid 155 at the bottom of the de-methanizer 150, also referred to as de-methanizer reboiler feed 155, can flow to the cold box 199 where the liquid can be partially or fully vaporized and routed back to the de-methanizer 150. If additional pressure is needed to provide flow, a de-methanizer reboiler pump (not shown) can be used to pressurize the de-methanizer reboiler feed 155.
The de-methanizer 150 can include additional side draws (such as 157, 158, and 159) that can be heated or vaporized in the cold box 199 before returning to the de-methanizer 150. For example, the temperature of a first side draw 157 can increase by approximately 20° F. to 30° F., and the first side draw 157 can vaporize while flowing through the cold box 199. The temperature of a second side draw 158 can increase by approximately 20° F. to 30° F., and the second side draw 158 can vaporize while flowing through the cold box 199. The temperature of a third side draw 159 can increase by approximately 40° F. to 50° F., and the third side draw 159 can vaporize while flowing through the cold box 199.
The liquid recovery process 100 of
In some implementations, the primary refrigerant 161 can be partitioned for various uses. A first portion 161a of the primary refrigerant 161 (for example, approximately 30 mass % to 40 mass %) can flow from the water cooler 172 and through the subcooler 174 to be further cooled to a temperature in a range of approximately 80° F. to 90° F. The first portion 161a of the primary refrigerant 161 can flow through the cold box 199 to be further cooled to a temperature in a range of approximately 10° F. to 20° F. The first portion 161a of the primary refrigerant 161 can flow to a feed drum 180 and then flow through an LP throttling valve 182 and decrease in pressure to approximately 1 to 2 bar. The decrease in pressure through the LP valve 182 can cause the first portion 161a of the primary refrigerant 161 to be cooled to a temperature in a range of approximately −30° F. to −10° F. The decrease in pressure through the LP valve 182 can also cause the first portion 161a of the primary refrigerant 161 to flash—that is, evaporate—into a two-phase mixture. The first portion 161a of the primary refrigerant 161 can separate into liquid and vapor phases in an LP separator 186.
A liquid phase 163 of the first portion 161a of the primary refrigerant 161, also referred to as LP primary refrigerant liquid 163, can have a different composition from the primary refrigerant 161, depending on the vapor-equilibrium at the operation conditions of the LP separator 186. The LP primary refrigerant liquid 163 can be a mixture of propane (16 mol % to 26 mol %), propylene (33 mol % to 43 mol %), n-butane (15 mol % to 25 mol %), and i-butane (16 mol % to 26 mol %). In a specific example, the LP primary refrigerant liquid 163 is composed of 21.1 mol % propane, 38.2 mol % propylene, 20 mol % n-butane, and 20.7 mol % i-butane. The LP primary refrigerant liquid 163 can flow from the LP separator 186 to the cold box 199, for instance at a flow rate of approximately 60 to 70 kg/s. As the LP primary refrigerant liquid 163 evaporates, the LP primary refrigerant liquid 163 can provide cooling to the liquid recovery process 100. The LP primary refrigerant liquid 163 can exit the cold box 199 as mostly vapor at a temperature in a range of approximately 20° F. to 40° F.
A vapor phase 167 of the first portion 161a of the primary refrigerant 161, also referred to as LP primary refrigerant vapor 167, can have a composition that differs from the composition of the primary refrigerant 161. The LP primary refrigerant vapor 167 can be a mixture of propane (23 mol % to 33 mol %), propylene (55 mol % to 65 mol %), n-butane (0.1 mol % to 10 mol %), and i-butane (2 mol % to 12 mol %). In a specific example, the primary refrigerant vapor 167 is composed of 28.2 mol % propane, 59.7 mol % propylene, 4.7 mol % n-butane, and 7.4 mol % i-butane. The LP primary refrigerant vapor 167 can flow from the LP separator 186, for instance, at a flow rate of approximately 5 to 15 kg/s. The LP primary refrigerant vapor 167 can flow to a subcooler 174 and be heated to a temperature in a range of approximately 80° F. to 100° F.
