Resin material remolding method and resin material pulverized piece selecting apparatus

FIELD OF THE INVENTION

[0001] The present invention relates to a resin material remolding method which, when recycling coated resin molded products, prepares pulverized pieces obtained upon pulverization and coating film peeling, separates the pulverized pieces into those having the coating film adhered and those having no coating film adhered, and performs molding by using only the pulverized pieces having no coating film adhered, and a resin material pulverized piece selecting apparatus.

BACKGROUND OF THE INVENTION

[0002] Generally, when coated resin molded products such as resin bumpers as automobile parts are to be recycled, if a coating film remains as foreign matter in this resin, the resin cracks from this portion when an external force is applied to the resin. In addition to this physical property problem, the external appearance worsens.

[0003] Accordingly, it is being desired to perform recycling by using only a resin having no coating film as foreign matter.

[0004] To reuse plastic molded products, therefore, a plastic recycling method which recycles plastic molded products by peeling a coating film has already been invented.

[0005] That is, this plastic recycling method (e.g., Japanese Patent Laid-Open No. 2001-353721) includes a fine plastic piece formation step of forming a plate-like fine piece aggregate (i.e., fine pieces) of coated plastic molded products, a coating film peeling step of peeling the coating film from the coated fine plastic pieces by rubbing using a mechanical force to obtain a fine piece/powder mixture of the fine pieces from which the coating film is peeled and the coating film powder, and a fine piece/powder separation step of separating this fine piece/powder mixture into the fine pieces from which the coating film is peeled and the coating film powder.

[0006] In this method disclosed in Japanese Patent Laid-Open No. 2001-353721, coated resin molded products are pulverized, the coating film is removed by peeling from the pulverized pieces having the coating film adhered, and performs remolding by using the pulverized pieces from which the coating film is peeled.

[0007] Unfortunately, this conventional method and its apparatus have the following problems.

[0008] That is, peeling the coating film from the pulverized pieces of the coated resin molded products requires a certain processing time (e.g., 50 to 60 min or more) in the rubbing action using the mechanical force, and the removal ratio of the coating film is low compared to the coating film peeling time. It is practically very difficult to completely peel the coating film only with the rubbing action using the mechanical force; even when the processing time is extended to 50 to 60 min or more, the coating film removal ratio does not increase so much.

[0009] In addition, if the coating film peeling process described above is continued, the rubbing action by the mechanical force is also exerted on pulverized pieces from which the coating film is already peeled. This decreases the particle diameter of the pulverized pieces too much, and excessively reduces the amount of the pulverized pieces. Consequently, recycle molding cannot be well performed, or the resin collection ratio largely decreases. Furthermore, when the coating film peeling process is continued, the coating film area on each pulverized piece becomes too small. Therefore, if pulverized pieces having the coating film adhered are to be sensed by using a sensor instead of the means disclosed in Japanese Patent Laid-Open No. 2001-353721 by which the fine resin pieces and coating film powder are separated by screening, the sensor is required to have high sensing accuracy, and sensing errors occur.

SUMMARY OF THE INVENTION

[0010] The present invention is made on the basis of the novel findings that when, after pulverization and coating film peeling, pulverized pieces to which the coating film not peeled by the coating film peeling adheres and pulverized pieces having no coating film adhered are separated, a substantial coating film removal ratio effectively increases, and has as its object to provide a resin material remolding method which prepares pulverized pieces obtained upon pulverization and coating film peeling of coated resin molded products, senses and determines the presence/absence of adhesion of the coating film for each individual pulverized piece, separates a pulverized piece having the coating film adhered from pulverized pieces having no coating film adhered on the basis of the determination result, and performs molding by using the pulverized pieces having no coating film adhered after the separation, thereby effectively increasing the coating film removal ratio (the collection ratio of pulverized pieces having no coating film adhered to all pulverized pieces to be processed) within a short time period without taking a long time in the coating film peeling/separation process, and increasing the material yield.

[0011] It is another object of the present invention to provide a resin material pulverized piece selecting apparatus which, from pulverized pieces subjected to pulverization and coating film peeling, senses a pulverized piece having the coating film adhered on the basis of the coating film itself or a specific material present in the coating film, determines the pulverized piece having the coating film adhered on the basis of the result of sensing, and separates the pulverized piece having the coating film adhered from pulverized pieces having no coating film adhered on the basis of the determination result, thereby effectively increasing the coating film removal ratio within a short time period without taking a long time in the coating film peeling process, and increasing the material yield.

[0012] A resin material remolding method according to the present invention, comprises a preparation step of preparing pulverized pieces obtained upon pulverization of a coated resin molded product and coating film peeling of pulverized pieces, a determination step of sensing and determining the presence/absence of adhesion of the coating film for each individual pulverized piece after the preparation step, a separation step of separating a pulverized piece having the coating film adhered from pulverized pieces having no coating film adhered, on the basis of the determination result, and a molding step of performing molding by using the pulverized pieces having no coating film adhered after the separation step.

[0013] Coating film peeling in the preparation step of the present invention is preferably complete within a time period (e.g., 30 min or less) shorter than the conventional processing time (e.g., 50 to 60 min).

[0014] In the preparation step of the present invention, pulverized pieces obtained upon pulverization of coated resin molded products and coating film peeling of pulverized pieces are prepared. In the next determination step, the presence/absence of adhesion of the coating film is sensed and determined for each individual pulverized piece. In the next preparation step, a pulverized piece having the coating film adhered (a product having the residual coating film) is separated from pulverized pieces having no coating film adhered (products having no residual coating film) on the basis of the determination result. In the next molding step, molding is performed using the pulverized pieces having no coating film adhered after the separation step.

[0015] As described above, after pulverization and coating film peeling, pulverized pieces having the coating film adhered and pulverized pieces having no coating film adhered are separated. Therefore, it is possible to effectively increase the coating film removal ratio (the collection ratio of pulverized pieces having no coating film adhered with respect to all pulverized pieces to be processed) within a short time period without taking a long time in the coating film peeling process. Consequently, the material yield can be increased.

[0016] Especially when coating film peeling is terminated while the area of the coating film remaining on some pulverized pieces is relatively large and the thus prepared pulverized pieces are selectively separated into those having the coating film adhered and those having no coating film adhered, the selection accuracy increases, and the reduction in weight of the resin decreases. As a consequence, it is possible to obtain a high collection ratio and increase the coating film removal ratio.

[0017] According to an embodiment of the present invention, the determination step senses and determines the presence/absence of adhesion of the coating film by sensing the coating film itself or a specific material present in the coating film by using a sensor.

[0018] The sensor for sensing the coating film itself can be a photosensor such as a CCD sensor. The sensor for sensing a specific material present in the coating film can be X-ray sensing means for sensing X-rays having a specific wavelength excited from a specific material in the coating film irradiated with X-rays. The specific material can be specified to titanium oxide TiO2 as a main component of a white pigment, or chlorine Cl as a component of a primer (undercoating of painting) below black coating.

[0019] In the above embodiment, it is readily possible to sense a pulverized piece having the coating film adhered by using the sensor.

[0020] According to another embodiment of the present invention, the determination step executes the sensing by using a photosensor for sensing the coating film on the basis of a difference in lightness, saturation, or hue from a background color set behind the pulverized pieces and different from a coating film color.

