Patent Application
20050129593
The present invention relates to a reaction apparatus and a reaction method using the apparatus. More specifically, the present invention relates to a heat exchanger-integrated reaction apparatus and a reaction method using the apparatus where the reaction is performed with solid catalyst or solid reactive agent at high temperature.
Known examples of the conventional apparatus where a heat exchanger and a catalytic reactor are integrated include:
In the case of the high-temperature catalytic apparatus of (1), the apparatus itself may be made relatively compact but since the gases before and after treatment use separate flow-paths, a plurality of pipes are necessary for gas and the apparatus requires a space in the periphery. Furthermore, the treated gas after passing through the catalyst layer filled in the reactor comes into contact with the connection part of the reactor and the heat exchanger before it passes through the heat exchanger and the connection part may be heated to a high temperature, therefore, a material having high resistance against heat must be selected for the construction material of a packing or the like for sealing the connection part and the heat exchanger. In addition, the high-temperature catalytic apparatus of (1) has a problem that the flange part is baked.
In the case of the catalytic oxidation apparatus of (2) where a catalyst is coated on a honeycomb structure, the heat efficiency is improved because the heat-exchanging portion is covered with a catalyst, but the apparatus as a whole must be disassembled at the time of exchanging the catalyst and this raises a problem in view of cost and maintenance.
Furthermore, when a heater such as electric furnace is used for the heat source, the layer filled with catalyst or reactive agent undergoes a phenomenon that a temperature distribution arises in the treated gas flow direction. Even if a preheater is provided, it is difficult to improve this phenomenon and efficiently eliminate the temperature distribution, and in many cases, the catalyst or reactive agent filled in the reactor cannot be effectively used.
Under these circumstances, an object of the present invention is to provide a compact heat exchanger-integrated reaction apparatus where the temperature distribution of the reactor can be kept uniform in the gas flow direction, the heat energy recovery efficiency can be improved, the flange part in the apparatus can be prevented from overheating and a sealing material composed of a normal low-temperature construction material can be used for the flange, and also provide a reaction method using the apparatus.
As a result of extensive investigations to attain the above-described object, the present inventors have found that the object can be attained by using a reaction apparatus comprising a heat exchanger and a reactor with a heater, which are enclosed in an outer casing, the top of the heat exchanger being connected to the reactor, the other end part (the lower end) of the heat exchanger and the bottom of the outer casing being fixed by a flange, and a double piping for introducing a gas to be treated and discharging the treated gas being connected to the lower end part of the heat exchanger. The present invention has been accomplished based on this finding.
Specifically, the present invention relates to the following reaction apparatus and reaction method.
1. A reaction apparatus comprising a heat exchanger and a reactor with a heater, which are enclosed in an outer casing, the top of the heat exchanger being connected to the reactor, the other end part of the heat exchanger and the bottom of the outer casing being fixed to each other by a flange, and a double piping for introducing a gas to be treated and discharging the treated gas being connected to the other end part of the heat exchanger, such that the gas passes through the heat exchanger, the reactor and the heat exchanger in this order during the process from introducing gas through one of the inner tube and the outer tube in the double piping to discharging the gas through the other tube.
2. The reaction apparatus as described in 1 above, wherein the heat exchanger is a shell and tube-type heat exchanger.
3. The reaction apparatus as described in 1 above, wherein the outer casing has an eyebolt fixing part on the ceiling part, thereby the outer casing is detachable.
4. The reaction apparatus as described in 1 above, wherein the reactor has fins in the inside thereof.
5. The reaction apparatus as described in 1 above, wherein the fins are provided inside the inner tube in the double piping and/or between the inner tube and the outer tube in the double piping.
6. The reaction apparatus as described in 1 above, comprising a mechanism where the gas to be treated is introduced through the inner tube and discharged through the outer tube.
7. The reaction apparatus as described in 6 above, wherein the outer tube of the double piping has a heat radiating plate.
8. The reaction apparatus as described in 1 above, wherein the reaction apparatus is adapted to be installed horizontally and the reactor with a heater and the heat exchanger are placed horizontally with respect to each other.
9. A reaction method comprising passing a gas to be treated sequentially into one tube of the inner tube and the outer tube in a double piping, a heat exchanger, a reactor with a heater, the heat exchanger and the other tube in the double piping in this order, and heating the gas to be treated by the heater before the gas to be treated is introduced into the reactor, thereby adjusting the temperature difference in the gas flow direction inside the reactor.
10. The reaction method as described in 9 above, wherein the gas to be treated is introduced through the inner tube of the double piping and discharged through the outer tube.
11. The reaction method as described in 9 or 10 above, wherein the temperature difference is adjusted to 50° C. or less.
The reaction apparatus and reaction method of the present invention are described in detail below.
