Roofing underlayment with hydrophobic nonwoven core

Information

  • Patent Grant
  • 11518137
  • Patent Number
    11,518,137
  • Date Filed
    Tuesday, June 23, 2020
    4 years ago
  • Date Issued
    Tuesday, December 6, 2022
    2 years ago
  • Inventors
  • Original Assignees
  • Examiners
    • Vonch; Jeffrey A
    Agents
    • Calfee, Halter & Griswold LLP
Abstract
A roofing underlayment includes a hydrophobic nonwoven core layer that provides enhanced resistance to water infiltration. In addition to the hydrophobic nonwoven core layer, the roofing underlayment includes a coating layer adhered to a surface of the hydrophobic nonwoven core layer, and an exterior surface layer adhered to the coating layer. A roofing system that includes the roofing underlayment is also provided.
Description
FIELD

The general inventive concepts relate to underlayments and, more particularly, to a roofing underlayment having a hydrophobic nonwoven core layer that provides enhanced resistance to water infiltration.


BACKGROUND

Underlayments are commonly used in roofing applications along with an overlayment roofing material, such as asphalt shingles, slate tiles, wooden shakes, metal roofing, and so forth. Underlayments are generally secured to a roof deck and provide the first protection against water infiltration into the interior structure of a building during construction and subsequently become a secondary barrier to water infiltration into the interior upon installation of the primary overlayment roofing material.


Conventional synthetic roofing underlayments typically utilize a woven polymer scrim as a core layer. Based on their structure, woven scrims can allow water infiltration and, thus, rely on outer coating layers for protection against water infiltration. Furthermore, conventional synthetic roofing underlayments tend to lack sufficient bulk such that common worksite debris (e.g., roofing granules) can easily penetrate the underlayment and create openings for water infiltration.


SUMMARY

The general inventive concepts relate to a roofing underlayment having a hydrophobic nonwoven core layer that provides enhanced resistance to water infiltration. To illustrate various aspects of the general inventive concepts, several exemplary embodiments of the roofing underlayment are disclosed.


In one exemplary embodiment, a roofing underlayment includes a hydrophobic nonwoven core layer, a first coating layer adhered to a first surface of the hydrophobic nonwoven core layer, and a first exterior surface layer adhered to the first coating layer. The hydrophobic nonwoven core layer enhances resistance to water infiltration through the roofing underlayment due to the hydrophobic nature of the hydrophobic nonwoven core layer as well as the structure of the hydrophobic nonwoven core layer. The hydrophobic nonwoven core layer has a basis weight of 100 g/m2 to 250 g/m2.


In one exemplary embodiment, a roofing system is provided. The roofing system includes a roof deck, a roofing underlayment attached to the roof deck, and a roofing material positioned on the roofing underlayment. The roofing underlayment includes a hydrophobic nonwoven core layer, a first coating layer adhered to a first surface of the hydrophobic nonwoven core layer, and a first exterior surface layer adhered to the first coating layer. The hydrophobic nonwoven core layer has a basis weight of 100 g/m2 to 250 g/m2.


Other aspects, advantages, and features of the general inventive concepts will become apparent to those skilled in the art from the following detailed description, when read in light of the accompanying drawings.





BRIEF DESCRIPTION OF THE DRAWINGS

The general inventive concepts, as well as embodiments and advantages thereof, are described below in greater detail, by way of example, with reference to the drawings in which:



FIG. 1 is a cross-sectional view of an embodiment of a roofing underlayment according to the present disclosure;



FIG. 2 is a cross-sectional view of an embodiment of a roofing underlayment according to the present disclosure; and



FIG. 3 is a cross-sectional view of an embodiment of a roofing system according to the present disclosure.





DETAILED DESCRIPTION

While the general inventive concepts are susceptible of embodiment in many different forms, there are shown in the drawings, and will be described herein in detail, specific embodiments thereof with the understanding that the present disclosure is to be considered as an exemplification of the principles of the general inventive concepts. Accordingly, the general inventive concepts are not intended to be limited to the specific embodiments illustrated herein.


The general inventive concepts relate to roofing underlayments configured to enhance resistance against water infiltration. As will be described in further detail below, enhanced resistance against water infiltration is achieved by incorporating a hydrophobic nonwoven core layer into the roofing underlayment. The term “hydrophobic” as used herein refers to a material and/or a surface that exhibits a water contact angle of at least 90°, including a water contact angle of 90° to 180°, a water contact angle of 100° to 170°, a water contact angle of 110° to 160°, a water contact angle of 120° to 150°, and also including a water contact angle of 90° to 120°.


In one exemplary embodiment, a roofing underlayment 100 is provided. Referring to FIG. 1, the roofing underlayment 100 comprises a hydrophobic nonwoven core layer 10 having a first surface 12 (e.g., a top surface) and a second surface 14 (e.g., a bottom surface), and a first coating layer 20 adhered to the first surface 12 of the hydrophobic nonwoven core layer 10. The roofing underlayment 100 also includes a first exterior surface layer 30 adhered to the first coating layer 20.


The hydrophobic nonwoven core layer 10 of the present disclosure may be formed from a variety of hydrophobic materials, most typically one or more hydrophobic polymeric materials. Exemplary materials suitable for forming the hydrophobic nonwoven core layer 10 of the present disclosure include, but are not limited to, a polyolefin (e.g., polyethylene, polypropylene), a polyester, a glass (e.g., woven glass mat, nonwoven glass mat), a polystyrene, a polyamide, a polyimide, a polycarbonate, an acrylic polymer, a fluoropolymer (e.g., polyvinylidene fluoride, polytetrafluoroethylene), a polyvinyl chloride, and combinations thereof. The material used to form the hydrophobic nonwoven core layer 10 of the present disclosure may comprise a virgin material and/or a recycled/reprocessed material. In general, the material used to form the hydrophobic nonwoven core layer 10 will be in the form of fibers, which may be continuous and/or discontinuous (e.g., chopped) fibers. In certain embodiments, the hydrophobic nonwoven core layer 10 comprises a polyolefin. In certain embodiments, the hydrophobic nonwoven core layer 10 comprises at least one of a polypropylene and a polyethylene. The hydrophobic nonwoven core layer 10 of the present disclosure may also comprise additives such as colorants, pigments, antioxidants, U.V. stabilizers, fire retardants, fillers, and the like.