[0021] In the embodiment, the coating film can be sensed by using the background color different from the coating film color. Since this reduces sensing errors, the coating film sensing accuracy can be simply and effectively increased.

[0022] According to still another embodiment of the present invention, the sensing is executed by sensing means for irradiating the pulverized pieces with X-rays, and sensing X-rays having a specific wavelength excited from a specific material present in the coating film.

[0023] The specific wavelength in the embodiment is 4.508 Å when the specific material is titanium oxide, and 2.621 Å when the specific material is chlorine.

[0024] In the embodiment, the coating film sensing accuracy can be easily and effectively increased even if the coating film color is the same as or close to the color of the pulverized piece itself.

[0025] According to still another embodiment of the present invention, the sensing is executed for the pulverized pieces in a plurality of directions.

[0026] The plurality of directions in the above arrangement are preferably a plurality of directions at different angles.

[0027] In the embodiment, adhesion of the coating film is sensed in a plurality of directions by the sensor. Accordingly, a pulverized piece having the coating film adhered can be accurately sensed regardless of the posture of the pulverized piece.

[0028] According to still another embodiment of the present invention, the determination step executes the sensing in a specific position midway along a moving path in which the pulverized pieces are moved in a specific direction, and the separation step executes the separation, when a pulverized piece having the coating film adhered is sensed in the determination step, by blowing a gas against the pulverized piece to change a moving direction of the pulverized piece having the coating film adhered to a direction different from a moving direction of a pulverized piece having no coating film adhered.

[0029] The specific moving direction of the pulverized pieces in the above arrangement can be any of a vertical direction, horizontal direction, and inclined direction.

[0030] In the embodiment, coating film sensing can be efficiently executed on a large number of pulverized pieces. Additionally, since the course of moving of a pulverized piece having the coating film adhered can be changed by air blow, pulverized pieces having the coating film adhered and pulverized pieces having no coating film adhered can be separated by a simple method.

[0031] According to still another embodiment of the present invention, the movement of the pulverized pieces is falling.

[0032] The falling can be natural falling.

[0033] The embodiment obviates the need for special moving means (or conveying means) such as conveyor rollers or conveyor belts for moving the pulverized pieces, so pulverized pieces having the coating film adhered and pulverized pieces having no coating film adhered can be separated by a simpler method. Additionally, coating film sensing by the sensor is executed while the pulverized pieces are falling. This allows rapid and easy execution of the series of sensing and separation steps.

[0034] According to still another embodiment of the present invention, in the pulverization, the coated resin molded product is pulverized at random by using a cutting tool having a rotary blade, and the determination step is executed, after pulverized pieces are classified into a plurality of groups in accordance with particle diameters of the pulverized pieces, for each classified particle-diameter group.

[0035] In the embodiment, the coated resin molded products can be easily pulverized by the cutting tool described above. The pulverized pieces obtained by this random pulverization have various sizes. When coating film sensing is performed, therefore, small-particle-diameter pulverized pieces having the coating film adhered are hidden behind large-particle-diameter pulverized pieces having no coating film adhered, so the sensing accuracy decreases. This can be prevented by classifying the pulverized pieces in accordance with the particle diameter.

[0036] According to still another embodiment of the present invention, the coated resin molded product is a used automobile part.

[0037] The automobile part in the embodiment can be a coated resin molded product such as a front bumper, rear bumper, front grill, mirror housing, or spoiler.

[0038] In the above arrangement, the used automobile part can be recycled through pulverization, coating film peeling, and remolding.

[0039] An apparatus for selecting resin material pulverized pieces obtained upon pulverization of a coated resin molded product and coating film peeling of pulverized pieces according to the present invention, comprises a sensor placed in a specific position with respect to the pulverized pieces to sense a pulverized piece having a coating film adhered on the basis of the coating film itself or a specific material present in the coating film, determining means for determining the pulverized piece having the coating film adhered on the basis of the result of sensing by the sensor, and separating means for separating the pulverized piece having the coating film adhered from pulverized pieces having no coating film adhered on the basis of the result of determination by the determining means.

[0040] In the apparatus, the sensor senses a pulverized piece having the coating film adhered among other pulverized pieces on the basis of the coating film itself or the specific material present in the coating film. The determining means determines the pulverized piece having the coating film adhered on the basis of the result of sensing by the sensor. The separating means separates the pulverized piece having the coating film adhered from pulverized pieces having no coating film adhered on the basis of the result of determination by the determining means.

[0041] As described above, sensing, determination, and separation of the pulverized pieces having the coating film adhered and pulverized pieces having no coating film adhered are executed after pulverization and coating film peeling. Therefore, it is possible to effectively increase the coating film removal ratio (the collection ratio of pulverized pieces having no coating film adhered with respect to all pulverized pieces to be processed) within a short time period without taking a long time in the coating film peeling process. Consequently, the material yield can be increased.

[0042] According to an embodiment of the present invention, the sensor is a photosensor for sensing the coating film on the basis of a difference in lightness, saturation, or hue from a background color different from a coating film color.

[0043] The photosensor in the embodiment can be a CCD sensor.

[0044] In the embodiment, coating film sensing is executed by using the background color different from the coating film color. Since this reduces sensing errors, the coating film sensing accuracy can be easily and effectively increased.

[0045] According to another embodiment of the present invention, the sensor is X-ray sensing means for sensing X-rays having a specific wavelength excited from a specific material present in the coating film when a pulverized piece is irradiated with X-rays.

[0046] The specific material in the embodiment can be specified to titanium oxide TiO2 as a main component of a white pigment, or chlorine Cl as a component of a primer below black painting. When the specific material is TiO2, the specific wavelength is 4.508 Å. When the specific material is Cl, the specific wavelength is 2.621 Å.

[0047] In the embodiment, the coating film sensing accuracy can be easily and effectively increased even if the coating film color is the same as or close to the color of the pulverized piece itself.

[0048] According to still another embodiment of the present invention, a plurality of the sensors are arranged to sense the presence/absence of adhesion of the coating film for pulverized pieces in a plurality of directions.

[0049] The plurality of directions in the embodiment are preferably a plurality of directions at different angles.

[0050] In the embodiment, adhesion of the coating film is sensed in a plurality of directions by the sensor. Therefore, a pulverized piece having the coating film adhered can be accurately sensed regardless of the posture of the pulverized piece.

[0051] According to still another embodiment of the present invention, the apparatus further comprises moving means for moving pulverized pieces in a specific direction, and the separating means is placed in a specific position midway along a moving path of the moving means for moving pulverized pieces and comprises gas blowing means for, when the determining means senses a pulverized piece having the coating film adhered, blowing a gas against the pulverized piece to change a moving direction of the pulverized piece having the coating film adhered to a direction different from a moving direction of a pulverized piece having no coating film adhered, thereby executing the separation.

[0052] The specific moving direction of pulverized pieces in the embodiment can be any of a vertical direction, horizontal direction, and inclined direction.

[0053] In the embodiment, the coating film of a large number of pulverized pieces can be efficiently sensed. In addition, the course of moving of a pulverized piece having the coating film adhered can be changed by air blow. Therefore, pulverized pieces having the coating film adhered and pulverized pieces having no coating film adhered can be separated with a simple arrangement.

[0054] According to still another embodiment of the present invention, the moving means is dropping means for dropping pulverized pieces.

[0055] The falling can be natural falling.

