This application is based upon and claims the benefit of priority from the prior Japanese Patent Applications No. 2008-244475, filed on Sep. 24, 2008, the entire contents of which are incorporated herein by reference.
1. Field of the Invention
The present invention relates to a semiconductor memory device and manufacturing method thereof.
2. Related Art
Ferroelectric random access memories have been attracted attention as one of nonvolatile semiconductor memories. Further, “Series connected TC unit type ferroelectric RAM (hereinafter, also “ferroelectric RAM”)” have been developed recently.
Lower electrodes of ferroelectric capacitors are connected to cell transistors by conductive contact plugs under the ferroelectric capacitors, which is a so-called COP (Capacitor On Plug) structure. Because polarization characteristics of the ferroelectric capacitors are degraded by a reducing process of hydrogen, hydrogen barrier films are used frequently for protecting the ferroelectric capacitors from hydrogen.
Upper electrodes of the ferroelectric RAM with the COP structure are conventionally connected via contact plugs formed by burying tungsten or aluminum in contact holes (damascene process) to local interconnections. To sufficiently reduce a contact resistance between the contact plugs and the upper electrodes in spite of downscaled memory cells, the amount of over etching must be increased during a process of forming contact holes. The increased amount of over etching leads to hollowing out of the upper electrodes, and induces damage like oxygen vacancy in the ferroelectric capacitors during etching process. Such hollowing out in the upper electrodes may reduce a signal difference between data “0” and “1”.
When the contact holes are downscaled, it is difficult to bury metal in the contact holes. Although metal is probably buried in small contact holes by reflow, reflow devices and CMP (Chemical-Mechanical Polishing) devices must be provided, resulting in cost increase.
When metal is buried in the contact holes by MO-CVD, the polarization characteristics of the ferroelectric capacitors may be degraded by hydrogen, due to oxygen vacancy increasing.
A semiconductor memory device according to an embodiment of the present invention comprises: a transistor on a semiconductor substrate; an interlayer dielectric film covering the transistor; a ferroelectric capacitor comprising a first upper electrode, a ferroelectric film, and a lower electrode on the interlayer dielectric film; a contact plug which is in the interlayer dielectric film and electrically connects the lower electrode to the transistor; a second upper electrode on the first upper electrode, a side surface of the second upper electrode being formed in a forward tapered shape; and an interconnection electrically connected via the second upper electrode to the first upper electrode.
A manufacturing method of a semiconductor memory device according to an embodiment of the present invention, comprises: forming a plurality of transistors on a semiconductor substrate; forming a first interlayer dielectric film covering the transistors; forming a plurality of first contact plugs passing through the first interlayer dielectric film to be connected to the transistors; forming a plurality of ferroelectric capacitors each of which comprises a first upper electrode, a ferroelectric film, and a lower electrode above one of the first contact plugs; forming a second interlayer dielectric film between adjacent ferroelectric capacitors; depositing a second upper electrode material on the first upper electrode and the second interlayer dielectric film; processing the second upper electrode material to form a second upper electrode on each of the first upper electrodes; forming a third interlayer dielectric film between the adjacent second upper electrodes; forming a second contact plug passing through the third and the second interlayer dielectric films to be electrically connected to the transistor; and forming an interconnection on the third interlayer dielectric film, the second upper electrode, and the second contact plug.
A manufacturing method of a semiconductor memory device according to an embodiment of the present invention, comprises: forming a plurality of transistors on a semiconductor substrate; forming a first interlayer dielectric film covering the transistors; forming a plurality of first contact plugs passing through the first interlayer dielectric film to be connected to the transistors; depositing materials of ferroelectric capacitors each of which comprises a first upper electrode, a ferroelectric film, and a lower electrode above one of the first contact plugs; depositing a second upper electrode material on the first upper electrode; depositing a mask material on the second upper electrode material; processing the mask material into a pattern of the second upper electrode; forming sidewall firms on side surfaces of the mask material and the second upper electrode; etching the materials of the ferroelectric capacitors using the mask material and the sidewall firms as a mask to form a plurality of ferroelectric capacitors.
Embodiments of the present invention will be explained below in detail with reference to the accompanying drawings. Note that the invention is not limited thereto.
