(1) Field of the Invention
The present invention relates to a semiconductor device and a method of manufacturing such a semiconductor device, and more particularly to a semiconductor device having a transistor structure capable of moving electrons or holes as a carrier at a high speed, and a method of manufacturing such a semiconductor device.
(2) Description of the Related Art
In recent years, the society is rapidly growing more and more information-intensive, and efforts are being made to make many information-processing electronic devices such as large-size computers, personal computers (PCs), personal digital assistants (PDAs), cell phones, etc. higher in operational speed and functionality and lower in power consumption. For further advancing those information-processing electronic devices, it is essential to make semiconductor devices which support the advancement as internal components also higher in operational speed and functionality and lower in power consumption.
A semiconductor device 100 shown in
Heretofore, it has been customary to improve the performance of transistors by reducing the size of gate electrodes. However, since enormous facility investments are required to reduce the size of gate electrodes and limitations will sometimes be posed on attempts to reduce the size of gate electrodes, there have been efforts to improve the performance of transistors without reducing the size of gate electrodes. Conventional semiconductor devices according to first through third examples for the purpose of improving the performance of transistors are shown in
A semiconductor device 200 shown in
A semiconductor device 300 shown in
A semiconductor device 400 shown in
Heretofore, the above transistor structures based on strains have been adopted to increase the electron or hole mobility without reducing the size of the gate electrodes. However, with conventional general transistor structures, a parasitic capacitance due to a pn junction exists between the source/drain and the substrate and between the channel and the substrate, and the operation of the transistor is delayed by such a parasitic capacitance. It has strongly been desired to solve such a problem and produce high-speed, low-power-consumption transistors.
To solve the problem of the parasitic capacitance due to the pn junction, there has been proposed a semiconductor device having a cavity defined below a semiconductor layer where a source/drain and a channel are formed (for example, see Japanese Unexamined Patent Publication No. 2000-22158 (paragraph Nos. [0019] through [0025], [0035] through [0039], FIGS. 1, 3, and 4). According to this proposal, the semiconductor layer is formed above the cavity which serves as an insulating layer, providing an SOI (Silicon On Insulator) structure. By providing the cavity whose dielectric constant is lower than that of an insulating layer such as a silicon oxide (SiO2) layer formed beneath a semiconductor layer in a usual SOI structure, the capacitance between the source/drain and the substrate and the capacitance between the channel and the substrate are reduced, preventing the transistor operation from being delayed. The semiconductor device can be produced by forming a sacrificial oxide film and a semiconductor layer on a semiconductor substrate, pattering the sacrificial oxide film and the semiconductor layer to the size of the gate of a transistor to be formed, and covering the exposed portion with a protective oxide film. After forming an opening with the protective oxide film left as a side wall, an etching liquid is introduced through the opening to selectively remove the sacrificial oxide film. Thereafter, the opening is closed by an insulating film deposited according to CVD (Chemical Vapor Deposition) or sputtering. A gate electrode and a source/drain are formed on the semiconductor layer above the cavity which has been formed by removal of the sacrificial oxide film.
There is provided in accordance with the present invention a semiconductor device having a gate electrode formed on a semiconductor layer with a gate insulating film interposed therebetween, and a source/drain formed in the semiconductor layer. The semiconductor device is characterized in that the semiconductor layer is curved from a region directly below the gate electrode sandwiched by the source/drain toward a region near the source/drain.
There is also provided in accordance with the present invention a method of manufacturing a semiconductor device having a gate electrode formed on a semiconductor layer with a gate insulating film interposed therebetween, and a source/drain formed in the semiconductor layer. The method comprises the steps of forming a laminated region of a sacrificial layer and a semiconductor layer and a device separating region surrounding the laminated region, on a substrate, forming a gate electrode on the device separating region and the semiconductor layer with a gate insulating film interposed therebetween, forming an opening through which the sacrificial layer is exposed between the device separating region and the semiconductor layer, and removing the sacrificial layer through the opening to form a cavity below the semiconductor layer.
There is further provided in accordance with the present invention a method of manufacturing a semiconductor device having a gate electrode formed on a semiconductor layer with a gate insulating film interposed therebetween and a source/drain formed in the semiconductor layer. The method comprises the steps of forming a laminated region of a sacrificial layer and a semiconductor layer and a device separating region surrounding the laminated region, on a substrate, forming a gate electrode on the device separating region and the semiconductor layer with a gate insulating film interposed therebetween, forming a source/drain in the semiconductor layer in sandwiching relation to a region directly below the gate electrode, forming an interlayer insulating film on the entire surface, forming a contact hole extending through the interlayer insulating film, and removing the sacrificial layer through the contact hole to form a cavity below the semiconductor layer.
There is further provided in accordance with the present invention a semiconductor device having a gate electrode formed on a semiconductor layer with a gate insulating film interposed therebetween and a source/drain formed in the semiconductor layer. The semiconductor device comprises a dome-shaped semiconductor disposed on a substrate, a gate insulating film and a gate electrode disposed on an outer wall surface of the dome-shaped semiconductor, and a semiconductor layer disposed on an inner wall surface of the dome-shaped semiconductor and having a source/drain formed therein in sandwiching relation to a region directly below the gate electrode.
There is also provided in accordance with the present invention a method of manufacturing a semiconductor device having a gate electrode formed on a semiconductor layer with a gate insulating film interposed therebetween and a source/drain formed in the semiconductor layer. The method comprises the steps of forming a first semiconductor layer partly on a surface of a substrate, forming a second semiconductor layer on an entire surface, forming a gate insulating film and a gate electrode on the second semiconductor layer directly above the first semiconductor layer, forming an opening extending to the first semiconductor layer in the second semiconductor layer and selectively removing the first semiconductor layer thereby to form a dome-shaped semiconductor which comprises the second semiconductor layer, and forming a third semiconductor layer on an inner wall surface of the dome-shaped semiconductor, with a source/drain formed in the third semiconductor layer.
The above and other objects, features, and advantages of the present invention will become apparent from the following description when taken in conjunction with the accompanying drawings which illustrate preferred embodiments of the present invention by way of example.
As described in the Related Art, there have been proposed various conventional transistor structures which are designed for high-speed operation by straining the channel region. In the future, the carrier mobility that is achieved by the transistor structures according to the above first through third examples will not be sufficient enough. These transistor structures may not necessarily be highly effective to increase both the hole mobility and the electron mobility, and may fail to make both p- and n-type transistors high in speed due to structural limitations as when p- and n-type transistors are to be formed on one substrate. Furthermore, if the strained SiGe structure or the strained Si structure is employed, then since the crystal surface morphology tends to be degraded as the film thickness increases upon epitaxial growth of semiconductor layers having different lattice constants, some countermeasures are needed to prevent crystal defects such as dislocations from occurring in the SiGe layer and the Si layer where the channel is to be formed.