The reaction apparatus of the present invention comprises a heat exchanger 5 and a reactor 1 with a heater 2, which are enclosed in an outer casing 6, and in this reaction apparatus, one end part (typically, the top end part) of the heat exchanger 5 is connected to the reactor 1, the other end part (typically, the lower end part) of the heat exchanger 5 and one end part (typically, the lower end part) of the outer casing 6 are fixed by a flange 4, and a double piping 7 for introducing a gas to be treated and discharging the treated gas is connected to the end part (typically, the lower end part) of the heat exchanger 5.
The reaction apparatus of the present invention can be used, for example, in a reaction using solid reactive agent or solid catalyst for decomposition-treating a dry etching or cleaning gas discharged in the process of producing a semiconductor device, a liquid crystal display device or the like. Also, the reaction apparatus of the present invention can be used in a reaction using solid catalyst for decomposing and thereby removing nitrous oxide contained in a purge gas line for cabinet or in a waste anesthetic gas discharged from an operating room.
The reaction apparatus shown in
The bottom part of an outer casing 6 and the lower end part of the heat-exchanger are fixed to each other by a flange 4.
The shell and tube-type heat exchanger 5 means a heat exchanger where a large number of small caliber straight pipes (tube 12) are fixed by inserting their both ends into two disks and housed in one shell, and this heat exchanger is characterized in that a wide heat transfer surface can be housed in a small volume. To the disk surface at the bottom part of the heat exchanger is connected a double piping 7 which consists of an inner tube 7a for the gas before treatment to be introduced through into the heat-exchanger and an outer tube 7b for the gas after treatment to be discharged through out of the system.
The ceiling and side wall parts of the outer casing 6 are integrally formed, or the outer casing has a integrated structure where the ceiling and side wall parts are integrally joined. The outer casing has an eyebolt fixing part 9 on the ceiling part, thereby the outer casing 6 can be detached from the heat-exchanger 5 and the reactor 1 which the outer casing 6 covers, and solid reactive agents or catalysts can be easily exchanged smoothly.
In the reaction apparatus of the present invention, as a heat exchanger, although a normal type where gases flowing in countercurrent exchange heat may be used, a shell-and-tube heat exchanger is more preferably used.
In the reaction apparatus shown in
The gas to be treated, which enters from the center part of the cylindrical heat exchanger 5, flows toward the outside of the cylinder through the flow path partitioned by baffles 10 in the shell, and again flows to the center part. In
The gas before treatment (gas to be treated), which flows zigzag from side to center through a flow-path partitioned by baffles 10 in the shell and undergoes heat-exchange, then moves toward the reactor 1 through a flow port 8 present between the heat exchanger 5 and the reactor 1. The gas, which is further heated while flowing through the space between the heater 2 present on the reactor 1 and the outer casing 6 (the space in the outer side of the reactor 1), enters into the reactor 1 from the punching metal plate 3 present on the ceiling part of the reactor 1, to be reaction-treated by solid catalyst or reactive agent 11 previously filled in the reactor 1. The gas after treated outgoing from the reactor 1 flows down toward the vertical bottom through the tube 12 in the heat exchanger 5 and during this flow, is heat-exchanged with the gas before treatment as described above. After the temperature is lowered, the gas enters into the outer tube 7b of the double piping 7, heat-exchanged with the gas before treatment (gas to be treated) flowing in the inner tube 7a, and then discharged out of the system.
By using the reaction apparatus of the present invention, heat exchange can be efficiently performed between gases before and after treatment due to the above-described flow of treated gas, so that, for example, the catalyst layer filled in the reactor 1 can be greatly improved in the temperature distribution in the treated gas flow direction as compared with conventional reactors, and the temperature difference in the catalyst layer can be kept to be 50° C. or less.
Highly efficient heat exchange is essential so that the agent (catalyst) filled in the reactor 1 can keep a temperature difference of 50° C. or less uniformly in the temperature distribution in the flow direction, but more efficient heat exchange can be realized by using the reaction apparatus of the present invention, and the reasons for this include, for example:
The reactor 1 preferably has fins 13 in the inside thereof in order to increase the heat conducting region, and fins 13 placed toward the center part in the reactor contribute to making more uniform the temperature of the reactive agent or catalyst filling the reactor 1. In particular, the effect is larger when the diameter of the reactor is larger than 10 cm, though this varies depending on the conditions used.
The double piping 7 consists of an inner tube 7a and an outer tube 7b. The double piping structure is a very important factor not only for merely elevating the heat efficiency but also for saving space in the periphery of the reactor, for example, a preheater or the like for performing the preheating can be dispensed with.
Fins are preferably provided between the inner tube 7a and the outer tube 7b so that the heat exchange efficiency can be more elevated.
In the outer tube 7b of the double pining 7, where the gas after treatment flows, a heat radiating plate is preferably placed so that the heat release efficiency can be elevated and the temperature of the gas discharged out of the system can be more lowered.