The hydrophobic nonwoven core layer 10 of the present disclosure has a nonwoven structure, which may be formed in a variety of ways. For example, in certain embodiments, the hydrophobic nonwoven core layer 10 may be formed using a spun melt process (e.g., spunbond, melt-blown), a dry-laid process (e.g., air-laid, carded), or a wet-laid process. In certain embodiments, the hydrophobic nonwoven core layer 10 is a spunbond nonwoven material. Regardless of the process used to form the hydrophobic nonwoven core layer 10, the fibers comprising the hydrophobic nonwoven core layer 10 are generally bonded together. For example, in certain embodiments, the fibers comprising the hydrophobic nonwoven core layer 10 may be mechanically bonded (e.g., hydroentangled, needle-punched), thermally bonded, chemically bonded (e.g., adhesive, binder), or combinations of these bonding methods. In certain embodiments, the hydrophobic nonwoven core layer 10 is thermally bonded using heated calender rollers. In certain embodiments, the hydrophobic nonwoven core layer 10 is point bonded. Point bonded nonwovens are bonded, for example, using heated nips on rolls, usually in the form of a pattern, to bond certain points of the nonwoven and leave other portions loose or unbonded.


As mentioned above, the hydrophobic nonwoven core layer 10 of the present disclosure has a nonwoven structure. In conventional roofing underlayments that include a nonwoven layer, the nonwoven layer typically forms an outer surface of the roofing underlayment and has a basis weight of less than 110 g/m2, and typically less than 100 g/m2, and the roofing underlayment has a total basis weight of 150 g/m2 to 180 g/m2. Such conventional nonwoven layers can be susceptible to water infiltration, and even more so if an outer layer (e.g., a coating layer) is omitted or otherwise damaged during installation by worksite debris (e.g., roofing granules), or when the roofing underlayment is mechanically secured to a roof deck with fasteners (e.g., nails, staples). In contrast to conventional roofing underlayments that include a nonwoven layer, the hydrophobic nonwoven core layer 10 of the present disclosure forms the primary reinforcing structure of the roofing underlayment 100 and has a basis weight of 100 g/m2 to 250 g/m2. Such a basis weight yields a structure having a strength and a thickness that protects against damage, such as holes and/or punctures, caused by common worksite debris. Furthermore, the basis weight of the hydrophobic nonwoven core layer 10 of the present disclosure promotes enhanced resistance to water infiltration when the roofing underlayment 100 is mechanically secured to a roof deck or other substrate using fasteners.


In certain embodiments, the hydrophobic nonwoven core layer 10 of the present disclosure has a basis weight of 110 g/m2 to 250 g/m2. In certain embodiments, the hydrophobic nonwoven core layer 10 of the present disclosure has a basis weight of 120 g/m2 to 245 g/m2. In certain embodiments, the hydrophobic nonwoven core layer 10 of the present disclosure has a basis weight of 130 g/m2 to 240 g/m2. In certain embodiments, the hydrophobic nonwoven core layer 10 of the present disclosure has a basis weight of 135 g/m2 to 230 g/m2. In certain embodiments, the hydrophobic nonwoven core layer 10 of the present disclosure has a basis weight of 140 g/m2 to 220 g/m2. In certain embodiments, the hydrophobic nonwoven core layer 10 of the present disclosure has a basis weight of 150 g/m2 to 200 g/m2. In certain embodiments, the hydrophobic nonwoven core layer 10 of the present disclosure has a basis weight of 135 g/m2 to 155 g/m2. In certain embodiments, the hydrophobic nonwoven core layer 10 of the present disclosure has a basis weight of 140 g/m2 to 150 g/m2. In certain embodiments, the hydrophobic nonwoven core layer 10 of the present disclosure has a basis weight of 105 g/m2 to 115 g/m2. In certain embodiments, the hydrophobic nonwoven core layer 10 of the present disclosure has a basis weight of 115 g/m2 to 125 g/m2.


In certain embodiments, the hydrophobic nonwoven core layer 10 of the present disclosure has a thickness of 0.1 mm (about 3.9 mil) to 1 mm (about 40 mil). In certain embodiments, the hydrophobic nonwoven core layer 10 of the present disclosure has a thickness of 0.3 mm (about 12 mil) to 1 mm (about 40 mil), including a thickness of 0.4 mm (about 15.7 mil) to 1 mm (about 40 mil), a thickness of 0.5 mm (about 19.7 mil) to 0.9 mm (about 35.43 mil), a thickness of 0.6 mm (about 23.6 mil) to 0.85 mm (about 33.5 mil), and also including a thickness of 0.7 mm (about 27.5 mil) to 0.8 mm (about 31.5 mil).


As mentioned above, the hydrophobic nonwoven core layer 10 is the primary reinforcing structure of the roofing underlayment 100 of the present disclosure. In certain embodiments, the hydrophobic nonwoven core layer 10 comprises at least 50% of a total basis weight of the roofing underlayment 100. In certain embodiments, the hydrophobic nonwoven core layer 10 comprises from 50% to 80% of the total basis weight of the roofing underlayment 100. In certain embodiments, the hydrophobic nonwoven core layer 10 comprises from 50% to 65% of the total basis weight of the roofing underlayment 100. In certain embodiments, the hydrophobic nonwoven core layer 10 comprises from 55% to 60% of the total basis weight of the roofing underlayment 100. In certain embodiments, the hydrophobic nonwoven core layer 10 of the present disclosure has a basis weight of 135 g/m2 to 155 g/m2 and the hydrophobic nonwoven core layer 10 comprises from 50% to 80% of the total basis weight of the roofing underlayment 100. In certain embodiments, the hydrophobic nonwoven core layer 10 of the present disclosure has a basis weight of 105 g/m2 to 115 g/m2 and the hydrophobic nonwoven core layer 10 comprises from 50% to 60% of the total basis weight of the roofing underlayment 100. In certain embodiments, the hydrophobic nonwoven core layer 10 of the present disclosure has a basis weight of 115 g/m2 to 125 g/m2 and the hydrophobic nonwoven core layer 10 comprises from 55% to 65% of the total basis weight of the roofing underlayment 100. In certain embodiments, the hydrophobic nonwoven core layer 10 of the present disclosure comprises 45% to 55% by weight virgin polypropylene, 40% to 50% by weight recycled/reprocessed polypropylene, and 0.5% to 5% by weight colorant (e.g., color masterbatch), based on the total weight of the hydrophobic nonwoven core layer 10.