The conventional transistor structure in which the cavity is formed beneath the semiconductor layer where a channel is to be formed is problematic in that since a thin gate electrode is formed over the cavity, the gate electrode is liable to fall into the cavity. The opening for removing the sacrificial oxide film to form the cavity is defined in a region relatively close to the gate electrode. Consequently, when the opening is closed by an epitaxial layer or the like, the epitaxial layer or the like may possibly enter deeply into the cavity, filling up the cavity. If the cavity is filled up, then the performance of small-size transistors cannot sufficiently be improved. If the cavity is thick, then it has a large ability to reduce the parasitic capacitance. However, if the cavity is not made thick for preventing the insulating film from entering the cavity, then a sufficient ability to reduce the parasitic capacitance is not achieved.
A first embodiment of the present invention will first be described below.
A semiconductor device 1 shown in
The thin-film Si layer 5 of the semiconductor device 1 is connected to the gate electrode 8 with the gate insulating film 8 interposed therebetween. As shown in
With the semiconductor device 1 thus constructed, the thin-film Si layer 5 is curved and hence is elongated to produce stresses, developing very large strains in the channel region directly below the gate electrode 8. While it has heretofore been customary to produce microscopic atomic-level strains in the channel region by changing lattice constants, the semiconductor device 1 according to the present invention has the thin-film Si layer 5 dynamically curved to develop large strains in the channel region. Large strains developed in the channel region drastically increase the carrier mobility. Furthermore, the cavity 4 is formed below the curved thin-film Si layer 5 to provide an SOI structure (so-called SON (Silicon On Nothing) structure) for reducing a parasitic capacitance due to a pn junction for increasing the high-speed performance of the transistor and reducing the power consumption thereof.
A method of manufacturing the semiconductor device 1 having the above structure will be described below by way of example with reference to
In the first manufacturing step, SiGe and Si are epitaxially grown to respective thicknesses on an Si substrate 2, forming a laminated substrate comprising the Si substrate 2, an SiGe layer 14 serving as a sacrificial layer, and a thin-film Si layer 5 as shown in
In the second manufacturing step, a trench extending into the Si substrate 2 is formed, and SiO2 or the like is deposited in the trench and planarized to form a device separating region 3. A region surrounded by the device separating region 3 as shown in
In the third manufacturing step, the thin-film Si layer 5 is oxidized or nitrided to form a gate insulating film 7 as shown in
In the fourth manufacturing step, a gate electrode 8 and a side wall 9 are formed. For example, after polysilicon (poly-Si) is formed on the entire surface by CVD, the assembly is anisotropically etched using a resist pattern formed by photolithography as a mask, forming the gate electrode 8. Then, using the gate electrode 8 as a mask, ions are introduced by ion implantation, forming an LDD region (or an extension region). For forming the LDD region, boron ions (B+) or phosphorus ions (P+) are introduced into the thin-film Si layer 5 under the conditions of an acceleration energy of 5 keV and a dose of 4×1014 cm−2. Thereafter, silicon nitride (SiN) or the like is deposited on the entire surface by CVD, and then anisotropically etched to form the side wall 9 on the side edges of the gate electrode 8. The assembly is then processed by wet etching or the like to remove the exposed gate insulating film 7. The gate insulating film 7 may not necessarily be removed at this time, but may be removed at least until plugs will be formed.
In the fifth manufacturing step, a resist pattern 16 is formed over the gate electrode 8 within the device separating region 3 by photolithography as shown in
In the sixth manufacturing step, the SiGe layer 14 as the sacrificial layer is selectively removed by wet etching as shown in
In the seventh manufacturing step, the thin-film Si layer 5 is curved to develop strains therein. Processes of curving the thin-film Si layer 5 will be described below. The thin-film Si layer 5 may be curved by a process which utilizes a surface tension produced when the assembly is processed in a wet environment, a process which utilizes a film (thermally elongatable film) having different stresses from the thin-film Si layer 5, a process which utilizes a heat treatment after ion implantation, a process which utilizes a laser beam application, or a process which utilizes the ejection of a fluid such as a gas or a liquid.
In
According this process, after the SiGe layer 14 is removed through the opening 17 by the wet etching, the assembly is immersed in pure water to wash away the etching liquid attached to the assembly. After the assembly is washed by the pure water, the assembly is immersed in an aqueous solution of nitric acid. When the assembly is immersed in the aqueous solution of nitric acid, the surfaces of the Si substrate 2 and the thin-film Si layer 5 are slightly oxidized and become hydrophilic. After the assembly is immersed in the aqueous solution of nitric acid, the assembly is immersed again in pure water to wash away the nitric acid. Then, the assembly is slowly lifted out of the pure water. At this time, a surface tension acts between the Si substrate 2 and the thin-film Si layer 5. Since the thin-film Si layer 5 is connected to the gate electrode 8, the thin-film Si layer 5 is curved from its portion directly underneath the gate electrode 8 in a substantially arcuate cross-sectional shape as shown in
If the thin-film Si layer 5 is curved by the process which utilizes a surface tension produced when the assembly is processed in a wet environment, then ions may be introduced for forming the LDD region after the gate electrode 8 is formed in the fourth manufacturing step, the side wall 9 may be formed, and the gate insulating film 7 may be partly removed, all after the thin-film Si layer 5 is curved. Specifically, after the gate electrode 8 is formed in the fourth manufacturing step, the thin-film Si layer 5 may be curved by a surface tension, and thereafter ions may be introduced for forming the LDD region, the side wall 9 may be formed, and the gate insulating film 7 may be partly removed.
Other processes of curving the thin-film Si layer 5 will be described below.
