SEALING RESIN COMPOSITION, SEALING FILM, WIRING BOARD, TFT DEVICE, OLED DEVICE, AND LED DEVICE

Abstract
A sealing resin composition, which coats silver wiring or a laminate including the silver wiring, comprises: a fluorine-based resin (A); and a migration inhibitor (B) having a fluorine content rate of equal to or more than 35 mass % and less than 65 mass %, wherein the mass ratio ((B)/(A)) of the migration inhibitor (B) to the fluorine-based resin (A) is equal to or more than 0.0010 and less than 0.10.
Description
BACKGROUND OF THE INVENTION

The present invention relates to a sealing resin composition and a sealing film. Particularly, the present invention relates to a sealing resin composition and a sealing film, each of which contains a fluorine-based resin and a migration inhibitor having a predetermined fluorine content rate in predetermined amounts.


The present invention also relates to a wiring board, a TFT device, an OLED device, and an LED device, each of which includes the sealing film.


In recent years, with the miniaturization, high integration and high performance of electronic components, the microfabrication of metal wiring has progressed. Consequently, the electromigration (hereinafter, also referred to as “ion migration”) occurring between the metal wiring causes a serious problem in that wiring reliability is decreased. Particularly, in the case of metal wiring formed using silver, the problem is remarkably serious.


In order to solve this problem, JP 59-151491 A suggests a method of suppressing ion migration by forming an insulating material layer containing a fluorine-based resin on metal wiring.


SUMMARY OF THE INVENTION

Meanwhile, in recent years, as the microfabrication of metal wiring has progressed, the characteristics required for insulation reliability between metal wiring have been more and more raised.


The present inventors examined the insulation reliability between metal wiring using the method described in JP 59-151491 A. As a result, it was found that the insulation reliability between metal wiring obtained by the method does not satisfy the level currently required and further improvement thereof is required.


As the method of suppressing ion migration, there is a method of also using a so-called migration inhibitor. However, generally, the compatibility of a migration inhibitor with respect to a fluorine-based resin is low, and thus, there is a problem in that the planar characteristics of the formed sealing layer are deteriorated. Therefore, it is difficult to use a migration inhibitor.


In view of the above circumstances, an object of the present invention is to provide a sealing resin composition which can be applied to silver wiring and a laminate including the silver wiring, and can form a sealing film exhibiting excellent ion migration-inhibiting ability and excellent planar characteristics.


Another object of the present invention is to provide a sealing film and a wiring board including the sealing film.


As a result of conducting intensive examination, the present inventors found that the above problems can be solved by using a fluorine-based resin and a migration inhibitor having a predetermined fluorine content rate, and based on this finding, the present invention was accomplished.


That is, the above objects can be accomplished by the following means.


(1) A sealing resin composition, which coats silver wiring or a laminate including the silver wiring, comprising:


a fluorine-based resin (A); and


a migration inhibitor (B) having a fluorine content rate of equal to or more than 35 mass % and less than 65 mass %,


wherein the mass ratio ((B)/(A)) of the migration inhibitor (B) to the fluorine-based resin (A) is equal to or more than 0.0010 and less than 0.10.


(2) The sealing resin composition according to (1), wherein the migration inhibitor (B) is at least one selected from the group consisting of compounds represented by General Formulae (1) to (5) described later, a compound represented by General Formula (22) described later, a compound represented by General Formula (23) described later, and a compound having a group represented by General Formula (24) described later and a group represented by General Formula (25) described later.


(3) The sealing resin composition according to (2), wherein the compound represented by the General Formula (1) described later is at least one selected from the group consisting of compounds represented by General Formulae (6) to (21) described later.


(4) The sealing resin composition according to (2) or (3),


wherein the compound represented by General Formula (5) described later is at least one selected from the group consisting of compounds represented by General Formulae (51) to (54) described later.


(5) The sealing resin composition according to (4),


wherein the migration inhibitor (B) is at least one selected from the group consisting of the compounds represented by General Formula (6) described later, General Formula (7) described later, General Formula (10) described later, General Formula (11) described later, General Formula (21) described later, General Formula (51) described later, General Formula (53) described later, and General Formula (54) described later.


(6) The sealing resin composition according to any one of (1) to (5),


wherein the fluorine-based resin (A) has at least a repeating unit represented by General Formula (P-1) described later.


(7) The sealing resin composition according to any one of (1) to (6),


wherein the fluorine-based resin (A) has a silicon-containing group that has a hydroxyl group or a hydrolyzable group bonded to a silicon atom and that can be crosslinked by forming a siloxane bond.


(8) A sealing film, which coats silver wiring or a laminate including the silver wiring, comprising:


a fluorine-based resin (A); and


a migration inhibitor (B) having a fluorine content rate of equal to or more than 35 mass % and less than 65 mass %,


wherein the mass ratio ((B)/(A)) of the migration inhibitor (B) to the fluorine-based resin (A) is equal to or more than 0.0010 and less than 0.10.


(9) The sealing film according to (8), wherein the migration inhibitor (B) is at least one selected from the group consisting of compounds represented by General Formulae (1) to (5) described later, a compound represented by General Formula (22) described later, a compound represented by General Formula (23) described later, and a compound having a group represented by General Formula (24) described later and a group represented by General Formula (25) described later.


(10) The sealing film according to (9), wherein the compound represented by the General Formula (1) described later is at least one selected from the group consisting of compounds represented by General Formulae (6) to (21) described later.


(11) The sealing film according to (9) or (10),


wherein the compound represented by General Formula (5) described later is at least one selected from the group consisting of compounds represented by General Formulae (51) to (54) described later.


(12) The sealing film according to (11),


wherein the migration inhibitor (B) is at least one selected from the group consisting of the compounds represented by General Formula (6) described later, General Formula (7) described later, General Formula (10) described later, General Formula (11) described later, General Formula (21) described later, General Formula (51) described later, General Formula (53) described later, and General Formula (54) described later.


(13) The sealing film according to any one of (8) to (12),


wherein the fluorine-based resin (A) is a polymer compound having at least a repeating unit represented by General Formula (P-1) described later.


(14) The sealing film according to any one of (8) to (13),


wherein the fluorine-based resin (A) has a silicon-containing group that has a hydroxyl group or a hydrolyzable group bonded to a silicon atom and that can be crosslinked by forming a siloxane bond.


(15) A wiring board comprising:


a substrate;


silver wiring disposed on the substrate; and


the sealing film according to any one of (8) to (14) disposed on the silver wiring.


(16) A TFT device comprising the sealing film any one of (8) to (14).


(17) An OLED device comprising the sealing film according to any one of (8) to (14).


(18) An LED device comprising the sealing film according to any one of (8) to (14).


According to the present invention, it is possible to provide a sealing resin composition which can be applied to silver wiring and a laminate including the silver wiring, and can form a sealing film exhibiting excellent ion migration-inhibiting ability and excellent planar characteristics.


In addition, according to the present invention, it is possible to provide a sealing film and a wiring board including the sealing film.





BRIEF DESCRIPTION OF THE DRAWINGS


FIG. 1 is a schematic cross-sectional view showing a preferred embodiment of a wiring board of the present invention.





DETAILED DESCRIPTION OF THE INVENTION

Hereinafter, preferred embodiments of a sealing resin composition, a sealing film, and a wiring board of the present invention will be described.


First, the characteristics of the present invention will be specifically described in comparison with the conventional technique.


In the present invention, it was found that if a fluorine-based resin and a migration inhibitor having a predetermined fluorine content rate are used in predetermined amounts, desired effects can be obtained. If a predetermined amount of fluorine atoms is contained in the migration inhibitor, the compatibility (affinity) of the migration inhibitor with the fluorine-based resin is improved, bleed-out of the migration inhibitor from the fluorine-based resin is suppressed, and thus, planar characteristics are improved. In addition, since it becomes easier for the migration inhibitor to remain in the fluorine-based resin, ion migration-inhibiting ability is further improved.


Hereinafter, first, the sealing resin composition will be described in detail, and then, the sealing film and the wiring beard will be described in detail.


<Sealing Resin Composition>


The sealing resin composition contains a fluorine-based resin (A) and a migration inhibitor (B) in predetermined amounts.


First, the fluorine-based resin (A) and the migration inhibitor (B) will be described in detail, and then embodiments of the sealing resin composition will be described in detail.


(Fluorine-Based Resin (A))


The fluorine-based resin refers to a resin containing a fluorine atom. The type of the fluorine-based resin is not particularly limited as long as it contains a fluorine atom. Here, the contact angle of the fluorine-based resin with water is preferably equal to or more than 85°, and more preferably equal to or more than 95°.


Examples of the fluorine-based resin include polyvinylidene fluoride (PVDF), polytetrafluoroethylene (PTFE), a tetrafluoroethylene-ethylene copolymer (ETFE), a tetrafluoroethylene-perfluoroalkoxyethylene copolymer (PFA), and a perfluoro(butenyl vinyl ether) cyclized polymer.


Further, the fluorine-based resin may be a resin obtained by polymerizing fluorine-containing (meth)acrylic monomers. Examples of the fluorine-containing (meth)acrylic monomer include 1H,1H,2H,2H-heptadecafluorodecyl methacrylate, 1H,1H,5H-octafluoropentyl methacrylate, 2,2,3,3-tetrafluoropropyl methacrylate, 2,2,2-trifluoroethyl methacrylate, 1H,1H,2H,2H-heptadecafluorodecyl acrylate, 1H,1H,5H-octafluoropentyl acrylate, 2,2,3,3-tetrafluoropropyl acrylate, 2,2,2-trifluoroethyl acrylate, perfluorooctylethyl methacrylate, and perfluorooctylethyl acrylate.


As the fluorine-based resin, commercially available products, such as CYTOP (registered trademark) manufactured by Asahi Glass Co., Ltd., TEFLON (registered trademark) AF manufactured by DuPont Corporation, polyvinylidene fluoride, LUMIFLON manufactured by Asahi Glass Co., Ltd., and OPSTAR manufactured by JSR Corporation, can also be used.


The weight average molecular weight of the fluorine-based resin is not particularly limited. However, from the viewpoint of ion migration-inhibiting ability and film-forming ability, it is preferably 5000 to 1000000, and more preferably 20000 to 500000.


As one preferred embodiment of the fluorine-based resin, the fluorine content rate of the fluorine-based resin is preferably equal to or more than 65 mass %, and more preferably equal to or more than 67.5 mass %. When the fluorine content rate is within the above range, the ion migration-inhibiting ability of the sealing layer to be formed is better. The upper limit thereof is not particularly limited. However, from the viewpoint of the synthesis thereof, it is generally equal to or less than 77.5 mass % in many cases.


The fluorine content rate refers to a percentage (content rate) of mass occupied by fluorine atoms in the total molecular weight of the fluorine-based resin.


As another preferred embodiment of the fluorine-based resin, the fluorine-based resin preferably has at least a repeating unit represented by General Formula (P-1) below. When the fluorine-based resin contains the repeating unit, the fluorine-based resin is excellent in solubility in a solvent and in coating properties, and is also excellent in the compatibility with the migration inhibitor.


The content rate of the repeating unit represented by General Formula (P-1) in the fluorine-based resin is not particularly limited. However, from the viewpoint of better effects of the present invention, it is preferably equal to or more than 60 mol % and equal to or less than 98 mol % with respect to the total repeating units.




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As another preferred embodiment of the fluorine-based resin, the fluorine-based resin preferably has a silicon-containing group that has a hydroxyl group or a hydrolyzable group bonded to a silicon atom and that can be crosslinked by forming a siloxane bond. (hereinafter, briefly referred to as “a silicon-containing group”). If the fluorine-based resin contains the silicon-containing group, adhesiveness of the sealing layer (sealing film) formed from the sealing resin composition with respect to various substrates and layers adjacent thereto is further improved. The bonding position of the silicon-containing group in the fluorine-based resin is not particularly limited, and may be either a terminal or a side chain.


More specifically, the silicon-containing group is preferably a group represented by General Formula (P-2) below.





—Si(Ra)x(Rb)y  General Formula (P-2)


Ra represents a hydroxyl group or a hydrolyzable group. Rb represents a non-hydrolyzable group. x represents an integer of 1 to 3, y represents an integer of 0 to 2, and a relationship of x+y=3 is satisfied.


The hydrolyzable group represents a group capable of forming a silanol group or a group capable of forming a siloxane condensate. Specific examples thereof include a halogen group, an alkoxy group, an acyloxy group, an isocyanate group, and the like. Among these, an alkoxy group (carbon number of 1 to 2 is preferable) is preferable.


Examples of the non-hydrolyzable group include a hydrogen atom; an aliphatic hydrocarbon group such as an alkyl group, an alkenyl group, and an alkynyl group; an aromatic hydrocarbon group such as an aryl group; and a group composed of any combination of these.


(Migration Inhibitor (B))


The migration inhibitor (anti-migration agent) is a compound that suppresses ion migration by trapping silver ions or the like.


The fluorine content rate of the migration inhibitor used in the present invention is equal to or more than 35 mass % and less than 65 mass %. Especially, from the viewpoints that the ion migration-inhibiting ability of the sealing layer (sealing film) formed from the sealing resin composition is more excellent and the planar characteristics thereof are also more excellent, the fluorine content rate thereof is preferably 40 mass % to 60 mass %, and more preferably 42 mass % to 55 mass %.


When the fluorine content rate is less than 35 mass %, the compatibility of the migration inhibitor with the fluorine-based resin is deteriorated, and thus, the ion migration-inhibiting ability and planar characteristics of the sealing layer are deteriorated. When the fluorine content rate is equal to or more than 65 mass %, the rate of migration-inhibiting sites in a molecule is reduced, and thus, it is necessary to practically add a large amount of migration inhibitors, which leads to occurrence of problems in the solubility, the compatibility, and the like of the migration inhibitor.


Here, the fluorine content rate refers to a percentage (content rate) (%) of mass occupied by fluorine atoms in the total molecular weight of the migration inhibitor. That is, the fluorine content rate is a value represented by {(number of fluorine atoms in the compound)×(atomic weight of fluorine)/(the total molecular weight of the compound)}×100(%). For example, when the total molecular weight of the migration inhibitor is 100 and three fluorine atoms are contained therein, the percentage (%) of mass occupied by the fluorine atoms is calculated as {(19×3)/100}×100, that is, 57 mass %.


The type of the migration inhibitor is not particularly limited as long as the migration inhibitor has the above fluorine content rate and ion migration-inhibiting ability. Examples of the migration inhibitor include phenol-based compounds, compounds having a mercapto group or a free radical group, antioxidants, and the like.


Among these, from the viewpoint that the ion migration-inhibiting ability of the sealing layer (sealing film) formed from the sealing resin composition is further improved, compounds represented by General Formulae (1) to (5), a compound represented by General Formula (22), a compound represented by General Formula (23), and a compound having a group represented by General Formula (24) and a group represented by General Formula (25), which will be described later, are preferable.


(Compound Represented by General Formula (1))


First, the compound represented by General Formula (1) will be described.





P—(CR1═Y)n-Q  General Formula (1)


In the General Formula (1), each of P and Q is independently OH, NR2R3, or CHR4R5. However, when n is 0, neither both P and Q are CHR4R5, nor both P and Q are OH. Y represents CR6 or a nitrogen atom.


In the General Formula (1), each of R2 and R3 is independently a hydrogen atom or a group which can be substituted with a nitrogen atom.


The group which can be substituted with a nitrogen atom is not particularly limited as long as it can be substituted with a nitrogen atom, and examples thereof include an alkyl group (including a cycloalkyl group), an alkenyl group (including a cycloalkenyl group and a bicycloalkenyl group), an alkynyl group, an aryl group, a heterocyclic group, alkyl and aryl sulfinyl groups, alkyl and aryl sulfonyl groups, an acyl group, an alkoxy carbonyl group, an aryloxy carbonyl group, a carbamoyl group, a phosphino group, a phosphinyl group, and a group composed of any combination of these.


More specifically, preferred examples thereof include the following groups <A> to <M>.