The now-vaporized LP primary refrigerant liquid 163 from the cold box 199 can mix with the heated LP primary refrigerant vapor 167 from the subcooler 174 to reform the first portion 161a of the primary refrigerant 161. The first portion 161a of the primary refrigerant 161 then enters an LP knockout drum 162 operating at approximately 1 to 2 bar. The first portion 161a of the primary refrigerant 161 exiting the LP knockout drum 162 to the suction of an LP compressor 166 can have a temperature in a range of approximately 30° F. to 50° F. The LP compressor 166 can increase the pressure of the first portion 161a of the primary refrigerant 161 to a pressure of approximately 8 to 9.5 bar. The increase in pressure can cause the first portion 161a of the primary refrigerant 161 temperature to increase to a temperature in a range of 180° F. to 200° F.
A second portion 161b of the primary refrigerant 161 (for example, approximately 60 mass % to 70 mass %) can flow through an HP throttling valve 184 and decrease in pressure to approximately 8 to 9.5 bar. The decrease in pressure through the HP valve 184 can cause the second portion 161b of the primary refrigerant 161 to be cooled to a temperature in a range of approximately 80° F. to 95° F. The decrease in pressure through the HP valve 184 can also cause the second portion 161b of the primary refrigerant 161 to flash—that is, evaporate—into a two-phase mixture. The second portion 161b of the primary refrigerant 161 can separate into liquid and vapor phases in an HP separator 188.
A liquid phase 165 of the second portion 161b of the primary refrigerant 161, also referred to as HP primary refrigerant liquid 165, can have a different composition from the primary refrigerant 161, depending on the vapor-equilibrium at the operation conditions of the HP separator 188. The HP primary refrigerant liquid 165 can be a mixture of propane (17 mol % to 27 mol %), propylene (35 mol % to 45 mol %), n-butane (14 mol % to 24 mol %), and i-butane (14 mol % to 24 mol %). In a specific example, the HP primary refrigerant liquid 165 is composed of 21.8 mol % propane, 40.3 mol % propylene, 18.5 mol % n-butane, and 19.4 mol % i-butane. The HP primary refrigerant liquid 165 can flow from the HP separator 188 to the cold box 199, for instance, at a flow rate of approximately 120 to 130 kg/s. As the HP primary refrigerant liquid 165 evaporates, the HP primary refrigerant liquid 165 can provide cooling to the liquid recovery process 100. The HP primary refrigerant liquid 165 can exit the cold box 199 as mostly vapor at a temperature in a range of approximately 115° F. to 135° F.
A vapor phase 169 of the second portion 161b of the primary refrigerant 161, also referred to as HP primary refrigerant vapor 169, can have a composition that differs from the composition of the primary refrigerant 161. The HP primary refrigerant vapor 169 can be a mixture of propane (22 mol % to 32 mol %), propylene (51 mol % to 61 mol %), n-butane (2 mol % to 12 mol %), and i-butane (5 mol % to 15 mol %). In a specific example, the HP primary refrigerant vapor 169 is composed of 26.9 mol % propane, 56 mol % propylene, 7.3 mol % n-butane, and 9.8 mol % i-butane. The HP primary refrigerant vapor 169 can flow from the HP separator 188, for instance, at a flow rate of approximately 0.1 to 10 kg/s.
The now-vaporized HP primary refrigerant liquid 165 from the cold box 199 can mix with the HP primary refrigerant vapor 169 and the first portion 161a of the primary refrigerant 161 from the HP separator 188 and the LP compressor 166, respectively, to reform the primary refrigerant 161. The primary refrigerant 161 then enters an HP knockout drum 164 operating at approximately 8 to 9.5 bar. The primary refrigerant 161 exiting the HP knockout drum 164 to the suction of an HP compressor 168 can have a temperature in a range of approximately 130° F. to 160° F. The HP compressor 168 can increase the pressure of the primary refrigerant 161 to a pressure of approximately 9.5 to 11 bar. The increase in pressure can cause the primary refrigerant 161 temperature to increase to a temperature in a range of 160° F. to 180° F. The LP compressor 166 and the HP compressor 168 can use a combined power of approximately 30-40 MMBtu/h (for instance, approximately 36 MMBtu/h (11 MW)). The primary refrigerant 161 can return to the coolers (170 and 172) to continue the refrigeration cycle 160.
In certain implementations, the feed gas stream 101 enters the cold box 199 at compartment #16 and exits at compartment #14 to the first chill down separator 102. Across compartments #14 through #16, the feed gas 101 can provide its available thermal duty to the various cold streams: the first side draw 157 which can enter the cold box 199 at compartment #12 and exit at compartment #15; the de-methanizer reboiler feed 155 which can enter the cold box 199 at compartment #13 and exit at compartment #15; and the HP refrigerant liquid 165 which can enter and exit the cold box 199 at compartment #16.