The process which utilizes a thermally elongatable film will be described below with reference to
According to this process, the thin-film Si layer 5 is curved using an SiN film 18 shown in
After the SiN film 18 is formed, the assembly is processed in a manner similar to the fifth and sixth manufacturing steps. Specifically, after the SiN film 18 is formed, a resist pattern 16 is formed on the SiN film 18. Using the resist pattern 16 as a mask, the SiN film 18 and the thin-film Si layer 5 are etched to form an opening 17 through which the SiGe layer 14 is exposed. Then, the SiGe layer 14 is selectively removed by wet etching, thus forming a cavity 4 beneath the thin-film Si layer 5 as shown in
A process which utilizes ion implantation will be described below with reference to
According to this process, the thin-film Si layer 5 is curved to develop strains therein by utilizing ion implantation for forming the source/drain 10. Specifically, after ions are introduced to form the LDD region, the side wall 9 is formed, and the gate insulating film 7 is partly removed in the fourth manufacturing step, ions are introduced to form the source/drain 10. For forming the source/drain 10, boron ions (B+) or phosphorus ions (P+) are introduced under the conditions of an acceleration energy of 20 keV and a dose of 5×1015 cm−2. The thin-film Si layer 5 and the SiGe layer 14 in the region where the ions are introduced have their crystal fully or partly broken (amorphous state) depending on the dose. This crystal state has a crystal defect distribution in the direction of the depth of the Si substrate 2 and the thin-film Si layer 5. Generally, the Si substrate 2 and the thin-film Si layer 5 have such a crystal defect distribution that there are more crystal defects in a shallow region of the thin-film Si layer 5 near the surface thereof, progressively fewer crystal defects in a deeper region of the thin-film Si layer 5, more crystal defects in a shallow region of the SiGe layer 14 beneath the thin-film Si layer 5, and fewer crystal defects in a deeper region of the SiGe layer 14. Usually, after the ion implantation, the assembly is heated to remove crystal defects and activate impurities. In this example, the SiGe layer 14 is removed before the assembly is heated.
Specifically, after the ion implantation for forming the source/drain 10, a resist pattern 16 is formed in a manner similar to the fifth and sixth manufacturing steps, and using the resist pattern 16 as a mask, an opening 17 is formed through which the SiGe layer 14 is exposed. The SiGe layer 14 is selectively removed by wet etching, thus forming a cavity 4 beneath the thin-film Si layer 5 as shown in
Then, the assembly is heated at 1030° C. for 1 second, for example, primarily for the purpose of removing crystal defects and activating impurities. As a result, the thin-film Si layer 5 whose crystal has been broken by the ion implantation is recrystallized. At this time, the thin-film Si layer 5 has its volume changed. The volume change depends on the crystal state before the assembly is heated, such that the volume is expanded greatly particularly near the surface where the crystal is broken to a large extent. Therefore, as shown in
While ions are introduced to form the source/drain 10 prior to the removal of the SiGe layer 14 in the above process, the ions may be introduced after the SiGe layer 14 is removed to form the cavity 4 (after the sixth manufacturing step). Specifically, after the ion implantation, the assembly may be heated to curve the thin-film Si layer 5 and activate impurities to form the source/drain 10.
In the above process, the thin-film Si layer 5 is curved by using the ion implantation process for forming the source/drain 10. However, the thin-film Si layer 5 may be curved by an ion implantation process which is separate from the ion implantation process for forming the source/drain 10. Specifically, ions as of Argon (Ar), nitrogen (N), or the like are introduced into the thin-film Si layer 5 before or after the removal of the SiGe layer 14. With these ions introduced, the thin-film Si layer 5 in the region where the ions are introduced has its crystal partly or fully broken. After the ion implantation, the SiGe layer 14 is removed, and the assembly is heated to curve the thin-film Si layer 5.
The process which utilizes a laser beam application will be described below. According to this process, a laser beam is applied to the thin-film Si layer 5 to quickly heat the surface thereof to thermally expand the surface for thereby curving the thin-film Si layer 5 to develop strains therein. The surface of the thin-film Si layer 5 is quickly heated and thermally expanded. As a result, the thin-film Si layer 5 is curved to develop strains therein. Thereafter, the processing goes to an eighth manufacturing step to be described later on.
If the thin-film Si layer 5 is curved by a laser beam application, then ions may be introduced for forming the LDD region after the gate electrode 8 is formed in the fourth manufacturing step, the side wall 9 may be formed, and the gate insulating film 7 may be partly removed, all after the thin-film Si layer 5 is curved. Specifically, after the gate electrode 8 is formed in the fourth manufacturing step, the cavity 4 may be formed according to the fifth and sixth manufacturing steps, a laser beam may be applied to the surface of the thin-film Si layer 5 to curve the thin-film Si layer 5, and thereafter ions may be introduced for forming the LDD region, the side wall 9 may be formed, and the gate insulating film 7 may be partly removed.
The process which utilizes a fluid will be described below. According to this process, an N2 gas or pure water is ejected to the thin-film Si layer 5 to curve the thin-film Si layer 5 under the pressure of the applied fluid to develop strains in the thin-film Si layer 5. First, after the sixth manufacturing step, a gas or a liquid is ejected to the surface of the thin-film Si layer 5. If a gas is used, then an N2 gas, for example, is ejected to the surface of the thin-film Si layer 5 from a position that is spaced 10 cm to 30 cm from the surface of the thin-film Si layer 5 under a pressure of 0.5 kg/cm2 at a rate ranging from 1 L/min. to 2 L/min. If a liquid is used, pure water, for example, is ejected to the surface of the thin-film Si layer 5 at a speed ranging from 1 km/h to 60 km/h. The thin-film Si layer 5 is curved under the pressure of the ejected N2 gas or pure water to develop strains in the thin-film Si layer 5. Thereafter, the processing goes to an eighth manufacturing step to be described later on.
If a gas or a liquid is used, then when the thin-film Si layer 5 is curved to have its ends brought into contact with the surface of the Si substrate 2, the ends of the thin-film Si layer 5 are bonded to the Si substrate 2 under interatomic forces provided the surface of the Si substrate 2 is clean. As a result, the curved thin-film Si layer 5 does not easily restore its original shape even after the gas or liquid pressure is removed. If a gas is used, then when the gas is ejected to the thin-film Si layer 5 while it is being wet, such as after the assembly is immersed in pure water, the ends of the thin-film Si layer 5 and the Si substrate 2 are bonded to each other more strongly than when the gas is ejected to the thin-film Si layer 5 while it is being dry. In view of a path through which the gas or the liquid escapes, the flow rate and pressure of the gas and the shape of a nozzle for ejecting the gas need to be optimized. It is also effective to eject the gas or the liquid locally and scan the ejection of the gas or the liquid, rather than to eject the gas or the liquid all over the entire surface at once, in order to increase the uniformity in the wafer.