<A> An alkyl group which is a linear, branched, or cyclic substituted or unsubstituted alky group. Examples of the alkyl group include an alkyl group (preferably, an alkyl group having 1 to 30 carbon atoms, for example, methyl, ethyl, n-propyl, isopropyl, t-butyl, n-octyl, eicosyl, 2-chloroethyl, 2-cyanoethyl, or 2-ethylhexyl), a cycloalkyl group (preferably, a substituted or unsubstituted cycloalkyl group having 3 to 30 carbon atoms, for example, cyclohexyl, cyclopentyl, or 4-n-dodecylcyclohexyl), and a bicycloalkyl group (preferably, a substituted or unsubstituted bicycloalkyl group having 5 to 30 carbon atoms, that is, a monovalent group obtained by removing one hydrogen atom from a bicycloalkane having 5 to 30 carbon atoms, for example, bicyclo[1.2.2]heptane-2-yl, or bicyclo[2.2.2]octane-3-yl). Examples of the alkyl group further include a tricyclo structure having many cyclic structures and the like. Among the substituents to be described below, an alkyl group (for example, an alkyl group of an alkylthio group) represents the aforementioned alkyl group.


<B> An alkenyl group which is a linear, branched, or cyclic substituted or unsubstituted alkenyl group. Examples of the alkenyl group include an alkenyl group (preferably, a substituted or unsubstituted alkenyl group having 2 to 50 carbon atoms, for example, vinyl, allyl, prenyl, geranyl, or oleyl), a cycloalkenyl group (preferably, a substituted or unsubstituted cycloalkenyl group having 3 to 30 carbon atoms, that is, a monovalent group obtained by removing one hydrogen atom from cycloalkene having 3 to 30 carbon atoms, for example, 2-cyclopentene-1-yl or 2-cyclohexene-1-yl), and a bicycloalkenyl group (a substituted or unsubstituted bicycloalkenyl group, preferably a substituted or unsubstituted bicycloalkenyl group having 5 to 30 carbon atoms, that is, a monovalent group obtained by removing one hydrogen atom from bicycloalkene having one double bond, for example, bicyclo[2.2.1]hept-2-en-1-yl or bicyclo[2.2.2]oct-2-en-4-yl.


<C> An alkynyl group (preferably, a substituted or unsubstituted alkynyl group having 2 to 30 carbon atoms, for example, ethynyl, propargyl, or a trimethylsilyl ethynyl group).


<D> An aryl group (preferably, a substituted or unsubstituted aryl group having 6 to 50 carbon atoms, for example, phenyl, p-tolyl, naphthyl, m-chlorophenyl, or o-hexadecanoylaminophenyl).


<E> A heterocyclic group (preferably, a monovalent group obtained by removing one hydrogen atom from a 5- or 6-membered substituted or unsubstituted aromatic or non-aromatic heterocyclic compound, and more preferably a 5- or 6-membered aromatic heterocyclic group having 3 to 30 carbon atoms, for example, 2-furanyl, 2-thienyl, 2-pyrimidinyl, or 2-benzothiazolinyl).


<F> Alkyl and aryl sulfinyl groups (preferably, a substituted or unsubstituted alkylsulfinyl group having 1 to 30 carbon atoms and a substituted or unsubstituted arylsulfinyl group having 6 to 30 carbon atoms, for example, methylsulfinyl, ethylsulfinyl, phenylsulfinyl, or p-methylphenylsulfinyl).


<G> Alkyl and aryl sulfonyl groups (preferably, a substituted or unsubstituted alkylsulfonyl group having 1 to 30 carbon atoms and a substituted or unsubstituted arylsulfonyl group having 6 to 30 carbon atoms, for example, methylsulfonyl, ethylsulfonyl, phenylsulfonyl, or p-methylphenylsulfonyl).


<H> An acyl group (preferably, a formyl group, a substituted or unsubstituted alkylcarbonyl group having 2 to 30 carbon atoms, a substituted or unsubstituted arylcarbonyl group having 7 to 30 carbon atoms, and a substituted or unsubstituted heterocyclic carbonyl group having 4 to 30 carbon atoms in which a carbon atom is bonded with a carbonyl group, for example, acetyl, pivaloyl, 2-chloroacetyl, stearoyl, benzoyl, p-n-octyloxyphenylcarbonyl, 2-pyridylcarbonyl, or 2-furylcarbonyl).


<I> An aryloxy carbonyl group (preferably, a substituted or unsubstituted aryloxy carbonyl group having 7 to 30 carbon atoms, for example, phenoxycarbonyl, o-chlorophenoxycarbonyl, m-nitrophenoxycarbonyl, or p-t-butyl-phenoxycarbonyl).


<J> An alkoxycarbonyl group (preferably, a substituted or unsubstituted alkoxycarbonyl group having 2 to 30 carbon atoms, for example, methoxycarbonyl, ethoxycarbonyl, t-butoxycarbonyl, or n-octadecyloxycarbonyl).


<K> A carbamoyl group (preferably, a substituted or unsubstituted carbamoyl group having 1 to 30 carbon atoms, for example, carbamoyl, N-methylcarbamoyl, N,N-dimethylcarbamoyl, N,N-di-n-octylcarbamoyl, or N-(methylsulfonyl)carbamoyl).


<L> A phosphino group (preferably, a substituted or unsubstituted phosphino group having 2 to 30 carbon atoms, for example, dimethylphosphino, diphenylphosphino, or methylphenoxyphosphino).


<M> A phosphinyl group (preferably, a substituted or unsubstituted phosphinyl group having 2 to 30 carbon atoms, for example, phosphinyl, dioctyloxyphosphinyl, or diethoxyphosphinyl).


Among the above functional groups, functional groups having a hydrogen atom may be further substituted by removing the hydrogen atom.


The alkyl group represented by R2 and R3 in the General Formula (1) is a linear, branched, or cyclic substituted or unsubstituted alkyl group. The alkyl group has preferably 1 to 50 carbon atoms, more preferably 1 to 30 carbon atoms, and particularly preferably 1 to 20 carbon atoms.


Preferable examples of the alkyl group include methyl, ethyl, n-propyl, isopropyl, cyclopropyl, butyl, isobutyl, t-butyl, sec-butyl, pentyl, isopentyl, neopentyl, t-pentyl, hexyl, cyclohexyl, heptyl, cyclopentyl, octyl, 2-ethylhexyl, nonyl, decyl, dodecyl, tetradecyl, hexadecyl, octadecyl, eicosyl, docosyl, triacontyl, and the like. More preferable examples thereof include methyl, ethyl, n-propyl, isopropyl, butyl, isobutyl, t-butyl, sec-butyl, t-butyl, pentyl, isopentyl, neopentyl, hexyl, cyclohexyl, octyl, 2-ethylhexyl, dodecyl, hexadecyl, and octadecyl. Particularly preferable examples thereof include methyl, ethyl, n-propyl, isopropyl, butyl, t-butyl, pentyl, isopentyl, hexyl, cyclohexyl, octyl, 2-ethylhexyl, dodecyl, hexadecyl, and octadecyl.


The alkyl group may include a linking group such as —CO—, —NH—, —O—, —S—, or a group composed of any combination of these. Here, when the linking group is included in the alkyl group, the position of the linking group is not particularly limited, and may be the terminal of the alkyl group. —S—Rx (Rx: alkyl group) may be exemplified.


The alkyl group represented by R2 and R3 may further include a substituent.


Examples of the substituent include a halogen atom, an alkyl group (including a cycloalkyl group), an alkenyl group (including a cycloalkenyl group and a bicycloalkenyl group), an alkynyl group, an aryl group, a heterocyclic group, a cyano group, a hydroxyl group, a nitro group, a carboxyl group, an alkoxy group, an aryloxy group, a silyloxy group, a heterocycloxy group, an acyloxy group, a carbamoyloxy group, an alkoxycarbonyloxy group, an aryloxycarbonyloxy group, an amino group (including an anilino group), an acylamino group, an amino carbonyl amino group, an alkoxycarbonyl amino group, an aryloxycarbonylamino group, a sulfamoylamino croup, alkyl and aryl sulfonyl amino group, a mercapto group, an alkylthio group, an arylthio group, a heterocyclic thio group, a sulfamoyl group, a sulfo group, alkyl and aryl sulfinyl groups, alkyl and aryl sulfonyl groups, an acyl group, an aryloxy carbonyl group, an alkoxycarbonyl group, a carbamoyl group, aryl and heterocyclic azo groups, an imide group, a phosphino group, a phosphinyl group, a phosphinyloxy group, a phosphinylamino group, a silyl group, and a group composed of any combination of these.


More specifically, examples of the substituent include a halogen atom (for example, a chlorine atom, a bromine atom, or an iodine atom); an alkyl group; and an alkenyl group. Here, the alkyl group represents a linear, branched, or cyclic substituted or unsubstituted alkyl group. Examples of the alkyl group include an alkyl group (preferably, an alkyl group having 1 to 30 carbon atoms, for example, methyl, ethyl, n-propyl, isopropyl, t-butyl, n-octyl, eicosyl, 2-chloroethyl, 2-cyanoethyl, or 2-ethylhexyl), a cycloalkyl group (preferably, a substituted or unsubstituted cycloalkyl group having 3 to 30 carbon atoms, for example, cyclohexyl, cyclopentyl, or 4-n-dodecyl cyclohexyl), and a bicycloalkyl group (preferably, a substituted or unsubstituted bicycloalkyl group having 5 to 30 carbon atoms, that is, a monovalent group obtained by removing one hydrogen atom from bicycloalkane having 5 to 30 carbon atoms, for example, bicyclo[1.2.2]heptane-2-yl or bicyclo[2.2.2]octane-3-yl. Examples of the alkyl group further include a tricyclo structure having many cyclic structures, and the like. Among the substituents to be described below, an alkyl group (for example, an alkyl group of an alkylthio group) represents the aforementioned alkyl group.


The alkenyl group represents a linear, branched, or cyclic substituted or unsubstituted alkenyl group. Examples of the alkenyl group include an alkenyl group (preferably, a substituted or unsubstituted alkenyl group having 2 to 30 carbon atoms, for example, vinyl, allyl, prenyl, geranyl, or oleyl), a cycloalkenyl group (preferably, a substituted or unsubstituted cycloalkenyl group having 3 to 30 carbon atoms, that is, a monovalent group obtained by removing one hydrogen atom from cycloalkene having 3 to 30 carbon atoms, for example, 2-cyclopentene-1-yl or 2-cyclohexen-1-yl), and a bicycloalkenyl group (a substituted or unsubstituted bicycloalkenyl group, preferably, a substituted or unsubstituted bicycloalkenyl group having 5 to 30 carbon atoms, that is, a monovalent group obtained by removing one hydrogen atom from bicycloalkene having one double bond, for example, bicyclo[2.2.1]hept-2-en-1-yl or bicyclo[2.2.2]oct-2-en-4-yl).


Examples of the substituent further include an alkynyl group (preferably, a substituted or unsubstituted alkynyl group having 2 to 50 carbon atoms, for example, ethynyl, propargyl, or a trimethylsilylethynyl group);


an aryl group (preferably, a substituted or unsubstituted aryl group having 6 to 30 carbon atoms, for example, phenyl, p-tolyl, naphthyl, m-chlorophenyl, or o-hexadecanoylaminophenyl); a heterocyclic group (preferably, a monovalent group obtained by removing one hydrogen atom from a 5- or 6-membered substituted or unsubstituted aromatic or non-aromatic heterocyclic compound, and more preferably a 5- or 6-membered aromatic heterocyclic group having 3 to 30 carbon atoms, for example, 2-furanyl, 2-thienyl, 2-pyrimidinyl, or 2-benzothiazolinyl);


a cyano group; a hydroxyl group; a nitro group; a carboxyl group; an alkoxy group (preferably, a substituted or unsubstituted alkoxy group having 1 to 30 carbon atoms, for example, methoxy, ethoxy, isopropoxy, t-butoxy, n-octyloxy, or 2-methoxyethoxy); an aryloxy group (preferably, a substituted or unsubstituted aryloxy group having 6 to 30 carbon atoms, for example, phenoxy, 2-methylphenoxy, 4-t-butylphenoxy, 3-nitrophenoxy, or 2-tetradecanoyl aminophenoxy); a silyloxy group (preferably, a silyloxy group having 3 to 20 carbon atoms, for example, trimethylsilyloxy or t-butyldimethylsilyloxy); a heterocycloxy group (preferably, a substituted or unsubstituted heterocycloxy group having 2 to 30 carbon atoms, for example, 1-phenyl tetrazole-5-oxy or 2-tetrahydropyranyloxy); an acyloxy group (preferably, a formyloxy group, a substituted or unsubstituted alkylcarbonyloxy group having 2 to 30 carbon atoms, and a substituted or unsubstituted arylcarbonyloxy group having 6 to 30 carbon atoms, for example, formyloxy, acetyloxy, pivaloyloxy, stearoyloxy, benzoyloxy, or p-methoxyphenylcarbonyloxy); a carbamoyloxy group (preferably a substituted or unsubstituted carbamoyloxy group having 1 to 30 carbon atoms, for example, N,N-dimethylcarbamoyloxy, N,N-diethylcarbamoyloxy, morpholino carbonyloxy, N,N-di-n-octyl aminocarbonyloxy, or N-n-octylcarbamoyloxy); an alkoxycarbonyloxy group (preferably a substituted or unsubstituted alkoxycarbonyloxy group having 2 to 30 carbon atoms, for example, methoxycarbonyloxy, ethoxycarbonyloxy, t-butoxycarbonyloxy, or n-octyl carbonyloxy); an aryloxycarbonyloxy group (preferably a substituted or unsubstituted aryloxycarbonyloxy group having 7 to 30 carbon atoms, for example, phenoxycarbonyloxy, p-methoxyphenoxy carbonyloxy, or p-n-hexadecyloxy phenoxycarbonyloxy); an amino group (preferably, an amino group, a substituted or unsubstituted alkylamino group having 1 to 30 carbon atoms, and a substituted or unsubstituted anilino group having 6 to 30 carbon atoms, for example, amino, methylamino, dimethylamino, anilino, N-methyl-anilino, or diphenylamino); an acylamino group (preferably, a formylamino group, a substituted or unsubstituted alkyl carbonylamino group having 1 to 30 carbon atoms, and a substituted or unsubstituted arylcarbonylamino group having 6 to 30 carbon atoms, for example, formylamino, acetylamino, pivaloylamino, lauroylamino, benzoylamino, or 3,4,5-tri-n-octyloxyphenylcarbonylamino); an aminocarbonylamino group (preferably, a substituted or unsubstituted aminocarbonylamino group having 1 to 30 carbon atoms, for example, carbamoylamino, N,N-dimethylaminocarbonyl amino, N,N-diethylamino carbonylamino, or morpholinocarbonylamino); an alkoxycarbonylamino group (preferably, a substituted or unsubstituted alkoxycarbonylamino group having 2 to 30 carbon atoms, for example, methoxycarbonylamino, ethoxycarbonylamino, t-butoxycarbonylamino, n-octadecyloxycarbonylamino, or N-methyl-methoxy carbonyl amino); an aryloxycarbonylamino group (preferably, a substituted or unsubstituted aryloxycarbonylamino group having 7 to 30 carbon atoms, for example, phenoxycarbonylamino, p-chloro phenoxycarbonylamino, or m-n-octyloxy phenoxycarbonylamino); a sulfamoylamino group (preferably, a substituted or unsubstituted sulfamoylamino group having 0 to 30 carbon atoms, for example, sulfamoylamino, N,N-dimethylaminosulfonylamino, or N-n-octyl aminosulfonylamino); alkyl and aryl sulfonylamino groups (preferably a substituted or unsubstituted alkylsulfonylamino having 1 to 30 carbon atoms, and a substituted or unsubstituted arylsulfonylamino having 6 to 30 carbon atoms, for example, methylsulfonylamino, butylsulfonylamino, phenyl sulfonylamino, 2,3,5-trichlorophenyl sulfonylamino, or p-methylphenyl sulfonylamino);