[0056] The embodiment eliminates the need for any special moving means such as conveyor rollers and conveyor belts for moving the pulverized pieces. Accordingly, pulverized pieces having the coating film adhered and pulverized pieces having no coating film adhered can be separated with a simpler arrangement. Additionally, since coating film sensing by the sensor is performed while the pulverized pieces are falling, the series of sensing and separation steps can be rapidly and easily performed.

[0057] According to still another embodiment of the present invention, the apparatus further comprises classifying means placed in a pulverized piece charge port to classify pulverized pieces into a plurality of groups in accordance with particle diameters of the pulverized pieces, and the sensor performs the sensing for each of the plurality of groups of the pulverized pieces.

[0058] In the embodiment, the classifying means classifies the pulverized pieces into a plurality of groups in accordance with the particle diameter. If the pulverized pieces have various sizes, small-particle-diameter pulverized pieces having the coating film adhered are hidden behind large-particle-diameter pulverized piece having no coating film adhered while coating film sensing is performed by the sensor, so the sensing accuracy decreases. Therefore, this can be prevented by a simple arrangement.

[0059] According to still another embodiment of the present invention, the classifying means is a screening device for classifying pulverized pieces in accordance with the particle diameter.

[0060] In the screening classification in the embodiment, pulverized pieces can be classified into two groups of large and small pieces, three groups of large, medium, and small pieces, or a larger number of groups.

[0061] In the embodiment, classification can be appropriately performed by a simple apparatus. The screening device is an apparatus which uses a screen or porous plate having meshes of a predetermined size, and classifies (screens) the pulverized pieces into those which pass through the meshes and those which do not.

[0062] Other features and advantages of the present invention will be apparent from the following description taken in conjunction with the accompanying drawings, in which like reference characters designate the same or similar parts throughout the figures thereof.

BRIEF DESCRIPTION OF THE DRAWINGS

[0063] The accompanying drawings, which are incorporated in and constitute a part of the specification, illustrate embodiments of the invention and, together with the description, serve to explain the principles of the invention.

[0064]
FIG. 1 is a view for explaining a pulverizer for pulverizing coated resin molded products;

[0065]
FIG. 2 is a view for explaining a coating film peeling apparatus;

[0066]
FIG. 3 is a view for explaining a resin material pulverized piece selecting apparatus;

[0067]
FIG. 4 is an enlarged side view of the main components shown in FIG. 3;

[0068]
FIG. 5 is a view for explaining an air-blow portion;

[0069]
FIG. 6 is a block diagram of a control circuit;

[0070]
FIG. 7 is a flow chart showing a resin material remolding method;

[0071]
FIG. 8 is a flow chart showing a classification step, determination step, and separation step;

[0072]
FIG. 9 is a graph showing the relationship between the processing time, residual coating film area, and frequency;

[0073]
FIG. 10 is a graph showing the relationship between the coating film peeling time and coating film removal ratio;

[0074]
FIG. 11 is a graph showing the characteristics of the coating film removal ratio;

[0075]
FIG. 12 is a sectional view showing another embodiment of the present invention;

[0076]
FIG. 13 is a sectional view showing still another embodiment of the present invention;

[0077]
FIG. 14 is a side view showing still another embodiment of the present invention;

[0078]
FIG. 15 is a block diagram of a control circuit of the apparatus shown in FIG. 14; and

[0079]
FIG. 16 is a side view showing still another embodiment of the present invention.

DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS

[0080] Preferred embodiments of the present invention will now be described in detail in accordance with the accompanying drawings.

[0081] These drawings illustrate a resin material remolding method and resin material pulverized piece selecting apparatus. First, the arrangement of an apparatus for use in the resin material remolding method will be described below with reference to FIGS. 1 to 5. For the sake of convenience of explanation, used automobile parts (coated resin molded products) are resin bumpers in the following embodiments.

[0082]
FIG. 1 shows a pulverizer 3 for pulverizing a coated resin molded product 1 (resin bumper) into pulverized pieces 2. The pulverizer 3 has a cutter mill 6 as a cutting tool in a pulverization space 5 which continues to a charge port 4. A plurality of rotary blades 7 are integrated with the outer circumferential surface of the cutter mill 6, and a screen 8 is placed below the cutter mill 6. The coated resin molded product 1 charged into the pulverization space 5 is coarsely pulverized at random by rotating the cutter mill 6 in the direction of an arrow, and the pulverized pieces 2 are allowed to fall through the meshes of the screen 8.

[0083] The pulverized pieces 2 have various sizes, and the coating film has not been peeled from the pulverized pieces 2. Therefore, a coating film b is sticking to a resin a. In FIG. 1, the resin a is hatched, and the coating film b is blanked.

[0084]
FIG. 2 shows a coating film peeling apparatus 9 for peeling the coating film b from the resin a of the pulverized pieces 2 obtained by the pulverizer 3 shown in FIG. 1. In the coating film peeling apparatus 9, a plurality of blades 12 are attached to a rotary member 11 formed on the inner bottom surface of a peeling bath 10. A driving unit 13 having a built-in motor is placed below the peeling bath 10. When the pulverized pieces 2 are charged into the peeling path 10 and the rotary member 11 is rotated, the coating film b of the pulverized pieces 2 is peeled by the blades 12.

[0085] As shown in FIG. 3, the pulverized pieces 2 processed by the coating film peeling apparatus 9 contain pulverized pieces (to be simply referred to as OK products hereinafter) A from which the coating film b is completely removed and which hence has no coating film adhered, and pulverized products (to be simply referred to as NG products hereinafter) B having the coating film b remaining on the resin a, i.e., having the coating film adhered.

[0086]
FIG. 3 shows a resin material pulverized piece selecting apparatus 14 for performing classification, coating film sensing, and separation for the pulverized products 2 (including both the OK products A and NG products B) processed by the coating film peeling apparatus 9 shown in FIG. 2.

[0087] The selecting apparatus 14 includes a material charge port 15 for charging the pulverized pieces 2 having various sizes and containing both the OK products A and NG products B,

[0088] a conveyor 16 for conveying upward the pulverized pieces 2 charged through the material charge port 15,

[0089] a conveyor 18 formed between the upper portion of the conveyor 16 and a position above a charge port 17a of a hopper 17 to supply the pulverized pieces 2 into the charge port 17a of the hopper 17,

[0090] a screening device 19 formed inside the hopper 17 below the charge port 17a to function as a classifying means for classifying the pulverized pieces 2 into a plurality of groups in accordance with the particle diameter (or particle size),

[0091] two chutes 20 and 21 (dropping means) as moving means for naturally dropping the pulverized pieces 2 classified by the screening device 19 separately as small pulverized pieces 2S and large pulverized pieces 2L, thereby moving the pulverized pieces 2 in a specific direction, i.e., downward,

[0092] a sensor 23 placed below the chutes 20 and 21 to sense the NG products B of the falling pulverized pieces 2 for each of the plurality of groups,

[0093] a separator 24 placed below the sensor 23 to separate the NG products B from the OK products A, and

[0094] collection tanks 25 and 26 formed below the separator 24 to separately collect the NG products B and OK products A, respectively.

[0095] The screening device 19 has a screen or porous plate 19b having meshes 19a of a predetermined size, and screens the pulverized pieces 2 charged from the charge port 17a into the small pulverized pieces 2S which pass through the meshes 19a and the large pulverized pieces 2L which do not pass through the meshes 19a. The small pulverized pieces 2S thus screened naturally fall into the chute 20 as a dropping means, and the large pulverized pieces 2L naturally fall into the chute 21 as another dropping means.

