This application is based on and claims priority under 35 U.S.C. § 119 to Korean Patent Application No. 10-2023-0030198, filed on Mar. 7, 2023, in the Korean Intellectual Property Office, the disclosure of which is incorporated by reference herein in its entirety.
The disclosure relates to a semiconductor device and a method of manufacturing the same.
As miniaturization for improving the degree of integration of semiconductor devices progresses, performance limitations due to scaling of 3D bulk materials are emerging. To overcome these limitations, research on two-dimensional semiconductor material-based semiconductor devices is in progress.
In general, a high-k oxide, which has high permittivity and is used as an insulating film in a high-performance transistor, is deposited through atomic layer deposition (ALD). However, it is difficult to deposit other materials on the surface of a two-dimensional material with consistency and/or high quality, and this issue has been especially observed in techniques such as ALD. Accordingly, technologies for facilitating ALD on the surface of a two-dimensional material have been developed.
Provided are a semiconductor device including a high-quality insulating layer formed on a two-dimensional material, and a method of manufacturing the semiconductor device.
Additional aspects will be set forth in part in the description which follows and, in part, will be apparent from the description, or may be learned by practice of the presented embodiments of the disclosure.
According to an aspect of the disclosure, a semiconductor device includes a semiconductor layer including a semiconductor layer comprising a two-dimensional semiconductor material; a source electrode and a drain electrode electrically connected to respective edge regions of the semiconductor layer; gate electrode on the semiconductor layer; and an insulating layer between the semiconductor layer and the gate electrode, the insulating layer comprising a single-crystal layer.
The insulating layer may be lattice-matched with the two-dimensional semiconductor material of the semiconductor layer.
The insulating layer may have the same crystal orientation as the semiconductor layer.
The insulating layer may include Sb2O3 or MoOx.
A thickness of the insulating layer may be greater than or equal to about 1 nm and less than or equal to about 5 nm.
The semiconductor layer may include at least one MoS2, MoSe2, MoTe2, WS2, WSe2, MoTe2, or PtSe2.
The semiconductor device may further include a high-k dielectric layer between the insulating layer and the gate electrode.
The high-k dielectric layer may include a material having a higher permittivity than that of the insulating layer.
The high-k dielectric layer may include at least one of HfO2 or ZrO2.
The semiconductor device may include a field-effect transistor.
According to another aspect of the disclosure, a semiconductor device includes an electrode layer comprising a two-dimensional conductive material; a semiconductor layer comprising a two-dimensional semiconductor material; a first insulating layer between the electrode layer and the semiconductor layer, the first insulating layer comprising a single-crystal layer; and a source electrode and a drain electrode electrically connected to respective edge regions of the semiconductor layer.
The first insulating layer may be lattice-matched with the two-dimensional conductive material of the electrode layer.
The first insulating layer may have the same crystal orientation as the electrode layer.
The first insulating layer may include Sb2O3 or MoOx.
A thickness of the first insulating layer may be greater than or equal to about 1 nm and less than or equal to about 5 nm.
The electrode layer may include at least one of graphene, NbSe2, NbS2, TiS2, TiSe2, VS2, VSe2, or WTe2.
The semiconductor layer may include at least one of MoS2, MoSe2, MoTe2, WS2, WSe2, MoTe2, or PtSe2.
The semiconductor device may further include a second insulating layer arranged on the semiconductor layer, and a gate electrode arranged on the second insulating layer.
The above and other aspects, features, and advantages of certain embodiments of the disclosure will be more apparent from the following description taken in conjunction with the accompanying drawings, in which:
Reference will now be made in detail to embodiments, examples of which are illustrated in the accompanying drawings, wherein like reference numerals refer to like elements throughout. In this regard, the present embodiments may have different forms and should not be construed as being limited to the descriptions set forth herein. Accordingly, the embodiments are merely described below, by referring to the figures, to explain aspects. As used herein, the term “and/or” includes any and all combinations of one or more of the associated listed items. Expressions such as “at least one of,” when preceding a list of elements, modify the entire list of elements and do not modify the individual elements of the list.
A semiconductor device and a method of manufacturing the same will now be described more fully with reference to the accompanying drawings. In the drawings, like reference numerals refer to like elements throughout and sizes of constituent elements may be exaggerated for convenience of explanation and the clarity of the specification. In the following drawings, the size of each component in the drawings may be exaggerated for clarity and convenience of description. In addition, the embodiments described below are an example only, and can be subjected to various modifications. Additionally, when the terms “about” or “substantially” are used in this specification in connection with a numerical value and/or geometric terms, it is intended that the associated numerical value includes a manufacturing tolerance (e.g., ±10%) around the stated value and/or term, unless indicated otherwise. Further, regardless of whether numerical values and/or geometric terms are modified as “about” or “substantially,” it will be understood that these values should be construed as including a manufacturing or operational tolerance (e.g., ±10%) around the stated numerical values and/or geometry. When referring to “within” and/or “C to D”, this means C inclusive to D inclusive unless otherwise specified. Also, embodiments described herein may have different forms and should not be construed as being limited to the descriptions set forth herein.
