This patent application claims the priority of German patent application 10 2006 046 297.1 filed Sep. 29, 2006, the disclosure content of which is hereby incorporated by reference.
The invention relates to a semiconductor laser, in particular to a single-mode semiconductor laser.
Lasers having good beam quality, high coherence length and small spectral width are desirable or even necessary for many applications. These properties can be obtained in particular with single-mode lasers such as, for example, DFB lasers, surface emitting semiconductor lasers (VCSEL—Vertical Cavity Surface Emitting Laser) or ridge lasers.
The patent specification U.S. Pat. No. 6,711,197 B2 describes a ridge laser having a p-type cladding layer composed of AlGaN, wherein an SiO2 film and an Si film disposed downstream of the SiO2 film for absorption of higher modes are arranged on the p-type cladding layer.
In the case of the laser described, the SiO2 film must be sufficiently thin in order that higher modes can reach right into the Si film and be absorbed. The small thickness of the SiO2 film can have a disadvantageous effect on the electrical properties; in particular, the breakdown strength can be reduced or leakage currents can occur.
It is an object of the present invention to provide a semiconductor laser which supplies a comparatively high beam quality in conjunction with improved electrical properties.
This and other objects are attained in accordance with one aspect of the present invention directed to a semiconductor laser comprising a semiconductor layer sequence having an active zone for generating electromagnetic radiation, and an absorber zone for attenuating higher modes, wherein the absorber zone is arranged within the semiconductor layer sequence or adjoins the semiconductor layer sequence.
Higher modes of 1st and 2nd order occur, in particular, without an absorber zone. In an advantageous manner, the proportion of the higher modes can be significantly reduced by means of the absorber zone and the beam quality can thus be correspondingly improved. The respective measures proposed in the context of the invention for absorption of the higher modes are preferably not mode-specific, but rather are suitable for the higher modes that occur overall.
The semiconductor laser according to the invention can be produced in two embodiments: as an edge emitting semiconductor laser or a surface emitting semiconductor laser. In the case of the edge emitting semiconductor laser, the emission takes place in the extension direction of the pumped active zone and the laser radiation emerges via the lateral flanks of the active zone. In the case of the surface emitting semiconductor laser, the laser radiation emerges at right angle to the pumped active zone.
The active zone can have, for example, a pn junction, a double heterostructure, a single quantum well or particularly preferably a multiple quantum well structure (MQW). Such structures are known to the person skilled in the art and are therefore not explained in any greater detail here. Examples of MQW structures are described in the documents U.S. Pat. No. 6,849,881, U.S. Pat. No. 6,172,382, U.S. Pat. No. 5,831,277, and U.S. Pat. No. 5,684,309, the disclosure content of all of which relating to the MQW structures is hereby incorporated by reference.
In accordance with one preferred variant, the absorber zone has an absorbing material.
In accordance with a further preferred variant, the absorbing material is an oxide or nitride, in particular an ITO or an oxide or nitride of Si, Ti, Al, Ga, Nb, Zr, Ta, Hf, Zn, Mg, Rh, In. These materials are particularly suitable in the case of a semiconductor laser based on nitride compound semiconductors, as is preferred in the context of the invention.
In the present connection, “based on nitride compound semiconductors” means that at least one layer of the semiconductor layer sequence comprises a nitride compound semiconductor material, preferably AlnGamIn1-n-mN, where 0≦n≦1, 0≦m≦1 and n+m≦1. In this case, said material need not necessarily have a mathematically exact composition according to the above formula. Rather, it can have one or a plurality of dopants and also additional constituents which do not substantially change the characteristic physical properties of the AlnGamIn1-n-mN material. For the sake of simplicity, however, the above formula comprises only the essential constituents of the crystal lattice (Al, Ga, In, N) even though these can be replaced in part by small quantities of further substances.
Preferably, the radiation emitted by the semiconductor laser has a wavelength in the ultraviolet, blue or green spectral range.