a mercapto group; an alkylthio group (preferably, a substituted or unsubstituted alkylthio group having 1 to 30 carbon atoms, for example, methylthio, ethylthio, or n-hexadecylthio); an arylthio group (preferably, a substituted or unsubstituted arylthio group having 6 to 30 carbon atoms, for example, phenylthio, p-chlorophenylthio, or m-methoxyphenylthio); a heterocyclic thio group (preferably a substituted or unsubstituted heterocyclic thio group having 2 to 30 carbon atoms, for example, 2-benzothiazolylthio or 1-phenyltetrazole-5-ylthio); a sulfamoyl group (preferably a substituted or unsubstituted sulfamoyl group having 0 to 30 carbon atoms, for example, N-ethylsulfamoyl, N-(3-dodecyloxypropyl) sulfamoyl, N,N-dimethylsulfamoyl, N-acetyl sulfamoyl, N-benzoylsulfamoyl, or N—(N′-phenylcarbamoyl) sulfamoyl); a sulfo group; alkyl and aryl sulfinyl groups (preferably a substituted or unsubstituted alkyl sulfinyl group having 1 to 30 carbon atoms, and a substituted or unsubstituted aryl sulfinyl group having 6 to 30 carbon atoms, for example, methylsulfinyl, ethylsulfinyl, phenylsulfinyl, or p-methyl phenylsulfinyl);


alkyl and aryl sulfonyl groups (preferably a substituted or unsubstituted alkyl sulfonyl group having 1 to 30 carbon atoms, and a substituted or unsubstituted aryl sulfonyl group having 6 to 30 carbon atoms, for example, methylsulfonyl, ethylsulfonyl, phenylsulfonyl, or p-methyl phenylsulfonyl); an acyl group (preferably, a formyl group, a substituted or unsubstituted alkylcarbonyl group having 2 to 30 carbon atoms, a substituted or unsubstituted arylcarbonyl group having 7 to 30 carbon atoms, and a substituted or unsubstituted heterocyclic carbonyl group having 4 to 30 carbon atoms in which a carbon atom is bonded with the carbonyl group, for example, acetyl, pivaloyl, 2-chloroacetyl, stearoyl, benzoyl, p-n-octyloxyphenyl carbonyl, 2-pyridylcarbonyl, or 2-furyl carbonyl); an aryloxycarbonyl group (preferably, a substituted or unsubstituted aryloxy carbonyl group having 7 to 30 carbon atoms, for example, phenoxycarbonyl, o-chlorophenoxycarbonyl, m-nitrophenoxycarbonyl, or p-t-butylphenoxycarbonyl); an alkoxycarbonyl group (preferably, a substituted or unsubstituted alkoxycarbonyl group having 2 to 30 carbon atoms, for example, methoxycarbonyl, ethoxycarbonyl, t-butoxycarbonyl, or n-octadecyl oxycarbonyl);


a carbamoyl group (preferably a substituted or unsubstituted carbamoyl having 1 to 30 carbon atoms, for example, carbamoyl, N-methylcarbamoyl, N,N-dimethylcarbamoyl, N,N-di-n-octylcarbamoyl, or N-(methylsulfonyl)carbamoyl); aryl and heterocyclic azo groups (preferably a substituted or unsubstituted aryl azo group having 6 to 30 carbon atoms, and a substituted or unsubstituted heterocyclic azo group having 3 to 30 carbon atoms, for example, phenylazo, p-chlorophenyl azo, or 5-ethylthio-1,3,4-thiadiazole-2-yl azo); an imide group (preferably, N-succinimide, no N-phthalimide); a phosphino group (preferably, a substituted or unsubstituted phosphino group having 2 to 30 carbon atoms, for example, dimethylphosphino, diphenylphosphino, or methylphenoxy phosphino); a phosphinyl group (preferably, a substituted or unsubstituted phosphinyl group having 2 to 30 carbon atoms, for example, phosphinyl, dioctyloxyphosphinyl, or diethoxyphosphinyl); a phosphinyloxy group (preferably, a substituted or unsubstituted phosphinyloxy group having 2 to 30 carbon atoms, for example, diphenoxyphosphinyloxy or dioctyloxyphosphinyloxy); a phosphinylamino group (preferably a substituted or unsubstituted phosphinylamino group having 2 to 30 carbon atoms, for example, dimethoxyphosphinylamino or dimethylamino phosphinylamino); and a silyl group (preferably a substituted or unsubstituted silyl group having 3 to 30 carbon atoms, for example, trimethylsilyl, t-butyldimethylsilyl, or phenyldimethylsilyl).


Among the above functional groups, functional groups having a hydrogen atom may be further substituted with the above groups by removing the hydrogen atom. Examples of such functional groups include an alkylcarbonylaminosulfonyl group, an arylcarbonylaminosulfonyl group, an alkylsulfonyl aminocarbonyl group, an arylsulfonyl aminocarbonyl group, and the like. Examples thereof include methylsulfonylaminocarbonyl, p-methylphenyl sulfonyl aminocarbonyl, acetylamino sulfonyl, benzoylaminosulfonyl group, and the like.


The alkenyl group represented by R2 and R3 is a linear, branched, or cyclic substituted or unsubstituted alkenyl group. The alkenyl group has preferably 2 to 50 carbon atoms, more preferably 2 to 30 carbon atoms, and particularly preferably 2 to 20 carbon atoms. Preferable examples thereof include vinyl, allyl, prenyl, geranyl, oleyl, 2-cyclopentene-1-yl, 2-cyclohexene-1-yl, bicyclo[2.2.1]hept-2-en-1-yl, bicyclo[2.2.2]oct-2-en-4-yl, and the like. More preferable examples thereof include vinyl, allyl, prenyl, geranyl, oleyl, 2-cyclopentene-1-yl, and 2-cyclohexene-1-yl.


The alkenyl group represented by R2 and R3 may further include a substituent. Examples of the substituent include the substituents of the above-mentioned alkyl group represented by R2 and R3.


In addition, similarly to the above-mentioned alkyl group, the alkenyl group may include a linking group such as —CO—, —NH—, —O—, —S—, or a group composed of any combination of these.


The alkynyl group represented by R2 and R3 is a linear, branched, or cyclic substituted or unsubstituted alkynyl group. The alkynyl group has preferably 2 to 50 carbon atoms, more preferably 2 to 30 carbon atoms, and particularly preferably 2 to 20 carbon atoms. Preferable examples thereof include ethynyl, propargyl, and the like.


The alkynyl group represented by R2 and R3 may further include a substituent. Examples of the substituent include the substituents of the above-mentioned alkyl group represented by R2 and R3.


In addition, similarly to the above-mentioned alkyl group, the alkynyl group may include a linking group such as —CO—, —NH—, —O—, —S—, or a group composed of any combination of these.


The aryl group represented by R2 and R3 is a substituted or unsubstituted aryl group. The aryl group has preferably 6 to 50 carbon atoms, more preferably 6 to 30 carbon atoms, and particularly preferably 6 to 20 carbon atoms. Preferable examples thereof include phenyl, 2-methylphenyl, 3-methylphenyl, 4-methylphenyl, 2-ethylphenyl, 4-ethylphenyl, 2,4-dimethylphenyl, 2,6-dimethylphenyl, 2,4,6-trimethylphenyl, 1-naphthyl, 2-naphthyl, 2-chlorophenyl, 3-chlorophenyl, 4-chlorophenyl, 2-methoxyphenyl, 3-methoxyphenyl, 4-methoxyphenyl, 2-benzylphenyl, 4-benzylphenyl, 2-methylcarbonylphenyl, 4-methylcarbonylphenyl, and the like.


More preferable examples thereof include phenyl, 2-methylphenyl, 4-methylphenyl, 2-ethylphenyl, 4-ethylphenyl, 2,4-dimethylphenyl, 2,6-dimethylphenyl, 2,4,6-trimethylphenyl, 1-naphthyl, 2-naphthyl, 2-chlorophenyl, 4-chlorophenyl, 2-methoxyphenyl, 3-methoxyphenyl, 4-methoxyphenyl, 2-benzylphenyl, 4-benzylphenyl, and the like. Particularly preferable examples thereof include phenyl, 2-methylphenyl, 4-methylphenyl, 2,4-dimethylphenyl, 2,6-dimethylphenyl, 2,4,6-trimethylphenyl, 1-naphthyl, 2-naphthyl, 2-chlorophenyl, 4-chlorophenyl, 2-methoxyphenyl, 4-methoxyphenyl, 2-benzylphenyl, 4-benzylphenyl, and the like.


The aryl group represented by R2 and R3 may further include a substituent. Examples of the substituent include the substituents of the above-mentioned alkyl group represented by R2 and R3.


Each of R4 and R5 independently represents a hydrogen atom or a substituent.


Examples of the substituents represented by R4 and R5 may include the substituents of the above-mentioned alkyl group represented by R2 and R3 (the substituents which the alkyl group may have). Preferable examples thereof include an alkyl group, an alkenyl group, an alkynyl group, an aryl group, and a group composed of any combination of these, and preferable examples of the respective groups include the examples of the above-mentioned R2 and R3.


The group represented by R4 and R5 may further include a substituent. Examples of the substituent include the substituents of the above-mentioned alkyl group represented by R2 and R3.


Each of R1 and R6 independently represents a hydrogen atom or a substituent.


Examples of the substituents represented by R1 and R6 may include the substituents of the above-mentioned alkyl group represented by R2 and R3. Preferable examples thereof include an alkyl group, an alkenyl group, an alkynyl group, an aryl group, and a group composed of any combination of these, and preferable examples of the respective groups include the examples of above-mentioned R2 and R3.


The group represented by R1 and R6 may further include a substituent. Examples of the substituent include the substituents of the above-mentioned alkyl group represented by R2 and R3.


n is an integer of 0 to 5. However, when n is 0, neither both P and Q are OH, nor both P and Q are CHR4R5. When n is 2 or more, a plurality of atomic groups represented by (CR1═Y) may be the same as or different from each other.


The compound represented by General Formula (1) may be a chain compound or a cyclic compound. When the compound is a cyclic compound, at least two of groups represented by R1, R2, R3, R4, R5, and R6 may be bonded to each other to form a ring.


When the two groups are bonded to each other, the coupling form may be any of a single bond, a double bond, and a triple bond.


At least one group of R1 to R6 contains a fluorine atom. Here, the fluorine atom is contained such that the content rate thereof is within the aforementioned range. The fluorine atom may substitute for any carbon atom of the compound represented by the General Formula (1).


Further, it is preferable that some or all hydrogen atoms contained in at least one group of R1 to R6 (preferably, some or all hydrogen atoms bonded to carbon atoms) are substituted with fluorine atoms. Especially, it is preferable that fluorine atoms are contained as a fluoroalkyl group (hereinafter, referred to as an Rf group) or a group substituted with the Rf group. In other words, it is preferable that a fluoroalkyl group is contained in at least one group of R1 to R6.


It is preferable for the Rf group to be a linear or branched perfluoroalkyl group having 1 to 14 carbon atoms or a substituent having 2 to 20 carbon atoms and substituted with the linear or branched perfluoroalkyl group having 1 to 14 carbon atoms.


Examples of the linear or branched perfluoroalkyl group having 1 to 14 carbon atoms include CF3—, C2F5—, C3F7—, C4F9—, C5F11—, (CF3)2—CF—(CF2)2—, C6F13—, C7F15—, (CF3)2—CF—(CF2)4—, C8F17—, C9F19—, C10F21—, C12F25—, and C14F29—.


Examples of the substituent having 2 to 20 carbon atoms and substituted with the linear or branched perfluoroalkyl group having 1 to 14 carbon atoms include, but are not limited to, (CF3)2CF(CF2)4(CH2)2—, C9F19CH2—, C8F17CH2CH(OH)CH2—, C8F17CH2CH(OH)CH2OC═OCH2—, (CF3)2CF(CF2)4(CH2)2OC═OCH2—, C8F17CH2CH(OH)CH2OC═O (CH2)2—, (CF3)2CF(CF2)4(CH2)2OC═O (CH2)2—, (CF3)2CFOC2F4—, and CF3CF2CF2O[CF(CF3) CF2O]4—CF(CF3)—.


It is preferable that 1 to 4 Rf groups are contained in a molecule.


Two or more kinds of the compound represented by the General Formula (1) may be used.


It is preferable that the compound represented by General Formula (1) is at least one selected from the group consisting of compounds represented by General Formulae (6) to (21).


Each of compounds represented by General Formulae (6) to (21) contains fluorine atoms in an amount of satisfying the above-mentioned fluorine content rate.




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The compound represented by the General Formula (6) is an example of the compound of General Formula (1) in which P and Q are OH respectively, Y is CR6, n is 2, and R1 on the carbon atom adjacent to P and R6 on the carbon atom adjacent to Q are bonded to each other to form a ring having a double bond.


In the General Formula (6), V6 represents a substituent. a is an integer of 1 to 4 (preferably 1 to 2, and more preferably 1). At least one of V6 contains a fluorine atom. In other words, in the case of one V6, the fluorine atom is contained in the substituent, and, in the case of two or more V6, the fluorine atom may be contained in at least one V6. It is preferable that fluorine atoms are introduced by substituting some or all hydrogen atoms of at least one group represented by V6 (preferably, some or all hydrogen atoms bonded to carbon atoms) with the fluorine atoms. In this case, it is preferable that the above Rf group is contained in V6.


As the substituent represented by V6, there can be exemplified the substituents of the above-mentioned alkyl group represented by R2 and R3 in the General Formula (1). When a plurality of V6 are present in the General Formula (6), the respective groups may be the same as or different from each other, and may be bonded to each other to form a ring.


Specific examples of the compound represented by the General Formula (6) are shown below. However, the present invention is not limited thereto. Hereinafter, the percentage described with the structural formula of each of the compounds is intended to represent the mass content rate of fluorine atoms (fluorine content rate).




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The compound represented by the General Formula (7) is an example of the compound of General Formula (1) in which P and Q are OH respectively, Y is CR6, n is 1, and R1 on the carbon atom adjacent to P and R6 on the carbon atom adjacent to Q are bonded to each other to form a ring.


In the General Formula (7), V7 represents a substituent. a is an integer of 1 to 4 (preferably 1 to 2, and more preferably 1). At least one V7 contains a fluorine atom. In other words, in the case of one V7, the fluorine atom is contained in the substituent, and, in the case of two or more V7, the fluorine atom may be contained in at least one V7. It is preferable that fluorine atoms are introduced by substituting some or all hydrogen atoms of at least one group represented by V7 (preferably, some or all hydrogen atoms bonded to carbon atoms) with the fluorine atoms. In this case, it is preferable that the above Rf group is contained in V7.


As the substituent represented by V7, there can be exemplified the substituents of the above-mentioned alkyl group represented by R2 and R3 in the General Formula (1). When a plurality of V7 are present in the General Formula (7), the respective groups may be the same as or different from each other, and may be bonded to each other to form a ring.


Specific examples of the compound represented by the General Formula (7) are shown below. However, the present invention is not limited thereto.




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The compound represented by the General Formula (8) is an example of the compound of General Formula (1) in which P is OH, Q is NR2R3, Y is CR6, n is 2, and R1 on the carbon atom adjacent to P and R6 on the carbon atom adjacent to Q are bonded to each other to form a ring having a double bond.


In the General Formula (8), V8 represents a substituent. b is an integer of 0 to 4 (preferably 1 to 2, and more preferably 1). As the substituent represented by V8, there can be exemplified the substituents of the above-mentioned alkyl group represented by R2 and R3 in the General Formula (1). When a plurality of V8 are present in the General Formula (8), the respective groups may be the same as or different from each other, and may be bonded to each other to form a ring.


Each of R81 and R82 independently represents a hydrogen atom or a group which can be substituted with a nitrogen atom. Preferable examples of the group which can be substituted with a nitrogen atom include the groups exemplified in the above-mentioned R2 and R3 of the General Formula (1).


At least one of V8, R81, and R82 contains a fluorine atom. Especially, it is preferable that some or all hydrogen atoms of at least one group of V8, R81, and R82 (preferably, some or all hydrogen atoms bonded to carbon atoms) are substituted with fluorine atoms. In addition, it is more preferable that the above Rf group is contained in at least one of V8, R81, and R82.


Further, in the case where a plurality of V8 is contained in the compound, the fluorine atom is contained in at least one group of the plurality of V8, R81, and R82.


