This application is based on Japanese Patent Applications No. 2007-112784 filed on Apr. 23, 2007, and No. 2008-64209 filed on Mar. 13, 2008, the disclosures of which are incorporated herein by reference.
The present invention relates to a semiconductor device having multiple wiring layers.
A wiring of a LSI circuit is made of aluminum in a prior art. Recently, the wiring of the LSI circuit is made of copper so as to improve signal delay attributed to a capacitance between wirings and a wiring resistance. This is because that copper has a wiring resistance lower than that of aluminum.
A method for forming the wring made of copper is, for example, a copper dual damascene method, which is disclosed in JP-B2-3403058. In this method, an interlayer insulation film is formed on a semiconductor substrate. A wiring groove for forming an upper wiring is formed on the insulation film. A via hole for connecting the upper wiring and a lower wiring is formed in the insulation film. By supplying copper or copper alloy material for forming the wiring, the upper wiring is formed together with filling the via hole with the copper or the copper alloy material. Thus, a connection wiring in the via hole and the upper wiring are simultaneously formed.
Next, as shown in
As shown in
When the protection film 120 is made of P—SiN, adhesiveness between the protection film 120 and the copper wiring 118 is low, so that the protection film 120 may be removed from the copper wiring 118 by applying stress in the CMP process, and/or removed from the copper wiring 118 by a blister formed on the wiring 118. To improve the adhesiveness between the protection film 120 and the copper wiring 118, an anneal process, a plasma processing process and/or the like are necessary for reforming a surface of the copper wiring 118. Thus, a manufacturing method of the wiring is complicated. Further, a diffusion pass through a boundary between the copper wiring 118 and the protection film 120 may be formed, and therefore, the copper material in the copper wiring 118 may migrate. Thus, a life time of the copper wiring 118 is shortened.
Further, as shown in
Thus, it is required for the semiconductor device to prevent the copper material in the copper wiring 118 from penetrating into the interlayer insulation film 112.
In view of the above-described problem, it is an object of the present disclosure to provide a semiconductor device having multiple wiring layers.
According to a first aspect of the present disclosure, a semiconductor device includes: a semiconductor substrate; and a plurality of wiring layers staked on the substrate. Each wiring layer includes: an interlayer insulation film having a wiring groove with a via hole, which penetrates the interlayer insulation film along with a thickness direction of the interlayer insulation film; a copper wiring disposed in the wiring groove and the via hole and made of copper or copper alloy; an inner wall barrier metal layer disposed between an inner wall of the wiring groove with the via hole and the copper wiring; and an upper barrier metal layer disposed on the interlayer insulation film and covering an upper surface of the copper wiring. The inner wall barrier metal layer prevents a copper component in the copper wiring from diffusing into the interlayer insulation film. The plurality of wiring layers includes an upper layer and a lower layer. The copper wiring of the upper layer is electrically coupled with the copper wiring of the lower layer. The upper barrier metal layer of the lower layer prevents a copper component in the copper wiring of the lower layer from diffusing into the interlayer insulation film of the upper layer.
In the above device, the copper component in the copper wiring of the lower layer is prevented from diffusing into the interlayer insulation film in the upper layer. Further, a manufacturing method of the device is simple, so that a manufacturing cost is also small.
According to a second aspect of the present disclosure, a semiconductor device includes: a semiconductor substrate having a substrate wiring; and first and second wiring layers staked on the substrate in this order. The substrate wiring is disposed on a principal surface of the substrate. The first wiring layer includes: a first interlayer insulation film having a first wiring groove with a first via hole, wherein the first via hole penetrates the first interlayer insulation film along with a thickness direction of the first interlayer insulation film so that the first via hole reaches the substrate wiring on the substrate; a first copper wiring disposed in the first wiring groove and the first via hole; a first inner wall barrier metal layer disposed between an inner wall of the first wiring groove with the first via hole and the first copper wiring, and disposed on a part of the substrate wiring, wherein the part of the substrate wiring is exposed in the first via hole; and a first upper barrier metal layer disposed on the first interlayer insulation film and covering an upper surface of the first copper wiring. The second wiring layer includes: a second interlayer insulation film having a second wiring groove with a second via hole, wherein the second via hole penetrates the second interlayer insulation film along with a thickness direction of the second interlayer insulation film so that the second via hole reaches the first upper barrier metal layer in the first wiring layer; a second copper wiring disposed in the second wiring groove and the second via hole; a second inner wall barrier metal layer disposed between an inner wall of the second wiring groove with the second via hole and the second copper wiring, and disposed on a part of the first upper barrier metal layer, wherein the part of the first upper barrier metal layer is exposed in the second via hole; and a second upper barrier metal layer disposed on the second interlayer insulation film and covering an upper surface of the second copper wiring. The first inner wall barrier metal layer prevents a copper component in the first copper wiring from diffusing into the first interlayer insulation film, and the second inner wall barrier metal layer prevents a copper component in the second copper wiring from diffusing into the second interlayer insulation film. The second copper wiring is electrically coupled with the first copper wiring. The first upper barrier metal layer prevents a copper component in the first copper wiring from diffusing into the second interlayer insulation film.