Preferably, the absorptance of the absorber zone is set by means of the material composition. In particular, the composition of the absorbing material is non-stoichiometric. This means that there is no stoichiometry present with regard to the material composition, that is to say that a composition does not follow quantitative laws. While the composition SiO2 can be referred to as stoichiometric, SiO1.6, a composition that is preferred in the present case, is non-stoichiometric.
In an advantageous manner, in the variant mentioned, the material composition or the absorptance can also be changed subsequently, that is to say for example after the production of the semiconductor laser or first measurements of the beam quality. In particular, a greatly absorbing material such as Si can be oxidized in a specific manner and the absorptance can thereby be reduced. This has the advantage, for example, that a plurality of semiconductor lasers can be produced together and subsequently be configured correspondingly depending on the requirement (for example with a low threshold current or high secondary mode suppression).
This advantage is also afforded in a further configuration, in which the absorber zone has an absorbing doped semiconductor material. The absorptance in this case can be set by means of the doping. Since the band gap of the semiconductor material can be varied by means of the doping, it is possible to choose the band gap in such a way that higher modes are absorbed, while the fundamental mode is amplified in the semiconductor laser and finally coupled out. In the semiconductor laser according to an embodiment of the invention, the absorber zone is doped with Mg. Suitable semiconductor materials are a semiconductor material based on phosphide, arsenide or nitride, Si or Ge.
As an alternative, the semiconductor material is undoped. By way of example, the semiconductor material can be AlnGamIn1-n-mP, AlnGamIn1-n-mAs or AlnGamIn1-n-mN, where 0≦n≦1, 0≦m≦1 and n+m≦1. In this case, the band gap and hence the absorptance in the absorber zone can likewise be set by means of the material composition of the semiconductor material, in particular by variation of the In and/or Al proportion.
In accordance with one preferred configuration, the absorber zone comprises a dielectric material. In particular, the dielectric material can be an oxide or nitride, as listed above.
In accordance with another preferred configuration, the absorber zone is electrically insulating. As a result, the absorber zone can advantageously additionally serve as passivation for preventing breakdowns or leakage currents. The absorber zone can have, for example, silicon nitride in a region facing the active zone and silicon oxide in a region remote from the active zone. In the case of silicon nitride, a non-stoichiometric material composition can be obtained in a simple manner and the absorptance can advantageously be set thereby. By contrast, silicon oxide is suitable for passivation.
In particular, the electrically insulating absorber zone can serve as a current baffle. The current injection into the semiconductor laser can thus be limited to a desired region.
In a further embodiment, absorbing inclusions are admixed with the absorber zone. The inclusions are expediently suitable for attenuating or absorbing higher modes.
The absorptance of the absorber zone can be set by means of the proportion of the inclusions. Since differences in the optical properties of the semiconductor lasers can occur on account of production, a settable absorptance is particularly advantageous.
The inclusions can be atoms, clusters or particles which comprise or consist of a metal, semiconductor material or organic material. In particular, the inclusions can comprise or consist of Ti, Pt, Si or C.
The absorber zone comprising the inclusions can contain an oxide or nitride, in particular an ITO or an oxide or nitride of Si, Ti, Al, Ga, Nb, Zr, Ta, Hf, Zn, Mg, Rh, In or a polyimide.
The absorptance can be set by means of the proportion of the inclusions.
Furthermore, the absorber zone can have a super lattice formed from a sequence of at least one layer containing an absorbing material and at least one layer containing a less absorbing material. For example, Si can be used as absorbing material and an oxide or nitride, as listed above, as less absorbing material.
Furthermore, the absorptance of the absorber zone can be set by means of diffusion of absorber material into the absorber zone or from the absorber zone. This variant makes it possible to regulate the overlapping of the absorber zone with the radiation field of the semiconductor laser. By means of a diffusion of the absorber material nearer to the active zone, the overlapping with the radiation field can be increased, whereby a greater absorption can be obtained. Conversely, by means of a diffusion of the absorber material away from the radiation field, a reduction of the overlapping with the radiation field can be effected, whereby a lower absorption takes place. In this case, there is the possibility of thermally and/or electrically supporting or controlling the diffusion.