It will also be understood that when an element is referred to as being “on” or “above” another element, the element may be in direct contact with the other element or other intervening elements may be present. It will also be understood that spatially relative terms, such as “above”, “top”, etc., are intended to encompass different orientations of the device in use or operation in addition to the orientation depicted in the figures, and that the device may be otherwise oriented (rotated 90 degrees or at other orientations) and the spatially relative terms used herein interpreted accordingly. The singular forms include the plural forms unless the context clearly indicates otherwise. It should be understood that, when a part “comprises” or “includes” an element, unless otherwise defined, other elements are not excluded from the part and the part may further include other elements.
The use of the terms “a” and “an” and “the” and similar referents are to be construed to cover both the singular and the plural. The steps of all methods described herein can be performed in any suitable order unless otherwise indicated herein or otherwise clearly contradicted by context, and are not limited to the described order.
Functional elements, including elements that process at least one function or operation, may be implemented as processing circuitry such as hardware, software, or a combination of hardware and software, unless expressly indicated otherwise. For example, the processing circuitry more specifically may include, but is not limited to, electrical components such as at least one of transistors, resistors, capacitors, etc., and/or electronic circuits including said components, a central processing unit (CPU), an arithmetic logic unit (ALU), a digital signal processor, a microcomputer, a field programmable gate array (FPGA), a System-on-Chip (SoC), a programmable logic unit, a microprocessor, application-specific integrated circuit (ASIC), etc. Furthermore, the connecting lines, or connectors illustrated in the various figures presented are intended to represent exemplary functional relationships and/or physical or logical couplings between the various elements. It should be noted that many alternative or additional functional relationships, physical connections or logical connections may be present in a practical device.
The use of any and all examples, or exemplary language (e.g., “such as”) provided herein, is intended merely to better illuminate the disclosure and does not pose a limitation on the scope of the disclosure unless otherwise claimed.
Referring to
In at least some examples, the substrate 110 may include a semiconductor material. For example, the substrate 110 may include an elemental and/or a compound semiconductor substrate. The substrate 110 may include, for example, silicon (Si), germanium (Ge), silicon germanium (SiGe), silicon carbide (SiC), gallium arsenide (GaAs), indium arsenide (InAs), indium phosphide (InP), etc. In addition, the substrate 110 may further include an insulating material such as oxide, silicon nitride, silicon oxynitride, etc. The substrate 110 may be doped with a P-type dopant or an N-type dopant. The substrate 110 may be a substrate for growth of the semiconductor layer 120.
The semiconductor layer 120 includes a two-dimensional (2D) semiconductor material. For example, the semiconductor layer 120 may include, for example, a transition metal dichalcogenide (TMD). The semiconductor layer 120 may include, for example, at least one of MoS2, MoSe2, MoTe2, WS2, WSe2, MoTe2, or PtSe2. The semiconductor layer 120 may be a single layer or a multilayer (when several single layers are stacked). The semiconductor layer 120 may act as a channel layer of the semiconductor device 100. The semiconductor layer 120 may include a sheet of the two-dimensional material and/or a stack including a plurality of sheets, such that the two-dimensional lattice of the two-dimensional material extends parallel (or substantially parallel) to an upper surface of the substrate 110.
The insulating layer 130 may be provided on the semiconductor layer 120. The insulating layer 130 may be formed on the semiconductor layer 120 through epitaxial growth, as described in further detail below. The insulating layer 130 formed through epitaxial growth may be lattice-matched with the semiconductor layer 120. For example, the insulating layer 130 formed through epitaxial growth may have the same crystal orientation as the semiconductor layer 120. By using epitaxial growth, a material having a high permittivity may be deposited on the semiconductor layer 120.
The insulating layer 130 may include a material having a higher permittivity than that of silicon oxide. The insulating layer 130 may have a permittivity higher than that of hexagonal boron nitride (h-BN). The insulating layer 130 may include, for example, Sb2O3 or MoOx, but is not limited thereto, and may include an insulating material that may be formed on the semiconductor layer 120 through epitaxial growth.