In the above device, the copper component in the copper wiring of the first wiring layer is prevented from diffusing into the interlayer insulation film in the second wiring layer. Further, a manufacturing method of the device is simple, so that a manufacturing cost is also small.
The above and other objects, features and advantages of the present invention will become more apparent from the following detailed description made with reference to the accompanying drawings. In the drawings:
A semiconductor device 1 according to a first embodiment is shown in
In
The first wiring layer 33 is formed on the principal surface 10a of the substrate 10. The substrate 10 is made of a SOI substrate or the like. The first wiring layer 33 includes an interlayer insulation film 12, an inner wall barrier metal layer 15, a copper wiring 18 and an upper barrier metal layer 19.
A substrate wiring 11 for connecting to the CMOS element 31 and the LDMOS element 32 is formed on the principal surface 10a.
The insulation film 12 is made of a SiO2 film. Each insulation film 12 may have low dielectric constant so that the insulation film 12 reduces cross talk. In this case, the insulation film 12 is made of a low-k film. Thus, the insulation film 12 may be made of a TEOS film, a SiOC film, a FSG (i.e., fluorine-doped silicate glass) film, a PSG (i.e., phosphorus-contained silicate glass) film, a BPSG (i.e., boron and phosphorus-contained silicate glass) film or a SOG (i.e., spin on glass), film. Here, the SiOC film is a SiO2 film including a large amount of carbon.
The insulation film 12 includes a wiring groove 13 having a via portion 13a and a wiring portion 13b. The via portion 13a is filled with a connection member, which connects the substrate wiring 11 and the copper wiring 18. The wiring portion 13b is filled with a predetermined pattern wiring. The wiring groove 13 penetrates the insulation film 12. The wiring portion 13b covers the via portion 13a, and a width of the wiring portion 13b is larger than a width of the via portion 13a.
It is required for the LDMOS element 32 to reduce an on-state resistance so that the LDMOS flows a large amount of current. Thus, it is necessary to increase the thickness of the copper wiring 18. Accordingly, the thickness of the insulation film 12, in which the copper wiring 18 is formed, is in a range between 1.0 μm and 2.0 μm. In this embodiment, the thickness of the insulation film 12 is 1.5 μm.
The wiring groove 13 is filled with copper material or a copper alloy material so that the copper wiring 18 is formed. Specifically, the copper wiring 18 is formed on an inner wall of the wiring groove 13 through the inner wall barrier metal layer 15. The inner wall barrier metal layer 15 is a coating film having conductivity, which is formed by a sputtering method, CVD method or the like, so that the inner wall barrier metal layer 15 prevents the copper material in the copper wiring 18 from being diffused in the insulation film 12. In this embodiment, the inner wall barrier metal layer 15 is made of, for example, TaN.
The upper barrier metal layer 19 covers an upper surface 18a of the copper wiring 18. The upper barrier metal layer 19 is made of the same material as the inner wall barrier metal layer 15. The width of the upper barrier metal layer 19 is larger than the width of the upper surface 18a of the copper wiring 18.
The copper wiring 18 connects the LDMOS element 32 as a power device. The width of the copper wiring 18 becomes wider as it goes to an upper layer. Thus, the width of the upper barrier metal layer 19 in the LDMOS element 32 becomes wider as it goes to the upper layer. Specifically, the width of the copper wiring 18 in the third wiring layer 35 is larger than that in the second wiring layer 34, and the width of the copper wiring 18 in the second wiring layer 34 is larger than that in the first wiring layer 33. Thus, the width of the upper barrier metal layer 19 in the third wiring layer 35 is larger than that in the second wiring layer 34, and the width of the upper barrier layer 19 in the second wiring layer 34 is larger than that in the first wiring layer 33.
To minimize the dimensions of the device 1, a required wiring width in the CMOS element 31 is small. Thus, the width of the copper wiring 18 in the CMOS element 31 is set to be in a range between 0.5 μm and 1.0 μm.
Here, an aspect ratio of the copper wiring 18, i.e., a ratio between the thickness of the copper wiring 18 and the width of the copper wiring 18 is set to be equal to or smaller than two. In this case, embedding property such as embedding strength of the copper wiring 18 into the wiring groove 13 is improved.