In one particular configuration of the semiconductor laser, the absorber zone is structured. By means of the structuring, the absorption in the absorber zone can be reduced on account of the reduction of the absorbing area in comparison with a whole-area application. This is advantageous particularly in the case of a greatly absorbing material. By way of example, the absorber zone can have a point-type, strip-type or field-line-like structure. Furthermore, single or multiply repeating structures are conceivable. The absorber zone can firstly be applied over the whole area and subsequently be structured or be applied already in structured fashion. The latter is advantageous in the case of resonator mirrors, for example, because this means that damage or contamination of the resonator mirrors by subsequent structuring can be prevented. In an advantageous manner, the absorption of individual transverse and/or longitudinal modes can be set in a specific manner by structured application or by alteration of the spatial distribution of the absorber material.
In the case of an array of semiconductor lasers, in which a semiconductor laser arranged in the center typically becomes warmer during operation than a semiconductor laser arranged at the edge, the different operating conditions can be taken into account by means of differently configured absorber zones.
In accordance with one embodiment of the semiconductor laser, the absorber zone is a mask layer used for epitaxial lateral overgrowth (ELOG). The ELOG method is advantageous particularly in the case of an absorber zone arranged within the semiconductor laser sequence, since it is thereby possible to incorporate a zone into the semiconductor layer sequence which contains a material that differs from the semiconductor material used for the semiconductor layer sequence. The absorber zone serving as ELOG mask layer can be applied by sputtering or vapor deposition and structured. After the production of the absorber zone, the semiconductor layer sequence is grown further.
The configurations described below are suitable particularly in the case of an absorber zone adjoining the semiconductor layer sequence.
In a particular embodiment, the absorber zone is formed from a layer terminating the semiconductor layer sequence by means of altering the crystal structure of the semiconductor layer sequence. As a result, the absorber zone has altered absorption properties in comparison with the semiconductor layer sequence. By way of example, the crystal structure can be altered by means of plasma or temperature action. Plasma damages or absorption centers arise in this case. In the case of GaN, Ga absorption centers are formed for example by evaporation of N2.
Furthermore, the absorber zone can be formed from a metal layer. In particular, the metal layer is applied to the semiconductor layer sequence. However, it is also conceivable to implant or indiffuse a metal as absorber material into the semiconductor layer sequence.
The metal layer can contain a metal having a low work function, for example Ti, Al or Cr. As a result, the metal layer is not suitable as an electrical contact, and no current injection or pumping of the active zone takes place in the region of the absorber zone.
In accordance with one variant of the semiconductor laser, an electrical insulation layer is arranged on a side of the absorber zone that is remote from the semiconductor layer sequence. In particular, the electrical insulation layer is provided for improving the electrical properties of the semiconductor laser independently of the absorption effect of the absorber zone adjoining the semiconductor layer sequence.
The insulation layer further preferably has a different refractive index than the absorber zone. In an advantageous manner, given a sufficiently thin absorber zone, the penetration depth of the radiation field into the electrical insulation layer can be set by way of the refractive index thereof, whereby the overlapping of the radiation field with the absorber zone and hence the absorption effect thereof can in turn be set. By way of example, the refractive index can be altered by oxidation of the material used for the absorber zone.
For different degrees of attenuation of different modes, a gradual or stepped change in the absorptance can be produced both by means of the material composition in the absorber zone and by means of suitable structuring of the absorber zone. By way of example, the structures of the absorber zone can be distributed in varying density, such that regions of a mode which lie further outward are absorbed to a greater extent.
In a further embodiment, the absorber zone has a metal contact for electrically setting the absorption. In the region of the metal contact, the absorption of the active zone is set by pumping between transparent and greatly absorbing, such that, in particular, higher modes are attenuated to a greater extent than the fundamental mode.