With continued reference to FIG. 1, the roofing underlayment 100 of the present disclosure also includes a first coating layer 20 adhered to the first surface 12 of the hydrophobic nonwoven core layer 10. The first coating layer 20 of the present disclosure is generally water impermeable and may be formed from a variety of materials, most typically one or more polymeric materials. Exemplary materials suitable for forming the first coating layer 20 of the present disclosure include, but are not limited to, a polyolefin (e.g., polyethylene, polypropylene), a polyester, a polystyrene, a polyamide, a polyurethane, a polycarbonate, an ethylene-acrylic copolymer, an adhesive (e.g., hot melt adhesive), a thermoplastic elastomer (e.g., a styrenic block copolymer, a thermoplastic polyolefin elastomer, a thermoplastic vulcanizate, a thermoplastic polyurethane, a thermoplastic copolyester, a thermoplastic polyamide), and combinations thereof. The material used to form the first coating layer 20 of the present disclosure may comprise a virgin material and/or a recycled/reprocessed material. In certain embodiments, the first coating layer 20 comprises a polyolefin. In certain embodiments, the first coating layer 20 comprises at least one of a polypropylene and a polyethylene. In certain embodiments, the first coating layer 20 comprises a thermoplastic elastomer and a polyolefin, such as a polypropylene and/or a polyethylene. The first coating layer 20 of the present disclosure may also comprise additives such as colorants, pigments, antioxidants, U.V. stabilizers, fire retardants, fillers, and the like.


The first coating layer 20 of the present disclosure may be structured in a variety of ways. For example, the first coating layer 20 may be a woven material, a nonwoven material, or a film material. In certain embodiments, the first coating layer 20 is a film material that is formed using an extrusion process. For example, the first coating layer 20 is applied between the hydrophobic nonwoven core layer 10 and the first exterior surface layer 30 as a curtain of molten polymer material, which is laminated together to form the roofing underlayment 100. Thus, in addition to providing a water impermeable layer, the first coating layer 20 may also function as an adhesive to join the hydrophobic nonwoven core layer 10 to the first exterior surface layer 30. In certain embodiments, the first coating layer 20 of the present disclosure has a basis weight of 14 g/m2 to 50 g/m2, including a basis weight of 20 g/m2 to 45 g/m2, a basis weight of 25 g/m2 to 40 g/m2, and also including a basis weight of 25 g/m2 to 35 g/m2.


In certain embodiments, the first coating layer 20 is a film material, preferably formed using an extrusion process, comprising at least one of a polypropylene and a polyethylene, and having a basis weight of 25 g/m2 to 35 g/m2. In certain embodiments, the first coating layer 20 is a film material, preferably formed using an extrusion process, having a basis weight of 25 g/m2 to 35 g/m2 and comprises 35% to 50% by weight recycled/reprocessed polypropylene, 35% to 45% by weight virgin polypropylene, 5% to 20% by weight low density polyethylene (LDPE), and 2% to 8% by weight colorant (e.g., color masterbatch), wherein the weight percentages are based on the total weight of the first coating layer 20.


In certain embodiments, the first coating layer 20 is a film material, preferably formed using an extrusion process, comprising at least one of a polypropylene and a polyethylene, and having a basis weight of 15 g/m2 to 25 g/m2. In certain embodiments, the first coating layer 20 is a film material, preferably formed using an extrusion process, having a basis weight of 15 g/m2 to 25 g/m2 and comprises 40% to 50% by weight recycled/reprocessed polypropylene, 30% to 40% by weight virgin polypropylene, 10% to 20% by weight low density polyethylene (LDPE), and 4% to 8% by weight colorant (e.g., color masterbatch), wherein the weight percentages are based on the total weight of the first coating layer 20.


In certain embodiments, the first coating layer 20 is a film material, preferably formed using an extrusion process, comprising at least one of a thermoplastic elastomer, a polypropylene, and a polyethylene, and having a basis weight of 15 g/m2 to 25 g/m2. In certain embodiments, the first coating layer 20 is a film material, preferably formed using an extrusion process, having a basis weight of 15 g/m2 to 25 g/m2 and comprises 40% to 50% by weight recycled/reprocessed polypropylene, 25% to 35% by weight thermoplastic elastomer, 10% to 20% by weight LDPE, 2% to 8% by weight colorant (e.g., color masterbatch), and 1% to 7% by weight virgin polypropylene, wherein the weight percentages are based on the total weight of the first coating layer 20.


In certain embodiments, when the first coating layer 20 of the present disclosure comprises a hot melt adhesive, the first coating layer 20 may have a basis weight of 5 g/m2 to 30 g/m2, including a basis weight of 5 g/m2 to 25 g/m2, a basis weight of 5 g/m2 to 20 g/m2, and also including a basis weight of 5 g/m2 to 15 g/m2.


The roofing underlayment 100 of the present disclosure also includes a first exterior surface layer 30. As shown in FIG. 1, the first exterior surface layer 30 is the top surface layer of the roofing underlayment 100. The first exterior surface layer 30 may be formed from a variety of materials, most typically one or more polymeric materials. Exemplary materials suitable for forming the first exterior surface layer 30 include, but are not limited to, a polyolefin (e.g., a polyethylene, a polypropylene), a thermoplastic elastomer (e.g., a styrenic block copolymer, a thermoplastic polyolefin elastomer, a thermoplastic vulcanizate, a thermoplastic polyurethane, a thermoplastic copolyester, a thermoplastic polyamide), a polyester, a polystyrene, a polyamide, a polyurethane, a polycarbonate, an ethylene-acrylic copolymer, an ethylene methyl acrylate (EMA) copolymer, an ethylene vinyl acetate (EVA) copolymer, and combinations thereof. The material used to form the first exterior surface layer 30 may comprise a virgin material and/or a recycled/reprocessed material. In certain embodiments, the first exterior surface layer 30 comprises at least one of a polyolefin and a thermoplastic elastomer. In certain embodiments, the first exterior surface layer 30 comprises at least one of a polypropylene and a thermoplastic elastomer. The first exterior surface layer 30 may also comprise additives such as colorants, pigments, antioxidants, U.V. stabilizers, fire retardants, fillers, and the like.


The first exterior surface layer 30 shown in FIG. 1 may be structured in a variety of ways. For example, the first exterior surface layer 30 may be a nonwoven material, a woven material, or a film material. In certain embodiments, the first exterior surface layer 30 is a spunbond nonwoven material. In general, and regardless of form, the first exterior surface layer 30 has a basis weight of 10 g/m2 to 120 g/m2, including a basis weight of 10 g/m2 to 100 g/m2, a basis weight of 10 g/m2 to 80 g/m2, a basis weight of 15 g/m2 to 75 g/m2, a basis weight of 20 g/m2 to 75 g/m2, a basis weight of 35 g/m2 to 75 g/m2, a basis weight of 40 g/m2 to 65 g/m2, and also including a basis weight of 45 g/m2 to 55 g/m2. In certain embodiments, the first exterior surface layer 30 is a spunbond nonwoven material comprising at least one of a polyolefin and a thermoplastic elastomer, and having a basis weight of 45 g/m2 to 55 g/m2. In certain embodiments, the first exterior surface layer 30 is a spunbond nonwoven material comprising at least one of a polypropylene and a thermoplastic elastomer, and having a basis weight of 45 g/m2 to 55 g/m2. The inclusion of a thermoplastic elastomer material in the first exterior surface layer 30 can promote enhanced walkability (i.e., foot traction) due to the rubbery nature and gripping ability associated with thermoplastic elastomer materials. The term “walkability” refers to characteristics of an underlayment that make it less likely for a person walking on the underlayment to slip or lose foot traction thereon.