In certain implementations, the dehydrated first chill down vapor 115 from the one or more feed gas dehydrators 108 enters the cold box 199 at compartment #13 and exits at compartment #8. Across compartments #8 through #13, the dehydrated first chill down vapor 115 can provide its available thermal duty to the various cold streams: the second side draw 158 which can enter the cold box 199 at compartment #7 and exit at compartment #9; the first side draw 157 which can enter the cold box 199 at compartment #12 and exit at compartment #15; the de-methanizer reboiler feed 155 which can enter the cold box 199 at compartment #13 and exit at compartment #15; the overhead LP residue gas 153 which can enter the cold box 199 at compartment #1 and exit at compartment #11; the LP primary refrigerant liquid 163 which can enter the cold box 199 at compartment #5 and exit at compartment #10.
In certain implementations, the second chill down vapor 119 from the second chill down separator 104 enters the cold box 199 at compartment #7 and exits at compartment #3. Across compartments #3 through #7, the second chill down vapor 119 can provide its available thermal duty to various cold streams: the second side draw 158 which can enter the cold box 199 at compartment #7 and exit at compartment #9; the overhead LP residue gas 153 which can enter the cold box 199 at compartment #1 and exit at compartment #11; the LP primary refrigerant liquid 163 which can enter the cold box 199 at compartment #5 and exit at compartment #10; and the third side draw 159 which can enter the cold box 199 at compartment #2 and exit at compartment #3.
In certain implementations, the third chill down vapor 123 from the third chill down separator 106 enters the cold box 199 at compartment #2 and exits at compartment #1. Across compartments #1 through #2, the third chill down vapor 123 can provide its available thermal duty to various cold streams: the third side draw 159 which can enter the cold box 199 at compartment #2 and exit at compartment #3 and the overhead LP residue gas 153 which can enter the cold box 199 at compartment #1 and exit at compartment #11.
In certain implementations, the first chill down liquid 105 from the first chill down separator 102 enters the cold box 199 at compartment #14 and exits at compartment #6. Across compartments #6 through #14, the first chill down liquid 105 can provide its available thermal duty to various cold streams: the second side draw 158 which can enter the cold box 199 at compartment #7 and exit at compartment #9; the overhead LP residue gas 153 which can enter the cold box 199 at compartment #1 and exit at compartment #11; the LP primary refrigerant liquid 163 which can enter the cold box 199 at compartment #5 and exit at compartment #10; the first side draw 157 which can enter the cold box 199 at compartment #12 and exit at compartment #15; and the de-methanizer reboiler feed 155 which can enter the cold box 199 at compartment #13 and exit at compartment #15.
In certain implementations, the second chill down liquid 117 from the second chill down separator 104 enters the cold box 199 at compartment #7 and exits at compartment #6. Across compartments #6 through #7, the second chill down liquid 117 can provide its available thermal duty to various cold streams: the second side draw 158 which can enter the cold box 199 at compartment #7 and exit at compartment #9; the overhead LP residue gas 153 which can enter the cold box 199 at compartment #1 and exit at compartment #11; and the LP primary refrigerant liquid 163 which can enter the cold box 199 at compartment #5 and exit at compartment #10.
In certain implementations, the primary refrigerant 161 from the subcooler 174 enters the cold box 199 at compartment #13 and exits at compartment #9. Across compartments #9 through #13, the primary refrigerant 161 can provide its available thermal duty to various cold streams: the overhead LP residue gas 153 which can enter the cold box 199 at compartment #1 and exit at compartment #11; the second side draw 158 which can enter the cold box 199 at compartment #7 and exit at compartment #9; the LP primary refrigerant liquid 163 which can enter the cold box 199 at compartment #5 and exit at compartment #10; the de-methanizer reboiler feed 155 which can enter the cold box 199 at compartment #13 and exit at compartment #15; and the first side draw 157 which can enter the cold box 199 at compartment #12 and exit at compartment #15.
The cold box 199 can include 46 thermal passes but has 63 potential passes as can be determined using the method previously provided. An example of stream data and heat transfer data for the cold box 199 is provided in the following table:
The total thermal duty of the cold box 199 distributed across its 16 compartments can be approximately 690-700 MMBtu/h (for instance, approximately 695 MMBtu/h), with the refrigeration portion being approximately 258-268 MMBtu/h (for instance, approximately 263 MMBtu/h).