According to the reaction apparatus of the present invention, the temperature distribution in the reactor can be made uniform, so that the objective temperature of the catalyst or reactive agent filling the reactor can be selected over a wide range and this can lead to improvement in efficient use of catalyst or reactive agent, elevation of the reaction ratio and reduction of costs.
At the vertical bottom of the integrated structure of which a heat exchanger 5 is connected to the lower part of the reactor 1 which has a heater 2, an outer casing 6 having a flange 4 is provided, so that the reactor 1 is laid apart from the flange 4 and heating at the flange 4 can be suppressed. For instance, even when the reaction temperature is as high as 450° C., the flange 4 can be kept at a temperature of 100° C. or less.
In conventional apparatuses, the flange near the reaction part is baked problematically, however, such a problem can be prevented by using the heat exchanger-integrated reaction apparatus of the present invention. Accordingly, a special sealing material (packing) such as carbon and metal packing is not necessary and a low-temperature sealing material (packing) usually usable at a temperature of around 100° C., such as O-ring of Viton (product name, manufactured by DuPont Dow Elastomers L.L.C.), can be used.
The reaction apparatus of the present invention, wherein the outer casing 6 has the flange 4 at the bottom, is advantageous not only in that a low-temperature sealing material can be selected but also in that the heat insulating material for fixing to the outer casing can be smoothly attached or removed and therefore, resulting in easy maintenance. Furthermore, the outer casing 6 can be disengaged from the reactor 1 integrated with the heat exchanger 5 by screwing an eyebolt into an eyebolt fixing part 9 which is provided in the ceiling part of the outer casing 6 integrated with the ceiling part, whereby the reactive agent or the catalyst can be smoothly exchanged.
The temperature on use of the reactor 1 having a heater can be set to a range from 50 to 700° C. and is preferably from 100 to 500° C., more preferably from 250 to 450° C., however, this temperature can be appropriately selected according to the kind of reaction.
The catalyst or reactive agent (filler) to fill the reactor 1 can be freely selected according to the kind of reaction and is not particularly limited. The amount of the filler, and the length or diameter of the reactor and heat exchanger are not particularly limited and can be freely selected according to the reaction conditions. In order to make uniform the temperature in the center part of the agent filling the reactor 1, fins provided for transferring heat from the portion having a heater toward the center of the reactor 1 contribute to making the temperature distribution uniform. The number of fins and the length thereof are not particularly limited and these can be freely selected according to the reaction conditions.
The reaction method of the present invention is characterized by passing a gas to be treated sequentially into one of an inner tube 7a and an outer tube 7b in a double piping 7, a heat exchanger 5, a reactor 1 with a heater 2, the heat exchanger 5 and the other tube of the inner tube 7a and the outer tube 7b in the double piping 7, and heating the gas to be treated by the heater 2 before the gas to be treated is introduced into the reactor 1, thereby adjusting the temperature difference in the gas flow direction inside the reactor.
According to the reaction method of the present invention, the temperature difference in the temperature distribution with respect to the gas flow direction in the layer filled with catalyst/reactive agent in the reactor can be uniformly kept to be 50° C. or less. Therefore, the reaction method of the present invention can be used for various decomposition reactions and synthesis reactions where the reaction temperature needs to be controlled to be uniform.
For comparison, with respect to a conventional reaction apparatus for 40 L having an externally heating system as shown by
The present invention provides an apparatus comprising a structure where a shell and tube-type heat exchanger and a reactor with a heater are integrated and the piping for flowing a gas through in the reaction apparatus has a double piping structure consisting of an inner tube and an outer tube for passing the gases before treatment and after treatment in the countercurrent flow.
By using the apparatus of the present invention, the heat exchange efficiency is elevated. In addition, the reactor having a heater is useful for the temperature distribution in the gas flow direction inside the reactor to be made uniform. The catalyst or reactive agent filling the reactor can be kept at the objective temperature over a wide area and the catalyst or the like can be effectively used in catalytic reactions and the like where temperature control is desirable. Furthermore, since a heat exchanger and a reactor with a heater are integrated and the piping for flowing a gas through in the reaction apparatus has a double piping structure consisting of an inner tube and an outer tube for passing the gases before treatment and after treatment in the countercurrent flow, the reaction apparatus can be downsized and the space in the periphery of the reaction apparatus can be saved.
| Number | Date | Country | Kind |
|---|---|---|---|
| 2002-085149 | Mar 2002 | JP | national |
This application is based on the provisions of 35 U.S.C. Article 111(a) with claiming the benefit of filing dates of U.S. provisional application Ser. No. 60/368,965 filed on Apr. 2, 2002 under the provisions of 35 U.S.C. 111(b), pursuant to 35 U.S.C. Article 119(e)(1).
| Filing Document | Filing Date | Country | Kind |
|---|---|---|---|
| PCT/JP03/03591 | 3/25/2003 | WO |
| Number | Date | Country | |
|---|---|---|---|
| 60368965 | Apr 2002 | US |