Each of the second wiring layer 34 and the third wiring layer 35 includes the interlayer insulation film 12, the inner wall barrier metal layer 15, the copper wiring 18 and the upper barrier metal layer 19, so that the second and third wiring layers 34, 35 have substantially the same structure as the first wiring layer 33.
The second wiring layer 34 is formed on an upper surface of the first wiring layer 33, which is a lower layer of the second wiring layer 34. The upper surface 18a of the copper wiring 18 in the first wiring layer 33 and a lower portion of the copper wiring 18 in the second wiring layer 34 are electrically connected to each other through the upper barrier metal layer 19 and the inner wall barrier metal layer 15.
The third wiring layer 35 is formed on an upper surface of the second wiring layer 34, which is a lower layer of the third wiring layer 35. The upper surface 18a of the copper wiring 18 in the second wiring layer 34 and a lower portion of the copper wiring 18 in the third wiring layer 35 are electrically connected to each other through the upper barrier metal layer 19 and the inner wall barrier metal layer 15.
In the semiconductor device 1, the upper barrier metal layer 19 covers the upper surface 18a of the copper wiring 18. The copper material in the copper wiring 18 is prevented from diffusing into the insulation film 12.
The upper barrier metal layer 19 is not removed from the copper wiring 18 since adhesiveness between the copper wiring 18 and the insulation film 12 is strong.
Further, it is not necessary for forming a passivation film between the copper wiring 18 and the insulation film 12 to cover the upper surface 18a of the copper wiring 18. Accordingly, it is not necessary to add an anneal process, a plasma process or the like for reforming the upper surface 18a of the copper wiring 18.
The forming method of the copper wiring 18 will be explained as follows. Here, the copper wiring 18 for each of the CMOS element 31 and the LDMOS element 32 in each of the first to third wiring layers 33-35 is formed by the same method.
As shown in
As shown in
As shown in
As shown in
As shown in
As shown in
As shown in
As shown in
By repeating the above steps shown in
Although the device 1 includes three wiring layers 33-35, the device 1 may include at least one wiring layer or multiple wiring layers. The thickness of the insulation film 12 may be different from 1.5 μm.
In this embodiment, the width of the upper barrier metal layer 19 is larger than the width of the upper surface 18a of the copper wiring 18. As shown in
Accordingly, the insulation film 12 in the first wiring layer 33 is not etched excessively. Thus, erosion or migration attributed to coverage failure of the inner wall barrier metal layer 15 is prevented.
In this embodiment, the alignment accuracy of the wiring groove 13 is in a range between −0.05 μm and +0.05 μm. The width of the copper wiring 18 is 1.0 μm. Accordingly, 5% of deviation in the alignment of the wiring groove 13 may arise. Thus, preferably, the width of the upper barrier metal layer 19 may be larger than 105% of the width of the upper surface 18a of the copper wiring 18.
In a case where the width of the copper wiring 18 is smaller than 1.0 μm, even when the alignment deviates, the width of the upper barrier metal layer 19 is set to be larger than 105% of the width of the upper surface 18a of the copper wiring 18 so that the upper barrier metal layer 19 functions as an etching stopper layer.
Although the upper barrier metal layer 19 is made of TaN, the upper barrier metal layer 19 may be made of another material that prevents the copper material in the copper wiring 18 from diffusing into the insulation film 12, and that adhesiveness between the upper barrier metal layer 19 and the copper wiring 18 and adhesiveness between the upper barrier metal layer 19 and the insulation film 12 are strong. For example, the upper barrier metal layer 19 may be made of Ti, TiN, Ta, TiW, W, Ni, or Pd. The upper barrier metal layer 19 may be a multi-layer. Further, the inner wall barrier metal layer 15 may be made of material different from the upper barrier metal layer 19.
When the upper barrier metal layer 19 is made of Ni or Pd, the upper barrier metal layer 19 may be formed by a plating method. When the upper barrier metal layer 19 is formed by the plating method, the upper barrier metal layer 19 may be formed by a selective plating method. In this case, a resist is formed on the insulation film 12, and then, a plating layer corresponding to the upper barrier metal layer 19 is formed on the resist having a predetermined pattern. These steps are replaced to the steps shown in
Although the copper wiring 18 is formed by the dual damascene method, the copper wiring 18 may be formed by a single damascene method.
In the semiconductor device 1, the upper barrier metal layer 19 is formed to cover the upper surface 18a of the copper wiring 18. The copper material in the copper wiring 18 is prevented from diffusing into the insulation film, 12.
Further, the upper barrier metal layer 19 is not removed since the adhesiveness of the copper wiring 18 and the insulation film 12 is strong.
Furthermore, it is not necessary to form the passivation film between the copper wiring 18 and the insulation film 12, and thereby, it is not necessary to add the anneal process or the plasma process for improving the surface of the copper wiring 18.