The thermal duty of compartment #1 can be approximately 72-82 MMBtu/h (for instance, approximately 77 MMBtu/h). Compartment #1 can have one pass (such as P1) for transferring heat from the HP residue gas 123 (hot) to the overhead LP residue gas 153 (cold). In certain implementations, the temperature of the hot stream 123 decreases by approximately 60° F. to 70° F. through compartment #1. In certain implementations, the temperature of the cold stream 153 increases by approximately 65° F. to 75° F. through compartment #1. The thermal duty for P1 can be approximately 72-82 MMBtu/h (for instance, approximately 77 MMBtu/h).
The thermal duty of compartment #2 can be approximately 38-48 MMBtu/h (for instance, approximately 43 MMBtu/h). Compartment #2 can have two passes (such as P2 and P3) for transferring heat from the HP residue gas 123 (hot) to the overhead LP residue gas 153 (cold) and the third side draw 159 (cold). In certain implementations, the temperature of the hot stream 123 decreases by approximately 30° F. to 40° F. through compartment #2. In certain implementations, the temperatures of the cold streams 153 and 159 increase by approximately 10° F. to 20° F. through compartment #2. The thermal duties for P2 and P3 can be approximately 15-25 MMBtu/h (for instance, approximately 19 MMBtu/h) and approximately 20-30 MMBtu/h (for instance, approximately 24 MMBtu/h), respectively.
The thermal duty of compartment #3 can be approximately 60-70 MMBtu/h (for instance, approximately 64 MMBtu/h). Compartment #3 can have two passes (such as P4 and P5) for transferring heat from the second chill down vapor 119 (hot) to the overhead LP residue gas 153 (cold) and the third side draw 159 (cold). In certain implementations, the temperature of the hot stream 119 decreases by approximately 15° F. to 25° F. through compartment #3. In certain implementations, the temperatures of the cold streams 153 and 159 increase by approximately 20° F. to 30° F. through compartment #3. The thermal duties for P4 and P5 can be approximately 23-33 MMBtu/h (for instance, approximately 28 MMBtu/h) and approximately 30-40 MMBtu/h (for instance, approximately 36 MMBtu/h), respectively.
The thermal duty of compartment #4 can be approximately 30-40 MMBtu/h (for instance, approximately 34 MMBtu/h). Compartment #4 can have one pass (such as P6) for transferring heat from the second chill down vapor 119 (hot) to the overhead LP residue gas 153 (cold). In certain implementations, the temperature of the hot stream 119 decreases by approximately 5° F. to 15° F. through compartment #4. In certain implementations, the temperature of the cold stream 153 increases by approximately 25° F. to 35° F. through compartment #4. The thermal duty for P6 can be approximately 30-40 MMBtu/h (for instance, approximately 34 MMBtu/h).
The thermal duty of compartment #5 can be approximately 7-17 MMBtu/h (for instance, approximately 12 MMBtu/h). Compartment #5 can have two passes (such as P7 and P8) for transferring heat from the second chill down vapor 119 (hot) to the overhead LP residue gas 153 (cold) and the LP primary refrigerant liquid 163 (cold). In certain implementations, the temperature of the hot stream 119 decreases by approximately 0.1° F. to 10° F. through compartment #5. In certain implementations, the temperatures of the cold streams 153 and 163 increase by approximately 0.1° F. to 10° F. through compartment #5. The thermal duties for P7 and P8 can be approximately 3-5 MMBtu/h (for instance, approximately 4 MMBtu/h) and approximately 7-9 MMBtu/h (for instance, approximately 8 MMBtu/h), respectively.