Specific examples of the compound represented by the General Formula (8) are shown below. However, the present invention is not limited thereto.




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The compound represented by the General Formula (9) is an example of the compound of General Formula (1) in which P is OH, Q is NR2R3, Y is CR6, n is 1, and R1 on the carbon atom adjacent to P and R6 on the carbon atom adjacent to Q are bonded to each other to form a ring.


In the General Formula (9), V9 represents a substituent. b is an integer of 0 to 4 (preferably 1 to 2, and more preferably 1). As the substituent represented by V9, there can be exemplified the substituents of the above-mentioned alkyl group represented by R2 and R3 in the General Formula (1). When a plurality of V9 are present in the General Formula (9), the respective groups may be the same as or different from each other, and may be bonded to each other to form a ring.


Each of R91 and R92 independently represents a hydrogen atom or a group which can be substituted with a nitrogen atom. Preferable examples of the group which can be substituted with a nitrogen atom include the groups exemplified in the above-mentioned R2 and R3 of the General Formula (1).


At least one of V9, R91, and R92 contains a fluorine atom. Especially, it is preferable that some or all hydrogen atoms of at least one group of V9, R91, and R92 (preferably, some or all hydrogen atoms bonded to carbon atoms) are substituted with fluorine atoms. In addition, it is more preferable that the above Rf group is contained in at least one of V9, R91, and R92.


Further, in the case where a plurality of V9 is contained in the compound, the fluorine atom is contained in at least one group of the plurality of V9, R91, and R92.


Specific examples of the compound represented by the General Formula (9) are shown below. However, the present invention is not limited thereto.




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The compound represented by the General Formula (10) is an example of the compound of General Formula (1) in which P is OH, Q is CHR4R5, Y is CR6, n is 2, and R1 on the carbon atom adjacent to P and R6 on the carbon atom adjacent to Q are bonded to each other to form a ring having a double bond.


In the General Formula (10), V10 represents a substituent. b is an integer of 0 to 4 (preferably 1 to 2, and more preferably 1). As the substituent represented by V10, there can be exemplified the substituents of the above-mentioned alkyl group represented by R2 and R3 in the General Formula (1). When a plurality of V10 are present in the General Formula (10), the respective groups may be the same as or different from each other, and may be bonded to each other to form a ring.


Each of R101 and R102 independently represents a hydrogen atom or a substituent.


As the substituent represented by R101 and R102, there can be exemplified the substituents of the above-mentioned alkyl group represented by R2 and R3. The substituent is preferably an alkyl group, an alkenyl group, an alkynyl group, or an aryl group. Preferable examples of the respective groups include the examples of the above-mentioned R2 and R3.


When R101 and R102 are substituents, each of these groups may further include a substituent. Examples of the substituent include the substituents of the above-mentioned alkyl group represented by R2 and R3 in the General Formula (1).


At least one of V10, R101, and R102 contains a fluorine atom. Especially, it is preferable that some or all hydrogen atoms of at least one group of V10, R101, and R102 (preferably, some or all hydrogen atoms bonded to carbon atoms) are substituted with fluorine atoms. In addition, it is preferable that the above Rf group is contained in at least one of V10, R101, and R102.


Further, in the case where a plurality of V10 is contained in the compound, the fluorine atom is contained in at least one group of the plurality of V10, R101, and R102.


Specific examples of the compound represented by the General Formula (10) are shown below. However, the present invention is not limited thereto.




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The compound represented by the General Formula (11) is an example of the compound of General Formula (1) in which P is OH, Q is CHR4R5, Y is CR6, n is 1, and R1 on the carbon atom adjacent to P and R6 on the carbon atom adjacent to Q are bonded to each other to form a ring.


In the General Formula (11), V11 represents a substituent. b is an integer of 0 to 4 (preferably 1 to 2, and more preferably 1). As the substituent represented by V11, there can be exemplified the substituents of the above-mentioned alkyl group represented by R2 and R3 in the General Formula (1). When a plurality of V11 are present in the General Formula (11), the respective groups may be the same as or different from each other, and may be bonded to each other to form a ring.


Each of R111 and R112 independently represents a hydrogen atom or a substituent.


As the substituent represented by R111 and R112, there can be exemplified the substituents of the above-mentioned alkyl group represented by R2 and R3. The substituent is preferably an alkyl group, an alkenyl group, an alkynyl group, or an aryl group. Preferable examples of the respective groups include the examples of the above-mentioned R2 and R3.


When R111 and R112 are substituents, each of these groups may further include a substituent. Examples of the substituent include the substituents of the above-mentioned alkyl group represented by R2 and R3 in the General Formula (1).


At least one of V11, R111, and R112 contains a fluorine atom. Especially, it is preferable that some or all hydrogen atoms of at least one group of V11, R111, and R112 (preferably, some or all hydrogen atoms bonded to carbon atoms) are substituted with fluorine atoms. In addition, it is preferable that the above Rf group is contained in at least one of V11, R111, and R112.


Further, in the case where a plurality of V11 is contained in the compound, the fluorine atom is contained in at least one group of the plurality of V11, R111, and R112.


Specific examples of the compound represented by the General Formula (11) are shown below. However, the present invention is not limited thereto.




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The compound represented by the General Formula (12) is an example of the compound of General Formula (1) in which P and Q are NR2R3 respectively, Y is CR6, n is 2, and R1 on the carbon atom adjacent to P and R6 on the carbon atom adjacent to Q are bonded to each other to form a ring having a double bond.


In the General Formula (12), V12 represents a substituent. b is an integer of 0 to 4 (preferably 1 to 2, and more preferably 1). As the substituent represented by V12, there can be exemplified the substituents of the above-mentioned alkyl group represented by R2 and R3 in the General Formula (1). When a plurality of V12 are present in the General Formula (12), the respective groups may be the same as or different from each other, and may be bonded to each other to form a ring.


Each of R121, R122, R123, and R124 independently represents a hydrogen atom or a group which can be substituted with a nitrogen atom. Preferable examples of the group which can be substituted with a nitrogen atom include the groups exemplified in the above-mentioned R2 and R3 of the General Formula (1).


At least one of V12, R121, R122, R123, and R124 contains a fluorine atom. In this case, it is preferable that some or all hydrogen atoms of at least one group of V12, R121, R122, R123, and R124 (preferably, some or all hydrogen atoms bonded to carbon atoms) are substituted with fluorine atoms. In addition, it is more preferable that the above Rf group is contained in at least one of V12, R121, R122, R123, and R124.


Further, in the case where a plurality of V12 is contained in the compound, the fluorine atom is contained in at least one group of the plurality of V12, R121, R122, R123, and R124.


Specific examples of the compound represented by the General Formula (12) are shown below. However, the present invention is not limited thereto.




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The compound represented by the General Formula (13) is an example of the compound of General Formula (1) in which P and Q are NR2R3 respectively, Y is CR6, n is 1, and R1 on the carbon atom adjacent to P and R6 on the carbon atom adjacent to Q are bonded to each other to form a ring.


In the General Formula (13), V13 represents a substituent. b is an integer of 0 to 4 (preferably 1 to 2, and more preferably 1). As the substituent represented by V13, there can be exemplified the substituents of the above-mentioned alkyl group represented by R2 and R3 in the General Formula (1). When a plurality of V13 are present in the General Formula (13), the respective groups may be the same as or different from each other, and may be bonded to each other to form a ring.


Each of R131, R132, R133, and R134 independently represents a hydrogen atom or a group which can be substituted with a nitrogen atom. Preferable examples of the group which can be substituted with a nitrogen atom include the groups exemplified in the above-mentioned R2 and R3 of the General Formula (1).


At least one of V13, R131, R132, R133, and R134 contains a fluorine atom. In this case, it is preferable that some or all hydrogen atoms of at least one group of V13, R131, R132, R133, and R134 (preferably, some or all hydrogen atoms bonded to carbon atoms) are substituted with fluorine atoms. In addition, it is more preferable that the above Rf group is contained in at least one of V13, R131, R132, R133, and R134.


Further, in the case where a plurality of V13 is contained in the compound, the fluorine atom is contained in at least one group of the plurality of V13, R131, R132, R133, and R134.


Specific examples of the compound represented by the General Formula (13) are shown below. However, the present invention is not limited thereto.




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The compound represented by the General Formula (14) is an example of the compound of General Formula (1) in which P and Q are OH respectively, Y is CR6, n is 1, and R1 on the carbon atom adjacent to P and R6 on the carbon atom adjacent to Q are bonded to each other to form a ring.


In the General Formula (14), V14 represents a substituent. c is an integer of 1 to 2 (preferably 1). At least one V14 contains a fluorine atom. In other words, in the case of one V14, the fluorine atom is contained in the substituent, and, in the case of two or more V14, the fluorine atom may be contained in at least one V14. It is preferable that fluorine atoms are introduced by substituting some or all hydrogen atoms of at least one group represented by V14 (preferably, some or all hydrogen atoms bonded to carbon atoms) with the fluorine atoms. In this case, it is more preferable that the above Rf group is contained in V14.


As the substituent represented by V14, there is exemplified the substituents of the above-mentioned alkyl group represented by R2 and R3 in the General Formula (1). When a plurality of V14 are present in the General Formula (14), the respective groups may be the same as or different from each other, and may be bonded to each other to form a ring.


Specific examples of the compound represented by the General Formula (14) are shown below. However, the present invention is not limited thereto.




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The compound represented by the General Formula (15) is an example of the compound of General Formula (1) in which P is OH, Q is NR2R3, Y is CR6, n is 1, and R1 on the carbon atom adjacent to P and R6 on the carbon atom adjacent to Q are bonded to each other to form a ring.


In the General Formula (15), V15 represents a substituent. b is an integer of 0 to 4 (preferably, 1 to 2, and more preferably 1). As the substituent represented by V15, there can be exemplified the substituents of the above-mentioned alkyl group represented by R2 and R3 in the General Formula (1). When a plurality of V15 are present in the General Formula (15), the respective groups may be the same as or different from each other, and may be bonded to each other to form a ring.


Each of R151 and R152 independently represents a hydrogen atom or a group which can be substituted with a nitrogen atom. Preferable examples of the group which can be substituted with a nitrogen atom include the groups exemplified in the above-mentioned R2 and R3 of the General Formula (1).


At least one of V15, R151, and R152 contains a fluorine atom. Especially, it is preferable that some or all hydrogen atoms of at least one group of V15, R151, and R152 (preferably, some or all hydrogen atoms bonded to carbon atoms) are substituted with fluorine atoms. In addition, it is preferable that the above Rf group is contained in at least one of V15, R151, and R152.


Further, in the case where a plurality of V15 is contained in the compound, the fluorine atom is contained in at least one group of the plurality of V15, R151, and R152.


Specific examples of the compound represented by the General Formula (15) are shown below. However, the present invention is not limited thereto.




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The compound represented by the General Formula (16) is an example of the compound of General Formula (1) in which P and Q are NR2R3 respectively, n is 0, and R2 and R3 are bonded to each other to form a ring.


In the General Formula (16), V16 represents a substituent. b is an integer of 0 to 4 (preferably, 1 to 2, and more preferably 1). As the substituent represented by V16, there can be exemplified the substituents of the above-mentioned alkyl group represented by R2 and R3 in the General Formula (1). When a plurality of V16 are present in the General Formula (16), the respective groups may be the same as or different from each other, and may be bonded to each other to form a ring.


Each of R161 and R162 independently represents a hydrogen atom or a group which can be substituted with a nitrogen atom. Preferable examples of the group which can be substituted with a nitrogen atom include the groups exemplified in the above-mentioned R2 and R3 of the General Formula (1).


At least one of V16, R161, and R162 contains a fluorine atom. Especially, it is preferable that some or all hydrogen atoms of at least one group of V16, R161, and R162 (preferably, some or all hydrogen atoms bonded to carbon atoms) are substituted with fluorine atoms. In addition, it is preferable that the above Rf group is contained in at least one of V16, R161, and R162.


Further, in the case where a plurality of V16 is contained in the compound, the fluorine atom is contained in at least one group of the plurality of V16, R161, and R162.


Specific examples of the compound represented by the General Formula (16) are shown below. However, the present invention is not limited thereto.




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The compound represented by the General Formula (17) is an example of the compound of General Formula (1) in which P and Q are NR2R3 respectively, n is 0, and R2 and R3 are bonded to each other to form a ring.


In the General Formula (17), V17 represents a substituent. d is 0 or 1. As the substituent represented by V17, there can be exemplified the substituents of the above-mentioned alkyl group represented by R2 and R3 in the General Formula (1). When a plurality of V17 are present in the General Formula (17), the respective groups may be the same as or different from each other, and may be bonded to each other to form a ring.


Each of R171, R172, and R173 independently represents a hydrogen atom or a group which can be substituted with a nitrogen atom. Preferable examples of the group which can be substituted with a nitrogen atom include the groups exemplified in the above-mentioned R2 and R3 of the General Formula (1).


At least one of V17, R171, R172, and R173 contains a fluorine atom. Especially, it is preferable that some or all hydrogen atoms of at least one group of V17, R171, R172, and R173 (preferably, some or all hydrogen atoms bonded to carbon atoms) are substituted with fluorine atoms. In addition, it is preferable that the above Rf group is contained in at least one of V17, R171, R172, and R173.


Further, in the case where a plurality of V17 is contained in the compound, the fluorine atom is contained in at least one group of the plurality of V17, R171, R172, and R173.


Specific examples of the compound represented by the General Formula (17) are shown below. However, the present invention is not limited thereto.




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The compound represented by the General Formula (18) is an example of the compound of General Formula (1) in which P and Q are OH respectively, Y is CR6 and nitrogen atom, n is 3, and R1 and R6 are bonded to each other to form a ring.


In the General Formula (18), V18 represents a substituent. b is an integer of 0 to 4 (preferably 1 to 2, and more preferably 1). As the substituent represented by V18, there can be exemplified the substituents of the above-mentioned alkyl group represented by R2 and R3 in the General Formula (1). When a plurality of V18 are present in the General Formula (18), the respective groups may be the same as or different from each other, and may be bonded to each other to form a ring.


R181 represents a hydrogen atom or a substituent. As the substituent represented by R181, there can be exemplified the substituents of the above-mentioned alkyl group represented by R2 and R3. The substituent is preferably an alkyl group, an alkenyl group, an alkynyl group, or an aryl group. Preferable examples of the respective groups include the examples of the above-mentioned R2 and R3.


When R181 represents a substituent, this group may further include a substituent. Examples of the substituent include the substituents of the above-mentioned alkyl group represented by R2 and R3 in the General Formula (1).


At least one of V18 and R181 contains a fluorine atom. Especially, it is preferable that some or all hydrogen atoms of at least one group of V18 and R181 (preferably, some or all hydrogen atoms bonded to carbon atoms) are substituted with fluorine atoms. In addition, it is preferable that the above Rf group is contained in at least one of V18 and R181.


Further, in the case where a plurality of V18 is contained in the compound, the fluorine atom is contained in at least one group of the plurality of V18 and R181.


Specific examples of the compound represented by the General Formula (18) are shown below. However, the present invention is not limited thereto.




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The compound represented by the General Formula (19) is an example of the compound of General Formula (1) in which P and Q are OH respectively, Y is CR6 and nitrogen atom, n is 2, and R1 and R6 are bonded to each other to form a ring.


In the General Formula (19), V19 represents a substituent. b is an integer of 0 to 4 (preferably 1 to 2, and more preferably 1). As the substituent represented by V19, there can be exemplified the substituents of the above-mentioned alkyl group represented by R2 and R3 in the General Formula (1). When a plurality of V19 are present in the General Formula (19), the respective groups may be the same as or different from each other, and may be bonded to each other to form a ring.


R191 represents a hydrogen atom or a substituent. As the substituent represented by R191, there can be exemplified the substituents of the above-mentioned alkyl group represented by R2 and R3. The substituent is preferably an alkyl group, an alkenyl group, an alkynyl group, or an aryl group. Preferable examples of the respective groups include the examples of the above-mentioned R2 and R3.


When R191 represents a substituent, this group may further include a substituent. Examples of the substituent include the substituents of the above-mentioned alkyl group represented by R2 and R3 in the General Formula (1).


