Embodiments of the present invention will be described hereinafter with reference to the accompanying drawings.
In the semiconductor device 101 illustrated in
In general, an SiGe thin film is formed by chemical vapor deposition (CVD) process, molecular beam epitaxy (MBE) process, or the like. When the strained SiGe layer 113 is formed, for example, by CVD process, an SOI substrate including the Si substrate 111, the insulating layer 112, and an Si layer is prepared, an SiGe layer is formed on the SOI substrate heated to 550° C. using a raw material Si gas and a raw material Ge gas, and oxidation in an oxygen atmosphere, such as an enrichment method (T. Tezuka et al., IEDM Tech. Dig., 946 (2001)), is performed, so that an SOI substrate including the Si substrate 111, the insulating layer 112, and the strained SiGe layer 113 is formed. Such an SOI substrate may be formed by forming the strained SiGe layer 113, using a bonding method, on the insulating layer 112 formed on the Si substrate 111, directly or via an insulating layer such as an oxide layer.
Although the strained semiconductor layer 113 is an SiGe layer here, the layer may be another semiconductor layer other than the SiGe layer. For example, the strained semiconductor layer 113 may be a semiconductor layer containing at least one of carbon (C), nitrogen (N), oxygen (O), silicon (Si), germanium (Ge), gallium (Ga), arsenic (As), indium (In), antimony (Sb), hafnium (Hf), tantalum (Ta), tungsten (W), nickel (Ni), platinum (Pt), and gold (Au). Examples of such a strained semiconductor layer 113 include an SiC layer, an SiN layer, an HfO2 layer, a GaN layer, a GaAs layer, and the like.
In the semiconductor device 101 illustrated in
The thickness of the thinned part of the Si substrate 111 is preferably in the range from 5 to 500 nm, particularly, in the range from 100 to 300 nm. The thickness of the thinned part is approximately 200 nm here. In addition, the Si substrate 111 included in the strain measuring region 121 may be removed only partially as shown in
Although the Si substrate 111 included in the strain measuring region 121 is removed here, the Si substrate 111 included in the strain measuring region 121 may be thinned. In this case, the thinned part of the Si substrate 111 included in the strain measuring region 121 is preferably as thick as not to disturb electron beam diffraction. The thickness of the thinned part is, for example, 300 nm or less, preferably, 10 nm or less. The Si substrate 111 included in the strain measuring region 121 may be thinned only partially or may otherwise be thinned entirely, like in the case of removal.
In strain measurement in the present embodiment, there are performed electron beam irradiation at the strain measuring region 121 and diffraction image measurement thereof. Specifically, an electron beam 201A of 10 nm in diameter is projected from the topside of the Si substrate 111 onto the top surface of the strained SiGe layer 113 in the strain measuring region 121, and a diffraction image (diffraction pattern image) 202A of the electron beam 201A is recorded in a diffraction image monitor at the backside of the Si substrate 111. Alternatively, the electron beam 201A may be projected from the backside of the Si substrate 111, and the diffraction image 202A may be recorded at the topside of the Si substrate 111.
In addition, in strain measurement in the present embodiment, there are performed electron beam irradiation at the reference information measuring region 122 and diffraction image measurement thereof. Specifically, an electron beam 201B of 10 nm in diameter is projected from the topside of the Si substrate 111 onto the top surface of the Si substrate 111 in the reference information measuring region 122, and a diffraction image (diffraction pattern image) 202B of the electron beam 201B is recorded in a diffraction image monitor at the backside of the Si substrate 111. Alternatively, the electron beam 201B may be projected from the backside of the Si substrate 111, and the diffraction image 202B is recorded at the topside of the Si substrate 111.