The thermal duty of compartment #6 can be approximately 8-18 MMBtu/h (for instance, approximately 13 MMBtu/h). Compartment #6 can have six potential passes; however, in some implementations, compartment #6 has four passes (such as P9, P10, P11, and P12) for transferring heat from the first chill down liquid 105 (hot), the second chill down liquid 117 (hot), and the second chill down vapor 119 (hot) to the overhead LP residue gas 153 (cold) and the LP primary refrigerant liquid 163 (cold). In certain implementations, the temperatures of the hot streams 105, 117, and 119 decrease by approximately 0.1° F. to 10° F. through compartment #6. In certain implementations, the temperatures of the cold streams 153 and 163 increase by approximately 0.1° F. to 10° F. through compartment #6. The thermal duties for P9, P10, P11, and P12 can be approximately 0.2-0.4 MMBtu/h (for instance, approximately 0.3 MMBtu/h), approximately 0.8-1.2 MMBtu/h (for instance, approximately 1 MMBtu/h), approximately 2-4 MMBtu/h (for instance, approximately 3 MMBtu/h), and approximately 7-9 MMBtu/h (for instance, approximately 8 MMBtu/h), respectively.
The thermal duty of compartment #7 can be approximately 73-83 MMBtu/h (for instance, approximately 78 MMBtu/h). Compartment #7 can have nine potential passes; however, in some implementations, compartment #7 has five passes (such as P13, P14, P15, P16, and P17) for transferring heat from the first chill down liquid 105 (hot), the second chill down liquid 117 (hot), and the second chill down vapor 119 (hot) to the overhead LP residue gas 153 (cold), the second side draw 158 (cold), and the LP primary refrigerant liquid 163 (cold). In certain implementations, the temperatures of the hot streams 105, 117, and 119 decrease by approximately 20° F. to 30° F. through compartment #7. In certain implementations, the temperatures of the cold streams 153, 158, and 163 increase by approximately 10° F. to 20° F. through compartment #7. The thermal duties for P13, P14, P15, P16, and P17 can be approximately 1-3 MMBtu/h (for instance, approximately 2 MMBtu/h), approximately 5-7 MMBtu/h (for instance, approximately 6 MMBtu/h), approximately 7-17 MMBtu/h (for instance, approximately 12 MMBtu/h), approximately 18-28 MMBtu/h (for instance, approximately 23 MMBtu/h), and approximately 30-40 MMBtu/h (for instance, approximately 35 MMBtu/h), respectively.
The thermal duty of compartment #8 can be approximately 3-13 MMBtu/h (for instance, approximately 8 MMBtu/h). Compartment #8 can have six potential passes; however, in some implementations, compartment #8 has four passes (such as P18, P19, P20, and P21) for transferring heat from the first chill down liquid 105 (hot) and the dehydrated first chill down vapor 115 (hot) to the overhead LP residue gas 153 (cold), the second side draw 158 (cold), and the LP primary refrigerant liquid 163 (cold). In certain implementations, the temperatures of the hot streams 105 and 115 decrease by approximately 0.1° F. to 10° F. through compartment #8. In certain implementations, the temperatures of the cold streams 153, 158, and 163 increase by approximately 0.1° F. to 10° F. through compartment #8. The thermal duties for P18, P19, P20, and P21, can be approximately 0.1-0.3 MMBtu/h (for instance, approximately 0.2 MMBtu/h), approximately 1-3 MMBtu/h (for instance, approximately 2 MMBtu/h), approximately 1-3 MMBtu/h (for instance, approximately 2 MMBtu/h), and approximately 2-4 MMBtu/h (for instance, approximately 3 MMBtu/h), respectively.
The thermal duty of compartment #9 can be approximately 25-35 MMBtu/h (for instance, approximately 30 MMBtu/h). Compartment #9 can have nine potential passes; however, in some implementations, compartment #9 has five passes (such as P22, P23, P24, P25, and P26) for transferring heat from the first chill down liquid 105 (hot), the primary refrigerant 161 (hot), and the dehydrated first chill down vapor 115 (hot) to the overhead LP residue gas 153 (cold), the second side draw 158 (cold), and the LP primary refrigerant liquid 163 (cold). In certain implementations, the temperatures of the hot streams 105, 161, and 115 decrease by approximately 5° F. to 15° F. through compartment #9. In certain implementations, the temperatures of the cold streams 153, 158, and 163 increase by approximately 0.1° F. to 10° F. through compartment #9. The thermal duties for P22, P23, P24, P25, and P26 can be approximately 0.8-1.2 MMBtu/h (for instance, approximately 1 MMBtu/h), approximately 3-5 MMBtu/h (for instance, approximately 4 MMBtu/h), approximately 2-4 MMBtu/h (for instance, approximately 3 MMBtu/h), approximately 8-10 MMBtu/h (for instance, approximately 9 MMBtu/h), and approximately 10-20 MMBtu/h (for instance, approximately 14 MMBtu/h), respectively.