In certain embodiments, the first exterior surface layer 30 is a spunbond nonwoven material comprising a polyolefin and having a basis weight of 45 g/m2 to 55 g/m2. In certain embodiments, the first exterior surface layer 30 is a spunbond nonwoven material having a basis weight of 45 g/m2 to 55 g/m2 and comprises 45% to 55% by weight virgin polypropylene, 40% to 50% by weight recycled/reprocessed polypropylene, and 1% to 5% by weight colorant (e.g., color masterbatch), based on the total weight of the first exterior surface layer 30.


In certain embodiments, the first exterior surface layer 30 comprises a bicomponent spunbond nonwoven material formed using a dual beam spunbond process, as known in the art. In certain embodiments, the bicomponent spunbond nonwoven material includes a polyolefin layer and a thermoplastic elastomer layer which are bonded together (e.g., by heat pressing, calendering, needling, ultrasonic bonding or welding, adhesives, tie layers, and/or point bonding) to form the first exterior surface layer 30. In these embodiments, the polyolefin layer of the first exterior surface layer 30 is configured to abut the first coating layer 20 of the roofing underlayment 100 and, thus, the thermoplastic elastomer layer of the first exterior surface layer 30 forms an outermost surface of the roofing underlayment 100.


In certain embodiments, the first exterior surface layer 30 comprises a bicomponent spunbond nonwoven material having a polyolefin layer and a thermoplastic elastomer layer. In certain embodiments, the first exterior surface layer 30 has a total basis weight of 30 g/m2 to 60 g/m2. In certain embodiments, the polyolefin layer of the first exterior surface layer 30 has a basis weight of 15 g/m2 to 30 g/m2, including a basis weight of 15 g/m2 to 25 g/m2 and a basis weight of 20 g/m2 to 30 g/m2, and comprises 84% to 98% by weight virgin polypropylene, 1% to 8% by weight U.V. stabilizer (e.g., a U.V. masterbatch), and 1% to 8% by weight colorant (e.g., color masterbatch), based on the total weight of the polyolefin layer; and the thermoplastic elastomer layer of the first exterior surface layer 30 has a basis weight of 15 g/m2 to 30 g/m2, including a basis weight of 15 g/m2 to 25 g/m2 and a basis weight of 20 g/m2 to 30 g/m2, and comprises 70% to 80% by weight virgin polypropylene, 15% to 25% thermoplastic elastomer, 1% to 8% by weight U.V. stabilizer (e.g., a U.V. masterbatch), and 1% to 8% by weight colorant (e.g., color masterbatch), based on the total weight of the thermoplastic elastomer layer.


In certain embodiments, the first exterior surface layer 30 comprises a bicomponent spunbond nonwoven material having a polyolefin layer and a thermoplastic elastomer layer. In certain embodiments, the first exterior surface layer 30 has a total basis weight of 45 g/m2 to 55 g/m2. In certain embodiments, the polyolefin layer of the first exterior surface layer 30 has a basis weight of 20 g/m2 to 30 g/m2 and comprises 45% to 55% by weight virgin polypropylene, 40% to 50% by weight recycled/reprocessed polypropylene, and 1% to 5% by weight colorant (e.g., color masterbatch), based on the total weight of the polyolefin layer; and the thermoplastic elastomer layer of the first exterior surface layer 30 has a basis weight of 20 g/m2 to 30 g/m2 and comprises 70% to 80% by weight virgin polypropylene, 15% to 25% thermoplastic elastomer, and 1% to 5% by weight colorant (e.g., color masterbatch), based on the total weight of the thermoplastic elastomer layer.


In certain embodiments, the first exterior surface layer 30 is a melt-blown nonwoven material. In certain embodiments, the first exterior surface layer 30 is a melt-blown nonwoven material comprising a polyolefin and having a basis weight of 10 g/m2 to 80 g/m2. In certain embodiments, the first exterior surface layer 30 is a melt-blown nonwoven material comprising a polypropylene and having a basis weight of 25 g/m2 to 50 g/m2. In certain embodiments, the first exterior surface layer 30 is a melt-blown nonwoven material having a basis weight of 30 g/m2 to 40 g/m2 and comprising a polypropylene and a U.V. stabilizer (e.g., a U.V. masterbatch). In certain embodiments, the first exterior surface layer 30 is a melt-blown nonwoven material having a basis weight of 30 g/m2 to 40 g/m2 and comprising a polypropylene. In certain embodiments, the first exterior surface layer 30 is a melt-blown nonwoven material having a basis weight of 40 g/m2 to 50 g/m2 and comprising a polypropylene. Configuring the first exterior surface layer 30 as a melt-blown nonwoven layer 30 may enhance walkability by providing a rough surface.


Referring now to FIG. 2, an exemplary embodiment of a roofing underlayment 100a of the present disclosure is shown. The roofing underlayment 100a shown in FIG. 2 is structured similarly to the roofing underlayment 100 illustrated in FIG. 1 except the roofing underlayment 100a shown in FIG. 2 includes a second exterior surface layer 40a. As seen in FIG. 2, the roofing underlayment 100a comprises a hydrophobic nonwoven core layer 10a having a first surface 12a (e.g., a top surface) and a second surface 14a (e.g., a bottom surface), a first coating layer 20a adhered to the first surface 12a of the hydrophobic nonwoven core layer 10a, and a first exterior surface layer 30a adhered to the first coating layer 20a. The second exterior surface layer 40a is adhered to the second surface 14a of the hydrophobic nonwoven core layer 10a. The various embodiments of the individual layers 10, 20, 30 of the roofing underlayment 100 described above with reference to FIG. 1 may also be used for the individual layers 10a, 20a, 30a of the roofing underlayment 100a illustrated in FIG. 2.


