1. Field of the Invention
The present invention relates generally to a semiconductor device, and particular to a semiconductor device having a transistor formed on the (551) surface of a silicon semiconductor substrate.
2. Description of the Related Art
Conventionally, transistors have enhanced the performance mainly by shortening a channel length L and thinning the gate insulating film. However, along with the decrease in the channel length L, the problem of variations in the transistor threshold has become conspicuous. In addition, along with the decrease in the thickness of the gate insulating film, an increase in the off leakage current has become problematic. That is, it is essential today to improve the performance of the transistor itself. In particular, reduction of the series resistance of a transistor is expected to yield a large effect for improving the performance, and several researches have recently been conducted.
The present inventors have also published a prior-art research in, for example, IEICE Technical Report, “Low Resistance Source/Drain Contacts with Low Schottky Barrier for High Performance Transistors” (SDM2010-157) (NPL 1). In NPL 1, the present inventors proposed a method of reducing the series resistance of the transistor, and implements a silicide having a Schottky barrier height (to also be abbreviated as “SBH” hereinafter) of 0.3 eV for a p+-type region and an n+-type region.
The components of the series resistance of the transistor include the resistance of the heavily doped layer region of the source/drain regions and the contact resistance between the heavily doped layer region and the silicide layer region. The impurity concentration of the heavily doped layer region is close to the theoretical value. Reduction of the resistance of the heavily doped layer region has shifted to the challenge upon the manufacturing process associated with how to maximize activation of an impurity. Reduction of the contact resistance between the heavily doped layer region and the silicide layer region essentially depends on how to reduce the barrier height between the silicide layer region and the heavily doped layer region, as described in NPL 1.
a shows the simulation result of the contact resistivity and the saturation drain current.
The contact width (the width in the same direction as the channel length direction) of each of the silicide regions of the source electrode and the drain electrode is 45 nm, and the electron/hole density of the source region/drain region is 2×1020 cm−3. As is apparent, when the contact resistivity exceeds 1×10−9 Ωcm2, the current driving capability lowers accordingly. Hence, how to reduce the contact resistivity to 1×10−9 Ωcm2 or less is the factor to increase the current driving capability.
On the other hand, the silicide layer region is formed at the same time as the activation of the heavily doped layer region by providing a metal layer on the heavily doped layer region and performing annealing on it. Depending on the metal used for silicidation, the silicide in the formed silicide layer region may be oxidized, and the resistance may rise. To solve this problem, the present inventors have showed that a silicide layer region having a satisfactory contact resistivity can be formed by providing a second metal layer different from the silicidation metal, and more specifically, a tungsten (W) layer on the metal layer to be silicidized (for example, Japanese Patent Laid-Open No. 2010-109143 (PLT 1)).
According to the first embodiment of the present invention, a semiconductor device comprises: an n-type transistor formed on a (551) surface of a silicon substrate, wherein a silicide layer region in contact with a diffusion region (heavily doped region) of the n-type transistor has a thickness not more than 8.5 nm, a metal layer region in contact with the silicide layer has a thickness of 25 nm (inclusive) to 400 nm (inclusive), and a barrier height between the silicide layer region and the diffusion region has a minimum value in this thickness relationship.
According to the second embodiment of a present invention, a semiconductor device has the n- type transistor formed on the (551) surface of silicon, wherein a silicide layer in contact with a diffusion region of the n-type transistor has a thickness of 2 nm (inclusive) to 8.5 nm (inclusive).
According to the third embodiment of a present invention, the silicide layer has a thickness of 2 nm (inclusive) to 8.5 nm (inclusive) in the semiconductor device according to the first embodiment.
Other features and advantages of the present invention will be apparent from the following descriptions taken in conjunction with the accompanying drawings, in which like reference characters designate the same or similar parts throughout the figures thereof.
The accompanying drawings, which are incorporated in and constitute a part of the specification, illustrate embodiments of the invention and, together with the description, serve to explain the principles of the invention.
a is a schematic explanatory view for explaining the contact resistivity dependence of the current driving capability (saturation drain current) per 1-μm channel width of a transistor having a channel length of 45 nm;
b is a schematic explanatory view for explaining the contact resistivity dependence of the current driving capability (saturation drain current) per 1-μm channel width of the transistor having the channel length of 45 nm;
a is a schematic sectional explanatory view for explaining a manufacturing step a of a semiconductor device according to a preferable embodiment of the present invention by example;
b is a schematic sectional explanatory view for explaining a manufacturing step b of the semiconductor device according to the preferable embodiment of the present invention by example;
c is a schematic sectional explanatory view for explaining a manufacturing step c of the semiconductor device according to the preferable embodiment of the present invention by example;
d is a schematic sectional explanatory view for explaining a manufacturing step d of the semiconductor device according to the preferable embodiment of the present invention by example;
e is a schematic sectional explanatory view for explaining a manufacturing step e of the semiconductor device according to the preferable embodiment of the present invention by example;
f is a schematic sectional explanatory view for explaining a manufacturing step f of the semiconductor device according to the preferable embodiment of the present invention by example;
g is a schematic sectional explanatory view for explaining a manufacturing step g of the semiconductor device according to the preferable embodiment of the present invention by example;
h is a schematic sectional explanatory view for explaining a manufacturing step h of the semiconductor device according to the preferable embodiment of the present invention by example;
i is a schematic sectional explanatory view for explaining a manufacturing step i of the semiconductor device according to the preferable embodiment of the present invention by example;
j is a schematic sectional explanatory view for explaining a manufacturing step j of the semiconductor device according to the preferable embodiment of the present invention by example;
k is a schematic sectional explanatory view for explaining a manufacturing step k of the semiconductor device according to the preferable embodiment of the present invention by example;
l is a schematic sectional explanatory view for explaining a manufacturing step l of the semiconductor device according to the preferable embodiment of the present invention by example;
m is a schematic sectional explanatory view for explaining a manufacturing step m of the semiconductor device according to the preferable embodiment of the present invention by example; and
n is a schematic sectional explanatory view for explaining a manufacturing step n of the semiconductor device according to the preferable embodiment of the present invention by example.