The thermal duty of compartment #10 can be approximately 45-55 MMBtu/h (for instance, approximately 50 MMBtu/h). Compartment #10 can have six potential passes; however, in some implementations, compartment #10 has four passes (such as P27, P28, P29, and P30) for transferring heat from the first chill down liquid 105 (hot), the primary refrigerant 161 (hot), and the dehydrated first chill down vapor 115 (hot) to the overhead LP residue gas 153 (cold) and the LP primary refrigerant liquid 163 (cold). In certain implementations, the temperatures of the hot streams 105, 161, and 115 decrease by approximately 10° F. to 20° F. through compartment #10. In certain implementations, the temperatures of the cold streams 153 and 163 increase by approximately 10° F. to 20° F. through compartment #10. The thermal duties for P27, P28, P29, and P30 can be approximately 0.8-1.2 MMBtu/h (for instance, approximately 1 MMBtu/h), approximately 5-7 MMBtu/h (for instance, approximately 6 MMBtu/h), approximately 6-16 MMBtu/h (for instance, approximately 11 MMBtu/h), and approximately 27-37 MMBtu/h (for instance, approximately 32 MMBtu/h), respectively.
The thermal duty of compartment #11 can be approximately 2-12 MMBtu/h (for instance, approximately 7 MMBtu/h). Compartment #11 can have three passes (such as P31, P32, and P33) for transferring heat from the first chill down liquid 105 (hot), the primary refrigerant 161 (hot), and the dehydrated first chill down vapor 115 (hot) to the overhead LP residue gas 153 (cold). In certain implementations, the temperatures of the hot streams 105, 161, and 115 decrease by approximately 0.1° F. to 10° F. through compartment #11. In certain implementations, the temperature of the cold stream 153 increases by approximately 0.1° F. to 10° F. through compartment #11. The thermal duties for P31, P32, and P33 can be approximately 0.1-0.3 MMBtu/h (for instance, approximately 0.2 MMBtu/h), approximately 0.8-1.2 MMBtu/h (for instance, approximately 1 MMBtu/h), and approximately 5-7 MMBtu/h (for instance, approximately 6 MMBtu/h), respectively.
The thermal duty of compartment #12 can be approximately 55-65 MMBtu/h (for instance, approximately 59 MMBtu/h). Compartment #12 can have three passes (such as P34, P35, and P36) for transferring heat from the first chill down liquid 105 (hot), the primary refrigerant 161 (hot), and the dehydrated first chill down vapor 115 (hot) to the first side draw 157 (cold). In certain implementations, the temperatures of the hot streams 105, 161, and 115 decrease by approximately 15° F. to 25° F. through compartment #12. In certain implementations, the temperature of the cold stream 157 increases by approximately 15° F. to 25° F. through compartment #12. The thermal duties for P34, P35, and P36 can be approximately 1-3 MMBtu/h (for instance, approximately 2 MMBtu/h), approximately 6-8 MMBtu/h (for instance, approximately 7 MMBtu/h), and approximately 45-55 MMBtu/h (for instance, approximately 51 MMBtu/h), respectively.
The thermal duty of compartment #13 can be approximately 38-48 MMBtu/h (for instance, approximately 43 MMBtu/h). Compartment #13 can have six potential passes; however, in some implementations, compartment #13 has four passes (such as P37, P38, P39, and P40) for transferring heat from the first chill down liquid 105 (hot), the primary refrigerant 161 (hot), and the dehydrated first chill down vapor 115 (hot) to the first side draw 157 (cold) and the de-methanizer reboiler feed 155 (cold). In certain implementations, the temperatures of the hot streams 105, 161, and 115 decrease by approximately 10° F. to 20° F. through compartment #13. In certain implementations, the temperatures of the cold streams 157 and 155 increase by approximately 0.1° F. to 10° F. through compartment #13. The thermal duties for P37, P38, P39, and P40 can be approximately 0.8-1.2 MMBtu/h (for instance, approximately 1 MMBtu/h), approximately 0.8-1.2 MMBtu/h (for instance, approximately 1 MMBtu/h), approximately 3-5 MMBtu/h (for instance, approximately 4 MMBtu/h), and approximately 32-42 MMBtu/h (for instance, approximately 37 MMBtu/h), respectively.