If the thin-film Si layer 5 is curved by a gas or a liquid, then ions may be introduced for forming the LDD region after the gate electrode 8 is formed in the fourth manufacturing step, the side wall 9 may be formed, and the gate insulating film 7 may be partly removed, all after the thin-film Si layer 5 is curved. Specifically, after the gate electrode 8 is formed in the fourth manufacturing step, the cavity 4 may be formed according to the fifth and sixth manufacturing steps, a gas or a liquid may be ejected to the surface of the thin-film Si layer 5 to curve the thin-film Si layer 5, and thereafter ions may be introduced for forming the LDD region, the side wall 9 may be formed, and the gate insulating film 7 may be partly removed. The gate insulating film 7 may not necessarily be removed at this time, but may be removed at least until plugs will be formed.
The thin-film Si layer 5 may thus be curved according to any of the various processes typically described above to develop strains in the thin-film Si layer 5.
In the eighth manufacturing step, if ions have not been introduced to form the source/drain 10 in the previous manufacturing steps, then ions are introduced to form the source/drain 10 as shown in
In the ninth manufacturing step, an interlayer insulating film 11 of SiO2 or the like is formed on the entire surface, as shown in
In the tenth manufacturing step, as shown in
A semiconductor device 1a shown in
A semiconductor device 1b shown in
If an SOI substrate is used in such an application, then it is possible to form an Si layer and an SiGe layer successively on the SOI structure, and removing the Si layer as an uppermost layer on the SOI substrate and an Si layer formed thereon by way of wet etching, thus forming a transistor with the SiGe layer serving as a channel.
A semiconductor device 1c shown in
The semiconductor device 1c may employ a substrate of SOI structure of the Si substrate 2, the BOX layer, and the thin-film Si layer 5, with the cavity 4 formed by removing the BOX layer. Alternatively, the SOI substrate 2b may be employed instead of the Si substrate 2, and the SiGe layer 14 and the thin-film Si layer 5 may be formed on the SOI substrate 2b with the cavity 4 formed by removing the SiGe layer 14. While the surfaces of the gate electrode 8 and the source/drain 10 are silicidized in the above example, the source/drain 10 formed on the thin-film Si layer 5 may be silicidized in its entirety. If the thin-film Si layer 5 is silicidized in its entirety, then a lower-resistance electric connection can be achieved between the gate electrode 8 and the plugs 12 and between the source/drain 10 and the plugs 12.
A second embodiment of the present invention will be described below.
A semiconductor device 20 shown in
The thin-film Si layer 5 may be held out of contact with the Si substrate 2 as follows: If the thin-film Si layer 5 is curved by a surface tension, then pure water that is used to wash away the etching liquid may be mixed with a surface=active agent to reduce the surface tension that acts between the thin-film Si layer 5 and the Si substrate 2 when the assembly is lifted out of the pure water. If the thin-film Si layer 5 is curved by tensile stresses of the SiN film 18, then the SiN film 18 may be formed under such film growing conditions and head under such heating conditions as to reduce tensile stresses of the SiN film 18. If the thin-film Si layer 5 is curved by ion implantation and heat treatment, then ions may be introduced under such conditions as to break the crystal of the thin-film Si layer 5 to a smaller extent. If the thin-film Si layer 5 is curved by a laser beam application, then the energy of the applied laser beam may be adjusted to reduce a temperature rise of the thin-film Si layer 5. If the thin-film Si layer 5 is curved by ejecting a gas or a liquid, then the gas or the liquid may be ejected under such conditions as to reduce the pressure applied to the thin-film Si layer 5. The thin-film Si layer 5 may be of an increased thickness to make itself hard to be curved. Other details of the manufacturing process are identical to those of the process of manufacturing the semiconductor device 1 according to the first embodiment.
In the semiconductor device 20, the cavity 4 shown in
The semiconductor device 20 may employ a structure of SOI structure of the Si substrate 2, the Box layer, and the thin-film Si layer 5, with the cavity 4 formed by removing the BOX layer and the ends of the curved thin-film Si layer 5 may be held out of contact with the Si substrate 2. According to such a modification, the semiconductor device has a final structure which is the same as the structure shown in
A semiconductor device 20a shown in
A semiconductor device 20b shown in
In the semiconductor device 20, a substrate of SOI structure which is a laminated structure of the Si substrate 2, the BOX layer, and the thin-film Si layer 5 may be employed, or the Si substrate 2 may be replaced with the SOI substrate 2b. The source/drain 10 formed on the thin-film Si layer 5 may be silicidized in its entirety.
A third embodiment of the present invention will be described below.
A semiconductor device 30 shown in
The thin-film Si layer 5 of substantially cylindrical shape may be formed as follows: If the thin-film Si layer 5 is curved by a surface tension, then pure water that is used to wash away the etching liquid may not be mixed with a surface-active agent, and the cavity 4 may be of such a thickness as to allow the thin-film Si layer 5 to be greatly curved into a substantially cylindrical shape. If the thin-film Si layer 5 is curved by tensile stresses of the SiN film 18, then the thickness of the cavity 4 may be taken into account, and the SiN film 18 may be formed under such film growing conditions and head under such heating conditions as to increase tensile stresses of the SiN film 18. If the thin-film Si layer 5 is curved by ion implantation and heat treatment, then the thickness of the cavity 4 may be taken into account, and ions may be introduced under such conditions as to break the crystal of the thin-film Si layer 5 to a greater extent. If the thin-film Si layer 5 is curved by a laser beam application, then the thickness of the cavity 4 may be taken into account, and the energy of the applied laser beam may be adjusted to increase a temperature rise of the thin-film Si layer 5. If the thin-film Si layer 5 is curved by ejecting a gas or a liquid, then the thickness of the cavity 4 may be taken into account, and the gas or the liquid may be ejected under such conditions as to increase the pressure applied to the thin-film Si layer 5. The thin-film Si layer 5 may be of a reduced thickness to make itself easy to be curved. Other details of the manufacturing process are identical to those of the process of manufacturing the semiconductor device 1 according to the first embodiment.
In the semiconductor device 30, the plugs 12 is connected to both the source/drain 10 formed on the side walls of the largely curved thin-film Si layer 5 and the source/drain 10 formed on the Si substrate 2. If the ends of the thin-film Si layer 5 are held in contact with the Si substrate 2, then the plugs 12 may be connected to only the source/drain 10 formed on the Si substrate 2.