At least one of V19 and R191 contains a fluorine atom. In this case, it is preferable that some or all hydrogen atoms of at least one group of V19 and R191 (preferably, some or all hydrogen atoms bonded to carbon atoms) are substituted with fluorine atoms. In addition, it is preferable that the above Rf group is contained in at least one of V19 and R191.


Further, in the case where a plurality of V19 is contained in the compound, the fluorine atom is contained in at least one group of the plurality of V19 and R191.


Specific examples of the compound represented by the General Formula (19) are shown below. However, the present invention is not limited thereto.




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The compound represented by the General Formula (20) is an example of the compound of General Formula (1) in which P and Q are NR2R3 respectively, and n is 0.


In the General Formula (20), each of R201, R202, R203, and R204 independently represents a hydrogen atom or a group which can be substituted with a nitrogen atom. Preferable examples of the group which can be substituted with a nitrogen atom include the groups exemplified in the above-mentioned R2 and R3 of the General Formula (1).


At least one of R201, R202, R203, and R204 contains a fluorine atom. Especially, it is preferable that some or all hydrogen atoms of at least one group of R201, R202, R203, and R204 (preferably, some or all hydrogen atoms bonded to carbon atoms) are substituted with fluorine atoms. In addition, it is preferable that the above Rf group is contained in at least one of R201, R202, R203, and R204.


Specific examples of the compound represented by the General Formula (20) are shown below. However, the present invention is not limited thereto.




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The compound represented by the General Formula (21) is an example of the compound of General Formula (1) in which P is NR2R3, Q is OH, and n is 0.


In the General Formula (21), each of R211 and R212 independently represents a hydrogen atom or a group which can be substituted with a nitrogen atom. Preferable examples of the group which can be substituted with a nitrogen atom include the groups exemplified in the above-mentioned R2 and R3 of the General Formula (1).


At least one of R211 and R212 contains a fluorine atom. Especially, it is preferable that some or all hydrogen atoms of at least one group of R211 and R212 (preferably, some or all hydrogen atoms bonded to carbon atoms) are substituted with fluorine atoms. In addition, it is preferable that the above Rf group is contained in at least one of R211 and R212.


Specific examples of the compound represented by the General Formula (21) are shown below. However, the present invention is not limited thereto.




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Meanwhile, as the most preferred embodiment of the compound represented by the General Formula (1), there is exemplified a compound represented by General Formula (X) below.




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Each of Rx1 and Rx2 independently represents an alkyl group having 1 to 12 carbon atoms. From the viewpoints that the compatibility of the compound with the fluorine-based resin is more excellent and the ion migration-inhibiting ability of the sealing layer (sealing film) formed from the sealing resin composition is more excellent, the number of carbon atoms in the alkyl group is preferably 1 to 8, more preferably 1 to 6, and particularly preferably 1 to 5. Specific examples of the preferable alkyl group include methyl, ethyl, n-propyl, isopropyl, t-butyl, isobutyl, 2,2-dimethyl propyl, hexyl, cyclohexyl, and the like.


A represents an alkylene group having 1 to 2 carbon atoms. A is preferably —CH2— or —CH2CH2—, and more preferably —CH2CH2—.


X11 represents an alkylene group having 1 to 3 carbon atoms which may contain a hydroxyl group. X11 is preferably —CH2—, —CH2CH2—, —CH2CH(CH3)—, —CH2CH2CH2—, —CH2CH(OH)CH2— or —CH2CH(CH2OH)—, more preferably —CH2—, —CH2CH2—, —CH2CH(OH)CH2— or —CH2CH2CH2—, and particularly preferably —CH2— or —CH2CH2—.


Y11 represents a linear perfluoroalkyl group having 4 to 12 carbon atoms. Preferred examples of the perfluoroalkyl group include C4F9—, C5F11—, C6F13—, C7F15—, C8F17—, C9F19—, C10F21—, and C12F25—. When the number of carbon atoms is within the above range, the compatibility of the compound with the fluorine-based resin is more excellent, and the ion migration-inhibiting ability of the sealing layer (sealing film) formed from the sealing resin composition is more excellent.


Rx1, Rx2, A, and X11 may have the above-mentioned substituent.


(Compound Represented by General Formula (2))


Next, a compound represented by General Formula (2) will be described.





R7—C(═O)—H  General Formula (2)


In the present invention, the compound represented by the General Formula (2) also contains a compound exhibiting reducing properties due to the existence of equilibrium between aldehyde and hemiacetal (aldose or the like), or a compound forming aldehyde due to the isomerization between aldose and ketose by the L'Obree-Doburyuin-Fanedge Ken Stein dislocation reaction (fructose or the like).


In the General Formula (2), R7 represents an alkyl group, an alkenyl group, an alkynyl group, an aryl group, a heterocyclic group, or a group composed of any combination of these.


When R7 represents an alkyl group, an alkenyl group, an alkynyl group, or an aryl group, preferred examples of the respective groups include the examples of the above-mentioned R2 and R3.


When R7 represents a heterocyclic group, R7 is preferably a monovalent group obtained by removing one hydrogen atom from a 5- or 6-membered substituted or unsubstituted aromatic or non-aromatic heterocyclic compound, and more preferably a 5- or 6-membered aromatic or non-aromatic heterocyclic group having 3 to 30 carbon atoms. Preferred examples thereof include 2-furanyl, 2-thienyl, 2-pyrimidinyl, 2-benzothiazolyl, 2-benzoxazolyl, 2-imidazolyl, 4-imidazolyl, triazolyl, benzotriazolyl, thiadiazolyl, pyrrolidinyl, piperidinyl, imidazolidinyl, pyrazolidinyl, morpholinyl, tetrahydrofuranyl, tetrahydrothienyl, and the like.


R7 is more preferably an alkyl group, an alkenyl group, an alkynyl group, or an aryl group, and particularly preferably an alkyl or an aryl group.


The alkyl group, alkenyl group, alkynyl group, aryl group or heterocyclic group represented by R7 may further include a substituent. Examples of the substituent include the substituents of the above-mentioned alkyl group represented by R2 and R3 in the General Formula (1).


Some or all hydrogen atoms in the group represented by R7 (preferably, some or all hydrogen atoms bonded to carbon atoms) are substituted with fluorine atoms. In this case, it is preferable that the above R1 group is contained in R7. The compound represented by the General Formula (2) contains fluorine atoms in an amount of satisfying the above-mentioned fluorine content rate.


Moreover, a hydroxyl group or a group represented by —COO— may be contained in the group represented by R7.


Specific examples of the compound represented by the General Formula (2) are shown below. However, the present invention is not limited thereto.




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(Compound Represented by General Formula (3))


Next, a compound represented by General Formula (3) will be described.




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In the General Formula (3), each of the groups represented by R8, R9 and R10 independently represents an alkyl group, an alkenyl group, an alkynyl group, an aryl group, a heterocyclic group, or a group composed of any combination of these. Preferred examples of the alkyl group, alkenyl group, alkynyl group, aryl group, and heterocyclic group include the examples of the above-mentioned R2 and R3 in the General Formula (1).


Each of the groups represented by R8, R9, and R10 may further include a substituent. Examples of the substituent include the substituents of the above-mentioned alkyl group represented by R2 and R3 in the General Formula (1).


Some or all hydrogen atoms of at least one group of R8 to R10 (preferably, some or all hydrogen atoms bonded to carbon atoms) are substituted with fluorine atoms. Especially, it is preferable that the above Rf group is contained in at least one group of R8 to R10. The compound represented by the General Formula (3) contains fluorine atoms in an amount of satisfying the above-mentioned fluorine content rate.


Specific examples of the compound represented by the General Formula (3) are shown below. However, the present invention is not limited thereto.




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(Compound Represented by General Formula (4))


Next, a compound represented by General Formula (4) will be described.




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In the General Formula (4), each of R11 and R12 independently represents an alkyl group, an alkenyl group, an alkynyl group, an aryl group, a heterocyclic group, or a group composed of any combination of these. Preferred examples of the alkyl group, alkenyl group, alkynyl group, aryl group, and heterocyclic group include the examples of the above-mentioned R2 and R3 in the General Formula (1).


Each of the groups represented by R11 and R12 may further include a substituent. Examples of the substituent may include the substituents of the above-mentioned alkyl group represented by R2 and R3 in the General Formula (1).


Some or all hydrogen atoms of at least one group of R11 to R12 (preferably, some or all hydrogen atoms bonded to carbon atoms) are substituted with fluorine atoms. Especially, it is preferable that the above Rf group is contained in at least one group of R11 to R12. The compound represented by the General Formula (4) contains fluorine atoms in an amount of satisfying the above-mentioned fluorine content rate.


Specific examples of the compound represented by the General Formula (4) are shown below. However, the present invention is not limited thereto.




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(Compound Represented by General Formula (5))


Next, a compound represented by General Formula (5) will be described.





Z—SH  General Formula (5)


In the General Formula (5), Z represents an alkyl group, an alkenyl group, an alkynyl group, an aryl group, a heterocyclic group, or a group composed of any combination of these. Preferred examples of the alkyl group, alkenyl group, alkynyl group, aryl group, and heterocyclic group include the examples of the above-mentioned R2 and R3 in the General Formula (1).


The group represented by Z may further include a substituent. Examples of the substituent include the substituents of the above-mentioned alkyl group represented by R2 and R3 in the General Formula (1).


Some or all hydrogen atoms of the group represented by Z (preferably, some or all hydrogen atoms bonded to carbon atoms) are substituted with fluorine atoms. Especially, it is preferable that the above Rf group is contained in Z. The compound represented by the General Formula (5) contains fluorine atoms in an amount of satisfying the above-mentioned fluorine content rate.


The compound represented by General Formula (5) is preferably the respective compounds represented by General Formulae (51) to (54).




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In the General Formula (51), R511 represents a substituent containing a fluorine atom.


As the substituent, there can be exemplified the substituents of the above-mentioned alkyl group represented by R2 and R3 in the General Formula (1). The group represented by R511 may further include a substituent. Examples of the substituent include the substituents of the above-mentioned alkyl group represented by R2 and R3 in the General Formula (1).


In addition, R511 contains a fluorine atom. Especially, some or all hydrogen atoms of R511 (preferably, some or all hydrogen atoms bonded to carbon atoms) are substituted with fluorine atoms. Further, it is preferable that the above Rf group is contained in R511.


Specific examples of the compound represented by the General Formula (51) are shown below. However, the present invention is not limited thereto.




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In the General Formula (52), each of R521 and R522 independently represents a hydrogen atom or a substituent. R523 represents a hydrogen atom or a group which can be substituted with a nitrogen atom. Preferable examples of the group which can be substituted with a nitrogen atom include the groups exemplified in the above-mentioned R2 and R3 of the General Formula (1). Further, as the substituent, there can be exemplified the substituents of the above-mentioned alkyl group represented by R2 and R3 in the General Formula (1). R521, R522, and R523 may be the same as or different from each other, and may be bonded to each other to form a ring.


At least one group of R521, R522, and R523 contains a fluorine atom. Especially, it is preferable that some or all hydrogen atoms of at least one group of R521, R522, and R523 (preferably, some or all hydrogen atoms bonded to carbon atoms) are substituted with fluorine atoms. In addition, it is more preferable that the above Rf group is contained in at least one group of R521, R522, and R523.


Specific examples of the compound represented by the General Formula (52) are shown below. However, the present invention is not limited thereto.




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In the General Formula (53), R531 represents a hydrogen atom or a substituent. R532 represents a hydrogen atom or a group which can be substituted with a nitrogen atom. Preferable examples of the group which can be substituted with a nitrogen atom include the groups exemplified in the above-mentioned R2 and R3 of the General Formula (1). Further, as the substituent, there can be exemplified the substituents of the above-mentioned alkyl group represented by R2 and R3 in the General Formula (1). R531 and R532 may be the same as or different from each other, and may be bonded to each other to form a ring.


At least one group of R531 and R532 contains a fluorine atom. Especially, it is preferable that some or all hydrogen atoms of at least one group of R531 and R532 (preferably, some or all hydrogen atoms bonded to carbon atoms) are substituted with fluorine atoms. In addition, it is more preferable that the above Rf group is contained in at least one group of R531 and R532.


Specific examples of the compound represented by the General Formula (53) are shown below. However, the present invention is not limited thereto.




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In the General Formula (54), R541 represents a fluorine-atom containing group which can be substituted with a nitrogen atom. Preferable examples of the group which can be substituted with a nitrogen atom include the groups exemplified in the above-mentioned R2 and R3 of the General Formula (1).


R541 contains a fluorine atom. Especially, it is preferable that some or all hydrogen atoms of R541 (preferably, some or all hydrogen atoms bonded to carbon atoms) are substituted with fluorine atoms. In addition, it is more preferable that the above Rf group is contained in R541.


Specific examples of the compound represented by the General Formula (54) are shown below. However, the present invention is not limited thereto.




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Meanwhile, as the most preferred embodiment of the compound represented by the General Formula (5), there is exemplified a compound represented by the following General Formula (Y).




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In the General Formula (Y), each of Ry1 and Ry2 independently represents a hydrogen atom or an alkyl group. n1 is 1 or 2, and preferably 2. When n1 is 2, a plurality of unit structures represented by CRy1Ry2 may be the same as or different from each other.


When each of Ry1 and Ry2 represents an alkyl group, the alkyl group preferably has 1 to 30 carbon atoms, more preferably 1 to 15 carbon atoms, and particularly preferably 1 to 6 carbon atoms. Preferable examples thereof include methyl, ethyl, n-propyl, isopropyl, t-butyl, n-octyl, eicosyl, chloromethyl, hydroxymethyl, aminoethyl, N,N-dimethylaminomethyl, 2-chloroethyl, 2-cyanoethyl, 2-hydroxyethyl, 2-(N,N-dimethylamino)ethyl, 2-ethylhexyl, and the like.


The structure represented by (CRy1Ry2)n1 is preferably —CH2—, —CH2CH2— or —CH2CH(CH3)—, more preferably —CH2CH2— or —CH2CH(CH3)—, and particularly preferably —CH2CH2—.


Each of Ry3 and Ry4 independently represents a hydrogen atom or a substituent. m1 is an integer of 1 to 6. When m1 is 2 or more, a plurality of unit structures represented by CRy3Ry4 may be the same as or different from each other. Further, Ry3 and Ry4 may be bonded to each other to form a ring. The definition of the substituent is as described above.


The structure represented by (CRy3Ry4)m1 is preferably —CH2—, —CH2CH2—, —CH2CH(CH3)—, —CH2CH2CH2—, —CH2CH(OH)CH2— or —CH2CH(CH2OH)—, more preferably —CH2—, —CH2CH2—, —CH2CH(OH)CH2— or —CH2CH2CH2—, and particularly preferably —CH2— or —CH2CH2—.


l1 is an integer of 1 to 6. Especially, in terms of the compatibility with the fluorine-based resin being excellent, l1 is preferably 2 to 5, and more preferably 3 to 4.


q1 represents 0 or 1, p1 represents 2 or 3, and p1+q1 represents 3. Especially, in terms of the compatibility with the fluorine-based resin being excellent, it is preferable that q1 is 1, and p1 is 2.


Ry5 represents a perfluoroalkyl group having 1 to 14 carbon atoms. The perfluoroalkyl group may be either linear or branched.


Examples of the linear or branched perfluoroalkyl group having 1 to 14 carbon atoms include CF3—, C2F5—, C3F7—, C4F9—, C5F11—, C6F13—, C7F15—, C8F17—, C9F19—, C10F21—, C12F25—, C14F29—, and the like.


(Compound Represented by General Formula (22))


Next, a compound represented by General Formula (22) will be described. Here, the compound represented by formula (22) contains fluorine atoms in an amount of satisfying the above-mentioned fluorine content rate.




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In the General Formula (22), Rf1 represents a fluoroalkyl group having 22 or less carbon atoms, which may have an ethereal oxygen atom and in which at least one of hydrogen atoms is substituted with a fluorine atom, or represents a fluorine atom.