As mentioned above, the roofing underlayment 100a shown in FIG. 2 includes a second exterior surface layer 40a adhered to the second surface 14a of the hydrophobic nonwoven core layer 10a. The second exterior surface layer 40a of the present disclosure is generally water impermeable and may be formed from a variety of materials, most typically one or more polymeric materials. Exemplary materials suitable for forming the second exterior surface layer 40a of the present disclosure include, but are not limited to, a polyolefin (e.g., a polyethylene, a polypropylene), a thermoplastic elastomer (e.g., a styrenic block copolymer, a thermoplastic polyolefin elastomer, a thermoplastic vulcanizate, a thermoplastic polyurethane, a thermoplastic copolyester, a thermoplastic polyamide), a polyester, a polystyrene, a polyamide, a polyurethane, a polycarbonate, an ethylene-acrylic copolymer, an ethylene methyl acrylate (EMA) copolymer, an ethylene vinyl acetate (EVA) copolymer, and combinations thereof. The material used to form the second exterior surface layer 40a of the present disclosure may comprise a virgin material and/or a recycled/reprocessed material.


In certain embodiments, the second exterior surface layer 40a comprises at least one of a polyolefin and a thermoplastic elastomer. In certain embodiments, the second exterior surface layer 40a comprises at least one of a polypropylene, a polyethylene, and a thermoplastic elastomer. In certain embodiments, the second exterior surface layer 40a comprises a polypropylene, a polyethylene, and a thermoplastic elastomer. The second exterior surface layer 40a of the present disclosure may also comprise additives such as colorants, pigments, antioxidants, U.V. stabilizers, fire retardants, fillers, and the like.


The second exterior surface layer 40a of the present disclosure may be structured in a variety of ways. For example, the second exterior surface layer 40a may be a film material, a woven material, or a nonwoven material. In certain embodiments, the second exterior surface layer 40a is a film material that is extruded onto or laminated onto (e.g., using an adhesive) the second surface 14a of the hydrophobic nonwoven core layer 10a. In certain embodiments, the second exterior surface layer 40a is a multi-layer film material comprising a thermoplastic elastomer layer and a polyolefin layer that is formed using a co-extrusion process. In certain embodiments, the thermoplastic elastomer layer of the second exterior surface layer 40a comprises a thermoplastic elastomer and a polyolefin, such as a polypropylene and/or a polyethylene. In certain embodiments, the polyolefin layer of the second exterior surface layer 40a comprises at least one of a polypropylene and/or a polyethylene. The thermoplastic elastomer layer and/or the polyolefin layer of the second exterior surface layer 40a of the present disclosure may also comprise additives such as colorants, pigments, antioxidants, U.V. stabilizers, fire retardants, fillers, and the like.


In certain embodiments, the second exterior surface layer 40a is applied to the second surface 14a of the hydrophobic nonwoven core layer 10a (which may already include a first coating layer 20a adhered to the first surface 12a of the hydrophobic nonwoven layer 10a and a first exterior surface layer 30a adhered to the first coating layer 20a) as a curtain of molten material comprising a thermoplastic elastomer extrudate and a polyolefin extrudate, which are laminated together to form the roofing underlayment 100a. Preferably, the polyolefin layer of the second exterior surface layer 40a is adhered to the second surface 14a of the hydrophobic nonwoven core layer 10a and the thermoplastic elastomer layer of the second exterior surface layer 40a forms a bottommost surface (i.e., the surface intended to contact a roof deck or other substrate) of the roofing underlayment 100a. Because of the rubbery nature and gripping ability associated with thermoplastic elastomer materials, including a thermoplastic elastomer layer as the portion of the second exterior surface layer 40a that forms a bottommost surface of the roofing underlayment 100a imparts enhanced slip resistance (i.e., the ability to resist movement relative to a substrate) to the roofing underlayment 100a.


In certain embodiments, the second exterior surface layer 40a of the present disclosure has a basis weight of 10 g/m2 to 120 g/m2. In certain embodiments, the second exterior surface layer 40a has a basis weight of 10 g/m2 to 100 g/m2. In certain embodiments, the second exterior surface layer 40a has a basis weight of 10 g/m2 to 80 g/m2. In certain embodiments, the second exterior surface layer 40a has a basis weight of 15 g/m2 to 75 g/m2. In certain embodiments, the second exterior surface layer 40a has a basis weight of 20 g/m2 to 50 g/m2. In certain embodiments, the second exterior surface layer 40a has a basis weight of 20 g/m2 to 30 g/m2. In certain embodiments, the second exterior surface layer 40a is a multi-layer film material. The multi-layer film material may be formed using any suitable process. In certain embodiments, the second exterior surface layer 40a is a multi-layer film material formed using a co-extrusion process. In certain embodiments, the multi-layer film material comprises a polyolefin layer having a basis weight of 10.8 g/m2 to 28.8 g/m2 and a thermoplastic elastomer layer having a basis weight of 4.2 g/m2 to 11.2 g/m2. In certain embodiments, the multi-layer film material comprises a polyolefin layer having a basis weight of 10.8 g/m2 to 25.2 g/m2 and a thermoplastic elastomer layer having a basis weight of 4.2 g/m2 to 9.8 g/m2. In certain embodiments, the multi-layer film material forming the second exterior surface layer 40a comprises a polyolefin layer that includes a polypropylene and/or a polyethylene and has a basis weight of 14.4 g/m2 to 21.6 g/m2, and a thermoplastic elastomer layer that has a basis weight of 5.6 g/m2 to 8.4 g/m2.


In certain embodiments, the second exterior surface layer 40a is a multi-layer film material, preferably formed using a co-extrusion process, comprising a polyolefin layer having a basis weight of 15 g/m2 to 25 g/m2 and a thermoplastic elastomer layer having a basis weight of 2 g/m2 to 10 g/m2. In certain embodiments, the polyolefin layer of the second exterior surface layer 40a comprises 40% to 50% by weight recycled/reprocessed polypropylene, 30% to 40% by weight virgin polypropylene, 10% to 20% by weight LDPE, and 2% to 6% by weight colorant (e.g., color masterbatch), wherein the weight percentages are based on the total weight of the polyolefin layer; and the thermoplastic elastomer layer of the second coating layer 40a comprises 40% to 55% by weight thermoplastic elastomer, 25% to 45% by weight virgin polypropylene, 10% to 20% by weight LDPE, and 2% to 6% by weight colorant (e.g., color masterbatch), wherein the weight percentages are based on the total weight of the thermoplastic elastomer layer.


In certain embodiments, the second exterior surface layer 40a is a melt-blown nonwoven material. In certain embodiments, the second exterior surface layer 40a is a melt-blown nonwoven material comprising a polyolefin and having a basis weight of 25 g/m2 to 50 g/m2. In certain embodiments, the second exterior surface layer 40a is a melt-blown nonwoven material comprising a polypropylene and having a basis weight of 25 g/m2 to 50 g/m2. Configuring the second exterior surface layer 40a as a melt-blown nonwoven layer may enhance slip resistance by providing a rough surface that grips the roof deck or other substrate.