The ferroelectric random access memory of the first embodiment includes a plurality of word lines WLi (i is an integer) extending in a row direction, a plurality of bit lines BL, bBL extending in a column direction perpendicular to the row direction, a plurality of plate lines PL extending in the row direction, and block selection parts BSP.
A memory cell MC stores binary data or multibit data in its ferroelectric capacitor. The memory cell MC is provided at the intersection of the word line WLi and the bit line BL, bBL. Each word line WLi is connected to gates of cell transistors CT arranged in the row direction. Each bit line BL, bBL is connected to sources or drains of cell transistors CT arranged in the column direction.
The ferroelectric random access memory includes a plurality of cell blocks CEB each of which is configured by serially connecting memory cells MC each of which includes a ferroelectric capacitor FC and a cell transistor TC connected to each other in parallel. One end of the cell block CEB is connected to one end of the block selection part BSP. The other end of the cell block CEB is connected to the plate line PL. The other end of the block selection part BSP is connected to the bit line BL or bBL. That is, the bit lines BL and bBL are connected via the block selection part BSP to the cell block CEB.
The block selection part BSP includes an enhancement transistor TSE and a depletion transistor TSD. The enhancement transistor TSE and the depletion transistor TSD are controlled by a block selective line BSO or BS1. Thus, the block selection part BSP can connect either the bit line BL or bBL selectively to the bit line BL or bBL.
A sense amplifier SA is connected to the bit line pair BL, bBL. The sense amplifier SA detects data from memory cells transmitted through the bit line pair BL, bBL during data reads. Further, the sense amplifier SA can apply voltage to the bit line pair BL, bBL during data writes to write data in memory cells MC. The first embodiment can be operated in a 1T1C mode or a 2T2C mode.
A plurality of cell transistors CT are formed on a semiconductor substrate 10. A silicide layer 40 is provided on a source S or a drain D of the cell transistor CT and a top surface of a gate electrode G. A first interlayer dielectric film ILD1 is provided in order to cover the cell transistors CT.
A first contact plug PLG1 passes through the first interlayer dielectric film ILD1 to be connected to the source S or the drain D of the cell transistor CT. A metallic plug 20 is formed on the first contact plug PLG1. A conductive hydrogen barrier film 30 is provided on the metallic plug 20. The first contact plug PLG1 and the metallic plug 20 are made of tungsten, for example. The hydrogen barrier film 30 is made of TiN or TiAlN, for example.
A lower electrode LE is provided on the hydrogen barrier film 30. The lower electrode LE is electrically connected via the hydrogen barrier film 30, the metallic plug 20, and the first contact plug PLG1 to the source S or the drain D of the cell transistor CT. A ferroelectric film FE is provided on the lower electrode LE. A first upper electrode UE1 is provided on the ferroelectric film FE. The first upper electrode UE1, the ferroelectric film FE, and the lower electrode LE constitute the ferroelectric capacitor FC. The first upper electrode UE1 is made of TiAlN or IrO2, for example. The ferroelectric film FE is made of PZT film or SBT film, for example. The lower electrode LE is made of TiAlN or Ir or stacked layer of both materials for example.
A part of the top surface and the side surface of the ferroelectric capacitor FC are covered by dielectric hydrogen barrier films 50 and 60. The hydrogen barrier films 50 and 60 are made of alumina (Al2O3), for example. Other part of top surface of the ferroelectric capacitor FC is not covered by a second interlayer dielectric film ILD2 and connected to a second upper electrode UE2.
The second interlayer dielectric film ILD2 is loaded between adjacent ferroelectric capacitors FC. The second interlayer dielectric film ILD2 is formed on the side surface of the ferroelectric capacitor FC with the hydrogen barrier film 50 covering the side surface of the ferroelectric capacitor FC interposed therebetween.
