Claims
- 1. An improved fiber reinforced polyoxymethylene molding composition capable of forming composite articles exhibiting improved physical properties comprising an admixture of (1) a polyoxymethylene polymer, (2) about 2 to 60 percent by weight based on the total weight of the composition of a fibrous reinforcement, and (3) about 0.5 to 5 percent by weight based on the total weight of the composition of a polycarbodiimide which is (a) derived from an aromatic isocyanate which is unsubstituted or substituted with up to one methyl group per aromatic ring and (b) contains at least three carbodiimide units per polycarbodiimide molecule.
- 2. The improved fiber reinforced polyoxymethylene molding composition of claim 1 wherein the fibrous reinforcement is glass fiber in an amount of about 5 to 50 percent by weight based on the total weight of the composition.
- 3. The improved fiber reinforced polyoxymethylene molding composition of claim 2 wherein the polyoxymethylene polymer has an inherent viscosity of at least 0.8 (measured at 60.degree. C. in a 0.1 weight percent solution in p-chlorophenol containing 2 weight percent of alpha-pinene), a weight average molecular weight of at least 35,000, and a melting point of at least 150.degree. C.
- 4. The improved fiber reinforced polyoxymethylene molding composition of claim 3 wherein the polyoxymethylene polymer is a copolymer comprising about 60 to about 99.6 mole percent recurring --OCH.sub.2 -- groups.
- 5. The improved fiber reinforced polyoxymethylene molding composition of claim 4 wherein the polyoxymethylene polymer has been pre-stabilized by melt hydrolysis prior to admixture with components (2) and (3).
- 6. The improved fiber reinforced polyoxymethylene molding composition of claim 4 wherein the polyoxymethylene polymer is pre-stabilized by the addition of an antioxidant and an acid scavenger.
- 7. The improved fiber reinforced polyoxymethylene molding composition of claim 6 wherein said antioxidant is 2,2'-methylene-bis-(4-methyl-6-tertiary butyl phenol), and said acid scavenger is cyanoguanidine.
- 8. The improved fiber reinforced polyoxymethylene molding composition of claim 4 wherein said polycarbodiimide is selected from the group consisting of poly(tolyl carbodiimide), poly(4,4'-diphenylmethane carbodiimide), poly(3,3'-dimethyl-4,4'-biphenylene carbodiimide, poly(p-phenylene carbodiimide), poly(m-phenylene carbodiimide), poly(3,3'-dimethyl-4,4'-diphenylmethane carbodiimide), and mixtures thereof.
- 9. The improved fiber reinforced polyoxymethylene molding composition of claim 2 wherein the polyoxymethylene polymer is a mixture of a melt hydrolysis stabilized polymer and a solution hydrolysis stabilized polymer.
- 10. An improved fiber reinforced polyoxymethylene molding composition capable of forming composite articles exhibiting improved physical properties comprising an admixture of (1) a polyoxymethylene polymer, (2) about 2 to 60 percent by weight based on the total weight of the composition of a fibrous reinforcement, and (3) about 0.6 to 5 percent by weight based on the total weight of the composition of a polycarbodiimide which is (a) derived from an aromatic isocyanate which is unsubstituted or substituted with up to one methyl group per aromatic ring and (b) contains at least three carbodiimide units per polycarbodiimide molecule, and a high molecular weight thermoplastic phenoxy resin; the weight ratio of the polycarbodiimide to phenoxy resin being in the range of 1:16 to 50:1.
- 11. The improved fiber reinforced polyoxymethylene molding composition of claim 10 wherein the phenoxy resin has the repeating structure: ##STR4## and a weight average molecular weight of from about 15,000 to 75,000.
- 12. The improved fiber reinforced polyoxymethylene molding composition of claim 11 wherein the fibrous reinforcement in glass fiber in an amount of about 5 to 50 percent by weight based on the total weight of the composition.
- 13. The improved fiber reinforced polyoxymethylene molding composition of claim 12 wherein the polyoxymethylene polymer has an inherent viscosity of at least 0.8 (measured at 60.degree. C. in a 0.1 weight percent solution in p-chlorophenol containing 2 weight percent of alpha-pinene), a weight average molecular weight of at least 35,000, and a melting point of at least 150.degree. C.
- 14. The improved fiber reinforced polyoxymethylene molding composition of claim 13 wherein the polyoxymethylene polymer is a copolymer comprising about 60 mole to about 99.6 mole percent of recurring --OCH.sub.2 -- groups.
- 15. The improved fiber reinforced polyoxymethylene molding composition of claim 14 wherein the polyoxymethylene polymer has been pre-stabilized by melt hydrolysis prior to admixture with components (2) and (3).
- 16. The improved fiber reinforced polyoxymethylene molding composition of claim 14 wherein the polyoxymethylene polymer is pre-stabilized by the addition of an antioxidant and an acid scavenger.
- 17. The improved fiber reinforced polyoxymethylene molding composition of claim 16 wherein said antioxidant is 2,2'-methylene-bis-(4-methyl-6-tertiary butyl phenol), and said acid scavenger is cyanoguanidine.
- 18. The improved fiber reinforced polyoxymethylene molding composition of claim 14 wherein said polycarbodiimide is selected from the group consisting of poly(tolyl carbodiimide), poly(4,4'-diphenylmethane carbodiimide), poly (3,3'-dimethyl-4,4'-biphenylene carbodiimide), poly(p-phenylene carbodiimide), poly(m-phenylene carbodiimide), poly(3,3'-dimethyl-4,4'-diphenylmethane carbodiimide), and mixtures thereof.
- 19. The improved fiber reinforced polyoxymethylene molding composition of claim 12 wherein the polyoxymethylene polymer is a mixture of a melt hydrolysis stabilized polymer and a solution hydrolysis stabilized polymer.
- 20. A fiber reinforced injection molded polyoxymethylene composite article exhibiting improved physical properties formed from the molding composition of claim 1.
CROSS-REFERENCE TO RELATED APPLICATION
This is a continuation-in-part of U.S. Ser. No. 751,850, filed Dec. 17, 1976 now abandoned.
US Referenced Citations (3)
Number |
Name |
Date |
Kind |
3135718 |
Wagner et al. |
Jun 1964 |
|
3170896 |
Wagner et al. |
Feb 1965 |
|
3455867 |
Berardinelli et al. |
Jul 1969 |
|
Foreign Referenced Citations (1)
Number |
Date |
Country |
993,600 |
May 1965 |
GBX |
Continuation in Parts (1)
|
Number |
Date |
Country |
Parent |
751850 |
Dec 1976 |
|