The semiconductor device 30 may employ a substrate of SOI structure which is a laminated structure of the Si substrate 2, the BOX layer, and the thin-film Si layer 5, with the cavity 4 being formed by removing the BOX layer. According to such a modification, the semiconductor device has a final structure which is the same as the structure shown in
A semiconductor device 30a shown in
A semiconductor device 30b shown in
The semiconductor device may be of such a structure that only the source/drain 10 is silicidized, with the gate electrode 8 being not silicidized. To prevent the gate electrode 8 from being silicidized, an insulating film may be formed beforehand on the gate electrode 8.
In the semiconductor device 30b, a substrate of SOI structure which is a laminated structure of the Si substrate 2, the BOX layer, and the thin-film Si layer 5 may be employed, or the Si substrate 2 may be replaced with the SOI substrate 2b. The source/drain 10 formed on the thin-film Si layer 5 may be silicidized in its entirety.
A semiconductor device 30c shown in
As described above with respect to the first through third embodiments, strains in the thin-film Si layer 5 can be increased for drastically increasing the carrier mobility by curving the thin-film Si layer 5. By forming the cavity 4 below the curved thin-film Si layer 5 or filling the region below the curved thin-film Si layer 5 with the interlayer insulating film 11, the channel and the source/drain 10 can be of a SON structure or a SOI structure. Thus, it is possible to realize a high-speed, low-power-consumption semiconductor device having a transistor structure with a high carrier mobility and a low parasitic capacitance.
When the thin-film Si layer 5 is to be curved, the thin-film Si layer 5 may not necessarily be curved symmetrically with respect to a vertical axis as viewed in a cross section taken along line Y-Y′. This is because even if the thin-film Si layer 5 is curved asymmetrically with respect to a vertical axis, since the channel is formed in a region directly below the gate electrode 8, it is possible to produce greater strains in this region than possible with the conventional arrangement. In the first through third embodiments, at least one of the ends of the thin-film Si layer 5 that is curved from the region directly below the gate electrode 8 toward the source/drain 10 should preferably be curved closer to the Si substrate 2 by a length which is at least one-third of the thickness of the thin-film Si layer 5 from the region directly below the gate electrode 8. Alternatively, the ends of the thin-film Si layer 5 that is curved from the region directly below the gate electrode 8 toward the source/drain 10 should preferably be curved so as to be close to each other at a distance which is at most twice the radius of curvature of the curved thin-film Si layer 5.
In the above embodiments, the thin-film Si layer 5 is curved. An arrangement in which the performance of a transistor is increased without intentionally curving the thin-film Si layer 5 will be described below with respect to a fourth embodiment of the present invention.
A semiconductor device 40 shown in
A process for manufacturing a semiconductor device 40 according to the fourth embodiment will be described below.
The process for manufacturing the semiconductor device 40 has manufacturing steps identical to the first through sixth manufacturing steps which are described above with respect to the first embodiment. After the sixth manufacturing step, ions are introduced into the thin-film Si layer 5 with the cavity 4 formed therebelow, and the assembly is heated to form the source/drain 10. Then, the interlayer insulating film 11 is formed on the entire surface.
The interlayer insulating film 11 thus formed closes the opening of the cavity 4. After the interlayer insulating film 11 is formed, the plugs 12 extending to the gate electrode 8 and the source/drain 10 are formed, and finally the interconnection layer 13 is formed, completing the semiconductor device 40 shown in
When ions are introduced into the thin-film Si layer 5 with the cavity 4 formed therebelow, and the assembly is heated to form the source/drain 10 in the production of the semiconductor device 40, the thin-film Si layer 5 may possible be curved under certain processing conditions. To prevent the thin-film Si layer 5 from being thus curved, conditions for the ion implantation and the heat treatment may be appropriately established, or the film thickness of the thin-film Si layer 5 may be increased to prevent the thin-film Si layer 5 from being curved by the ion implantation, or ions may be introduced before the cavity 4 is formed. Furthermore, the thin-film Si layer 5 may possibly be curved under a surface tension upon wet etching for forming the cavity 4. To prevent the thin-film Si layer 5 from being thus curved, the pure water used to wash away the etching liquid may be mixed with a surface-active agent to reduce the surface tension, or the film thickness of the thin-film Si layer 5 may be increased to prevent the thin-film Si layer 5 from being curved under the surface tension. To prevent the thin-film Si layer 5 from being curved, the thin-film Si layer 5 and the device separating region 3 may be connected to each other in a region other than the region directly below the gate electrode 8. For example, in the fifth manufacturing step, resist patterns 16a, 16b shown in
The semiconductor device 40 has the cavity 4 formed below the source/drain 10 formed on the thin-film Si layer 5. Therefore, the parasitic capacitance can be reduced for increased high-speed transistor performance.
The semiconductor device 40 may employ a substrate of SOI structure of the Si substrate 2, the BOX layer, and the thin-film Si layer 5, with the cavity 4 formed by removing the BOX layer. Alternatively, the SOI substrate 2b may be employed instead of the Si substrate 2.
A semiconductor device 40a shown in
The semiconductor device 40a may employ a substrate of SOI structure of the Si substrate 2, the BOX layer, and the thin-film Si layer 5, with the cavity 4 formed by removing the BOX layer. Alternatively, the SOI substrate 2b may be employed instead of the Si substrate 2.
A semiconductor device 40b according to a third example is different from the semiconductor device 40 according to the first example in that the silicide layer 19 is formed on the surface of the gate electrode 8 and a source/drain 41 is silicidized in its entirety. The semiconductor device 40b is manufactured as follows: Before the cavity 4 is formed below the thin-film Si layer 5, ions are introduced to form the source/drain 41. As shown in
According to the fourth embodiment, the cavity 4 is formed by forming the resist pattern 16 as shown in
A resist pattern 16a shown in
A resist pattern 16b shown in
By forming the resist patterns 16a, 16b as shown in
The illustrated resist patterns 16a, 16b are given by way of example only, and may be of other shapes. For example, though the resist patterns 16a, 16b provide a plurality of openings 17a, 17b, they may be shaped to provide a single opening. The resist patterns may be shaped to provide an opening only in the region between the ends of the source/drain 10 in the direction of the gate length of the gate electrode 8 and the device separating region 3. Alternatively, the resist patterns may be shaped to provide an opening only in the region between the region directly below the gate electrode 8 and a region except between the ends of the source/drain 10 in the direction of the gate length of the gate electrode 8 and the device separating region 3.