From the result of measurement of the diffraction image 202A, it is possible to evaluate the lattice constant or a variation in the lattice constant of the strained SiGe layer 113. In the present embodiment, the result of measurement of the diffraction image 202A is utilized to evaluate the strain of the strained SiGe layer 113. Likewise, from the result of measurement of the diffraction image 202B, it is possible to evaluate the lattice constant of the Si substrate 111. In the present embodiment, the result of measurement of the diffraction image 202B is utilized as reference information for evaluating the strain of the strained SiGe layer 113. Accordingly, in the present embodiment, it is possible to evaluate the strain of the strained SiGe layer 113 based on absolute value evaluation, by evaluating the diffraction image 202A of the strained SiGe layer 113 on the basis of the diffraction image 202B of the Si substrate 111 which can be regarded as being constant. Consequently, in the present embodiment, the strain of each semiconductor layer of each semiconductor device can be compared with the strain of another semiconductor layer of the same or a different semiconductor device.
Now, an explanation will be made, with regard to a method of evaluating the diffraction image 202A on the basis of the diffraction image 202B.
First, since a spot-to-spot distance of the diffraction image 202A in the “X” direction, Xa, is approximately 0.99 times the corresponding spot-to-spot distance of the diffraction image 202B, Xb, it is understood that in the irradiated region of the electron beam 201A, the lattice constant of the strained SiGe layer 113 in the “X” direction (see
Second, since the spot-to-spot distance of the diffraction image 202A in the “Z” direction, Za, is almost equal to the corresponding spot-to-spot distance of the diffraction image 202B, Zb, it is understood that in the irradiated region of the electron beam 201A, the lattice constant of the strained SiGe layer 113 in the “Z” direction (see
Accordingly, it is understood from
Although a method of relatively evaluating the lattice variation of strained SiGe against Si is explained in the present embodiment, it is possible to obtain the lattice constant of the strained SiGe from the lattice constant of the Si substrate if the lattice constant of the Si substrate is previously known. The lattice constant of Si, if measured using a regular X-ray diffraction method, can be easily determined to an accuracy of approximately five decimal digits. Therefore, it has an accuracy sufficient for determining the lattice constant of the measuring region, with an accuracy based on the electron beam diffraction of the present method (Δd/d˜0.1%: approximately four digits). Consequently, in a case where there is a remarkable lattice constant distribution in an Si substrate, such as if the Si substrate has a remarkable warpage, it is desirable that a standard lattice constant of the Si substrate be previously measured in the vicinity of an area where electron beam diffraction is caused.
Since the diffraction images 202A and 202B are two-dimensional images in the present embodiment, it is possible to evaluate the lattice constants of the strained SiGe layer 113 and the Si substrate 111 in the “X” and “Z” directions from the diffraction images 202A and 202B, as described above. Accordingly, in the present embodiment, the strain of each strained semiconductor layer of each semiconductor device can be evaluated separately in two directions. This is useful when, for example, only a uniaxial strain in one direction needs to be measured with regard to a region where the uniaxial strain is applied in two directions as shown in
Examples of a method for measuring a diffraction image for analysis include recording the diffraction image projected onto an image surface (such as a fluorescent plate) on a photographic paper or the like, and capturing the diffraction image in a charge-coupled device (CCD). Although an interval between diffraction spots varies depending on a distance between a sample and an image surface and on the acceleration energy of an electron beam, the interval is in the order of approximately millimeters to centimeters.
In the present embodiment, as a beam for strain measurement, a beam other than an electron beam, capable of measuring the lattice constant of a crystal lattice, may be used in place of an electron beam. For example, an X ray may be used in place of an electron beam. Alternatively, a neutron beam, an ion beam or an intense light beam, which can pass through the Si substrate 111 and is diffracted by a crystal lattice, may be used. The beam to be used is preferably such a beam as can accurately measure the lattice constant of a crystal lattice. In addition, the beam to be used is preferably such a beam as to enable obtaining two-dimensional diffraction images so that the strain of the strained SiGe layer 113 can be evaluated separately in two directions. The strain measuring region 121 and the reference information measuring region 122 are configured so that the beam to be used can pass therethrough and can be diffracted thereby. For example, when carrying out the present embodiment using a regular X-ray generator for laboratory use, it is important to enhance the degree of collimation of an X-ray beam using a crystal monochromator or the like and to minimize the diameter of the X-ray beam. The X-ray beam is required to have a degree of collimation as high as 10 milliradian in terms of a divergence angle and, more preferably, as high as 10e−1 milliradian.