The second upper electrode UE2 comprises a lower layer film 71, a core part 72, and an upper layer film 73. The lower layer film 71 is connected to the first upper electrode UE1. The lower layer film 71 and the upper layer film 73 are made of a conductive material such as TiN or TiAlN. The core part 72 is made of any viscous conductive material capable of absorbing volumetric changes in the ferroelectric capacitor FC. That is, the core part 72 is preferably made of metallic films with inherent tensile stress. The core part 72 is made of aluminum, for example. The lower layer film 71 serves as a diffusion preventing film and is provided to suppress diffusion of metal of the core part 72 toward the ferroelectric capacitor FC. The upper layer film 73 serves as a reflection preventing film and is provided to suppress inferior pattering caused by the reflection of the core part 72 during a lithography process.
The side surface of the second upper electrode UE2 is formed in a forward tapered shape like the ferroelectric capacitor FC. This is because the second upper electrode UE2 is not a metallic plug buried by a damascene process but a laminated layer obtained by processing the deposited lower layer film 71, the core part 72, and the upper layer film 73 using lithography and RIE (Reactive Ion Etching).
According to the damascene process, contact holes are formed, metal is loaded in the contact holes, and the loaded metal is flattened, so that contact plugs are formed. The contact holes are formed by lithography and etching. At this time, the side surface of the contact hole is usually formed in a reverse tapered shape.
The second upper electrode UE2 of the first embodiment is formed by etching the laminated film without using the damascene process, like the ferroelectric capacitor FC. Thus, the side surface of the second upper electrode UE2 is formed in a forward tapered shape.
A hydrogen barrier film 80 is formed on the side surface of the second upper electrode UE2. A third interlayer dielectric film ILD3 is loaded between adjacent second upper electrodes UE2.
A second contact plug PLG2 passes through the third interlayer dielectric film ILD3 and the second interlayer dielectric film ILD2 to be connected to the metallic plug 20. A local interconnection LIC is provided on the third interlayer dielectric film ILD3, the second upper electrode UE2, and the second contact plug PLG2. The local interconnection LIC comprises a lower layer film 91, a core part 92, and an upper layer film 93. The lower layer film 91 and the upper layer film 93 are made of TiN or TiAlN, for example. The core part 92 is made of a low resistance interconnection material such as copper or aluminum. The lower layer film 91 serves as a diffusion preventing film and is provided to suppress the diffusion of metal of the core part 92 toward the second upper electrode UE2 and the ferroelectric capacitor FC. The upper layer film 93 serves as a reflection preventing film and is provided to suppress inferior patterning caused by the reflection of the core part 92 during a lithography process.
The first upper electrode UE1 of the ferroelectric capacitor FC is electrically connected via the second upper electrode UE2, the local interconnection LIC, the contact plugs PLG1 and PLG2, and the metallic plug 20 to either the source S or the drain D of the cell transistor CT. The first upper electrodes UE1 of two ferroelectric capacitors adjacent to each other in a direction the bit line BL extends are connected to each other by the local interconnection LIC.
Meanwhile, the first contact plug PLG1 and the metallic plug connected to the lower electrode LE of the ferroelectric capacitor FC electrically connect the lower electrodes LE of the two ferroelectric capacitor FC adjacent to each other in the extending direction of the bit line BL to the other of the source S and the drain D of the cell transistor CT. In this way, the ferroelectric RAM is formed.
In the first embodiment, the contact plug is not provided on the first upper electrode UE1 of the ferroelectric capacitor FC. Instead, the pillar-shaped second upper electrode UE2 is provided. When the contact plug is conventionally formed on the first upper electrode UE1, a contact hole must be formed in a thick interlayer dielectric film. At this time, the first upper electrode is hollowed out by over etching. This is because the amount of over etching must be increased as the film thickness of material to be etched is increased.
In contrast to the conventional technique, according to the first embodiment, to connect the second upper electrode UE2 to the first upper electrode UE1, the hydrogen barrier film 60 much thinner than the interlayer dielectric film is merely etched. Thus, the top surface of the first upper electrode UE1 is hardly hollowed out. As a result, the deterioration of the signal difference between the data “0” and “1” can be suppressed.
The second upper electrode UE2 of the first embodiment does not use the damascene process. Thus, devices for burying metals in contact holes with high aspect ratio are not necessary, resulting in suppressed manufacturing costs.