The thermal duty of compartment #14 can be approximately 5-15 MMBtu/h (for instance, approximately 10 MMBtu/h). Compartment #14 can have four potential passes; however, in some implementations, compartment #14 has three passes (such as P41, P42, and P43) for transferring heat from the first chill down liquid 105 (hot) and the feed gas 101 (hot) to the first side draw 157 (cold) and the de-methanizer reboiler feed 155 (cold). In certain implementations, the temperatures of the hot streams 105 and 101 decrease by approximately 0.1° F. to 10° F. through compartment #14. In certain implementations, the temperatures of the cold streams 157 and 155 increase by approximately 0.1° F. to 10° F. through compartment #1. The thermal duties for P41, P42, and P43 can be approximately 0.2-0.4 MMBtu/h (for instance, approximately 0.3 MMBtu/h), approximately 0.1-0.3 MMBtu/h (for instance, approximately 0.2 MMBtu/h), and approximately 8-10 MMBtu/h (for instance, approximately 9 MMBtu/h), respectively.
The thermal duty of compartment #15 can be approximately 0.1-10 MMBtu/h (for instance, approximately 4 MMBtu/h). Compartment #15 can have two passes (such as P44 and P45) for transferring heat from the feed gas 101 (hot) to the first side draw 157 (cold) and the de-methanizer reboiler feed 155 (cold). In certain implementations, the temperature of the hot stream 101 decreases by approximately 0.1° F. to 10° F. through compartment #15. In certain implementations, the temperatures of the cold streams 157 and 155 increase by approximately 0.1° F. to 10° F. through compartment #15. The thermal duties for P44 and P45 can be approximately 0.1-0.3 MMBtu/h (for instance, approximately 0.2 MMBtu/h) and approximately 3-5 MMBtu/h (for instance, approximately 4 MMBtu/h), respectively.
The thermal duty of compartment #16 can be approximately 158-168 MMBtu/h (for instance, approximately 163 MMBtu/h). Compartment #16 can have one passes (such as P46) for transferring heat from the feed gas 101 (hot) to the HP primary refrigerant liquid 165 (cold). In certain implementations, the temperature of the hot stream 101 decreases by approximately 60° F. to 70° F. through compartment #16. In certain implementations, the temperature of the cold stream 165 increases by approximately 40° F. to 50° F. through compartment #16. The thermal duty for P46 can be approximately 158-168 MMBtu/h (for instance, approximately 163 MMBtu/h).
In some examples, the systems described in this disclosure can be integrated into an existing gas processing plant as a retrofit or upon the phase out or expansion of propane or ethane refrigeration systems. A retrofit to an existing gas processing plant allows the power consumption of the liquid recovery system to be reduced with a relatively small amount of capital investment. Through the retrofit or expansion, the liquid recovery system can be made more compact. In some examples, the systems described in this disclosure can be part of a newly constructed gas processing plant.
While this specification contains many specific implementation details, these should not be construed as limitations on the scope of the subject matter or on the scope of what may be claimed, but rather as descriptions of features that may be specific to particular implementations. Certain features that are described in this specification in the context of separate implementations can also be implemented, in combination, in a single implementation. Conversely, various features that are described in the context of a single implementation can also be implemented in multiple implementations, separately, or in any suitable sub-combination. Moreover, although previously described features may be described as acting in certain combinations and even initially claimed as such, one or more features from a claimed combination can, in some cases, be excised from the combination, and the claimed combination may be directed to a sub-combination or variation of a sub-combination.
Particular implementations of the subject matter have been described. Other implementations, alterations, and permutations of the described implementations are within the scope of the following claims as will be apparent to those skilled in the art. While operations are depicted in the drawings or claims in a particular order, this should not be understood as requiring that such operations be performed in the particular order shown or in sequential order, or that all illustrated operations be performed (some operations may be considered optional), to achieve desirable results.
Accordingly, the previously described example implementations do not define or constrain this disclosure. Other changes, substitutions, and alterations are also possible without departing from the spirit and scope of this disclosure.
This application claims the benefit of priority to U.S. Provisional Application Ser. No. 62/599,509, filed on Dec. 15, 2017, and entitled “PROCESS INTEGRATION FOR NATURAL GAS LIQUID RECOVERY,” the contents of which are hereby incorporated by reference.
| Number | Date | Country | |
|---|---|---|---|
| 62599509 | Dec 2017 | US |