Since the shape and position of the opening can be determined by the shape of the resist that is formed, it is possible to form the opening in a position away from the gate electrode 8. In this case, when the opening is closed by the interlayer insulating film 11, the interlayer insulating film 11 is prevented from spreading into the cavity 4 directly below the gate electrode 8. As the cavity 4 is thicker, the ability to reduce the parasitic capacitance becomes greater. If the opening is spaced from the gate electrode 8, then the cavity 4 can be made sufficiently thick. The shape of the resist may be designed for semiconductor devices to be produced in view of the etching efficiency for forming the cavity 4, the strength of the connection between the thin-film Si layer 5 and the gate electrode 8, an the distance of the opening from the gate electrode 8, etc.
The process of forming the wet etching opening 17 using the resist pattern 16 and removing the sacrificial layer such as the SiGe layer 14 or the like through the opening 17 has been described above. However, the sacrificial layer may be removed by other processes. Other processes of removing the sacrificial layer are illustrated by way of first through third examples.
A sacrificial layer removing process according to a first example will be described below with reference to
After the first through fourth manufacturing steps described above with respect to the first embodiment, the processing goes to the eighth and ninth manufacturing steps where the interlayer insulating film 11 is formed on the entire surface without removal of the SiGe layer 14. Instead of the tenth manufacturing step described above with respect to the first embodiment, contact holes 42 extending through the interlayer insulating film 11 and the thin-film Si layer 5 to the SiGe layer 14 are formed.
After the contact holes 42 are formed, the assembly is processed by wet etching to remove the SiGe layer 14 through the contact holes 42, forming the cavity 4 between the Si substrate 2 and the thin-film Si layer 5.
After the SiGe layer 14 is removed, ions are introduced into the Si substrate 2 through the contact holes 42. The assembly is then heated to form an impurity diffusion layer 43 which corresponds to a source/drain.
After the impurity diffusion layer 43 is formed, an electrically conductive film is deposited to form plugs 44.
With the sacrificial layer removing process according to the first example, the electrically conductive film of the plugs in the contact holes 42 is connected tot the source/drain 10 and has its lower ends connected to the impurity diffusion layer 43. If the impurity diffusion layer 43 is not formed in the Si substrate 2, then a source-drain short circuit occurs when the electrically conductive film is connected to the Si substrate 2. However, with the impurity diffusion layer 43 formed in the Si substrate 2, even when the electrically conductive film contacts the Si substrate 2, it contacts a pn junction, providing a source-drain electric isolation. In the first example, though the ability to reduce the junction capacitance of the source/drain 10 is reduced by the impurity diffusion layer 43, it is possible to reduce the junction capacitance between the channel and the Si substrate 2.
If the SiGe layer 14 is relatively thin, the impurity diffusion layer 43 may be formed in the Si substrate 2 by introducing ions to form the source/drain 10 on the thin-film Si layer 5. If the impurity diffusion layer 43 is left after the removal of the SiGe layer 14, then ions may not be introduced through the contact holes 42 into the Si substrate 2 for forming the impurity diffusion layer 43. The sacrificial layer removing process according to the first example may be applied as it is even if the source/drain 10 has been silicidized.
A sacrificial layer removing process according to a second example will be described below with reference to
In the second example, the source/drain has been silicidized in its entirety. After the first through fourth manufacturing steps described above with respect to the first embodiment, the processing goes to the eighth manufacturing step where the source/drain, after it is formed, is silicidized to form a silicide layer 45. At this time, the silicide layer 45 is formed by forming the thin-film Si layer 5 as a thin layer in advance and silicidizing the source/drain in the thin-film Si layer 5 in its entirety.
After the silicide layer 45 is formed, the interlayer insulating film 11 is formed on the entire surface, and contact holes 42 extending through the interlayer insulating film 11 to the silicide layer 45 are formed. Then, the SiGe layer 14 is subjected to wet etching. Since the silicide layer 45 has many interstices, the etching liquid enters through the contact holes 42a into the SiGe layer 14 upon the wet etching.
The SiGe layer 14 is removed through the silicide layer 45 and the contact holes 42a by the introduced etching liquid, forming the cavity 4 below the silicide layer 45 and the thin-film Si layer 5. The silicide layer 45 is left on the bottoms of the contact holes 42a.
An electrically conductive film is formed in contact holes 42a to form plugs 44a. The electrically conductive film for forming the plugs 44a has poor coverage regardless of whether it is formed by sputtering or CVD, it cannot pass through the interstices of the silicide layer 45. As a result, a channel region and a region corresponding to the source/drain are formed over the cavity 4, reducing the junction capacitance between the channel and the Si substrate 2 and the junction capacitance of the source drain 10.
A sacrificial layer removing process according to a third example will be described below with reference to
In the third example, the general SOI substrate 2b which is of a laminated structure of the substrate 2ba, the BOX layer 2bb and the Si layer 2bc is employed. The SiGe layer 14 and the thin-film Si layer 5 are formed on the SOI substrate 2b. As with the first example, after the first through fourth manufacturing steps described above with respect to the first embodiment, the processing goes to the eighth and ninth manufacturing steps where the interlayer insulating film 11 is formed on the entire surface and the contact holes 42b extending to the SiGe layer 14 are formed.
After the contact holes 42b are formed, as with the first example, the assembly is processed by wet etching to remove the SiGe layer 14 through the contact holes 42b, forming the cavity 4 below the thin-film Si layer 5. The Si layer 2bc will be removed by wet etching before plugs 44b are formed. Since the thin-film Si layer 5 will be etched away together with the Si layer 2bc, the film thicknesses of those films are appropriately established to allow the thin-film Si layer 5 to remain unremoved after the Si layer 2bc will be removed.
After the removal of the Si layer 2bc, an electrically conductive film is formed in the contact holes 42b to form plugs 44b. Since the plugs 44b have lower ends connected to the BOX layer 2bb, there will be no source-drain short circuit.
By adjusting the conditions for growing the electrically conductive film to adjust the coverage, the plugs 44b may be formed with the electrically conductive film not reaching the bottoms of the contact holes. In such a modification, the Si layer 2bc shown in
If the SOI substrate 2b is employed with the BOX layer 2bb thereof serving as a sacrificial layer and with the Si layer 2bc serving as source/drain and channel regions, then the impurity diffusion layer 43 shown in
As described above in the first through third examples, if the thin-film Si layer 5 is not curved, the sacrificial layer such as the SiGe layer 14 or the like can be removed through the contact holes for forming the plugs to be connected to the source/drain 10.