The roofing underlayments 100, 100a of the present disclosure generally have a total basis weight of 190 g/m2 to 265 g/m2. In certain embodiments, the roofing underlayments 100, 100a have a total basis weight of 195 g/m2 to 265 g/m2. In certain embodiments, the roofing underlayments 100, 100a have a total basis weight of 210 g/m2 to 260 g/m2. In certain embodiments, the roofing underlayments 100, 100a have a total basis weight of 225 g/m2 to 250 g/m2. In certain embodiments, the roofing underlayments 100, 100a have a total basis weight of 240 g/m2 to 250 g/m2. The roofing underlayments 100, 100a of the present disclosure generally have a total thickness of 0.2 mm (about 7.87 mil) to 1.25 mm (about 50 mil). In certain embodiments, the roofing underlayments 100, 100a of the present disclosure have a total thickness of 0.25 mm (about 10 mil) to 1.25 mm (about 50 mil), including a total thickness of 0.3 mm (about 12 mil) to 1.25 mm (about 50 mil), a total thickness of 0.4 mm (about 15.7 mil) to 1.25 mm (about 50 mil), a total thickness of 0.5 mm (about 19.7 mil) to 1.25 mm (about 50 mil), a total thickness of 0.6 mm (about 23.6 mil) to 1 mm (about 39.4 mil), and also including a thickness of 0.75 mm (about 29.5 mil) to 1 mm (about 39.4 mil).


The roofing underlayments 100, 100a of the present disclosure may be configured as self-adhered (e.g., peel and stick) underlayments. In such embodiments, a layer of adhesive material (not shown) (e.g., an asphalt-based adhesive) is applied to a bottommost surface of the roofing underlayment 100, 100a, and the layer of adhesive material functions to adhere the roofing underlayment 100, 100a to a substrate, such as a roof deck, without using mechanical fasteners (e.g., nails, staples). The layer of adhesive material may be covered with a release material as is customary in the art.


The roofing underlayments 100, 100a of the present disclosure may be formed using conventional manufacturing techniques known to those of skill in the art. In certain embodiments, the roofing underlayments 100, 100a may be formed by adding each layer individually to build up the roofing underlayment 100, 100a. In these or other embodiments, certain layers (e.g., the first exterior surface layer, the hydrophobic nonwoven core layer) may be pre-formed and provided in a process in which additional layers (e.g., the first coating layer, the second exterior surface layer) are laminated or otherwise joined to the pre-formed layers. In certain embodiments, all of the layers may be stacked or arranged together and laminated in a single lamination process. In one or more embodiments, the layers may be bonded or otherwise adhered together by chemical bonding, mechanical bonding, and/or thermal bonding. Exemplary methods of bonding the layers include, but are not limited to, heat pressing, calendering, needling, ultrasonic bonding or welding, adhesives, tie layers, and/or point bonding.


Referring now to FIG. 3, an exemplary embodiment of a roofing system 100b of the present disclosure is shown. As seen in FIG. 3, the roofing system 100b includes a roof deck 102, a roofing underlayment 103 attached to the roof deck 102, and a roofing material 104 positioned on the roofing underlayment 103. The roofing underlayment 103 may be configured in accordance with any of the roofing underlayment embodiments and sub-embodiments described above (e.g., roofing underlayment 100 shown in FIG. 1, roofing underlayment 100a shown in FIG. 2). The roofing material 104 may be any conventional exterior roofing material such as asphalt shingles, shake shingles, slate shingles, roof tiles, and so forth.


All references to singular characteristics or limitations of the present disclosure shall include the corresponding plural characteristic or limitation, and vice versa, unless otherwise specified or clearly implied to the contrary by the context in which the reference is made.


All combinations of method or process steps as used herein can be performed in any order, unless otherwise specified or clearly implied to the contrary by the context in which the referenced combination is made.


All ranges and parameters, including but not limited to percentages, parts, and ratios, disclosed herein are understood to encompass any and all sub-ranges assumed and subsumed therein, and every number between the endpoints. For example, a stated range of “1 to 10” should be considered to include any and all subranges between (and inclusive of) the minimum value of 1 and the maximum value of 10; that is, all subranges beginning with a minimum value of 1 or more (e.g., 1 to 6.1), and ending with a maximum value of 10 or less (e.g., 2.3 to 9.4, 3 to 8, 4 to 7), and finally to each number 1, 2, 3, 4, 5, 6, 7, 8, 9, and 10 contained within the range.


The underlayments of the present disclosure can comprise, consist of, or consist essentially of the essential elements and limitations of the disclosure as described herein, as well as any additional or optional components or limitations described herein or otherwise known to be useful in underlayment or similar applications.


To the extent that the terms “include,” “includes,” or “including” are used in the specification or the claims, they are intended to be inclusive in a manner similar to the term “comprising” as that term is interpreted when employed as a transitional word in a claim. Furthermore, to the extent that the term “or” is employed (e.g., A or B), it is intended to mean “A or B or both A and B.” When the Applicant intends to indicate “only A or B but not both,” then the term “only A or B but not both” will be employed. Thus, use of the term “or” herein is the inclusive, and not the exclusive use. Furthermore, the phrase “at least one of A, B, and C” should be interpreted as “only A or only B or only C or any combinations thereof.” In the present disclosure, the words “a” or “an” are to be taken to include both the singular and the plural. Conversely, any reference to plural items shall, where appropriate, include the singular.


In some embodiments, it may be possible to utilize the various inventive concepts in combination with one another. Additionally, any particular element recited as relating to a particularly disclosed embodiment should be interpreted as available for use with all disclosed embodiments, unless incorporation of the particular element would be contradictory to the express terms of the embodiment. Additional advantages and modifications will be readily apparent to those skilled in the art. Therefore, the disclosure, in its broader aspects, is not limited to the specific details presented therein, the representative apparatus, or the illustrative examples shown and described. Accordingly, departures may be made from such details without departing from the spirit or scope of the general inventive concepts.


The scope of the general inventive concepts presented herein are not intended to be limited to the particular exemplary embodiments shown and described herein. From the disclosure given, those skilled in the art will not only understand the general inventive concepts and their attendant advantages, but will also find apparent various changes and modifications to the devices, systems, and methods disclosed. It is sought, therefore, to cover all such changes and modifications as fall within the spirit and scope of the general inventive concepts, as described and/or claimed herein, and any equivalents thereof.