[0096] In this embodiment, the pulverized pieces 2 are classified into two sizes, i.e., the small pulverized pieces 2S and large pulverized pieces 2L for the sake of illustrative convenience. However, the pulverized pieces 2 may also be classified into three or more sizes.

[0097]
FIG. 4 is an enlarged view for explaining the sensor 23 and collection tanks 25 and 26 shown in FIG. 3. The sensor 23, separator 24, and collection tanks 25 and 26 used for the small pulverized pieces 2S naturally falling in the chute 20 are the same as those used for the large pulverized pieces 2L naturally falling in the chute 21, so the operation of one of these systems will be explained in detail below.

[0098] As shown in FIG. 4, the chute 20 is inclined at a predetermined angle from the lower portion of the hopper 17 toward the collection tank 26. A chute extended portion 27 is formed on the extension line of the chute 20. Also, a chute branched portion 28 for guiding the NG products B to the collection tank 25 is branched from the middle portion of the chute extended portion 27.

[0099] A sensing space 29 is formed between the lower end of the chute 20 and the upper end of the chute extended portion 27. Instead of the sensing space 29, a colorless, transparent intermediate chute may also be used to connect the lower end of the chute 20 and the upper end of the chute extended portion 27.

[0100] A CCD sensor 30 as an photosensor and a background member 31 in background color, e.g., black, different from the coating film color oppose each other in positions above and below the sensing space 29.

[0101] The CCD sensor 30 is a photosensor for sensing the NG products B of the naturally falling pulverized pieces 2 from the front of the chute (i.e., in one direction).

[0102] To sense the NG products B in another direction, i.e., at an angle different from that of the CCD sensor 30, a CCD sensor 32 as another photosensor and a background member 33 in background color, e.g., black, different from the coating film color oppose each other in positions below and above the sensing space 29.

[0103] The CCD sensor 32 is a photosensor for sensing the NG products B of the naturally falling pulverized products 2 from the back of the chute (i.e., in the other direction). The CCD sensors 30 and 32 sense the coating film b on the basis of a difference in lightness, saturation, or hue from the background color of the background members 31 and 33, which is different from the coating film color.

[0104] A pair of color fluorescent lamps 34 as illuminating means are arranged near the image sensing lens of each of the CCD sensors 30 and 32. The color of light emitted from the color fluorescent lamps 34 is desirably green in order to reduce sensing errors.

[0105] In addition, an ejector 36 having a plurality of air-blow holes 35 (FIG. 5) is formed over the entire width of the falling flow path of the pulverized pieces 2, so as to oppose the upper end opening of the chute branched portion 28. An air-blow nozzle 37 is an air blowing means. When the CCD sensor 30 or 32 senses an NG product B, the air-blow nozzle 37 blows air as a gas against the falling NG product B in synchronism with the falling timing of the NG product B, thereby changing the course of falling from the chute extended portion 27 to the chute branched portion 28. In this manner, the air-blow nozzle 37 changes the moving direction of the NG product B to a direction different from the moving direction of the OK products A, thereby separating the NG product B from the OK products.

[0106] As shown in FIG. 5, when the CCD sensor 30 or 32 senses an NG product B, air is blown from a specific air-blow hole 35a of the ejector 36 in synchronism with the timing at which the NG product B falls to a position in front of the ejector 36. As shown in FIG. 4, the course of the NG product B is changed to the chute branched portion 28, and the NB product B is thus separated. If the size of an NG product B is large, air is blown from a plurality of corresponding air-blow holes 35 at the same time. The air-blow nozzle 37 is installed for each of the air-blow holes 35.

[0107]
FIG. 6 is a block diagram of a control circuit of the resin material pulverized piece selecting apparatus. On the basis of inputs from the CCD sensors 30 and 32 and a color difference meter 51 as a color difference measurement device, a CPU 50 controls driving of the air-blow nozzles 37 and color fluorescent lamps 34 in accordance with programs stored in a ROM 52. A RAM 53 stores necessary data such as a reference value (reference lightness) for separating the OK products A and NG products B.

[0108] Note that a CCD sensor 45 having an X-ray function is used in another embodiment (to be described later).

[0109] The CPU 50 also serves as a determining means for determining pulverized pieces 2 having the coating film b adhered, i.e., NG products B on the basis of the results of sensing by the CCD sensors 30 and 32. The separator 24 separates the NG products B from the OK products A on the basis of the results of determination by the CPU 50.

[0110] The resin material remolding method will be described below with reference to a flow chart shown in FIG. 7.

[0111] In collection step S1, used coated resin molded products 1 (resin bumpers) are collected.

[0112] In pulverization step S2, the coated resin molded products 1 are pulverized into pulverized pieces 2 by the pulverizer 3 shown in FIG. 1. That is, the coated resin molded products 1 are charged into the pulverizing space 5 from the charge port 4 of the pulverizer 3, and coarsely pulverized at random by the rotary blades 7 by the rotation of the cutter mill 6.

[0113] After pulverization step S2, the coating film b is sticking to the resin a of the pulverized pieces 2, and the pulverized pieces 2 have various sizes.

[0114] In peeling step S3, the coating film b is peeled from the pulverized pieces 2. That is, the pulverized pieces 2 obtained in pulverization step S2 are charged into the peeling bath 10 of the coating film peeling apparatus 9 shown in FIG. 2, and the coating film b is peeled from the resin a by the blades 12 by driving the rotary member 11. Steps S1, S2, and S3 of FIG. 7 make up a preparation step of pulverizing the coated resin molded products 1 and preparing the pulverized pieces 2 (including both OK products A and NG products B) from which the coating film is peeled.

[0115] In classification step S4 of FIG. 7, the pulverized pieces 2 from which the coating film is peeled are classified into a plurality of groups in accordance with the particle diameter. In determination step S5 of FIG. 7, the presence/absence of adhesion of the coating film is sensed and determined for each individual pulverized piece 2. In separation step S6 of FIG. 7, the NG products B are separated from the OK products A on the basis of the determination results. Details of steps S4, S5, and S6 will be explained below with reference to FIG. 8.

[0116] In step Q1 of FIG. 8, the pulverized pieces 2 obtained upon peeling step S3 (FIG. 7) are charged into the material charge port 15 of the selecting apparatus 14 shown in FIG. 3.

[0117] In step Q2, the charged pulverized pieces 2 are conveyed from the charge port 17a of the hopper 17 onto the screening device 19 via the conveyors 16 and 18. In step Q3, the pulverized pieces 2 are screened (classified) into small pulverized pieces 2S which pass through the meshes 19a and large pulverized pieces 2L which do not pass through the meshes 19a by horizontally reciprocating the porous plate 19b of the screening device 19.

[0118] The small pulverized pieces 2S having passed through the meshes 19a naturally fall in the chute 20, and the large pulverized pieces 2L not having passed through the meshes 19a naturally fall in the chute 21. That is, it is possible to classify the pulverized pieces 2 in accordance with the particle diameter or particle size, and allow the thus classified pulverized pieces 2 to fall in the chutes 20 and 21 in accordance with the particle diameter.

[0119] While the pulverized pieces 2 are naturally falling after the completion of step Q3, determination step S5 and separation step S6 in FIG. 7 are successively executed.