Further, if MO-CVD (Metalorganic-Chemical Vapor Deposition) is used for burying metals in contact holes, a large amount of hydrogen is generated. Hydrogen degrades the polarization characteristics of ferroelectric materials. Because a process of burying metals in contact holes is not provided in the first embodiment, however, MO-CVD is not required for forming the second upper electrode UE2. Thus, hydrogen is not generated when the second upper electrode UE2 is formed and the deterioration of polarization characteristics of the ferroelectric capacitor FC can be suppressed.
As shown in
The material for the hydrogen barrier film 30 (e.g., TiN or TiAlN) is deposited on the metallic plug 20. Materials for the lower electrode LE (e.g., TiAlN or Ir), the ferroelectric film FE (PZT film or SBT film), and the first upper electrode UE1 (e.g., TiAlN or IrO2) are deposited successively on the hydrogen barrier film 30. A mask material 95 is further deposited on the material of the first upper electrode UE1. The mask material 95 is made of Ai2O3 or TEOS, for example. Thus, configurations shown in
The mask material 95 is then processed in a pattern of the ferroelectric capacitor FC by lithography and RIE. The mask material 95 is processed in a pattern of the first upper electrode UE1. The materials for the first upper electrode UE1, the ferroelectric film FE, the lower electrode LE, and the hydrogen barrier film 30 are etched with RIE by using the mask material 95 as a mask. The ferroelectric capacitor FC is thus formed, as shown in
Next, as shown in
The second interlayer dielectric film ILD2 is deposited on the hydrogen barrier film 50 and then flattened by CMP. The second interlayer dielectric film ILD2 is ground until the top surface of the first upper electrode UE1 is exposed. As shown in
The hydrogen barrier film 60 at a part of top surface of the first upper electrode UE1 is then removed by lithography and RIE as shown in
As shown in
The materials for the upper layer film 73, the core part 72, and the lower layer film 71 are then etched by lithography and RIE. As shown in
As shown in
The third interlayer dielectric film ILD3 is then loaded between two second upper electrodes UE2 adjacent to each other in the direction the bit line BL extends. Further, as shown in
Next, as shown in
An interlayer dielectric film (not shown) is then deposited on the local interconnection LIC and a bit line contact is formed in that interlayer dielectric film. The bit line is formed on the bit line contact. Thus, the ferroelectric RAM of the first embodiment is completed.
According to the first embodiment, the second upper electrode UE2 connecting between the ferroelectric capacitor FC and the local interconnection LIC is processed into a pillar shape by lithography and RIE without using the damascene process. The hydrogen barrier film 60 much thinner than the interlayer dielectric film is merely etched to connect the second upper electrode UE2 to the first upper electrode UE1. Thus, the deterioration of the signal difference between the data “0” and “1” can be suppressed because the amount of over etching for the top surface of the first upper electrode UE1 is reduced.
Because the first embodiment does not use the damascene process, devices for burying metals in contact holes with high aspect ratio are not required, resulting in suppressed manufacturing costs.
The second upper electrode UE2 is made of a material with inherent tensile stress serving as the core part 72 (e.g., aluminum). Accordingly, even if the polarization state of the ferroelectric film FE changes so that the deposition of the ferroelectric film FE changes, the core part 72 can absorb the depositional change of the ferroelectric film FE. Thus, the deterioration of polarization characteristics of the ferroelectric film FE can be suppressed.
The second embodiment is different from the first embodiment in the configuration of the second upper electrode UE2. Other configurations of the second embodiment can be identical to those of the first embodiment. The second upper electrode UE2 of the second embodiment comprises a conductive lower layer film 71 on the first upper electrode UE1, a core part 75 on the lower layer film 71, a conductive upper layer film 73 on the core part 75, and a side conductive film 74 that is formed on the side surface of the core part 75 and connects between the upper layer film 73 and the lower layer film 71.
The lower layer film 71, the upper layer film 73, and the side conductive film 74 are conductive hydrogen barrier films and made of TiN or TiAlN, for example. The core part 75 is made of an insulation film such as TEOS.