Claims
  • 1. A roofing underlayment comprising: a hydrophobic nonwoven core layer having a basis weight of 100 g/m2 to 250 g/m2,a first coating layer adhered to a first surface of the hydrophobic nonwoven core layer, anda first exterior surface layer comprising a bicomponent spunbond nonwoven material having a total basis weight of 30 g/m2 to 60 g/m2 and comprising a polyolefin layer bonded to a thermoplastic elastomer layer, and wherein the polyolefin layer is adhered to the first coating layer.
  • 2. The roofing underlayment according to claim 1, wherein the hydrophobic nonwoven core layer comprises at least one of a polyolefin, a polyester, a polystyrene, a polyamide, a polyurethane, a polycarbonate, and an ethylene acrylic copolymer.
  • 3. The roofing underlayment according to claim 1, wherein the hydrophobic nonwoven core layer comprises a polypropylene.
  • 4. The roofing underlayment according to claim 1, wherein the hydrophobic nonwoven core layer has a basis weight of 105 g/m2 to 150 g/m2.
  • 5. The roofing underlayment according to claim 1, wherein the first coating layer comprises at least one of a polyolefin, a thermoplastic elastomer, a polyester, a polystyrene, a polyamide, a polyurethane, a polycarbonate, and an ethylene acrylic copolymer.
  • 6. The roofing underlayment according to claim 1, wherein the first coating layer has a basis weight of 15 g/m2 to 30 g/m2.
  • 7. The roofing underlayment according to claim 1, wherein the polyolefin layer has a basis weight of 15 g/m2 to 30 g/m2 and comprises 84% to 98% by weight virgin polypropylene, 1% to 8% by weight U.V. stabilizer, and 1% to 8% by weight colorant, based on the total weight of the polyolefin layer; and the thermoplastic elastomer layer has a basis weight of 15 g/m2 to 30 g/m2 and comprises 70% to 80% by weight virgin polypropylene, 15% to 25% thermoplastic elastomer, 1% to 8% by weight U.V. stabilizer, and 1% to 8% by weight colorant, based on the total weight of the thermoplastic elastomer layer.
  • 8. The roofing underlayment according to claim 1, wherein the polyolefin layer has a basis weight of 20 g/m2 to 30 g/m2 and comprises 45% to 55% by weight virgin polypropylene, 40% to 50% by weight recycled/reprocessed polypropylene, and 1% to 5% by weight colorant, based on the total weight of the polyolefin layer; and the thermoplastic elastomer layer has a basis weight of 20 g/m2 to 30 g/m2 and comprises 70% to 80% by weight virgin polypropylene, 15% to 25% thermoplastic elastomer, and 1% to 5% by weight colorant, based on the total weight of the thermoplastic elastomer layer.
  • 9. The roofing underlayment according to claim 1, further comprising a second exterior surface layer adhered to a second surface of the hydrophobic nonwoven core layer opposite the first surface.
  • 10. The roofing underlayment according to claim 9, wherein the second exterior surface layer is a co-extruded layer comprising a thermoplastic elastomer layer and a polyolefin layer and has a basis weight of 10 g/m2 to 120 g/m2.
  • 11. The roofing underlayment according to claim 10, wherein the polyolefin layer has a basis weight of 15 g/m2 to 25 g/m2 and comprises 40% to 50% by weight recycled/reprocessed polypropylene, 30% to 40% by weight virgin polypropylene, 10% to 20% by weight low density polyethylene, and 2% to 6% by weight colorant, based on the total weight of the polyolefin layer; and wherein the thermoplastic elastomer layer has a basis weight of 2 g/m2 to 10 g/m2 and comprises 40% to 55% by weight thermoplastic elastomer, 25% to 45% by weight virgin polypropylene, 10% to 20% by weight low density polyethylene, and 2% to 6% by weight colorant, based on the total weight of the thermoplastic elastomer layer.
  • 12. The roofing underlayment according to claim 1, wherein the roofing underlayment has a total basis weight of 190 g/m2 to 265 g/m2.
  • 13. The roofing underlayment according to claim 1, wherein the roofing underlayment has a total basis weight of 225 g/m2 to 250 g/m2.
  • 14. The roofing underlayment according to claim 1, wherein the hydrophobic nonwoven core layer comprises at least 50% of a total basis weight of the roofing underlayment.
  • 15. The roofing underlayment according to claim 1, wherein the hydrophobic nonwoven core layer comprises from 50% to 80% of the total basis weight of the roofing underlayment.
  • 16. A roofing underlayment comprising: a hydrophobic nonwoven core layer having a basis weight of 110 g/m2 to 155 g/m2;a first coating layer adhered to a first surface of the hydrophobic nonwoven core layer, wherein the first coating layer has a basis weight of 10 g/m2 to 40 g/m2;a first exterior surface layer adhered to the first coating layer, wherein the first exterior surface layer has a basis weight of 20 g/m2 to 60 g/m2; anda second exterior surface layer adhered to a second surface of the hydrophobic nonwoven core layer opposite the first surface, wherein the second exterior surface layer is a co-extruded layer comprising a thermoplastic elastomer layer having a basis weight of 2 g/m2 to 10 g/m2 and a polyolefin layer having a basis weight of 15 g/m2 to 25 g/m2,wherein the hydrophobic nonwoven core layer comprises from 50% to 80% of a total basis weight of the roofing underlayment.
CROSS-REFERENCE TO RELATED APPLICATIONS

This application claims priority to and the benefit of U.S. Provisional Patent Application No. 62/865,581, filed Jun. 24, 2019, the entire content of which is incorporated by reference herein.