[0120] In step Q4, the CPU 50 operates the CCD sensors 30 and 32 to sense the presence/absence of adhesion of the coating film for each of the pulverized pieces 2 naturally falling from the chute 20 to the chute extended portion 27 shown in FIG. 4 by using the background member 31 and CCD sensor 30, or the background member 33 and CCD sensor 32, opposing each other on the two sides of the sensing space 29. The CPU 50 loads the sensed image and performs image processing.

[0121] In step Q5, the color difference meter 51 connected to the CCD sensors 30 and 32 measures the color difference.

[0122] In step Q6, the CPU 50 compares the measured color difference with a reference value to determine whether the measured color difference is larger than the reference value. If the measured color difference is equal to or smaller than the reference value (NO in step Q6), the flow advances to step Q10. If the measured color difference is larger than the reference value (YES in Q6), the flow advances to step Q7.

[0123] In step Q10, the pulverized piece 2 of interest which is an OK product A having a measured color difference equal to or smaller than the reference value is collected from the chute extended portion 27 into the collection tank 26 below the chute extended portion 27, without operating the air-blow nozzles 37.

[0124] In step Q7, the position of air blow is specified because the pulverized piece 2 of interest is an NG product B having a measured color difference larger than the reference value. That is, of the air-blow holes shown in FIG. 5, a specific air-blow hole 35a to blow air is set in accordance with the NG product B.

[0125] In step Q8, the CPU 50 blows air from the specific air-blow hole 35a (FIG. 5) at the timing at which the NG product B falls in front of the ejector 36, thereby changing the course of fall of the NG product B from the chute extended portion 27 to the chute branched portion 28, i.e., changing the moving direction of the NG product B to a direction different from the moving direction of the OK products A. In this way, the CPU 50 separates the NG product B from the OK products A.

[0126] In step Q9, the NG product B is collected from the chute branched portion 28 into the collection tank 25 below the chute branched portion 28.

[0127] The above process in steps Q4 to Q10 is performed for the small pulverized pieces 2S. However, the same process is executed for the large pulverized pieces 2L.

[0128] That is, in step Q11, the CPU 50 operates the CCD sensors 30 and 32 to sense the presence/absence of adhesion of the coating film for each of the pulverized pieces 2 naturally falling from the chute 20 to the chute extended portion 27 shown in FIG. 4 by using the background member 31 and CCD sensor 30, or the background member 33 and CCD sensor 32, opposing each other on the two sides of the sensing space 29. The CPU 50 loads the sensed image and performs image processing.

[0129] In step Q12, the color difference meter 51 connected to the CCD sensors 30 and 32 measures the color difference.

[0130] In step Q13, the CPU 50 compares the measured color difference with the reference value to determine whether the measured color difference is larger than the reference value. If the measured color difference is equal to or smaller than the reference value (NO in step Q13), the flow advances to step Q17. If the measured color difference is larger than the reference value (YES in Q13), the flow advances to step Q14.

[0131] In step Q17, the pulverized piece 2 of interest which is an OK product A having a measured color difference equal to or smaller than the reference value is collected from the chute extended portion 27 into the collection tank 26 below the chute extended portion 27, without operating the air-blow nozzles 37.

[0132] In step Q14, the position of air blow is specified because the pulverized piece 2 of interest is an NG product B having a measured color difference larger than the reference value. That is, of the air-blow holes shown in FIG. 5, a specific air-blow hole 35a to blow air is set in accordance with the NG product B.

[0133] In step Q15, the CPU 50 blows air from the specific air-blow hole 35a (FIG. 5) at the timing at which the NG product B falls in front of the ejector 36, thereby changing the course of fall of the NG product B from the chute extended portion 27 to the chute branched portion 28, i.e., changing the moving direction of the NG product B to a direction different from the moving direction of the OK products A. In this way, the CPU 50 separates the NG product B from the OK products A.

[0134] In step Q16, the NG product B is collected from the chute branched portion 28 into the collection tank 25 below the chute branched portion 28.

[0135] The OK products A (i.e., the pulverized pieces 2 having no residual coating film b) collected in the collection tank 26 are formed into resin pellets by using an extruder in recycled material extrusion step S7 of the flow chart shown in FIG. 7. In molding step S8, the resin pellets are reused as they are molded into products such as resin bumpers by using an injection molder.

[0136] On the other hand, the NG products B (i.e., the pulverized pieces 2 having the residual coating film b) collected in the collection tank 25 are reused as they are molded into low-grade products (e.g., automobile parts used in positions where they cannot be seen from the outside) through steps S7 and S8.

[0137] The processing time in peeling step S3 described above is desirably not too short and not too long. FIG. 9 shows measurement data indicating the relationship between the processing time of peeling step S3, the residual coating film area, and the frequency. Referring to FIG. 9, the frequency of pulverized pieces 2 having no coating film is indicated by a hatched bar; the frequency of pulverized pieces 2 having a residual coating film area exceeding 50 mm2 is indicated by a solid bar; the frequency of pulverized pieces 2 having a residual coating film area of 10 to 50 mm2 is indicated by a blank bar; and the frequency of pulverized pieces 2 having a residual coating film area of less than 10 mm2 is indicated by a dotted bar.

[0138] As shown in FIG. 9, when the processing time exceeds 60 min (see bars of 65 min), not only the processing time is excessively long, but also the base material (resin a) reduces in weight to decrease the collection ratio.

[0139] To avoid this, setting is performed such that a predetermined amount of NG products B having a certain area of the coating film b remain (see bars of 15 and 40 min). In this case, the NG products B are reliably sensed and selected in determination step S5 and separation step S6, so the processing time can be shortened. In addition, the reduction in weight of the base material (resin a) also decreases, and this increases the collection ratio. If the processing time is less than 15 min, the coating film b which is originally removable also remains, so the coating film removal ratio worsens. Therefore, the processing time of peeling step S3 is desirably 15 to 50 min.

[0140]
FIG. 10 is a graph showing the relationship between the coating film peeling time and the coating film removal ratio. A curve c indicates the characteristic of this embodiment including steps S2 to S6; and d, the characteristic of a conventional example having only steps S2 and S3.

[0141] As shown in the graph of FIG. 10, this embodiment can greatly increase the coating film removal ratio because the pulverized pieces 2 are classified, and the NG products B are sensed and separated from the OK products A. To set the coating film removal ratio at a higher target value, the coating film peeling time is desirably set between 26 and 50 min.

[0142]
FIG. 11 is a graph in which the abscissa indicates a coating film removal ratio (the ratio of an area from which the coating film is removed to the total pulverized piece area) obtained by only steps S2 and S3, and the ordinate indicates a coating film removal ratio obtained by steps S2 to S6. A curve e indicates the characteristic (corresponding to the curve c in FIG. 10) of this embodiment; and f, the characteristic (corresponding to the curve d in FIG. 10) of the conventional example.

[0143] That is, as indicated by the curve e, the coating film removal ratio can be increased by stopping peeling of the coating film when the coating film removal ratio (abscissa) in peeling step S3 is 98.90 to 99.58, and executing steps S4, S5, and S6 after that.