Now, an explanation will be made, with regard to the measurement accuracy of the lattice constant d of the strained SiGe layer 113.
In the present embodiment, the electron beam 201A is projected perpendicular to the strained SiGe layer 113, the spot position of the diffraction image 202A is determined by the three-dimensional fitting of a spot shape and an intensity distribution, and the spot position of the diffraction image 202A is compared with that of the diffraction image 202B from the Si substrate 111; thereby, the lattice constant d of the strained SiGe layer 113 can be evaluated with an accuracy of approximately Δd/d˜±0.1%.
On the other hand, if the directions of incidence of the electron beams 201A and 201B are tilted from the vertical direction, three-dimensional diffraction images, such as Holts lines, can be obtained as the diffraction images 202A and 202B. Accordingly, in the present embodiment, it is possible to evaluate the lattice constant d of the strained SiGe layer 113, i.e., the strain of the strained SiGe layer 113, separately in three directions. In this case, the lattice constant d of the strained SiGe layer 113 can be evaluated with an accuracy of approximately Δd/d˜±0.02%. However, if the electron beams 201A and 201B are projected obliquely to the substrate surface (measuring plane), the spatial resolution is broadened depending on the angle of incidence. Especially, if the structure of elements positioned along the direction of entry of the electron beams 201A and 201B becomes uneven along with the advance of element miniaturization, it may become unable to obtain precise strain information. For this reason, the angles of incidence of the electron beams 201A and 201B are preferably perpendicular to the substrate surface (measuring plane) or otherwise no greater than 12 degrees.
The strain measuring region 121 and the reference information measuring region 122 of the present embodiment may be formed either before or after wafer dicing. In the former case, the process of forming the both regions and the process of strain measurement can be carried out as part of a so-called front-end process, and the result of the strain measurement based on the both regions can be reflected in the process of forming semiconductor elements (front-end process). Note that the strain measurement may also be carried out either before or after the wafer dicing.
As described above, in the present embodiment, it is possible to evaluate strains by absolute value evaluation and by separate evaluation in two or three directions. Accordingly, in the present embodiment, it is possible to efficiently set forward the consideration of conditions of a strain formation process and the failure analysis of semiconductor elements. Consequently, according to the present embodiment, it is possible to realize high-performance semiconductor elements more promptly than ever while applying a sufficient strain to a strained channel. This makes it possible to achieve cost reductions by shortening development period and speeding up quality control, and to appropriately meet the requirement of further miniaturization in the future.
In the semiconductor device 101 illustrated in
In the present embodiment, since the strained SiGe layer 113 is sandwiched between the insulating layer 112 adjacent to the bottom surface of the strained SiGe layer 113 and the insulating layer 114 adjacent to the top surface of the strained SiGe layer 113, the warpage of the strained SiGe layer 113 is constrained. Here, the top cross-sectional view of the strained SiGe layer 113 is shown in
The strain measurement of the semiconductor device illustrated in
Furthermore, it has turned out that strain measurement may become inaccurate in a case where the insulating layer 114 is absent, the thickness of the insulating layer 114 “T” is less than the thickness of the strained SiGe layer 113 “TSiGe”, or the thickness of the insulating layer 114 “T” is greater than twice the thickness of the insulating layer 112 “TBOX” (
The conditions that are preferably satisfied vary also depending on the strain, thickness, and size of the strained SiGe layer 113. For example, if the strain of the strained SiGe layer 113 is as small as 2 GPa or less, the overlying and underlying insulating layers may be thinned as much as possible. Specifically, even if the thickness of the underlying insulating layer 112 “TBOX” is no greater than 1 nm in terms of the thickness of silicon dioxide, accurate strain measurement may be feasible in some cases. In this case, the thickness of the overlying insulating layer 114 “T” preferably satisfies “T≧TBOX+1 nm” in terms of the thickness of silicon dioxide. The thickness of the strained SiGe layer 113 “TSiGe” is preferably no greater than 500 nm.