No matter whether in the technique of NPL 1 or that of PLT 1, there exist problems in no small numbers which need to be progressively subjected to research and development and solved from the practical point of view of transistors with ultimate performance.
The present invention has been made upon perceiving the above-described problems. Some emdodiments provide a technique advantageous for improving the operating speed of an integrated circuit.
Progressive and diligent studies solve the above-described problems to further improve the techniques of NPL 1 and PLT 1.
The present invention is based on research and development from such a viewpoint. Some embodiments provide a semiconductor device in which a lower barrier height is formed by setting the thickness of a second metal layer within a specific thickness range.
The present invention is based on findings in the course of the research and development about the facts that the barrier height is closely related with the thickness of the layer of the second metal such as tungsten, and the silicide formation metal and the second metal suitable for silicidation of the metal hold a relationship to minimize the barrier height.
According to some embodiments, the operating speed of the transistor dramatically improves. When forming an integrated circuit, the individual transistors constituting the integrated circuit have a uniform operating speed, and an integrated circuit suitable for a high-speed operation can be formed.
Special consideration is required for a silicide layer for an electrical contact formed on the (551) surface of a silicon substrate. In a silicide layer formed on the (551) surface of a silicon substrate in an n-type region, for example, an erbium silicide layer and a holmium silicide layer, the barrier height tends to be higher than in a palladium silicide layer formed on the (551) surface of the silicon in a p-type region, as pointed out by the present inventors in NPL 1 described above. In addition, a silicide layer formed on the (551) surface of the silicon substrate in the p-type region, for example, a palladium silicide layer cannot be even and coagulates unless it is thick to some extent, as pointed out by the present inventors in NPL 1 described above.
The above-described barrier height difference between the (100) surface and the (551) surface is assumed to occur because the surface density of silicon atoms is lowest at 6.8×1014 cm−2 on the (100) surface of silicon but highest at 9.7×1014 cm−2 on the (551) surface. The atomic radii of silicon (Si), palladium (Pd), erbium (Er), and holmium (Ho) are 0.117 nm, 0.13 nm, 0.175 nm, and 0.174 nm, respectively. As indicated by these numerical values, erbium and holmium atoms have very large radii. When a silicide layer is formed using erbium or holmium on the (551) surface of the silicon substrate with a high atomic surface density, very large stress occurs. This stress probably raises the barrier height of the silicide formed on the (551) surface.
a illustrates the contact resistivity dependence of the current driving capability (saturation drain current) per 1-μm channel width of a transistor having a channel length of 45 nm.
To implement a contact resistivity of 1×10−9 Ω cm2 and further improve the current driving capability of the transistor, the barrier height of 0.43 eV or less is obtained by setting the thickness of the erbium silicide layer to 8.5 nm or less. It was experimentally confirmed that when the thickness of the erbium silicide layer is smaller than 2 nm, no excellent erbium silicide layer can be formed. The reason for this still remains in the realm of speculation. Realistically, it was experimentally confirmed that when the thickness is 2.5 nm or more, the erbium silicide layer can be formed stably and reproducibly.
As for the upper limit of the thickness, an erbium silicide layer too thick is not preferable from the viewpoint of production efficiency. If the erbium silicide layer is too thick, the distortion of the layer itself exerts an influence, leading to a tendency to difficulty in forming an appropriate barrier height. Experimental examinations reveal that the upper limit of the thickness of the erbium silicide layer is 8.5 nm when the upper limit of the barrier height is allowed to be 0.43 eV.
In the present embodiment, the thickness of the erbium silicide layer is appropriately selected in consideration of the above-described points. The erbium silicide layer is formed on the (551) surface of an n-type silicon substrate to the thickness of preferably 2 nm (inclusive) to 8.5 nm (inclusive), more preferably, 2.5 nm (inclusive) to 6 nm (inclusive), and still more preferably, 2.5 nm (inclusive) to 4 nm (inclusive).