[0144] As described above, the resin material remolding method of this embodiment includes preparation steps S1 to S3 of pulverizing coated resin molded products 1 and preparing pulverized pieces 2 from which the coating film is peeled, determination step S5 of sensing and determining the presence/absence of adhesion of the coating film for each individual pulverized piece 2 after preparation steps S1 to S3, separation step S6 of separating, on the basis of the determination result, a pulverized piece (NG product B) having the coating film b adhered from pulverized pieces (OK products A) having no coating film b adhered, and molding step S8 of molding the OK products A after separation step S6.

[0145] With this arrangement, in preparation steps S1 to S3, pulverized pieces 2 obtained upon pulverization and coating film peeling of coating resin molded products 1 are prepared. In determination step S5, the presence/absence of adhesion of the coating film is sensed and determined for each individual pulverized piece 2 after reparation steps S1 to S3. In separation step S6, NG products B (products having the residual coating film) are separated from OK products A on the basis of the determination results. In molding step S8, molding is performed using the OK products A after separation step S6.

[0146] As described above, after pulverization and coating film peeling, pulverized pieces (NG products B) having the coating film adhered and pulverized pieces (OK products A) having no coating film adhered are separated. Therefore, it is possible to effectively increase the coating film removal ratio (the collection ratio of pulverized pieces having no coating film adhered with respect to all pulverized pieces to be processed) within a short time period without taking a long time in the coating film peeling process. Consequently, the material yield can be increased.

[0147] Especially when coating film peeling is terminated while the area of the coating film remaining on some pulverized pieces 2 is relatively large and the thus prepared pulverized pieces 2 are selectively separated into NG products B having the coating film adhered and OK products A having no coating film adhered, the selection accuracy increases, and the reduction in weight of the resin decreases. As a consequence, it is possible to obtain a high collection ratio and increase the coating film removal ratio.

[0148] In determination step S5, the presence/absence of adhesion of the coating film is determined by sensing the coating film b itself by the sensor (CCD sensor 30 or 32).

[0149] With this arrangement, it is readily possible to sense a pulverized piece 2 having the coating film b adhered, i.e., an NG product B, by using the sensor (CCD sensor 30 or 32).

[0150] Furthermore, determination step S5 executes the above sensing by using the photosensor (CCD sensor 30 or 32) which senses the coating film on the basis of the difference in lightness, saturation, or hue from the background color (the background member 31 or 33) different from the coating film color of the pulverized pieces 2.

[0151] With this arrangement, the coating film can be sensed by using the background color different from the coating film color. Since this reduces sensing errors, the coating film sensing accuracy can be simply and effectively increased.

[0152] In addition, the above sensing is executed on the pulverized pieces 2 in a plurality of directions.

[0153] With this arrangement, adhesion of the coating film is sensed in a plurality of directions by the CCD sensors 30 and 32. Accordingly, a pulverized piece 2 having the coating film b adhered can be accurately sensed regardless of the posture of the pulverized piece 2.

[0154] Also, in determination step S5, the above sensing is executed in a specific position midway along the moving path in which the pulverized pieces 2 are moved in a particular direction. In separation step S6, if an NG product B is sensed in determination step S5, air is blown against the NG product B to change the moving direction of the NG product B to a direction different from the moving direction of OK products A, thereby executing the separation described previously.

[0155] With this arrangement, coating film sensing can be efficiently executed on a large number of pulverized pieces 2. Additionally, since the course of moving of an NG product B can be changed by air blow, NG products B and OK products A can be separated by a simple method.

[0156] Also, the movement of the pulverized pieces 2 is falling.

[0157] This arrangement obviates the need for special moving means (or conveying means) such as conveyor rollers or conveyor belts for moving the pulverized pieces 2, so NG products B and OK products A can be separated by a simpler method. Additionally, coating film sensing by the CD sensors 30 and 32 is executed while the pulverized pieces 2 are falling. This allows rapid and easy execution of the series of sensing and separation steps.

[0158] Furthermore, in the pulverization described above, coated resin molded products 1 are randomly pulverized by the cutter mill 6 (FIG. 1) as a cutting tool having the rotary blades 7. The pulverized pieces 2 are classified into a plurality of groups in accordance with the particle diameter of each pulverized piece 2, and determination step S5 is executed for each classified particle diameter group.

[0159] With this arrangement, the coated resin molded products 1 can be easily pulverized by the cutting tool (cutter mill 6). The pulverized pieces 2 obtained by this random pulverization have various sizes. When coating film sensing is performed, therefore, small-particle-diameter pulverized pieces S2 having the coating film b adhered are hidden behind large-particle-diameter pulverized pieces 2L having no coating film b adhered, so the sensing accuracy decreases. This can be prevented by classifying the pulverized pieces 2 in accordance with the particle diameter.

[0160] In addition, the coated resin molded products 1 are used automobile parts such as vehicle bumpers.

[0161] With this arrangement, these used automobile parts can be recycled through pulverization, coating film peeling, and remolding.

[0162] The resin pulverized piece selecting apparatus (FIGS. 3 to 5) of the above embodiment is a selecting apparatus for the coated resin molded products 1 obtained upon pulverization and coating film peeling. This selecting apparatus includes the sensors (CCD sensors 30 and 32) installed in specific positions (in this embodiment, positions where these sensors face the sensing space 29) with respect to the pulverized pieces 2 to sense NG products B of the pulverized pieces 2 on the basis of the coating film b itself, the determining means (CPU 50) for determining the NG products B on the basis of the results of sensing by the sensors (CCD sensors 30 and 32), and the separating means (separator 24) for separating the NG products B from OK products A on the basis of the results of determination by the determining means (CPU 50).

[0163] With this arrangement, the sensors (CCD sensors 30 and 32) sense NG products B of the pulverized pieces 2 on the basis of the coating film b itself. The determining means (CPU 50) determines the NG products B on the basis of the results of sensing by the sensors (CCD sensors 30 and 32). The separating means (separator 24) separates the NG products B from the OK products A on the basis of the results of determination by the determining means (CPU 50).

[0164] As described above, sensing, determination, and separation of the NG products B and OK products A are executed after pulverization and coating film peeling. Therefore, it is possible to effectively increase the coating film removal ratio (the collection ratio of pulverized pieces having no coating film adhered with respect to all pulverized pieces to be processed) within a short time period without taking a long time in the coating film peeling process. Consequently, the material yield can be increased.

[0165] Also, the above sensors are photosensors (CCD sensors 30 and 32) which sense the coating film b on the basis of the difference in lightness, saturation, or hue from the background color different from the coating film color.

[0166] With this arrangement, coating film sensing is executed by using the background color different from the coating film color. Since this reduces sensing errors, the coating film sensing accuracy can be easily and effectively increased.

[0167] Furthermore, the sensors (CCD sensors 30 and 32) sense the presence/absence of adhesion of the coating film for the pulverized pieces 2 in a plurality of directions.

[0168] With this arrangement, adhesion of the coating film is sensed in a plurality of directions by the sensors (CCD sensors 30 and 32). Therefore, NG products B can be accurately sensed regardless of the postures of the pulverized pieces 2.

[0169] The moving means (chutes 20 and 21) moves the pulverized pieces 2 in a specific direction (in this embodiment, downward). Also, the separating means (separator 24) includes the air blowing means (air blow nozzle 37) placed in a specific position (in this embodiment, a position where the air blowing means faces the sensing space 29) midway along the moving path in which the pulverized pieces 2 are moved by the moving means. When the determining means (CPU 50) senses an NG product B, the air blowing means blows a gas (air) against the NG product B to change the moving direction of the NG product B to a direction different from the moving direction of OK products A, thereby executing the separation described above.