In principle, all the described variants are conceivable in the case of edge emitting semiconductor lasers with a ridge structure, with gain-guided structures, for example oxide-stripe lasers, in the case of laser arrays and in the case of surface emitting semiconductor lasers.
The absorber zone in the case of a ridge laser can extend in a lateral direction. The layers of the semiconductor layer sequence typically likewise extend in a lateral direction. In particular, the absorber zone and the semiconductor layer sequence are arranged essentially parallel to one another. Furthermore, the absorber zone in the case of the ridge laser is particularly preferably spaced apart from the active zone in a vertical direction.
In an advantageous manner, higher kink levels can be obtained with the semiconductor laser according to an embodiment of the invention in comparison with conventional semiconductor lasers, that is to say that higher radiation powers can be achieved without transverse mode jumps occurring.
The semiconductor laser according to the invention is suitable for numerous applications such as for data storage or for laser printing.
In the context of the invention, for example sputtering, vapor deposition, epitaxial growth or plasma coating are appropriate for producing the absorber zone.
a, 5b, 5c, 5d, 5e show a schematic illustration of exemplary embodiments of structures of absorber zones according to the invention,
a and 9b show graphs representing the internal loss of a conventional semiconductor laser and of a semiconductor laser according to the invention as a function of the etching depth,
a and 10b show graphs representing the angle-dependent intensity distribution of a conventional semiconductor laser and of a semiconductor laser according to the invention,
a and 11b show two graphs representing the threshold gain characteristic of conventional ridge lasers.
In
a relates to a ridge laser having a ridge width of 1.5 μm, while
Both graphs reveal that the threshold gain decreases as the etching depth increases. Likewise, the threshold gain decreases as the ridge width increases. What is problematic in both cases is that higher-order modes occur at increasing etching depth. As emerges from
Possible options as to how higher modes can be attenuated despite a large etching depth or despite a wider ridge are demonstrated below.
The illustrations of the semiconductor lasers have a wavy line at the lower edge, and said line is intended to illustrate that a semiconductor layer sequence 2 is not fixed to a specific configuration on this side. Conventional configurations of a semiconductor laser are suitable on this side. In particular, the semiconductor laser can have there a cladding layer, a waveguide layer, a mirror layer, a substrate and a contact layer.
In the exemplary embodiment illustrated, an absorber zone 4 adjoins the semiconductor layer sequence 2. In this case, the absorber zone 4 is sufficiently electrically nonconductive and thick enough, such that it simultaneously serves as passivation, whereby the breakdown strength is advantageously increased and leakage currents are reduced. The thickness D of the absorber zone 4 is in the region of 250 nm, for example, given an operating voltage of approximately 12 V to 15 V. Furthermore, the absorber zone 4 can contain two materials, for example silicon nitride and silicon oxide, wherein the materials can be contained in particular in layers arranged one above another.
A contact layer 5 for making electrical contact with the semiconductor layer sequence 2 is disposed downstream of the absorber zone 4 in the vertical direction.
The semiconductor laser 1 can be, as illustrated, a ridge laser having a ridge 6. The semiconductor laser 1 has an etching depth T and a ridge width B. The absorber zone 4 covers the semiconductor layer sequence 2, preferably including the sidewalls of the ridge 6. Only a strip-type region for current injection is not covered by the absorber zone 4. In this region, the contact layer 5 directly adjoins the semiconductor layer sequence 2.
By way of example, in this exemplary embodiment, silicon can be used for the absorber zone 4, while silicon oxide is used for the insulation layer 7. Besides the electrical conductivity, the refractive index can be influenced by means of the oxygen proportion.