Hydrogen atoms in the fluoroalkyl group may be substituted with a halogen atom other than the fluorine atom. It is preferable that the halogen atom other than the fluorine atom is a chlorine atom. The ethereal oxygen atom (—O—) may be present in the carbon-carbon bond ring of the fluoroalkyl group, or may be present at the terminal of the fluoroalkyl group. The structure of the fluoroalkyl group may be a linear structure, a branched structure, a cyclic structure or a partially cyclic structure, and among these, a linear structure is preferable.


Rf1 is preferably a perfluoroalkyl group or a polyfluoroalkyl group containing one hydrogen atom, and particularly preferably a perfluoroalkyl group (however, including a perfluoroalkyl group having an ethereal oxygen atom).


As Rf1, a perfluoroalkyl group having 4 to 6 carbon atoms, or a perfluoroalkyl group having 4 to 9 carbon atoms and containing an ethereal oxygen atom is preferable.


Specific examples of Rf1 include —CF3, —CF2CF3, —CF2CHF2, —(CF2)2CF3, —(CF2)3CF3, —(CF2)4CF3, —(CF2)5CF3, —(CF2)6CF3, —(CF2)7CF3, —(CF2)8CF3, —(CF2)9CF3, —(CF2)11CF3, —(CF2)15 CF3, —CF(CF3)O(CF2)5CF3, —CF2O(CF2CF2O)pCF3 (p is an integer of 1 to 8), —CF(CF3)O(CF2CF(CF3)O)qC6F13 (q is an integer of 1 to 4), and —CF(CF3)O(CF2CF(CF3)O)rC3F7 (r is an integer of 1 to 5).


Particularly preferably, Rf1 is —(CF2)CF3 or —(CF2)5CF3.


X1 represents a hydrogen atom, a fluorine atom, or a trifluoromethyl group.


Among them, a fluorine atom or trifluoromethyl group is preferable.


L1 represents a single bond or an alkylene group having 1 to 6 carbon atoms. Especially, an alkylene group having 1 to 2 carbon atoms is preferable.


L2 represents a single bond or an alkylene group having 1 to 6 carbon atoms which may be substituted with a hydroxyl group or a fluorine atom. Especially, an alkylene group having 1 to 2 carbon atoms is preferable.


L3 represents a single bond or an alkylene group having 1 to 6 carbon atoms. Especially, a single bond or an alkylene group having 1 or 2 carbon atoms is preferable.


Each of Y1 and Z1 independently represents a single bond, —CO2—, —CO—, —OC(═O)O—, —SO3—, —CONR222—, —NHCOO—, —O—, —S—, —SO2NR222—, or —NR222—. R222 represents a hydrogen atom or an alkyl group having 1 to 5 carbon atoms.


Among them, —CO2—, —O—, —S—, —SO2NR222—, or —CONR222— is preferable.


R221 represents a hydrogen atom, a linear or branched alkyl group having 1 to 8 carbon atoms, or Rf1—CFX1-L1-Y1-L2-Z1-L3-.


However, when both Y1 and Z1 are other than a single bond, L2 represents an alkylene group having 1 to 6 carbon atoms which may be substituted with a fluorine atom.


Specific examples of the compound represented by the General Formula (22) are shown below. However, the present invention is not limited thereto.




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(Compound Represented by General Formula (23))


Next, a compound represented by General Formula (23) will be described. Here, the compound represented by General Formula (23) contains fluorine atoms in an amount of satisfying the above-mentioned fluorine content rate.




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In the General Formula (23), each of R231 and R232 independently represents a hydrogen atom or an alkyl group. When each of R231 and R232 represents an alkyl group, the alkyl group has preferably 1 to 30 carbon atoms, more preferably 1 to 15 carbon atoms, and particularly preferably 1 to 6 carbon atoms. Preferable examples thereof include methyl, ethyl, n-propyl, isopropyl, t-butyl, n-octyl, eicosyl, chloromethyl, hydroxymethyl, aminoethyl, N,N-dimethylaminomethyl, 2-chloroethyl, 2-cyanoethyl, 2-hydroxyethyl, 2-(N,N-dimethylamino)ethyl, 2-ethylhexyl, and the like.


The structure represented by (CR231R232)n is preferably —CH2—, —CH2CH2— or —CH2CH(CH3)—, more preferably —CH2CH2— or —CH2CH(CH3)—, and particularly preferably —CH2CH2—.


Each of R233 and R234 independently represents a hydrogen atom or a substituent. Examples of the substituent may include the substituents of the above-mentioned alkyl group represented by R2 and R3.


The structure represented by (CR233R234)m is preferably —CH2—, —CH2CH2—, —CH2CH(CH3)—, —CH2CH2CH2—, —CH2CH(OH)CH2— or —CH2CH(CH2OH)—, more preferably —CH2—, —CH2CH2—, —CH2CH(OH)CH2— or —CH2CH2CH2—, and particularly preferably —CH2— or —CH2CH2—.


Y2 represents a single bond, —CO—, or —COO—.


When Y2 is a single bond or —CO—, n represents 0, and m represents an integer of 0 to 6. Especially, m is preferably 0 to 4, and more preferably 1 to 2.


When Y2 is —COO—, n represents 1 or 2, and preferably 2. m represents an integer of 1 to 6, preferably 1 to 4, and more preferably 1 to 2.


Rf2 represents a linear or branched perfluoroalkylene group having 1 to 20 carbon atoms, or a linear or branched perfluoroether group having 1 to 20 carbon atoms.


The number of carbon atoms in the perfluoroalkylene group is 1 to 20, but is preferably 2 to 15, and more preferably 3 to 12. Specific examples of the perfluoroalkylene group include —C4F8—, —C5F10—, —C6F12—, —C7F14—, —C8F16—, —C9F18—, —C10F20—, —C12F24—, and the like.


The perfluoroether group means a group in which an ethereal oxygen atom (—O—) is inserted between the carbon atoms at one or more places in the perfluoroalkylene group or is inserted in the bonding end of the perfluoroalkylene group. The number of carbon atoms in the perfluoroalkylene group is 1 to 20, but is preferably 2 to 15, and more preferably 3 to 12. As an specific example of the perfluoroether group, there is exemplified a perfluoroether group represented by the Formula —(CgF2gO)h— (here, each of g is independently an integer of 1 to 20, h is an integer of 1 or more, and g×h≦20).


p represents an integer of 2 to 3, l represents an integer of 0 to 1, and p+l=3. Especially, it is preferable that p is 3 and l is 0.


Specific examples of the compound represented by the General Formula (23) are shown below. However, the present invention is not limited thereto.




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(Compound Having Group Represented by General Formula (24) and Group Represented by General Formula (25))


Next, a compound (hereinafter, referred to as “compound X”) having a group represented by General Formula (24) and a group represented by General Formula (25) will be described. Here, the compound X contains fluorine atoms in an amount of satisfying the above-mentioned fluorine content rate.




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In the General Formula (24), each of R241, R242, R243, and R244 independently represents a hydrogen atom or a substituent. Examples of the substituent include the substituents of the above-mentioned alkyl group represented by R2 and R3. Especially, it is preferable for the substituent to be an alkyl group, and it is particularly preferable for each of R242 and R243 to be an alkyl group (particularly, tert-butyl group). Further, it is preferable for each of R241 and R244 to be a hydrogen atom.


* represents a binding position.


In the General Formula (25), X represents a hydrogen atom, a fluorine atom, or a trifluoromethyl group. Among them, a fluorine atom or a trifluoromethyl group is preferable.


Rf represents a fluoroalkyl group having 20 or loss carbon atoms, which may have an ethereal oxygen atom and in which at least one of hydrogen atoms is substituted with a fluorine atom, or represents a fluorine atom. The definition of Rf is the same as that of the above Rf1, except that the number of carbon atoms is different, and the preferred embodiments of Rf is also the same as those of the above Rf1.


* represents a binding position.


As a preferred embodiment of the compound X, there is exemplified a polymer having a repeating unit represented by the following General Formula (26) and a repeating unit represented by the following General Formula (27).




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In the General Formula (26) and the General Formula (27), each of R261 and R262 independently represents a hydrogen atom or a substituted or unsubstituted alkyl group having 1 to 4 carbon atoms.


Z2 represents a single bond, an ester group, an amide group, or an ether group.


L4 represents a single bond or a divalent organic group. In a preferred embodiment, the organic group represented by L4 is a linear, branched, or cyclic alkylene group, an aromatic group, or a group composed of the combination thereof. In the group composed of the combination of an alkylene group and an aromatic group, the alkylene group and the aromatic group may be combined through an ether group, an ester group, an amide group, a urethane group, or a urea group. Especially, it is preferable that the total number of carbon atoms in L4 is 1 to 15. Here, the total number of carbon atoms means, for example, the total number of carbon atoms contained in a substituted or unsubstituted divalent organic group represented by L4. Specific examples of the divalent organic group include a methylene group, an ethylene group, a propylene group, a butylene group, a phenylene group, substitutes of these with a methoxy group, a hydroxyl group, a chlorine atom, a bromine atom, a fluorine atom, or the like, and a group composed of any combination of these.


L5 represents a single bond or a divalent organic group having 1 to 6 carbon atoms and containing no fluorine. Especially, an alkylene group having 2 to 4 carbon atoms is preferable.


The definitions of R241 to R244, X and Rf in the General Formula (26) and the General Formula (27) are as described above.


The content of the repeating unit represented by the General Formula (26) in the polymer is not particularly limited, but, in terms of the effect of the present invention being more excellent, the content is preferably 5 to 90 mol %, and more preferably 10 to 70 mol %, based on the whole repeating unit in the polymer.


The content of the repeating unit represented by the General Formula (27) in the polymer is not particularly limited, but, in terms of the effect of the present invention being more excellent, the content is preferably 10 to 95 mol %, and more preferably 30 to 90 mol %, based on the whole repeating unit in the polymer.


The weight average molecular weight of the polymer is not particularly limited, but, in terms of the ion migration inhibiting ability being more excellent, the weight average molecular weight is preferably 3,000 to 500,000, and more preferably 5,000 to 100,000.


Specific examples of the compound X are shown below. However, the present invention is not limited thereto.




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The migration inhibitor (B) is preferably a compound represented by any one of General Formula (6), General Formula (7), General Formula (10), General Formula (11), General Formula (21), General Formula (51), General Formula (53), and General Formula (54), more preferably a compound represented by any one of General Formula (10), General Formula (11), General Formula (51), General Formula (53), and General Formula (54), and particularly preferably a compound represented by any one of General Formula (10), General Formula (11), and General Formula (51).


Although the detailed mechanism of the effects exhibited by the migration inhibitor (B) in the present invention has not been sufficiently elucidated, the compound represented by General Formula (1) is an organic compound exhibiting reducibility, which is known as Kendal-Pelz law, or is a reducing organic compound, which is generally known as a developing agent of various photographic sensitive materials. For example, the general structural formula thereof is exemplified in page 299 of “The Theory of the Photographic Process”, 4th edition, written by T. H. James, Macmillan Publishing Co., Inc.; lines 22 to 34, column 12 of U.S. Pat. No. 4,845,019 B; and the like, and the typical compound thereof is exemplified in pages 298 to 327 of “The Theory of the Photographic Process”, 4th edition, written by T. H. James, Macmillan Publishing Co., Inc.; page 6 of JP 2788831 B; pages 1 to 4 of JP 2890055 B; pages 12 to 15 of JP 4727637 B; and the like. Further, the compounds represented by General Formula (2), General Formula (3) and General Formula (4) and the compound X are also compounds exhibiting reducibility. It is presumed that if each of these reducing compounds exists in the vicinity of metal wiring in a fixed amount or more, the reducing compound reacts with metal ions generated by the ion migration of the metal wiring to reduce the metal ions by the self-oxidation thereof, thereby suppressing the migration of the metal wiring.


The compounds represented by General Formula (5), General Formula (22) and General Formula (23) are known as compounds capable of being adsorbed on a metal or compounds capable of being coordinated with a metal ion. It is presumed that the compound is adsorbed on the surface of a metal or forms a complex with the metal to form a film on the surface of the metal, thereby exhibiting the effect of corrosion protection or rust prevention, or that the compound forms a complex with the generated metal ions to suppress the diffusion of the metal ions, thereby suppressing the migration of the metal wiring.


As another preferred embodiment of the aforementioned compound represented by General Formula (1), a compound represented by General Formula (60) below is exemplified. The compound represented by General Formula (60) is a compound including the compounds represented by General Formulae (6) to (13).




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In General Formula (60), each of Wa independently represents OH, NR2R3 or CHR4R5. Each of Wb independently represents a hydrogen atom or a substituent. e represents 2, and f represents 4. Here, in the case in which at least one of Wa represents OH or NR2R3 and the one of Wa is NR2R3, the other Wa represents OH or NR2R3. Definitions of R2 to R5 are as described above.


At least one group of Wa and Wb includes a fluorine atom. Especially, it is preferable that some or all of hydrogen atoms of at least one group of Wa and Wb (preferably, a part or all of hydrogen atoms bonded to a carbon atom) are substituted with fluorine atoms. Further, it is more preferable that at least one group of Wa and Wb includes the aforementioned Rf group.


(Sealing Resin Composition)


The sealing resin composition contains the aforementioned fluorine-based resin (A) and migration inhibitor (B).


The mass ratio ((B)/(A)) of the migration inhibitor (B) to the fluorine-based resin (A) is equal to or more than 0.0010 and less than 0.10. Especially, from the viewpoints that the ion migration-inhibiting ability of the sealing layer (sealing film) formed from the sealing resin composition is more excellent and the planar characteristics thereof are also more excellent, the mass ratio ((B)/(A)) thereof is preferably 0.0025 to 0.06, and more preferably 0.010 to 0.05.


When the mass ratio ((B)/(A)) thereof is less than 0.0010, the ion migration-inhibiting ability is deteriorated. When the mass ratio ((B)/(A)) thereof is equal to or more than 0.10, the planar characteristics or the insulation performance is lowered.


If necessary, the sealing resin composition may contain a compound other than the aforementioned fluorine-based resin (A) and migration inhibitor (B).


For example, the sealing resin composition may contain a solvent. If the sealing resin composition contains a solvent, the handling property of the sealing resin composition is improved, and it is easy to form a sealing layer having a desired thickness.


The type of the solvent used is not particularly limited, and as the solvent, water or an organic solvent is exemplified.


Examples of the organic solvent used include alcohol-based solvents (for example, methanol, ethanol, isopropanol, sec-butanol, carbitol, and diethylene glycol monoethyl ether), ketone-based solvents (for example, acetone, methyl ethyl ketone, and cyclohexanone), aromatic hydrocarbon solvents (for example, toluene and xylene), amide-based solvents (for example, formamide, dimethyl acetamide, N-methyl pyrrolidone, and dimethyl propylene urea), nitrile-based solvents (for example, acetonitrile and propionitrile), ester-based solvents (for example, methyl acetate and ethyl acetate), carbonate-based solvents (for example, dimethyl carbonate and diethyl carbonate), ether-based solvents, halogen-based solvents, and the like. These solvents may be used in a mixture of two or more thereof.


As the use of the sealing resin composition, the sealing resin composition is used for coating silver wiring or a laminate including the silver wiring. More specifically, the sealing resin composition is used for coating the silver wiring by forming a sealing layer (sealing film) on the silver wiring. Further, the sealing resin composition is used for coating a laminate including the silver wiring by forming a sealing layer (sealing film) on the laminate. Here, the laminate including the silver wiring is not particularly limited as long as it includes the silver wiring. Generally, as the laminate, a laminate including a substrate, the silver wiring disposed on the substrate, and an insulating layer disposed on the silver wiring is used. The sealing resin composition is applied onto the insulating layer of the laminate to form a sealing layer (sealing film).


The method of using the sealing resin composition is not particularly limited, and generally, a method of forming a sealing layer (sealing film) by applying the sealing resin composition onto a substrate with silver wiring or a laminate including silver wiring is applied.


The method of applying the sealing resin composition is not particularly limited, and a known method (bar coating, spin coating, knife coating, or doctor blade coating) is applied.


If necessary, in order to remove a solvent, drying treatment may be performed after the application of the sealing resin composition. The heating conditions in the drying treatment are not particularly limited. However, from the viewpoint of productivity, the heating is preferably performed at 50° C. to 250° C. (preferably, 80° C. to 180° C.) for 5 minutes to 2 hours (preferably, 10 minutes to 1 hour).