[0170] With this arrangement, the coating film of a large number of pulverized pieces 2 can be efficiently sensed. In addition, the course of moving of an NG product B can be changed by air blow. Therefore, the NG products B and OK products A can be separated with a simple arrangement.

[0171] Furthermore, the moving means are dropping means (chutes 20 and 21) for dropping the pulverized pieces 2.

[0172] This arrangement eliminates the need for any special moving means such as conveyor rollers and conveyor belts for moving the pulverized pieces 2. Accordingly, the NG products B and OK products A can be separated with a simpler arrangement. Additionally, since coating film sensing by the sensors (CCD sensors 30 and 32) is performed while the pulverized pieces 2 are falling, the series of sensing and separation steps can be rapidly and easily performed.

[0173] The classifying means (screening device 19) is installed in the charge port 17a for the pulverized pieces 2 to classify the pulverized pieces 2 into a plurality of groups in accordance with the particle diameters of the pulverized pieces 2. The sensors (CCD sensors 30 and 32) perform the sensing described above for each of these groups.

[0174] With this arrangement, the classifying means (screening device 19) classifies the pulverized pieces 2 into a plurality of groups in accordance with the particle diameter. If the pulverized pieces have various sizes, small-particle-diameter pulverized pieces S2 having the coating film adhered are hidden behind large-particle-diameter pulverized pieces 2L having no coating film b adhered while coating film sensing is performed by the sensors, so the sensing accuracy decreases. However, this can be prevented by a simple arrangement.

[0175] The classifying means is the screening device 19 for classifying the pulverized pieces 2 in accordance with the particle diameter.

[0176] With this arrangement, classification can be appropriately performed by a simple apparatus. The screening device 19 uses the screen or porous plate 19b having the meshes 19a of a predetermined size and, classifies (screens) the pulverized pieces 2 into those which pass through the meshes 19a and those which do not.

[0177]
FIG. 12 shows another embodiment of the resin material remolding method and resin material pulverized piece selecting apparatus. This embodiment shown in FIG. 12 eliminates sensing errors by sensing a wavelength unique to titanium oxide TiO2 as a main component of a white pigment, or a wavelength unique to chlorine C as a component of a primer (undercoating of painting) below black painting, by using fluorescent X-rays.

[0178] To achieve this, the embodiment shown in FIG. 12 has the following apparatus in addition to the arrangement shown in FIG. 4.

[0179] That is, a lower chute 41 is formed below the inclined lower end portion of a chute extended portion 27 with a sensing space 40 being interposed between them. In addition, a lower chute branched portion 42 connects a middle portion of the lower chute 41 and a middle portion of a chute branched portion 28.

[0180] OK products A falling through a chute 20, the chute extended portion 27, and the lower chute 41 are collected by a collection tank 26. NG products B whose course is changed to the chute branched portion 28 and lower chute branched portion 42 are collected by a collection tank 25.

[0181] Also, an ejector 36 and air-blow nozzles 37 are arranged to oppose the upper end opening of the lower chute branched portion 42. The arrangements of the elements 36 and 37 are the same as shown in FIGS. 4 and 5.

[0182] This embodiment also includes an X-ray lamp 43 for emitting X-rays e to detect an NG product B from pulverized pieces 2 falling in the sensing space 40. Fluorescent X-rays f excited from the pulverized pieces 2 irradiated with the X-rays e are separated into spectral components by a spectral crystal 44. A CCD sensor 45 having an X-ray sensing function is an X-ray sensing means for sensing only X-rays g having a specific wavelength.

[0183] As shown in FIG. 12, fluorescent X-ray analyzers 46 using the above-mentioned fluorescent X-ray analyzing method are installed on the two sides of the sensing space 40.

[0184] Titanium oxide TiO2 as a main component of a white pigment is detected at the wavelength of titanium Ti. Therefore, the spectral crystal 44 is so chosen as to separate the X-rays g at the wavelength of titanium Ti=4.508 Å. To detect chlorine Cl as a primer component, the spectral crystal 44 is so chosen as to separate the wavelength of chlorine Cl=2.621 Å.

[0185] To prevent sensing errors by performing only determination and separation on the basis of lightness, saturation, or hue when the CCD sensor 45 senses the specific X-rays g, the air-blow nozzle 37 on the side of the fluorescent X-ray analyzer 46 is driven at the timing at which an NG product B falls to the position of the ejector 36, thereby changing the course of fall of the NG product B containing titanium Ti or chlorine Cl from the lower chute 41 to the lower chute branched portion 42.

[0186] This arrangement makes it possible to prevent sensing errors and greatly increase the coating film removal ratio.

[0187] In this embodiment shown in FIG. 12, CCD sensors 30 and 32 for sensing the coating film itself are arranged in the upper stage of the chute, and the CCD sensors 45 having an X-ray sensing function of sensing a specific material (Ti or Cl) present in the coating film are arranged in the lower stage of the chute. That is, coating film sensing is executed by these two, upper and lower stages. However, coating film sensing may also be executed only by one stage made up of the CCD sensors 45. Even in this case, the resin material remolding method is the same as shown in FIG. 7.

[0188] In determination step S5 described earlier, the presence/absence of coating film adhesion may also be sensed by thus sensing the specific material present in a coating film b by the sensor (CCD sensor 45). Even in this case, a pulverized product 2 having the coating film b adhered, i.e., an NG product B can be easily sensed by the sensor (CCD sensor 45).

[0189] In addition, the pulverized pieces 2 are irradiated with X-rays, and the sensing described above is executed by the sensing means (CCD sensor 45) for sensing X-rays having the specific wavelength excited from the specific material present in the coating film b. Accordingly, even if the color of the pulverized pieces 2 themselves is the same as or close to the coating film color, the coating film sensing accuracy can be easily and effectively increased.

[0190] In the embodiment shown in FIG. 12, the rest of the arrangements, functions, and effects is substantially the same as in the previous embodiment. Therefore, the same reference numerals as in the previous drawings denote the same parts in FIG. 12, and a detailed description thereof will be omitted. However, it is, of course, also possible to switch the positions of the determination/separation section using color and the determination/separation section using the fluorescent X-ray analyzers 46 shown in FIG. 12. That is, the fluorescent X-ray analyzers 46 may also be arranged upstream of the determination/separation section using color.

[0191]
FIG. 13 shows still another embodiment of the resin material remolding method and resin material pulverized piece selecting apparatus. This embodiment uses an optical bandpass filter (so-called BPF) 47 for passing only X-rays having a specific wavelength, and an X-ray sensor 48 for sensing X-rays g of the specific wavelength passing through the BPF 47 and converting the X-rays g into an electrical signal, instead of the spectral crystal 44 and the CCD sensor 45 having an X-ray sensing function in the embodiment shown in FIG. 12.

[0192] Fluorescent X-ray analyzers 49 each made up of an element 43, the BPF 47, and the X-ray sensor 48 are arranged on the two sides of a sensing space 40.

[0193] Titanium oxide TiO2 as a main component of a white pigment is detected at the wavelength of titanium Ti. Therefore, the BPF 47 is so selected as to separate the X-rays g at the wavelength of titanium Ti=4.508 Å. To detect chlorine Cl as a primer component, the BPF 47 is so selected as to separate the wavelength of chlorine Cl=2.621 Å.