Furthermore, even if the member adjacent to the bottom surface of the strained SiGe layer 113 is not an insulating material, it is possible to prevent post-processing deformations in the strained SiGe layer 113. For example, the member adjacent to the bottom surface of the strained SiGe layer 113 may be a crystal layer (Si layer for example) or an amorphous layer. In this case, the total thickness of the underlying crystal layer and the overlying insulating layer is preferably no greater than 500 nm and, for practical purposes, no greater than 300 nm.
In the present embodiment, since the strained SiGe layer 113 is shaped in an island form, a convex portion 131 is formed in the insulating layer 114 above the strained SiGe layer 113 as illustrated in
Hence in the present embodiment, when forming the insulating layer 114 over the strained SiGe layer 113, the thickness of the insulating layer 114 “T” is made to be greater than “TSiGe+TBOX”. Then, the convex portion 131 formed at the time is planarized by chemical mechanical polishin (CMP), FIB processing, or etching, as shown in
Before entering into the description of the semiconductor device illustrated in
In the uniaxially-strained region 141, a uniaxial compressive strain is applied in the “Lg” direction, and a relaxed uniaxial strain is applied in the “Wg” direction. The uniaxially-strained region 141 corresponds to the channel region of a real transistor. It is the uniaxial compressive strain applied in the “Lg” direction that contributes to enhancing the carrier mobility of this channel region of the real transistor. Accordingly, an object of the present embodiment is to appropriately control this uniaxial compressive strain, which is the object of strain measurement.
At both ends of the strained SiGe layer 113 in the strained direction of the uniaxial compressive strain (Lg direction), there are respectively provided the first biaxially-strained region 142 and the second biaxially-strained region 143. The first and second biaxially-strained regions 142 and 143 are adjacent to the uniaxially-strained region 141. The first and second biaxially-strained regions 142 and 143 are provided so as to support the uniaxially-strained region 141 from both sides thereof, thereby maintaining the uniaxial compressive strain of the uniaxially-strained region 141. The uniaxial tensile strain of the uniaxially-strained region 141 is relaxed as there is no support on both sides thereof.
Now, the semiconductor device illustrated in
In the semiconductor device 101 illustrated in
Furthermore, in the semiconductor device 101 illustrated in
The strain measuring region 121 and the reference information measuring region 122 of the present embodiment are formed, after wafer dicing, by FIB processing from an edge. For this reason, it is concerned that the strain of the strained SiGe layer 113 may be relaxed because the Si substrate 111 included in the strain measuring region 121 has been processed. In the present embodiment, however, the strain of the strained SiGe layer 113 is maintained even after the Si substrate 111 included in the strain measuring region 121 is processed, since both ends of the strained SiGe layer 113 are supported by the sufficiently thick Si substrate 111. Accordingly, in the present embodiment, it is possible to measure strain accurately.
On the other hand, in the present embodiment, when forming the strain measuring region 121 and the reference information measuring region 122 before wafer dicing, it is only necessary that either the strain measuring region 121 is completely surrounded by the Si substrate 111 as viewed horizontally or both ends of the strained SiGe layer 113 are supported by the Si substrate 111. In this case, the strain measuring region 121 and the reference information measuring region 122 are formed by processing from the backside. Positioning at the time can be done in such a manner as using the coordinates of a wafer, using a mask or the like on which element-forming positions are recorded, or using transmitted light or reflected light based on a laser or the like.