Since the width of the upper barrier metal layer 19 is larger than the width of the upper surface 18a of the copper wiring 18, the upper barrier metal layer 19 functions as an etching stopper layer in a step for forming the wiring groove 13 in the insulation film 12 of the second wiring layer 34 by etching the insulation layer 12 toward the copper wiring 18 of the first wiring layer 33 even when the alignment of the wiring groove 13 deviates from a proper position so that the wiring groove 13 deviates from the upper surface 18a of the copper wiring 18 in the first wiring layer 33. Accordingly, the insulation film 12 in the first wiring layer 33 is not etched excessively. Thus, erosion or migration attributed to coverage failure of the inner wall barrier metal layer 15 is prevented.
A semiconductor device 1 according to a second embodiment is shown in
Each via wiring 18b, 18c is disposed over the upper surface 18a of the copper wiring 18 in the first wiring layer 33. Each via wiring 18b, 18c is electrically connected to the copper wiring 18 in the first wiring layer 33. Thus, even when one of the via wirings 18b, 18c is broken so that the one has open circuit failure, the other via wiring 18b, 18c is electrically connected to the copper wiring 18 in the first wiring layer 33. Thus, electrical connection of the copper wiring 18 property functions.
Further, the copper wiring 18 in the second wiring layer 34 is connected to the copper wiring 18 in the first wiring layer 33 through the via wirings 18b, 18c such that connection by using the via wirings 18b, 18c provides parallel connection resistance. Thus, the resistance at the connection by the via wirings 18b, 18c is reduced.
In a case where the insulation film 12 in the second wiring layer 34 is etched toward the copper wiring 18 in the first wiring layer 33 so that the wiring groove 13 in the second wiring layer 34 is formed, even when the alignment of the groove 13 deviates from a proper position, one of the via wirings 18b, 18c is arranged on the upper surface 18a of the copper wiring 18 in the first wiring layer 33, and thereby, the copper wiring 18 in the second wiring layer 34 is electrically connected to the copper wiring 18 in the first wiring layer 33.
Although the copper wiring 18 in the second wiring layer 34 includes two via wirings 18b, 18c, the copper wiring 18 may have three or more via wirings. For example, as shown in
Even when the via wirings 18b, 18c are not disposed directly above the upper surface 18a of the copper wiring 18, as shown in
In this embodiment, in a case where the insulation film 12 in the second wiring layer 34 is etched toward the copper wiring 18 in the first wiring layer 33 so that the wiring groove 13 in the second wiring layer 34 is formed, even when the alignment of the groove 13 deviates from a proper position, one of the via wirings 18b, 18c is arranged on the upper surface 18a of the copper wiring 18 in the first wiring layer 33, and thereby, the copper wiring 18 in the second wiring layer 34 is electrically connected to the copper wiring 18 in the first wiring layer 33.
Even when one of the via wirings 18b, 18c is broken so that the one has open circuit failure, the other via wiring 18b, 18c is electrically connected to the copper wiring 18 in the first wiring layer 33. Thus, electrical connection of the copper wiring 18 property functions.
Even when the via wirings 18b, 18c are not disposed directly above the upper surface 18a of the copper wiring 18, as shown in
(Modifications)
The upper barrier metal layer 19 may be made of insulation material such as Al2O3, AlN by a sputtering method, a CVD method or the like.
In this case, when the wiring groove 13 in an upper wiring layer is formed by a photo lithography method and an etching method, a part of the upper barrier metal layer 19 covering the upper surface 18a of the copper wiring 18 is removed, so that the upper surface 18a of the copper wiring 18 is exposed from the layer 19. Thus, the copper wiring 18 in the upper wiring layer is electrically connected to the upper surface 18a of the copper wiring 18 in the lower wiring layer.
The upper surface 18a of the copper wiring 18 may be processed by a plasma processing method so that the upper surface 18a is reformed. For example, by using a nitrogen plasma processing method, the upper surface 18a of the copper wiring 18 is nitrided so that the upper surface 18a is stabilized. Alternatively, a N ion or a B ion is implanted on the upper surface 18a, and then, the upper surface 18a is annealed so that the upper surface 18a is reformed.
In the above cases, adhesiveness between the upper surface 18a of the copper wiring 18 and the upper barrier metal layer 19 is much improved.
While the invention has been described with reference to preferred embodiments thereof, it is to be understood that the invention is not limited to the preferred embodiments and constructions. The invention is intended to cover various modification and equivalent arrangements. In addition, while the various combinations and configurations, which are preferred, other combinations and configurations, including more, less or only a single element, are also within the spirit and scope of the invention.
Number | Date | Country | Kind |
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2007-112784 | Apr 2007 | JP | national |
2008-64209 | Mar 2008 | JP | national |