US Referenced Citations (93)
Number Name Date Kind
4041203 Brock Aug 1977 A
4342804 Meynard Aug 1982 A
4656082 Goodacre Apr 1987 A
4766029 Brock Aug 1988 A
4789699 Kieffer Dec 1988 A
5130178 Zerfass et al. Jul 1992 A
5204165 Schortmann Apr 1993 A
5308691 Lim et al. May 1994 A
5616408 Oleszczuk et al. Apr 1997 A
5687517 Wiercinski Nov 1997 A
5925581 Tolbert Jul 1999 A
5939341 Brown et al. Aug 1999 A
5942452 Daponte Aug 1999 A
6296912 Zickell Oct 2001 B1
6764968 Hindi et al. Jul 2004 B1
6804922 Egan Oct 2004 B1
6864194 Hindi et al. Mar 2005 B2
6925766 Di Pede Aug 2005 B2
7148160 Porter Dec 2006 B2
7718558 Galvin May 2010 B2
7786028 Souther et al. Aug 2010 B2
7803725 Payne et al. Sep 2010 B2
7882671 Bruce et al. Feb 2011 B2
7919420 Bornemann et al. Apr 2011 B2
7977259 Ratcliff et al. Jul 2011 B2
8349103 Suzuka et al. Jan 2013 B2
8765251 Strait Jul 2014 B2
9314994 Strait Apr 2016 B2
9359014 Yang Jun 2016 B1
9415563 Xiang Li Aug 2016 B2
9540820 Kalkanoglu et al. Jan 2017 B2
10161063 Westwood Dec 2018 B2
10161129 Hickie et al. Dec 2018 B2
20020055316 Araida et al. May 2002 A1
20020139076 Carr, III Oct 2002 A1
20030077964 Klein Apr 2003 A1
20040023585 Carroll et al. Feb 2004 A1
20040127120 Zanchetta Jul 2004 A1
20040148887 Di Pede Aug 2004 A1
20040214489 Porter Oct 2004 A1
20060046084 Yang Mar 2006 A1
20060228962 Souther et al. Oct 2006 A1
20060286347 Mehta Dec 2006 A1
20070077838 Binkley Apr 2007 A1
20070193167 Bruce Aug 2007 A1
20070194482 Douglas et al. Aug 2007 A1
20070249252 Galvin Oct 2007 A1
20070275621 Bennett et al. Nov 2007 A1
20070277450 Raulie Dec 2007 A1
20080020662 Strait Jan 2008 A1
20080026663 Zhang Jan 2008 A1
20080081152 Khan Apr 2008 A1
20080092474 Gan Apr 2008 A1
20080141604 Arthurs Jun 2008 A1
20080152867 Di Pede Jun 2008 A1
20080166533 Jones Jul 2008 A1
20080176022 Payne Jul 2008 A1
20080227350 Schroer Sep 2008 A1
20080227353 Klingelhage Sep 2008 A1
20080289289 Wiercinski Nov 2008 A1
20090041999 Schroer Feb 2009 A1
20090202803 Poloso Aug 2009 A1
20100056004 Galvin et al. Mar 2010 A1
20100077684 Socha Apr 2010 A1
20100173110 Wiercinski et al. Jul 2010 A1
20100178827 Thai Jul 2010 A1
20100260990 Lunghi Oct 2010 A1
20110003116 Drechsler Jan 2011 A1
20110009024 Clark Jan 2011 A1
20120096791 Cashin Apr 2012 A1
20120315471 Mancosh Dec 2012 A1
20130180203 Xiangli Jul 2013 A1
20140050894 Wahlquist Feb 2014 A1
20140062126 Weinberg Mar 2014 A1
20140147642 Weinberg May 2014 A1
20140215962 Xiang Li Aug 2014 A1
20160185077 Andrews Jun 2016 A1
20170036429 Harfmann Feb 2017 A1
20170190146 Shen Jul 2017 A1
20170198470 Hickie Jul 2017 A1
20170306628 Simonis Oct 2017 A1
20170326835 Xiang Li Nov 2017 A1
20170368810 Zacarias Dec 2017 A1
20180029345 Tijssen Feb 2018 A1
20180245349 Shepherd Aug 2018 A1
20180355617 Granovsky et al. Dec 2018 A1
20190211565 Hascher Jul 2019 A1
20190277028 Chevillard Sep 2019 A1
20200299966 Tang Sep 2020 A1
20200376796 Flaig Dec 2020 A1
20200399903 Vido Dec 2020 A1
20210079657 Vido Mar 2021 A1
20210316541 Bachon Oct 2021 A1
Foreign Referenced Citations (82)
Number Date Country
102794959 Nov 2012 CN
103696147 Apr 2014 CN
110154470 Aug 2019 CN
3737675 Oct 1988 DE
29801953 Apr 1998 DE
29805622 Jun 1998 DE
29811128 Sep 1998 DE
19755229 Jun 1999 DE
10234018 Feb 2004 DE
102006057139 Jun 2008 DE
102008024944 Feb 2009 DE
102013108521 Feb 2015 DE
102014001792 Aug 2015 DE
102017004350 Nov 2018 DE
0179162 Apr 1986 EP
708212 Apr 1996 EP
716176 Jun 1996 EP
742305 Nov 1996 EP
855479 Jul 1998 EP
885716 Dec 1998 EP
1022125 Jul 2000 EP
1024218 Aug 2000 EP
1085141 Mar 2001 EP
1191161 Mar 2002 EP
1500493 Jan 2005 EP
1772259 Apr 2007 EP
2065534 Jun 2009 EP
3002382 Apr 2016 EP
3345757 Jul 2018 EP
2341578 Mar 2000 GB
2494543 Mar 2013 GB
2495622 Apr 2013 GB
2496244 May 2013 GB
2518055 Mar 2015 GB
02118177 May 1990 JP
06264572 Sep 1994 JP
09078426 Mar 1997 JP
09111969 Apr 1997 JP
11050609 Feb 1999 JP
11091018 Apr 1999 JP
11166300 Jun 1999 JP
2001009945 Jan 2001 JP
2001132180 May 2001 JP
2001232710 Aug 2001 JP
2001240648 Sep 2001 JP
2001241118 Sep 2001 JP
2001279880 Oct 2001 JP
2002227352 Aug 2002 JP
2002339527 Nov 2002 JP
2002349021 Dec 2002 JP
2002349022 Dec 2002 JP
2002356958 Dec 2002 JP
2004052473 Feb 2004 JP
2006057444 Mar 2006 JP
2006177106 Jul 2006 JP
2006328879 Dec 2006 JP
2007120300 May 2007 JP
2007223046 Sep 2007 JP
2008303549 Dec 2008 JP
2008308903 Dec 2008 JP
2010275842 Dec 2010 JP
2012167451 Sep 2012 JP
2013064304 Apr 2013 JP
2013100648 May 2013 JP
5669969 Feb 2015 JP
2015169038 Sep 2015 JP
2015194048 Nov 2015 JP
2016003504 Jan 2016 JP
2016094735 May 2016 JP
2017125351 Jul 2017 JP
2018168554 Nov 2018 JP
2018176619 Nov 2018 JP
2018091556 Aug 2018 KR
WO-9636778 Nov 1996 WO
WO-9730244 Aug 1997 WO
WO-9902797 Jan 1999 WO
WO-9955983 Nov 1999 WO
WO-0046464 Aug 2000 WO
WO-0173242 Oct 2001 WO
WO-2006080907 Aug 2006 WO
WO-2012026532 Mar 2012 WO
WO-2015025503 Feb 2015 WO
Non-Patent Literature Citations (4)
Entry
Machine Translation of JP-0978426-A, Mar. 1997 (Year: 1997).
Machine Translation of EP-1024218-A2, Aug. 2000 (Year: 2000).
Machine Translation of DE-102013108521-A1, Feb. 2015 (Year: 2015).
Machine Translation of DE-102015000092-A1 used to cite EP-3002382-A1, Apr. 2016 (Year: 2016).
Related Publications (1)
Number Date Country
20200399904 A1 Dec 2020 US
Provisional Applications (1)
Number Date Country
62865581 Jun 2019 US