<Sealing Film>


Next, the sealing film of the present invention will be described in detail.


The sealing film contains the aforementioned fluorine-based resin (A) and the aforementioned migration inhibitor (B). The mass ratio ((B)/(A)) of the migration inhibitor (B) to the fluorine-based resin (A) in the sealing film is the same as that in the sealing resin composition, and preferred embodiments of the mass ratio ((B)/(A)) in the sealing film are also the same as those in the sealing resin composition. The sealing film is used for coating silver wiring or a laminate including the silver wiring.


The sealing film may be a sealing film not having a substrate (substrate-less sealing film), or may be a sealing film having a substrate in which a sealing film is disposed on at least one principal surface of the substrate (sealing film with a substrate, for example, a double-sided sealing film having a sealing film on each side of the substrate and a single-sided sealing film having a sealing film only on one side of the substrate).


In the sealing film with a substrate, the type of the substrate used is not particularly limited, but a transparent substrate is preferably used. Examples of the transparent substrate include a polyethylene terephthalate film, a polybutylene terephthalate film, a polyethylene naphthalate film, a polyethylene film, a polypropylene film, a cellophane film, a diacetylcellulose film, a triacetylcellulose film, an acetylcellulose butyrate film, a polyvinyl chloride film, a polyvinylidene chloride film, a polyvinyl alcohol film, an ethylene-vinyl acetate copolymer film, a polystyrene film, a polycarbonate film, a polymethyl pentene film, a polysulfone film, a polyether ether ketone film, a polyether sulfone film, a polyether imide film, a polyimide film, a fluorine resin film, a nylon film, an acrylic resin film, and the like.


The thickness of the sealing film is not particularly limited, and in terms of application to electronic precision devices, the thickness thereof is preferably 0.3 μm to 30 μm, and more preferably 0.5 μm to 20 μm.


The sealing film can be manufactured by a known method. For example, in the case of the substrate-less sealing film, the sealing film can be manufactured by applying the aforementioned sealing resin composition onto a separator (release liner) such that the thickness thereof after drying becomes a predetermined thickness to provide a coating layer of the sealing resin composition, then drying the coating layer and, if necessary, curing the coating layer, and thereafter detaching the separator from the coating layer.


In the case of the sealing film with a substrate, the sealing film may be manufactured by directly applying the sealing resin composition onto the surface of a substrate and drying the applied composition (direct coating method), or may be manufactured by forming a coating layer of the sealing resin composition on a separator in the same manner as above and then transferring (sticking) the coating layer to a substrate (transfer method).


From the viewpoint that the ion migration between the metal wiring can be further suppressed, the sealing film of the present invention can be widely applied to, for example, touch panels, electrodes for displays, electromagnetic wave shields, electrodes for organic or inorganic EL displays, electronic papers, electrodes for flexible displays, integrated solar cells, display devices (OLED devices and LED devices), and other various devices (TFT devices).


<Wiring Board>


Next, a preferred embodiment of the wiring board of the present invention will be described in detail with reference to the accompanying drawing.



FIG. 1 is a schematic cross-sectional view showing a preferred embodiment of the wiring board of the present invention. In FIG. 1, the wiring board 10 includes a substrate 12, silver wiring 14 disposed on the substrate 12, and a sealing film 18 covering the silver wiring 14. Here, the substrate 12 and the silver wiring 14 constitute the substrate with silver wiring 16.


Hereinafter, each member (substrate 12, silver wiring 14, and sealing film 18) will be described in detail.


(Substrate)


The type of the substrate is not particularly limited as long as the substrate can support the silver wiring, but it is preferable for the substrate to be an insulating substrate having insulation properties. For example, an organic substrate, a ceramic substrate, a glass substrate, or the like can be used as the insulating substrate.


In addition, the substrate may have a laminated structure composed of at least two substrates selected from the group consisting of an organic substrate, a ceramic substrate, and a glass substrate.


As the raw material of the organic substrate, resins are exemplified. For example, a thermosetting resin, a thermoplastic resin, or a mixture thereof is preferably used. Examples of the thermosetting resin include a phenolic resin, a urea resin, a melamine resin, an alkyd resin, an acrylic resin, an unsaturated polyester resin, a diallyl phthalate resin, an epoxy resin, a silicone resin, a furan resin, a ketone resin, a xylene resin, a benzocyclobutene resin, and the like. Examples of the thermoplastic resin include a polyimide resin, a polyphenylene oxide resin, a polyphenylene sulfide resin, an aramid resin, a liquid crystal polymer, and the like.


In addition, as the raw material of the organic substrate, a glass woven fabric, a glass non-woven fabric, an aramid woven fabric, an aramid non-woven fabric, an aromatic polyamide woven fabric, a material in which each of these fabrics is impregnated with each of the above-mentioned resins, or the like can also be used.


(Silver Wiring)


The silver wiring mainly contains silver. The silver may be contained in the silver wiring in the form of a silver alloy. When the silver wiring contains a silver alloy, examples of metal contained in the silver wiring together with the silver include tin, palladium, gold, nickel, chromium, and the like. A resin component such as a binder or a photosensitive compound may be contained in the silver wiring to the extent not impairing the effects of the present invention. Further, if necessary, other components may be contained in the silver wiring.


The width of the silver wiring is not particularly limited. However, from the viewpoint of securing the electrical reliability in the highly-integrated portion and the drawing wiring portion (leading out wiring portion) of the wiring board, the width thereof is preferably 0.1 μm to 10000 μm, more preferably 0.1 μm to 300 μm, even more preferably 0.1 μm to 100 μm, and particularly preferably 0.2 μm to 50 μm.


The interval between the silver wiring is not particularly limited. However, from the viewpoint of high integration of the wiring board, it is preferably 0.1 μm to 1000 μm, more preferably 0.1 μm to 300 μm, even more preferably 0.1 μm to 100 μm, and particularly preferably 0.2 μm to 50 μm.


The shape of the silver wiring is not particularly limited, and may be any shape. Examples of the shape of the wiring board include a linear shape, a curved shape, a rectangular shape, a circular shape, and the like. The arrangement (pattern) of the silver wiring is not particularly limited and, for example, a stripe pattern is exemplified.


Further, although in the wiring board shown in FIG. 1, the number of the silver wiring 14 is two, the number thereof is not particularly limited. Generally, a plurality of pieces of silver wiring is provided.


The thickness of the silver wiring is not particularly limited. However, from the viewpoint of high integration of the wiring board, the thickness thereof is preferably 0.001 μm to 100 μm, more preferably 0.01 μm to 30 μm, and even more preferably 0.01 μm to 20 μm.


The method of forming the silver wiring is not particularly limited, and examples thereof include a physical film forming method such as a deposition method and a sputtering method, a chemical vapor phase method such as a CVD method, a method of applying a silver paste containing silver nonoparticles or silver nanowires, a method of using a silver salt disclosed in JP 2009-188360 A, and the like.


In FIG. 1, the silver wiring 14 is provided only on one side of the substrate 12, but may be provided on both sides thereof. That is, the substrate with silver wiring 16 may be a single-sided substrate, or may be a double-sided substrate. When the silver wiring 14 is provided on both sides of the substrate 12, the sealing film 18 may also be provided on both sides thereof.


Further, in FIG. 1, an example of a wiring structure, in which the silver wiring 14 is a single layer, is shown. However, needless to say, the wiring structure is not limited thereto. For example, by using a substrate with silver wiring in which a plurality of pieces of silver wiring and a plurality of substrates are alternately laminated (multi-layer wiring board), a wiring board having a multi-layer wiring structure may be constituted.


(Sealing Film)


The sealing film is a layer which is disposed on the surface of the silver wiring side of the substrate with silver wiring, covers the surface of the silver wiring, and suppresses the ion migration of silver between the silver wiring. In other words, the sealing film corresponds to a silver ion diffusion inhibiting layer.


Definition of the sealing film is as described above.


The method of manufacturing the sealing film is not particularly limited. For example, there can be exemplified a method of forming a sealing film by applying the aforementioned sealing resin composition onto a substrate with silver wiring and, if necessary, removing a solvent. In addition, there can be exemplified a method of directly laminating (sticking) a sealing film onto a substrate with silver wiring.


From the viewpoint that the ion migration between the metal wiring can be further suppressed, the wiring board of the present invention can be widely applied to, for example, touch panels, electrodes for displays, electromagnetic wave shields, electrodes for organic or inorganic EL displays, electronic papers, electrodes for flexible displays, integrated solar cells, display devices (OLED devices, and LED devices), and other various devices (TFT devices).


EXAMPLES

Hereinafter, the present invention will be described in more detail by Examples, but the present invention is not limited thereto.


Synthesis Example 1
Compound A-1

3-(3,5-di-tert-butyl-4-hydroxyphenyl)propionic acid (3.5 g, 12.6 mmol), dichloromethane (20 ml), 2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-nonadecafluorodecane-1-ol (6.3 g, 12.6 mmol), tetrahydrofuran (10 ml), 1-ethyl-3-(3-dimethylaminopropyl) carbodiimide hydrochloride (2.4 g, 12.6 mmol), and 4-dimethylaminopyridine (0.05 g, 0.4 mmol) were put into a reaction container in this order to obtain a reaction solution.


The reaction solution was stirred at room temperature for 3 hours, 1N hydrochloric acid (50 ml) was added thereto, and then the resultant was extracted with 100 ml of ethyl acetate to obtain an organic layer. The organic layer was washed with saturated saline and dried with magnesium sulfate. After solid content was separated by filtration, the organic layer was concentrated under reduced pressure to obtain white crude crystals. The white crude crystals were recrystallized with methanol to obtain 6.0 g of the compound A-1 (yield 63%).



1H-NMR spectrum of the obtained compound A-1 was as follows.



1H-NMR (solvent: deuterated chloroform, reference: tetramethylsilane)


6.98 (2H, s), 5.09 (1H, s), 4.59 (2H, t), 2.90 (2H, t), 2.71 (2H, t), 1.43 (9H, s)


In the 1H-NMR data, the peak of each proton was observed at the characteristic position, and thus the resulting product was identified as the compound A-1.


Here, the fluorine content rate of the compound A-1 was 47.5 mass %.




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Synthesis Example 2
Compound A-2

1,3,4-thiadiazole-2,5-dithiol (manufactured by Wako Pure Chemical Industries, Ltd.) (4.0 g, 26.6 mmol) and tetrahydrofuran (80 ml) were put into a reaction container, and completely dissolved to obtain a reaction solution. Then, 3,3,4,4,5,5,6,6,7,8,8,8-dodecafluoro-7-(trifluoromethyl)octyl acrylate (12.5 g, 26.6 mmol) was dropped into the reaction solution over 0.5 hours by a dropping funnel. The reaction solution was stirred at 65° C. for 6 hours, cooled to room temperature, and then concentrated under reduced pressure. To the reaction solution, 200 mL of hexane was added, and the resultant was cooled in an ice bath to obtain 16 g of crude crystals. 8 g of the crude crystals were purified by silica gel column chromatography (mobile phase: hexane/ethyl acetate=2/1 to 1/1) to obtain 6 g of the compound A-2 (yield 72%).



1H-NMR spectrum of the obtained compound A-2 was as follows.



1H-NMR (solvent: deuterated chloroform, reference: tetramethylsilane)


11.1 (1H, br), 4.44 (2H, t), 3.40 (2H, t), 2.85 (2H, t), 2.49 (2H, t), 2.49 (2H, m)


In the 1H-NMR data, the peak of each proton was observed at the characteristic position, and thus the resulting product was identified as the compound A-2.


Here, the fluorine content rate of the compound A-2 was 47.2 mass %.




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Synthesis Example 3
Compound A-3

The compound A-3 was synthesized according to the same procedure as in Synthesis Example 1, except that 2,2,2-trifluoroethanol was used instead of 2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10,10-nonadecafluorodecane-1-ol.


Here, the fluorine content rate of the compound A-3 was 15.8 mass %.




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Synthesis Example 4
Compound A-4

The compound A-4 was synthesized according to Synthesis Example of the compound 3c disclosed in the Journal of Organic Chemistry, 2005, vol. 70, 1328-1339.


Here, the fluorine content rate of the compound A-4 is 0 mass %.




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Synthesis Example 5
Compound A-5

1H-benzotriazole-5-carboxylic acid (1.5 g, 9.19 mmol), tetrahydrofuran (27 ml), dimethylformamide (3 ml), 3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluoro-1-octanol (3.35 g, 9.19 mmol), 1-ethyl-3-(3-dimethylaminopropyl)carbodiimide hydrochloride (1.76 g, 9.19 mmol), and 4-dimethylaminopyridine (0.11 g, 0.91 mmol) were put into a reaction container in this order to obtain a reaction solution. After the reaction solution was stirred at 70° C. for 24 hours, 50 ml of water was added thereto, and then the reaction solution was extracted with 100 ml of ethyl acetate to obtain an organic layer. The organic layer was washed with saturated saline and dried with magnesium sulfate to obtain solids. After solid content was separated by filtration, the organic layer was concentrated under reduced pressure. The resultant was purified by silica gel column chromatography (mobile phase: hexane/ethyl acetate=2/1) to obtain 3.1 g of the compound A-5 (yield 66%).


Here, the fluorine content rate of the compound A-5 was 48.5 mass %.




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Synthesis Example 6
Compound A-6

Compound A-6A was synthesized according to the following scheme.




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1,3,4-thiadiazole-2,5-dithiol (manufactured by Wako Pure Chemical Industries, Ltd.) (4.0 g, 26.6 mmol) and tetrahydrofuran (80 ml) were put into a reaction container, and completely dissolved to obtain a reaction solution. Then, 3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctyl acrylate (11.3 g, 26.6 mmol) was dropped into the reaction solution over 0.5 hours by a dropping funnel. The reaction solution was stirred at 65° C. for 6 hours, cooled to room temperature, and then concentrated under reduced pressure. To the resulting reaction mixture, 200 mL of hexane was added, and the resultant was cooled in an ice bath to obtain 15 g of crude crystals. 7.5 g of the crude crystals were purified by silica gel column chromatography (mobile phase: hexane/ethyl acetate=2/1 to 1/1) to obtain 6 g of the compound A-6A (yield 79%).


Next, compound A-6 was synthesized using the obtained compound A-6A according to the following scheme.




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The compound A-6A (3.0 g, 5.28 mmol) and ethyl acetate (20 ml) were put into a reaction container, and completely dissolved to obtain a reaction solution. To the reaction solution, sodium iodide (79.1 mg, 0.528 mmol) and 30% hydrogen peroxide (22.11 mmol, 2.39 g) were added in this order, and the reaction solution was stirred at room temperature for 1 hour to precipitate crystals. The crystals precipitated were washed with 100 ml of water to obtain crude crystals, and 2.7 g of the crude crystals were purified by silica gel column chromatography (mobile phase: hexane/ethyl acetate=2/1 to 1/1) to obtain 2.4 g of the compound A-6 (yield 80%).



1H-NMR spectrum of the obtained compound A-6 was as follows.



1H-NMR (solvent: deuterated chloroform, reference: tetramethylsilane): 4.43 (2H, t), 3.60 (2H, t), 2.95 (2H, t), 2.49 (2H, m)


In the 1H-NMR data, the peak of each proton was observed at the characteristic position, and thus the resulting product was identified as the compound A-6.


Here, the fluorine content rate of the compound A-6 was 43.5 mass %.