A manufacturing method of the second embodiment is different from that of the first embodiment in formation of the second upper electrode UE2. Accordingly, only the formation of the second upper electrode UE2 will be described. After the ferroelectric capacitor FC is formed as shown in
The material for the side conductive film 74 is then deposited in order to cover top and side surfaces of a pillar formed of the core part 75 and the upper layer film 73. The side conductive film 74 is etched back, so that the material for the side conductive film 74 remains on the side surface of the pillar. At the same time, the material for the lower layer film 71 is further etched by using the side conductive film 74 as a mask. As a result, the pillar formed of the lower layer film 71, the core part 75, the upper layer film 73, and the side conductive film 74 are formed on each of the ferroelectric capacitors FC. The side conductive film 74 electrically connects between the lower layer film 71 and the upper layer film 73 along the side surface of the core part 75. In this way, the second upper electrode UE2 of the second embodiment is formed.
Because the material for the lower layer film 71 is etched by using the side conductive film 74 as a mask, the side conductive film 74 can keep contact with the lower layer film 71 at its end.
Because the core part 75 is made of an insulation film such as TEOS in the second embodiment, the lower layer film 71 can serve as an etching stopper for the core part 75. Thus, the lower layer film 71 is formed on the first upper electrode UE1 and the hydrogen barrier film 60 shown in
The third embodiment is different from the first embodiment in the configuration of the second upper electrode UE2. Other configurations of the third embodiment can be identical to those of the first embodiment. The second upper electrode UE2 of the third embodiment comprises a core part 72 made of a conductive material on the first upper electrode UE1 and a side wall film 76 on the side surface of the core part 72. A plane pattern of the second upper electrode UE2 is substantially the same as or similar to that of the first upper electrode UE1. That is, the bottom surface of the second upper electrode UE2 coincides substantially with the top surface of the first upper electrode UE1. The side surface of the second upper electrode UE2 is continuous with the side surface of the first upper electrode UE1 without any processes. The core part 72 is a conductive material and made of metal such as aluminum. The side wall film 76 is made of an insulation film such as Al2O3.
After the material for the first upper electrode UE1 is deposited as shown in
A mask material 82 (e.g., TEOS or silicon nitride film) is deposited on the core part 72. The mask material 82 is then processed in a pattern of the ferroelectric capacitor FC by lithography and RIE. As shown in
As shown in
A dielectric hydrogen barrier film 50 (e.g., Al2O3) is then deposited on the side surfaces of the ferroelectric capacitor FC and the second upper electrode UE2 and the top surfaces of the mask material 82, the first interlayer dielectric film ILD1, and the metallic plug 20. Further, the second interlayer dielectric film ILD2 is loaded between ferroelectric capacitors FC adjacent to each other in the direction the bit line BL extends and between second upper electrodes UE2 adjacent to each other in the direction the bit line BL extends. After the second interlayer dielectric film ILD2 is flattened by CMP, the second contact plug PLG2 is formed by the damascene process. Configurations shown in
Next, the hydrogen barrier film 50 and the mask material 82 are ground by CMP until the core part 72 is exposed. The local interconnection LIC is formed on the core part 72 and the second contact plug PLG2. Bit line contacts and bit lines are then formed like the manufacturing method of the first embodiment, so that the ferroelectric RAM of the third embodiment is completed.
According to the third embodiment, the material for the second upper electrode UE2 is deposited directly on the material for the ferroelectric capacitor FC and the second upper electrode UE2 is patterned. The ferroelectric capacitor FC is then formed in a self-aligned manner by using the second upper electrode UE2 as a mask. Thus, the hydrogen barrier film 60 is not required in the third embodiment. Contact holes do not need to be formed on the first upper electrode UE1. As a result, hollowing out caused by etching the first upper electrode UE1 is further suppressed in the third embodiment. The third embodiment can further achieve identical effects as those of the first embodiment.
The fourth embodiment is different from the third embodiment in the contact between the second upper electrode UE2 and the local interconnection LIC. Other configurations of the fourth embodiment can be identical to those of the third embodiment.
After the configurations shown in
The contact hole is formed on the second upper electrode UE2 in the fourth embodiment. Even if the material for the local interconnection LIC is deposited, the position of the second upper electrode UE2 can be found. Thus, lithography misalignment can be prevented when the local interconnection LIC is formed. The fourth embodiment can further achieve identical effects as those of the third embodiment.
Number | Date | Country | Kind |
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2008-244475 | Sep 2008 | JP | national |