The insulating layer 130 may be a single-crystal layer. A single-crystal structure applied to the insulating layer 130 may be advantageous in leakage current characteristics. The semiconductor device 100 according to the embodiment includes the insulating layer 130 that has a single-crystal structure in which an insulating material is epitaxially grown on a two-dimensional semiconductor material, and therefore lacks internal grain boundaries. In contrast, a poly-crystal structure is not suitable for use in a gate insulating layer because grain boundaries of the poly-crystal structure may be used as passages for a leakage current; however, it is generally known that making an insulating layer with a single-crystal structure is highly difficult. Thus, high-k materials having an amorphous structure have been generally preferred as insulating materials. However, it is difficult to directly grow the high-k materials on a two-dimensional semiconductor material. The insulating layer 130 may act as a gate insulating film with low leakage current. When the insulating layer 130 is grown as a single-crystal layer, the process of forming a seed layer in order to form a high-k material on a two-dimensional material according to the related art is not required, and thus the thickness of the insulating layer 130 may be reduced. The thickness of the insulating layer 130 may be, for example, greater than or equal to about 1 nm and less than or equal to about 5 nm. The thickness of the insulating layer 130 may be, for example, greater than or equal to 2 nm or and less than or equal to about 3 nm. In addition, since single-crystals have a relatively high permittivity, a high permittivity may be exhibited even with a small thickness, and thus, when the insulating layer 130 is deposited as a single-crystal layer, equivalent oxide thickness (EOT) scaling may be improved. The permittivity of the insulating layer 130 may be greater than 3.6, for example. The permittivity of the insulating layer 130 may be greater than 10, for example. The permittivity of the insulating layer 130 may be greater than 13, for example.
The source electrode 140 and the drain electrode 150 are provided on respective edge regions on the semiconductor layer 120, respectively. The source electrode 140 and the drain electrode 150 may be electrically connected to the edge regions of the semiconductor layer 120, respectively. The source electrode 140 and the drain electrode 150 may have various structures such as a raised structure or a recessed structure. The source electrode 140 and the drain electrode 150 may include a metal and/or a metallically conductive material. The source electrode 140 and the drain electrode 150 may include, for example, a metal material having excellent electrical conductivity, such as Ag, Au, Pt, Cu, etc.
The gate electrode 160 may be referred to as an upper gate. The gate electrode 160 may include a metal material and/or a conductive oxide. The metal material may include, for example, Au, Ti, TiN, TaN, W, Mo, WN, Pt, Ni, and/or a combination thereof. The conductive oxide may include, for example, indium tin oxide (ITO), indium zinc oxide (IZO), and/or the like. However, the above are only examples.
Referring to
The semiconductor device 101 of
The high-k dielectric layer 170 may include a material having a higher permittivity than that of the insulating layer 130. The permittivity of the material constituting the high-k dielectric layer 170 may be greater than 13.1, for example. The high-k dielectric layer 170 may include a metal oxide formed by a suitable method such as metal organic chemical vapor deposition (MOCVD), physical vapor deposition (PVD), atomic layer deposition (ALD), molecular beam epitaxy (MBE), and/or the like. The high-k dielectric layer 170 may include a bulk (or three-dimensional) insulator, for example, HfO2 or ZrO2. The insulating layer 130 may act as an interlayer under the high-k dielectric layer 170, and in this case, the thickness of the insulating layer 130 may be, for example, greater than or equal to about 1 nm and less than or equal to about 2 nm. Since the high-k dielectric layer 170 has a relatively high permittivity and the insulating layer 130 having a high permittivity act as an intermediate layer in deposition, EOT scaling of the semiconductor device 101 may be further improved.
Referring to
The electrode layer 161 acts as a gate electrode. The electrode layer 161 may be referred to as a lower gate. In at least one embodiment, the electrode layer 161 may include a two-dimensional metal material (or a two-dimensional conductive material). For example, the electrode layer 161 may include graphene NbSe2, NbS2, TiS2, TiSe2, VS2, VSe2, and WTe2. However, the examples are not limited thereto.
The insulating layer 131 may be provided on the electrode layer 161. The insulating layer 131 corresponds to the insulating layer 130 described above, and therefore may include the materials given as examples as those of the insulating layer 130 described above. For example, the insulating layer 131 may include Sb2O3 which is lattice-matched with graphene, and this way, ensures epitaxial single-crystalline growth of the insulating layer 131 on the electrode layer 161 that includes the two-dimensional material. The insulating layer 131 may be formed on the electrode layer 161 through epitaxial growth. The insulating layer 131 formed through epitaxial growth may have the same (or substantially similar) crystal orientation as the electrode layer 161. Therefore, the insulating layer 131 may be deposited on the electrode layer 161 to prevent surface roughness scattering according to surface roughness of the electrode layer 161. The insulating layer 131 may be deposited on the electrode layer 161 to provide a flat platform for the semiconductor layer 120 arranged on the electrode layer 161.