In the present embodiment, when forming a silicide layer region using a metal such as erbium, a refractory metal layer is formed in contact with a heavily doped region (diffusion region) in advance for the silicide layer region formation. The refractory metal layer assists forming a satisfactory electrical contact between the heavily doped region and the silicide layer region by relaxing or preventing distortion that occurs in the silicide layer region when annealing is performed to make the metal in the silicide formation metal layer and silicon in the heavily doped region dissolve with each other to form the silicide layer region. As a result, the barrier height formed between the heavily doped region and the silicide layer region is lower than in a case in which no refractory metal layer is provided, and the current driving capability of the formed transistor considerably improves.
As the metal used to form the refractory metal layer, a metal that does not dissolve or mix with the metal contained in the silicide layer region upon annealing is preferably selected. In addition, a metal that has excellent heat resistance and also provides an excellent oxygen permeation inhibition capability such that the silicide layer region does not oxidize due to the influence of heat during silicidation annealing or another annealing process is selected. In the present embodiment, tungsten (W) is employed as this refractory metal.
The thickness of the tungsten (W) layer and SBH of each sample are as follows.
This result shows that to obtain a barrier height of 0.43 eV or less, the thickness of the tungsten (W) layer needs to be 10 nm or more, and the practical upper limit is preferably 300 nm. In addition, according to the experiments of the present inventors, the SBH has the minimum value when the thickness of the tungsten (W) layer is 25 nm to 150 nm, and the upper limit of the thickness of the tungsten (W) layer is more preferably 150 nm or less considering that a lower SBH can be formed.
The above-described points also apply even when a silicide layer of holmium having an almost the same atomic radius as erbium is formed on the (551) surface of the n-type silicon substrate in place of the erbium silicide layer.
a to 5n are schematic sectional explanatory views for explaining the manufacturing steps (steps a to n) of a semiconductor device according to a preferable embodiment of the present invention by example.
A method of manufacturing the semiconductor device SD according to the preferred embodiment of the present invention will be described below with reference to
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The semiconductor device SD formed by the above-described steps has an arrangement with n- and p-type transistors formed on the (551) surface of the silicon substrate.
In the present invention, expression “the transistor is formed on the (551) surface” means that some (for example, gate oxide film) of the elements of the transistor are formed on the (551) surface. The n-type transistor can typically be an NMOS transistor, and the p-type transistor can typically be a PMOS transistor. The arrangement shown in
An example has representatively been described above in which the n-type transistor is an NMOS transistor, and the p-type transistor is a PMOS transistor. However, this does not intend that the present invention is limited to this arrangement.
The NMOS transistor includes, for example, the diffusion regions 103a′ including the source region and the drain region, the silicide layers 150, 150 in contact with the source region and the drain region in the diffusion region 103a′, the metal electrodes 144, 144 in contact with the upper surfaces of the silicide layers 150, 150, a gate insulating film 104′, and the gate electrode 105. The silicide layer 150 and the metal electrode 144 form a contact portion to the diffusion region 103a′. The PMOS transistor includes, for example, the diffusion regions 103b′ including the source region and the drain region, the silicide layers 120, 120 in contact with the source region and the drain region in the diffusion region 103b′, the metal electrodes 130, 130 in contact with the upper surfaces of the silicide layers 120, 120, the gate insulating film 104′, and the gate electrode 105. The silicide layer 120 and the metal electrode 130 form a contact portion to the diffusion region 103b′. The diffusion regions 103a′ and 103b′ may be formed on the insulator 102, as illustrated in
A thickness t1 of the silicide layers 150 of the NMOS transistor is preferably smaller than a thickness t2 of the silicide layers 120 of the PMOS transistor. The thickness t2 of the silicide layers 120 of the PMOS transistor is preferably, for example, 10 nm or more.
In the present invention, the (551) surface means not only the physically strict (551) surface but includes also a surface having an off angle of 4° or less with respect to the physically strict (551) surface.
Note that at the current point of time, to clarify the difference from an unknown related art, the present inventors may limit the definition of the (551) surface to a surface having an off angle equal to or smaller than an arbitrary angle such as 3° or less, 2° or less, 1° or less, or 0.5° or less with respect to the physically strict (551) surface after patent application.
The present invention is not limited to the above embodiments and various changes and modifications can be made within the spirit and scope of the present invention. Therefore, to apprise the public of the scope of the present invention, the following claims are made.
100 . . . SOI substrate
101 . . . silicon region
102 . . . insulator
103 . . . SOI layer
103
a . . . n-type well
103
b . . . p-type well
103
a′, 103b′. . . diffusion region
104 . . . gate insulating film
105 . . . gate electrode
106 . . . hard mask
112 . . . palladium film
120 . . . palladium silicide layer
130 . . . metal electrode
135 . . . silicon nitride film
140 . . . erbium film
142 . . . tungsten film
144 . . . metal electrode
150 . . . erbium silicide layer
165 . . . silicon nitride film
170 . . . oxide film
180 . . . palladium silicide layer
This application is a continuation of International Patent Application No. PCT/JP2012/002447 filed on Apr. 6, 2012, the entire content of which is incorporated herein by reference.
Number | Date | Country | |
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Parent | PCT/JP2012/002447 | Apr 2012 | US |
Child | 14501244 | US |