In the first through fourth embodiments described above, if necessary, a semiconductor layer may be formed by way of epitaxial growth on the thin-film Si layer 5, and thereafter ions may be introduced to form a stacked source/drain structure. Such a structure may be adopted to achieve a lower resistance.
A fifth embodiment of the present invention will be described below.
According to the fifth embodiment, after the gate electrode 8 and the side wall 9 have been formed in the fourth manufacturing step for manufacturing the semiconductor device 1 according to the first embodiment as shown in
By etching the device separating region 3 to expose the SiGe layer 14, it is not necessary to form the resist patterns 16, 16b, 16b as shown in
In the above first through fifth embodiments, for forming the device separating region 3, the SiGe layer 14 and the thin-film Si layer 5 are formed on the Si substrate 2 or the SOI substrate 2b, after which a trench is formed. The trench may be formed before the SiGe layer 14 and the thin-film Si layer 5 are formed. Another process for forming the device separating region 3 will be described below.
As shown in
As described above, the semiconductor devices 1, 1a, 1b, 1c, 20, 20a, 20b, 30, 30a, 30b, 30c, 40, 40a, 40b according to the first through fourth embodiments are of such a structure that the cavity 4 is disposed below the channel region and the source/drain 10 of the thin-film Si layer 5, or the cavity 4 is filled with the interlayer insulating film 11. With this structure, there can be realized a high-speed, high-functionality, low-power-consumption semiconductor device whose parasitic capacitance due to a pn junction is greatly reduced and whose carrier mobility is large. Particularly, the semiconductor devices 1, 1a, 1b, 1c, 20, 20a, 20b, 30, 30a, 30b, 30c according to the first through third embodiments has their high-speed performance greatly improved by curving the thin-film Si layer 5 to develop large strains in the thin-film Si layer 5 directly below the gate electrode 8. With the semiconductor devices 40, 40a, 40b according to the fourth embodiment, the opening used to form the cavity 4 below the thin-film Si layer 5 may be formed at a position spaced from the gate electrode 8. Therefore, when the cavity 4 is formed below the thin-film Si layer 5, the interlayer insulating film 11 is not introduced deeply into the cavity 4 even if the cavity 4 is thick, and hence the parasitic capacitance can be reduced by increasing the thickness of the cavity 4. Furthermore, the manufacturing process can be simplified as the cavity can be formed utilizing the contact holes without photolithography.
Inasmuch as the thin-film Si layer 5 where the channel is formed can be formed as a highly thin film by epitaxial growth, it is possible to suppress a transistor short-circuit channel effect, increase an S value, and reduce a leakage by suppressing a sub-threshold current. By thus forming the thin-film Si layer 5 by way of epitaxial growth, a device of SOI structure can be fabricated without using an SOI substrate.
The above embodiments are applicable to either one of PMOS and NMOS structures for better performance thereof. For example, though the strained-SiGe structure is effective only with the PMOS structure, the mobility can be increased for the NMOS structure by removing the SiGe layer from the NMOS structure to form a cavity to provide an SOI structure, or curving the layer to mechanically strain the same. Though the strained-Si structure is effective with the NMOS structure, but not significantly effective with the PMOS structure, it may become highly effective with the PMOS structure by forming the cavity in the PMOS structure to provide an SOI structure or mechanically curving the layer.
The film thicknesses of the SiGe layer 14, the thin-film Si layer 5, the gate insulating film 7, and the interlayer insulating film 11, and the gate length of the gate electrode 8 as described above may appropriately be established depending on the desired characteristics of a semiconductor device to be fabricated. Regardless of whether the thin-film Si layer 5 is curved or not, Si may be epitaxially grown in a region where the source/drain 10 is to be formed before the source/drain 10 is formed, and thereafter ions may be introduced and the assembly may be heated to form a stacked source/drain.
In the above description, the thin-film Si layer 5 is grown on the SiGe layer 14 which has been epitaxially grown on the Si substrate 2, and is used as a channel. The cavity 4 is formed below the thin-film Si layer 5 or the thin-film Si layer 5 is curved and strained for making transistors higher in speed. For the purpose of making transistors higher in speed, SiGe or Ge which is a material different from the substrate is epitaxially grown on the Si substrate that has heretofore been employed, and is used as a channel (see Japanese Unexamined Patent Publication No. 5-121450 and Japanese Unexamined Patent Publication No. 8-186249).
The above approach is based on the phenomenon that when a crystal having a lattice constant different from a substrate is grown to achieve a lattice match with the substrate, the crystal is strained, changing the band structure for an increased carrier mobility. According to heteroepitaxial growth for stacking different materials, however, the crystal surface morphology is generally degraded as the film thickness increases. Because the degraded crystal surface morphology is responsible for a reduction in the carrier mobility for those transistors which have a film surface serving as a channel, it is very important to make high-quality crystal growth. For epitaxial growth of semiconductor layers having different lattice constants, there may be employed a process of providing a graded layer whose the Ge ratio is gradually changed between layers to prevent dislocations from occurring. According to such a process, a plurality of epitaxial growth cycles need to be carried out, resulting in a complex process. Furthermore, since the gate is oxidized after a semiconductor layer having a high Ge concentration is formed, the problem of dislocations still remains unsolved. For epitaxial growth of semiconductor layers having widely different lattice constants, as the thickness of the film being grown increases, the crystal surface morphology is degraded, resulting in crystal defects such as dislocations. If crystal defects are present in the channel region, they impair high-speed movement of electrons or holes, presenting an obstacle to higher-speed operation of transistors.
A transistor structure in which an initial growth surface with good crystal surface morphology is used as a channel to reduce the effect that crystal defects have on the carrier mobility according to a sixth embodiment of the present invention, and a process of manufacturing such a transistor structure will be described below.
A semiconductor device 50 according to the sixth embodiment shown in
The substrate 51 of the semiconductor device 50 may be made of Si, SiGe, SiGeC, Ge, or the like. The second and fourth semiconductor layers 54, 59 are of the same material as the substrate 51. The third semiconductor layer 58 may be made of Si, SiGe, SiGeC, Ge, or the like. The gate insulating film 55 may be made of SiO2, silicon oxide nitride (SiON), or an insulating material such as HfO2 having a dielectric constant higher than SiO2.
A process of manufacturing the semiconductor device 50 thus constructed will be described below with reference to
In the first manufacturing step, a mask 52 is formed of SiO2 or the like on the substrate 51 by photolithography, exposing a portion of the substrate 51. The substrate 51 is made of Si(001), for example, and the mask 52 is deposited of SiO2, Si3N4, or the like by CVD.