The insulating layer 131 may be a single-crystal layer. By growing the insulating layer 131 as a single-crystal layer, there is no need to form an interlayer, and accordingly, the thickness of the insulating layer 131 may be reduced. The thickness of the insulating layer 131 may be, for example, greater than or equal to about 1 nm and less than or equal to about 5 nm. The thickness of the insulating layer 131 may be, for example, greater than or equal to about 2 nm and equal to or less than about 3 nm. In addition, since single-crystals have a relatively high permittivity, a high permittivity may be exhibited even with a small thickness, and thus, when the insulating layer 131 is deposited as a single-crystal layer, EOT scaling may be improved.
According to the semiconductor device 102 of the present examples, a layer-structured material is formed on a two-dimensional metal material using an epitaxial growth method. As such, a gate stack (a gate electrode and a gate insulating layer) may provide an atomically flat platform, for forming a semiconductor channel including a two-dimensional semiconductor material and/or a reduced thickness.
Referring to
The semiconductor device 103 may have a dual gate structure. The electrode layer 161 may act as a lower gate of the semiconductor device 103, and the gate electrode 160 may act as an upper gate of the semiconductor device 103. The semiconductor device 103 may exhibit improved device performance by simultaneously including the upper and lower gates.
The semiconductor devices 100, 101, 102, and 103 illustrated in
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Unlike other deposited thin films, the example Sb2O3 insulating layer grown on graphene (example Sb2O3/Gr) exhibits improved crystallinity as the thickness thereof becomes thinner. Since the Sb2O3 insulating layer tends to have a higher EBD as the thickness thereof decreases, and also has a strong EBD even at a thickness of 1 nm, EOT scaling may be improved by depositing an insulating layer including Sb2O3.
The semiconductor device of
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Accordingly, it may be confirmed that a high-performance FET may be obtained by using Sb2O3 insulating layer.
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The data storage unit 1200 may include a data storage unit used in a volatile or non-volatile memory device. The data storage unit 1200 may include, for example, a capacitor, and/or may include a magnetoresistive layer, a phase change layer, and/or the like. The electronic device 1000 may be referred to as a memory device.
Next, electronic devices according to at least one embodiment is described. Electronic devices according to at least one embodiment may include the semiconductor device or electronic device described above.
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In at least one example, the memory 2100 includes the electronic device of
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The controller 3100 may include at least one of a microprocessor, a digital signal processor, or a processing device similar thereto. The input/output device 3101 may include at least one of a touch screen, keypad, keyboard, display, speaker, and/or the like.
The memory 3102 is configured to store instructions executed by the controller 3100. For example, the memory 3102 may be used to store user data. The memory 3102 may include the semiconductor device of
The components included in the electronic system 3000, (e.g., the controller 3100, the input/output device (I/O) 3101, the memory 3102, and the wireless interface 3103), may include a switching element, and the switching element may include at least one of the semiconductor devices 100, 101, 102, and/or 103 according to the embodiments of
The electronic system 3000 may use the wireless interface 3103 to transmit/receive data over a wireless communication network. The wireless interface 3103 may include an antenna and/or a wireless transceiver. In some embodiments, the electronic system 3000 may be used in a communication interface protocol of a third generation communication system, for example, code division multiple access (CDMA), global system for mobile communications (GSM), north American digital cellular (NADC), extended-time division multiple access (E-TDMA), and/or wide band code division multiple access (WCDMA).
By epitaxially growing an insulating layer, the semiconductor device according to the disclosure may have improved performance even with a relatively small thickness.
The semiconductor device and the method of manufacturing the same have been described with reference to the embodiments shown in the drawings, but these are merely an example, and it will be understood by those skilled in the art that various modifications and equivalents thereto may be made. The disclosed embodiments should thus be considered in a descriptive sense only and not for purposes of limitation. The scope of the disclosure is defined not by the detailed description of the disclosure but by the appended claims, and all differences within the scope will be construed as being included in the scope of the disclosure.
According to the disclosed embodiments, the semiconductor device includes an insulating layer that is epitaxially grown on a two-dimensional material, and thus may have improved performance even with a relatively small thickness.
The semiconductor device described above may be used in memory devices.
It should be understood that embodiments described herein should be considered in a descriptive sense only and not for purposes of limitation. Descriptions of features or aspects within each embodiment should typically be considered as available for other similar features or aspects in other embodiments. While one or more embodiments have been described with reference to the figures, it will be understood by those of ordinary skill in the art that various changes in form and details may be made therein without departing from the spirit and scope as defined by the following claims.
Number | Date | Country | Kind |
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10-2023-0030198 | Mar 2023 | KR | national |