According to the present embodiment, the strain of the strained SiGe layer 113 can be maintained in spite of substrate processing after wafer dicing. Therefore, it is possible to realize accurate, prompt strain measurement at a substrate level.
According to the present embodiment, it is possible to separate a strain distribution into strain distributions on at least two independent crystal axes and measure the strain distributions simultaneously. Consequently, according to the present embodiment, it is possible to realize a high-performance semiconductor device while applying a sufficient strain to a strained channel.
As an advantage in relation to the element-forming process of the present embodiment, it can be mentioned that strain evaluation can be performed in an in-process manner prior to wafer dicing, by previously preparing a strained channel in a part of a semiconductor device. Therefore, it is possible to more promptly realize the establishment of process conditions for manufacturing a high-quality, high-performance semiconductor device, which enables to constrain the development costs of semiconductor elements.
The present embodiment is also applicable to the semiconductor device 101 with such a structure in which the uniaxially-strained region 141 having a uniaxial strain being measured is replaced with a uniaxial strain detecting region for detecting the presence or absence of a uniaxial strain. Consequently, there is realized a structure suited for examining the presence or absence of a uniaxial strain.
The Si substrate 111 of the semiconductor device 101 illustrated in
As described above, in the present embodiment, a real transistor structure and a strain measuring structure are formed on the same Si substrate 111. The structure of the strain measuring region 121 may be identical to or different from that of the real MOSFET, and is only required to be appropriate for the contents of strain measurement to be carried out. When performing strain measurement after the completion of the transistor or after wafer dicing, the strain measuring region 121 and the reference information measuring region 122 may be formed immediately before strain measurement. However, when performing strain measurement in an in-process manner, the strain measuring region 121 and the reference information measuring region 122 are required to be previously formed midway through an element manufacturing process. The real transistor need not be completed by the time of strain measurement.
Now, an explanation will be made, with regard to the structures of the real transistor section 301 and the strain measuring section 302.
In the real transistor section 301, an island-shaped strained SiGe layer 113 is formed on the buried insulating layer 112 on the Si substrate 111, a gate insulating film 151 is formed on the strained SiGe layer 113, and a gate electrode 152 is formed on the gate insulating film 151. Also in the strained SiGe layer 113 of the real transistor section 301, there are provided a uniaxially-strained region 141, a first biaxially-strained region 142, and a second biaxially-strained region 143, as illustrated in
The configuration of the strain measuring section 302 is as described in the first, second and third embodiments. Note that on the strained SiGe layer 113 and the gate electrode 152 of the real transistor section 301 and on the strained SiGe layer 113 of the strain measuring section 302, there is formed a common interlayer insulating layer 114.
The ratio of the number of strained SiGe layers 113 included in the real transistor section 301 to the number of strained SiGe layers 113 included in the strain measuring section 302, on a single Si substrate 111, is about 1000:1 for example. It is only necessary that there be at least one strain measuring structure for one type of semiconductor element on a single semiconductor substrate. Preferably, it is only necessary that there be at least one measuring structure for each die (chip) disposed on a substrate.
First, as illustrated in
Next, as illustrated in
Next, as illustrated in
Next, as illustrated in
Next, as illustrated in
In the process of manufacturing the semiconductor device 101, a failure may occur in a transistor of the real transistor section 301. In the present embodiment, such a defective transistor may be diverted to a strain measuring region 121 of the strain measuring section 302.
In this case, there is no need for forming the strain measuring region 121 in
This technique has an advantage that a defective transistor can be put in effective use. This technique is effective when, for example, the circuit area of the semiconductor device 101 has no room for such a strain measuring region 121 as shown in
As described above, the embodiments of the present invention provide a structure preferred for strain measurement, with regard to a semiconductor device including a strained semiconductor layer.
Number | Date | Country | Kind |
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2006-265507 | Sep 2006 | JP | national |