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Synthesis Example 7
Compound A-7

27.3 g of 4-methyl-2-pentanone (manufactured by Wako Pure Chemical Industries, Ltd.) was put into a 300 ml three-neck flask, and heated to 80° C. under a nitrogen stream. Then, a solution of 37.6 g of 3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctyl acrylate, 1.42 g of glycidyl methacrylate (manufactured by Tokyo Chemical Industry Co., Ltd.), 0.92 g of V-601 (manufactured by Wako Pure Chemical Industries, Ltd.), and 63.8 g of 4-methyl-2-pentanone (manufactured by Wako Pure Chemical Industries, Ltd.) was dropped thereinto over 4 hours. After the completion of the dropping, the resultant was stirred for 2 hours, heated to 90° C., and further stirred for 2 hours. To the resulting reaction solution, 3.34 g of 3-(3,5-di-tert-butyl-4-hydroxyphenyl)propionic acid and 0.21 g of dimethyldodecylamine (manufactured by Wako Pure Chemical Industries, Ltd.) were added, and the reaction solution was heated to 120° C. and reacted for 24 hours. After the completion of the reaction, to the resultant, 500 ml of hexane and 500 ml of ethyl acetate were added to obtain an organic layer. The organic layer was washed with 300 ml of a 5% aqueous citric acid solution, and then washed with 300 ml of a 5% aqueous ammonia solution. The organic layer was further washed with 300 ml of a 5% aqueous citric acid solution, and then washed with 300 ml of water. The organic layer was concentrated under reduced pressure, and then reprecipitated with hexane and dried under reduced pressure to obtain 30 g of the compound A-7 (Mw=7,000). Here, a weight average molecular weight refers to a value in terms of polystyrene measured by a gel permeation chromatography (GPC) method. The measurement of the weight average molecular weight of the compound A-7 by the GPC method was performed by dissolving the polymer in tetrahydrofuran, using a high-speed GPC (HLC-8220GPC, manufactured by Tosoh Corporation), using TSKgel SuperHZ4000 (manufactured by Tosoh Corporation, 4.6 mmI.D.×15 cm) as a column, and using THF (tetrahydrofuran) as an eluent.


Here, the fluorine content rate of the compound A-7 was 53.1 mass %.


The compound A-7 corresponds to the compound having the group represented by the General Formula (24) and the group represented by the General Formula (25).


Examples and Comparative Examples
Preparation of Sealing Resin Composition

Each of the aforementioned compounds A-1 to A-7, as a migration inhibitor, was added to the fluorine-based resin (B-1 or B-2), which will be described later, according to the mass ratio of Table 1 below, so as to prepare a sealing resin composition. At the time of adding the migration inhibitor, the migration inhibitor was dissolved in hexafluoroisopropanol, and then added.


(Fluorine-Based Resin)


B-1: CYTOP CTL-809M (manufactured by Asahi Glass Co., Ltd.)


B-2: CYTOP CTX-809AP2 (manufactured by Asahi Glass Co., Ltd.)











TABLE 1









Examples

































Comp.
Comp.
Comp.



Ex. 1
Ex. 2
Ex. 3
Ex. 4
Ex. 5
Ex. 6
Ex. 7
Ex. 8
Ex. 9
Ex. 10
Ex. 11
Ex. 1
Ex. 2
Ex. 3

























Fluorine-based
B-1
B-1
B-1
B-1
B-1
B-1
B-2
B-2
B-1
B-1
B-1
B-1
B-1
B-1


resin


Migration
A-1
A-1
A-1
A-1
A-2
A-2
A-1
A-2
A-5
A-6
A-7
A-1
A-3
A-4


inhibitor


Mass ratio
0.001
0.005
0.03
0.05
0.001
0.03
0.03
0.03
0.005
0.005
0.01
0.15
0.03
0.03


(B)/(A)









(Manufacture of Substrate with Silver Wiring)


Nanopaste NPS-JL (manufactured by Harima Chemicals Group, Inc.) was applied onto a glass epoxy substrate, which had been obtained by etching the copper portion of the glass epoxy multi-layer material MCL-E-67 (manufactured by Hitachi Chemical Co., Ltd.), by spin coating such that the film thickness after curing became 0.2 μm, and curing treatment was performed on the resultant at 180° C. for 1 hour to form a silver film. Then, PHOTEC RY-3310 (manufactured by Hitachi Chemical Co., Ltd.) was vacuum-laminated on the silver film, and exposure and development were performed on the vacuum-laminated silver film through a comb-like wiring pattern photomask of L/S=30 μm/30 μm. Then, silver of the non-covered portion of the PHOTEC RY-3310 was removed using AGRIP 940 (manufactured by Meltex Inc.), and then the PHOTEC RY-3310 was peeled off to manufacture a substrate with silver wiring for testing.


(Test Method)


(Planar Characteristics Evaluation Method)


As the evaluation method, first, the sealing resin composition was applied onto the manufactured substrate with silver wiring for testing by spin coating such that the thickness of a sealing layer (sealing film) became 1.5 μm, and curing treatment was performed on the sealing layer at 200° C. for 1 hour to prepare a wiring board for testing. The sealing layer of the wiring board for testing was observed with an optical microscope, and evaluation was performed according to the following criteria. A sealing layer of which the rank is B or higher (A) is practically usable, and a sealing layer of which the rank is A is preferable. The results of the evaluation are summarized in Table 2.


A: a sealing layer is transparent, and haze or surface unevenness is not recognized.


B: haze is slightly observed in a sealing layer, but visible light transmittance of 70% or more is secured.


C: haze or surface unevenness is remarkably observed in a sealing layer, and visible light transmittance is less than 70%.


(Adhesiveness Evaluation Method)


The adhesiveness of the sealing layer of the wiring board for testing prepared in the planar characteristics evaluation method was measured according to JIS K5600-5-6 ((ISO 2409) cross cut method, ISO adhesion tape/STANDARD of Elcometer Corporation is used), and evaluation was performed according to the following criteria. For practical use, the rank of a sealing layer needs to be B or higher (A). The results of the evaluation are summarized in Table 2.


A: a sealing layer is classified as 0 in JIS K5600-5-6


B: a sealing layer is classified as 1 to 2


C: a sealing layer is classified as 3 to 5


(Insulation Reliability Evaluation Method)


Using the wiring board for testing prepared in the planar characteristics evaluation method, lifetime measurement was performed under the conditions of a humidity of 85%, a temperature of 85° C., a pressure of 1.0 atm, and a voltage of 30 V (measuring equipment: EHS-221MD, manufactured by ESPEC Corporation).


In the evaluation method, lifetime measurement was performed under the above conditions by using the wiring board for testing, and by measuring the time T1 until the resistance value between the silver wiring becomes 1×105Ω.


Next, the lifetime measurement was performed in the same manner as described above by using a wiring board for comparative testing prepared using a sealing resin composition not containing the migration inhibitor, and by measuring the time T2 until the resistance value between the silver wiring becomes 1×105Ω.


The lifetime improvement effect (T1/T2) was calculated using the time T1 and the time T2 obtained. The evaluation was performed according to the following criteria. A sealing layer of which the rank is C or higher (B and A) is practically usable, and a sealing layer of which the rank is B or higher (A) is preferable. The results of the evaluation are summarized in Table 2.


A: T1/T2≧5


B: 5> T1/T2≧2


C: 2> T1/T2>1


D: 1≧T1/T2


Here, in Examples 1 to 6, Examples 9 to 11 and Comparative Examples 1 to 3 in which B-1 was used as the fluorine-based resin, the evaluation was performed using the wiring board for comparative testing in which the sealing layer was prepared by using only B-1.


In Examples 7 and 8 in which B-2 was used as the fluorine-based resin, the evaluation was performed using the wiring board for comparative testing in which the sealing layer was prepared by using only B-2.
























TABLE 2


















Comp.
Comp.
Comp.



Ex. 1
Ex. 2
Ex. 3
Ex. 4
Ex. 5
Ex. 6
Ex. 7
Ex. 8
Ex. 9
Ex. 10
Ex. 11
Ex. 1
Ex. 2
Ex. 3






























Planar
A
A
A
A
A
B
A
A
A
A
A
C
C
C


characteristics


evaluation result


Adhesiveness
A
A
A
A
A
A
B
B
A
A
A
A
A
A


evaluation result


Insulation
C
B
A
A
C
A
A
A
A
A
B
B
D
D


properties


evaluation result









As shown in Table 2 above, when the sealing resin composition of the present invention was used, the planar characteristics of the sealing layer were excellent, and the insulation properties between silver wiring were also excellent.


Particularly, from the comparison of Examples 1 to 4, it was found that when the mass ratio ((B)/(A)) of the migration inhibitor (B) to the fluorine-based resin (A) is equal to or more than 0.005, the insulation properties are excellent, and, particularly, when the mass ratio thereof is equal to or more than 0.03, the insulation properties are even more excellent.


Further, from the comparison of Examples 1 to 6 and Examples 7 and 8, it was found that when the fluorine-based resin contains the aforementioned silicon-containing group, the adhesiveness is more excellent.


From the comparison of Examples 2, 9, and 10, it was found that when the compound A-5 (compound represented by General Formula (22)) or the compound A-6 (compound represented by General Formula (23)) was used, the insulation properties are more excellent.


In contrast, in Comparative Example 1 in which the amount of the migration inhibitor is excessive, it was found that planar characteristics are poor. Further, in Comparative Examples 2 and 3 in which the migration inhibitor that does not satisfy the predetermined fluorine content rate is used, it was found that the insulation properties and the planar characteristics are poor.

Claims
  • 1. A sealing resin composition, which coats silver wiring or a laminate including the silver wiring, comprising: a fluorine-based resin (A); anda migration inhibitor (B) having a fluorine content rate of equal to or more than 35 mass % and less than 65 mass %,wherein the mass ratio ((B)/(A)) of the migration inhibitor (B) to the fluorine-based resin (A) is equal to or more than 0.0010 and less than 0.10.
  • 2. The sealing resin composition according to claim 1, wherein the migration inhibitor (B) is at least one selected from the group consisting of compounds represented by General Formulae (1) to (5), a compound represented by General Formula (22), a compound represented by General Formula (23), and a compound having a group represented by General Formula (24) and a group represented by General Formula (25): P—(CR1═Y)n-Q  General Formula (1)(in the General Formula (1), each of P and Q independently represents OH, NR2R3, or CHR4R5; each of R2 and R3 independently represents a hydrogen atom or a group which can be substituted with a nitrogen atom; each of R4 and R5 independently represents a hydrogen atom or a substituent; Y represents CR6 or a nitrogen atom; each of R1 and R6 independently represents a hydrogen atom or a substituent; at least two groups of groups represented by R1, R2, R3, R4, R5, and R6 may be bonded to each other to form a ring; n represents an integer of 0 to 5; when n is 0, neither both P and Q are CHR4R5, nor both P and Q are OH; when n is 2 or more, a plurality of atomic groups represented by (CR1═Y) may be the same as or different from each other; and at least one group of R1 to R6 contains a fluorine atom), R7—C(═O)—H  General Formula (2)(in the General Formula (2), R7 represents an alkyl group, an alkenyl group, an alkynyl group, an aryl group, a heterocyclic group, or a group composed of any combination of these; some or all hydrogen atoms of the group represented by R7 are substituted with fluorine atoms; and the group represented by R7 may contain a hydroxyl group or a group represented by —COO—),
  • 3. The sealing resin composition according to claim 2, wherein the compound represented by the General Formula (1) is at least one selected from the group consisting of compounds represented by General Formulae (6) to (21):
  • 4. The sealing resin composition according to claim 2, wherein the compound represented by General Formula (5) is at least one selected from the group consisting of compounds represented by General Formulae (51) to (54):
  • 5. The sealing resin composition according to claim 4, wherein the migration inhibitor (B) is at least one selected from the group consisting of the compounds represented by General Formula (6), General Formula (7), General Formula (10), General Formula (11), General Formula (21), General Formula (51), General Formula (53), and General Formula (54).
  • 6. The sealing resin composition according to claim 2, wherein the migration inhibitor (B) is at least one selected from the group consisting of a compound represented by General Formula (X), a compound represented by General Formula (Y), a polymer having a repeating unit represented by General Formula (26) and a repeating unit represented by General Formula (27), the compound represented by General Formula (22), and the compound represented by General Formula (23):
  • 7. The sealing resin composition according to claim 1, wherein the fluorine-based resin (A) has at least a repeating unit represented by General Formula (P-1).
  • 8. The sealing resin composition according to claim 1, wherein the fluorine-based resin (A) has a silicon-containing group that has a hydroxyl group or a hydrolyzable group bonded to a silicon atom and that can be crosslinked by forming a siloxane bond.
  • 9. A sealing film, which coats silver wiring or a laminate including the silver wiring, comprising: a fluorine-based resin (A); anda migration inhibitor (B) having a fluorine content rate of equal to or more than 35 mass % and less than 65 mass %,wherein the mass ratio ((B)/(A)) of the migration inhibitor (B) to the fluorine-based resin (A) is equal to or more than 0.0010 and less than 0.10.
  • 10. The sealing film according to claim 9, wherein the migration inhibitor (B) is at least one selected from the group consisting of compounds represented by General Formulae (1) to (5), a compound represented by General Formula (22), a compound represented by General Formula (23), and a compound having a group represented by General Formula (24) and a group represented by General Formula (25): P—(CR1═Y)n-Q  General Formula (1)(in the General Formula (1), each of P and Q independently represents OH, NR2R3, or CHR4R5; each of R2 and R3 independently represents a hydrogen atom or a group which can be substituted with a nitrogen atom; each of R4 and R5 independently represents a hydrogen atom or a substituent; Y represents CR6 or a nitrogen atom; each of R1 and R6 independently represents a hydrogen atom or a substituent; at least two groups of groups represented by R1, R2, R3, R4, R5, and R6 may be bonded to each other to form a ring; n represents an integer of 0 to 5; when n is 0, neither both P and Q are CHR4R5, nor both P and Q are OH; when n is 2 or more, a plurality of atomic groups represented by (CR1═Y) may be the same as or different from each other; and at least one of R1 to R6 contains a fluorine atom), R7—C(═O)—H  General Formula (2)(in the General Formula (2), R7 represents an alkyl group, an alkenyl group, an alkynyl group, an aryl group, a heterocyclic group, or a group composed of any combination of these; some or all hydrogen atoms of the group represented by R7 are substituted with fluorine atoms; and the group represented by R7 may contain a hydroxyl group or a group represented by —COO—),
  • 11. The sealing film according to claim 10, wherein the compound represented by the General Formula (1) is at least one selected from the group consisting of compounds represented by General Formulae (6) to (21):
  • 12. The sealing film according to claim 10, wherein the compound represented by General Formula (5) is at least one selected from the group consisting of compounds represented by General Formulae (51) to (54):
  • 13. The sealing film according to claim 12, wherein the migration inhibitor (B) is at least one selected from the group consisting of the compounds represented by General Formula (6), General Formula (7), General Formula (10), General Formula (11), General Formula (21), General Formula (51), General Formula (53), and General Formula (54).
  • 14. The sealing film according to claim 10, wherein the migration inhibitor (B) is at least one selected from the group consisting of a compound represented by General Formula (X), a compound represented by General Formula (Y), a polymer having a repeating unit represented by General Formula (26) and a repeating unit represented by General Formula (27), the compound represented by General Formula (22), and the compound represented by General Formula (23):
  • 15. The sealing film according to claim 9, wherein the fluorine-based resin (A) is a polymer compound having at least a repeating unit represented by General Formula (P-1) below.
  • 16. The sealing film according to claim 9, wherein the fluorine-based resin (A) has a silicon-containing group that has a hydroxyl group or a hydrolyzable group bonded to a silicon atom and that can be crosslinked by forming a siloxane bond.
  • 17. A wiring board comprising: a substrate;silver wiring disposed on the substrate; andthe sealing film according to claim 9 disposed on the silver wiring.
  • 18. A TFT device comprising the sealing film according to claim 9.
  • 19. An OLED device comprising the sealing film according to claim 9.
  • 20. An LED device comprising the sealing film according to claim 9.
Priority Claims (2)
Number Date Country Kind
2012-272280 Dec 2012 JP national
2013-073081 Mar 2013 JP national
CROSS-REFERENCE TO RELATED APPLICATIONS

This application is a Continuation of PCT International Application No. PCT/JP2013/082950 filed on Dec. 9, 2013, which claims priority under 35 U.S.C. §119(a) to Japanese Application No. 2012-272280 filed on Dec. 13, 2012 and Japanese Application No. 2013-073081 filed on Mar. 29, 2013. Each of the above application(s) is hereby expressly incorporated by reference, in its entirety, into the present application.

Continuations (1)
Number Date Country
Parent PCT/JP2013/082950 Dec 2013 US
Child 14728139 US