[0194] This arrangement also achieves substantially the same functions and effects as in the embodiment shown in FIG. 12. Accordingly, the same reference numerals as in FIG. 12 denote the same parts in FIG. 13, and a detailed explanation thereof will be omitted.

[0195]
FIG. 14 shows still another embodiment. In the previous embodiments, pulverized pieces 2 are allowed to naturally fall, and NG products B are detected during this natural fall. In this embodiment, however, an endless, colorless, transparent mesh-like belt 62 is looped between a pair of rollers 60 and 61. Pulverized pieces 2 (i.e., small pulverized pieces 2S or large pulverized pieces 2L) already classified by a screening device 19 are supplied onto the leading end portion of the belt 62, and NG products B are detected while the pulverized pieces 2 are moved from the leading end portion to the trailing end portion.

[0196] To allow air from air-blow nozzles 37 to pass through, the belt 62 is formed by fine meshes (e.g., square meshes of about 2 mm side or less). Also, PP (polypropylene), PE (polyethylene), PA (polyamide), or the like is used as the belt material to allow X-rays to pass through.

[0197] CCD sensors 30 and 32 and background members 31 and 33 oppose each other in different directions midway along the upstream side of a belt conveyor 63 made up of the pair of rollers 60 and 61 and belt 62. The air-blow nozzles 37 are arranged immediately downstream of this position where the sensors and background members oppose each other.

[0198] A pair of upper and lower fluorescent X-ray analyzers 46 each made up of elements 43, 44, and 45 are arranged midway along the downstream side of the belt conveyor 63. The air-blow nozzles 37 are arranged immediately downstream of this position where these analyzers are arranged.

[0199] Furthermore, a collection tank 26 for collecting OK products A is placed below the trailing end of the belt conveyor 63, and a collection tank 25 for collecting NG products B is placed outside the collection tank 26.

[0200] In addition, a main duct 64 extends from a position above the collection tank 25 to a position above the air-blow nozzles 37 in the middle of the upstream side to draw NG products B by a negative pressure. Also, a sub duct 65 extends from a middle portion of the main duct 64 to a position above the air-blow nozzles 37 in the middle of the downstream side.

[0201] A vacuum pump 66 is attached to the main duct 64 near the collection tank 25. A negative pressure is generated in the ducts 64 and 65 by driving the vacuum pump 66. The vacuum pump 66 is driven at all times. NG product suction ports 64a and 65a of the main ducts 64 and sub ducts 65, respectively, are formed to be thin and narrow over the entire width of the belt 62.

[0202] The air-blow nozzles 37 blow NG products B upward to negative-pressure areas (vacuum regions) of the suction ports 64a and 65a. The NG products B blown upward to the negative-pressure areas are drawn by the negative pressure, and collected in the collection tanks 25.

[0203]
FIG. 15 is a block diagram of a control circuit of the apparatus shown in FIG. 14. On the basis of inputs from the CCD sensors 30 and 32, a color difference meter 51, and the CCD sensors 45 having an X-ray sensing function, a CPU 50 controls driving of the air-blow nozzles 37, color fluorescent lamps 34, the belt conveyor 63, and the vacuum pump 66 in accordance with programs stored in a ROM 52. A RAM 53 stores necessary data such as a reference value (reference lightness) for separating OK products A and NG products B.

[0204] Even when the resin material pulverized piece selecting apparatus shown in FIG. 14 and the control circuit shown in FIG. 15 are used, resin material remolding can be performed following the same procedures as in the flow chart shown in FIG. 7 except for the moving direction of the pulverized pieces 2. Since the rest of the arrangements, functions, and effects is substantially the same as in the previous embodiments, the same reference numerals as in the previous drawings denote the same parts in FIGS. 14 and 15, and a detailed description thereof will be omitted.

[0205]
FIG. 16 shows still another embodiment. This embodiment shown in FIG. 16 uses a fluorescent X-ray analyzer 49 made up of elements 43, 47, and 48, instead of the fluorescent X-ray analyzer 46 made up of the elements 43, 44, and 45 in the embodiment shown in FIG. 14.

[0206] The rest of the arrangements, functions, and effects is substantially the same as the embodiment shown in FIGS. 14 and 15. Therefore, the same reference numerals as in the previous drawings denote the same parts in FIG. 16, and a detailed description thereof will be omitted. In the embodiments shown in FIGS. 14 and 16, the accuracy of sensing and determination of NG products B can be increased by properly controlling the running speed of the belt 62.

[0207] That is, in the embodiments shown in FIGS. 14 and 16, the moving speed of the pulverized pieces 2 can be properly controlled in accordance with selection by controlling the driving speed of the belt 62.

[0208] The coating film peeling apparatus used in peeling step S3 shown in FIG. 7 may also be the following apparatus, instead of the apparatus shown in FIG. 2.

[0209] That is, a coating film b made of a thermosetting resin can be peeled from a thermoplastic resin a such as polypropylene by using a mechanical peeling apparatus having a rotary blade on the bottom of a bath. In this apparatus, the coating film b is peeled by using a difference between the resin a which is easy to bend and the coating film b which is hard to bend by applying shear stress to a pulverized piece 2 at the softening temperature of the resin a as a base material.

[0210] It is also possible to use an apparatus (so-called cone press) which peels the coating film b from the resin a by applying a compressive force to a pulverized piece 2 in a slit between a fixed cone and liner by using vibrating compression, shearing force, and surface polishing produced between the fixed cone and liner, thereby lowering the adhesion of the coating film b.

[0211] In addition, a shot peening apparatus or shot blasting apparatus which peels the coating film b by impact by peening or blasting the surface of a pulverized piece 2 with shots (small spheres).

[0212] The arrangements of the present invention described in claims correspond to the aforementioned embodiments as follows.

[0213] That is, a coated resin molded product of the invention corresponds to the resin bumper of the embodiments.

[0214] Likewise,

[0215] a pulverized piece having the coating film adhered corresponds to the NG product B,

[0216] a pulverized piece having no coating film adhered corresponds to the OK product A,

[0217] a sensor corresponds to the CCD sensors 30 and 32, the CCD sensor 45 having an X-ray sensing function, or the X-ray sensor 48,

[0218] a cutting tool for pulverizing a molded product corresponds to the cutter mill 6,

[0219] a background color corresponds to the background members 31 and 33,

[0220] a charge port corresponds to the charge port 17a in the upper portion of the hopper 17,

[0221] separating means corresponds to the separator 24,

[0222] classifying means corresponds to the screening device 19,

[0223] gas blowing means corresponds to the air-blow nozzle 37,

[0224] a preparation step corresponds to steps S1 to S3 in FIG. 7,

[0225] a specific material corresponds to titanium oxide or chlorine,

[0226] sensing means for sensing X-rays corresponds to the CCD sensor 45 or X-ray sensor 48,

[0227] determining means corresponds to the CPU 50,

[0228] moving means corresponds to the chutes 20 and 21 and belt conveyor 63, and

[0229] dropping means corresponds to the chutes 20 and 21.

[0230] As many apparently widely different embodiments of the present invention can be made without departing from the spirit and scope thereof, it is to be understood that the invention is not limited to the specific embodiments thereof except as defined in the appended claims.

Number	Date	Country	Kind
2003-041259	Feb 2003	JP
2003-138170	May 2003	JP

Resin material remolding method and resin material pulverized piece selecting apparatus

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