In the second manufacturing step, the first semiconductor layer 53 of a material different from the substrate 51 is selectively formed on the exposed portion of the substrate 51. The first semiconductor layer 53 is made of Si0.8G0.2, for example. The first semiconductor layer 53 is selectively formed by CVD such that its film thickness is equal to or smaller than a critical film thickness of 10 nm. Alternatively, the first semiconductor layer 53 may be made of SiGe, SiGeC, Ge, or the like which contains Ge at a concentration higher than the substrate 51.
In the third manufacturing step, the mask 52 is selectively removed. For example, if the mask 52 is made of SiO2, then the assembly is immersed in a dilute HF solution to selectively etch only SiO2 away.
In the fourth manufacturing step, the second semiconductor layer 54 is deposited. If the substrate 51 is made of Si, for example, the second semiconductor layer 54 is also made of Si. In that case, the second semiconductor layer 54 is formed such that the thickness of the Si film which will be left after the gate insulating film 55 is formed in a fifth manufacturing step to be described below will be in the range from 1 nm to 3 nm.
In the fifth manufacturing step, the gate insulating film 55 is formed on the surface of the second semiconductor layer 54. For example, if the second semiconductor layer 54 is made of Si, then the surface thereof is thermally oxidized to form the gate insulating film 55. As described above, the thickness of the second semiconductor layer 54 which is left after the gate insulating film 55 is formed is in the range from 1 nm to 3 nm.
In the sixth manufacturing step, the gate electrode 56 is formed on the gate insulating film 55. The gate electrode 56 is formed by depositing poly-Si or poly-SiGe and thereafter processing the deposited layer according to photolithography and etching.
In the seventh manufacturing step, holes 57 extending through the gate insulating film 55 and the second semiconductor layer 54 to the first semiconductor layer 53 are formed by photolithography and etching.
In the eighth manufacturing step, the first semiconductor layer 53 is selectively etched through the holes 57. For example, if the first semiconductor layer 53 is made of SiGe, then only SiGe is selectively etched away by H2O2, a mixed solution of H2O2 and sulfuric acid (H2SO4), or a mixed solution of HF and H2O2. In this manner, the dome-shaped semiconductor comprising the second semiconductor layer 54 is formed on the substrate 51.
In the ninth manufacturing step, the fourth semiconductor layer 59 serving as a cap layer and the third semiconductor layer 58 where a source/drain is to be formed are selectively formed on the inner wall surface of the dome-shaped semiconductor, successively from the second semiconductor layer 54. The fourth semiconductor layer 59 reduces contaminations on the third semiconductor layer 58, such as carbon remaining on the surface of the second semiconductor layer 54, and has a film thickness of 1 nm or less. The fourth semiconductor layer 59 is made of Si if the substrate 51 is made of Si. The third semiconductor layer 58 is made of either one of Si, SiGe, SiGeC, and Ge, and may be of the n-type or the p-type with an impurity mixed.
After the third and fourth semiconductor layers 58, 59 are formed, ions are introduced into the second, third, and fourth semiconductor layers 54, 58, 59 in regions directly below both sides of the gate electrode 56, forming a source/drain. The third semiconductor layer 58 has an initial growth surface with good crystal surface morphology close to the gate electrode 56, the initial growth surface functioning as a channel.
In the tenth manufacturing step, the insulating film 60 is formed by CVD to fill the interior space of the dome-shaped semiconductor with the BOX layer 61, and also to cover the entire surface of the assembly. The insulating film 60 and the BOX layer 61 may be made of SiO2 or an insulating material having a dielectric constant lower than SiO2, for example.
In the eleventh manufacturing step, the entire surface is anisotropically etched to form the side wall 62 on the side edges of the gate electrode 56. After the side wall 62 is formed, ions may be introduced into the second, third, and fourth semiconductor layers 54, 58, 59 in the regions directly below both sides of the gate electrode 56.
Finally, the entire surface is covered with the interlayer insulating film 63. After a contact hole extending to the gate electrode 56 and the source/drain is formed by photolithography, the interconnection 64 is formed, thus completing the semiconductor device 50 shown in
With the semiconductor device 50, the third semiconductor layer 58 serving as a channel region is grown on the inner wall surface of the dome-shaped semiconductor from the gate electrode 56. Therefore, the heteroepitaxial initial growth surface suffering few crystal defects may be used as a channel, making it possible to provide a high-speed transistor. By forming the BOX layer 61 between the third semiconductor layer 58 and the substrate 51, the parasitic capacitance is reduced and the leakage current flowing toward the substrate is reduced for low-power consumption.
According to the present invention, as described above, the high-speed performance of the transistor is greatly enhanced to make the semiconductor device higher in speed, lower in power consumption, and higher in functionality.
The structure in which the semiconductor layer with the channel formed therein is curved according to the present invention is also applicable to a poly-Si layer or an Si layer where the channel of a thin-film transistor (TFT) is formed for an increased carrier mobility in the field of liquid crystal display devices.
According to the present invention, since the semiconductor layer is curved to develop large strains in the channel region, the carrier mobility is drastically increased for making the semiconductor device higher in speed. With the cavity or the insulating film formed below the curved semiconductor layer, the parasitic capacitance is reduced. Therefore, the semiconductor device can be higher in speed and lower in power consumption.
According to the present invention, furthermore, the dome-shaped semiconductor is formed on the substrate, and the initial growth surface of the semiconductor layer formed on the inner wall surface of the dome-shaped semiconductor serves as a channel. Consequently, the semiconductor device is made higher in speed. If the insulating layer is formed below the semiconductor layer with the channel formed therein, then the parasitic capacitance is reduced. Therefore, the semiconductor device can be higher in speed and lower in power consumption.
The foregoing is considered as illustrative only of the principles of the present invention. Further, since numerous modification and changes will readily occur to those skilled in the art, it is not desired to limit the invention to the exact construction and applications shown and described, and accordingly, all suitable modifications and equivalents may be regarded as falling within the scope of the invention in the appended claims and their equivalents.
Number | Date | Country | Kind |
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2003-332383 | Sep 2003 | JP | national |
This application is a divisional application of U.S. patent application Ser. No. 10/708,792, filed Mar. 25, 2004, which application is based upon and claims priority of Japanese Patent Application No. 2003-332383, filed on Sep. 24, 2003, the contents being incorporated herein by reference.
Number | Date | Country | |
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Parent | 10708792 | Mar 2004 | US |
Child | 11360775 | Feb 2006 | US |