If the absorptance in the region 4a is intended to be increased, it is possible to dispose downstream of the region 4a a region 4b containing an absorber material that diffuses into the region 4a in the arrow direction. As a result of this, the absorber material moves nearer to the active zone 3, whereby the overlapping with the radiation field is increased and a greater absorption takes place. Conversely, the absorptance in the region 4a can be decreased by virtue of absorber material diffusing from said region into the region 4b. As a result of this, the absorber material is further away from the active zone 3, whereby the overlapping with the radiation field is reduced and a reduced absorption takes place.
In particular, the absorber material contains inclusions. The inclusions can be atoms, clusters or particles comprising or consisting of a metal, semiconductor material or organic material. In particular, the inclusions can comprise or consist of Ti, Pt, Si or C.
The diffusion can be assisted thermally and/or electrically.
In the case of the semiconductor laser 1 illustrated in
a to 5e illustrate differently structured absorber zones 4. As shown in
The absorber zone 4 illustrated in
The absorber zone 4 illustrated in
The absorber zone 4 illustrated in
The absorber zone 4 shown in
The absorber zone 4 illustrated in
a to 5b show structures for different absorbing materials. The absorption coefficient increases from the embodiment of
c and 5d show irregularly structured absorber zones. This is because the ridge 6 also has irregularities as a consequence of the production process and, therefore, also the radiation field also has irregularities. So in different areas, there must be a difference in the strength of absorption.
e shows curved absorber lines. The absorber zones are curved at the edge of the laser where the facets are. This results in a reduced overlap between the radiation field and the absorber zone at the facets so that light can be coupled out in a better way.
In practice, the radiation field of the laser without absorber can be measured to determine where it differs from a Gaussian shape. Then, simulations can be done to find out the best position and spacing for the absorber zone by using the shapes disclosed herein in order to achieve the Gaussian shape.
In the case of the semiconductor laser 1 illustrated in
The variant of a semiconductor laser 1 which is illustrated in
The semiconductor laser 1 illustrated in
a and 9b illustrate simulations of the internal loss αi as a function of the etching depth for a conventional ridge laser (
The curves I, II and III represent the simulation results for the fundamental mode, the 1st-order mode and the 2nd-order mode.
As can be ascertained in a comparison of the curves, the internal loss αi for higher modes is significantly higher using an absorber material than without absorber material. In an advantageous manner, it is thereby possible to effect laser operation in the fundamental mode in conjunction with low threshold gains and comparatively high optical output powers.
a and 10b illustrate measurement results of the angle-dependent intensity distribution which were obtained with different ridge lasers. A conventional ridge laser without absorber material yields the measurements results illustrated in
The angle-dependent intensity distributions are results of measurements in the vertical far field. The different curves are to be assigned to ridge lasers having different ridge widths: curve I to a ridge laser having a ridge width of 2.5 μm; curve II to a ridge laser having a ridge width of 5 μm; curve III to a ridge laser having a ridge width of 8 μm; curve IV to a ridge laser having a ridge width of 10 μm. As emerges from
Consequently, the beam form in the vertical far field is significantly improved by the use of the absorber material. Furthermore, the use of the absorber material permits even ridge lasers having a wider ridge to be able to be operated in the fundamental mode. This has the advantage, on the one hand, that a structuring of the laser strips is significantly simplified and, on the other hand, that the operating voltage is reduced, since the contact and series resistances in the ridge laser have an inverse relationship with respect to the ridge width and the threshold current densities are lower in the case of larger ridge widths than in the case of smaller ridge widths. Furthermore, a larger ridge width can lead to higher output powers since the power density at the facet is lower and the critical power density leading to the destruction of the facet (COMD=Catastrophic Optical Mirror Damage) is thus higher.
The invention is not restricted by the description on the basis of the exemplary embodiments. Rather, the invention encompasses any new feature and also any combination of features, which in particular comprises any combination of features in the patent claims, even if this feature or this combination itself is not explicitly specified in the patent claims or embodiments.
Number | Date | Country | Kind |
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10 2006 046 297.1 | Sep 2006 | DE | national |