The disclosure relates to a semiconductor device, more particularly to a semiconductor memory device and its manufacturing process.
Flash memories have become increasingly popular in recent years. A typical flash memory includes a memory array having a large number of memory cells arranged as an array. Each of the memory cells may be fabricated as a field-effect transistor having a control gate (CG) and a floating gate (FG). The floating gate is capable of holding charges, and is separated from source and drain regions contained in a substrate by a layer of thin oxide. Each of the memory cells may be electrically charged by injecting electrons from the substrate into the floating gate. The charges may be removed from the floating gate by tunneling the electrons to the source region or an erase gate during an erase operation. The data in flash memory cells may thus be determined by the presence or absence of charges in the floating gates.
As the semiconductor industry introduces new generations of integrated circuits (ICs) having higher performance and greater functionality, cost reduction pressure becomes stronger. In particular, reducing a number of operations, such as lithography operations, has become desirable.
The present disclosure is best understood from the following detailed description when read with the accompanying figures. It is emphasized that, in accordance with the standard practice in the industry, various features are not drawn to scale and are used for illustration purposes only. In fact, the dimensions of the various features may be arbitrarily increased or reduced for clarity of discussion.
It is to be understood that the following disclosure provides many different embodiments, or examples, for implementing different features of the invention. Specific embodiments or examples of components and arrangements are described below to simplify the present disclosure. These are, of course, merely examples and are not intended to be limiting. For example, dimensions of elements are not limited to the disclosed range or values, but may depend upon process conditions and/or desired properties of the device. Moreover, the formation of a first feature over or on a second feature in the description that follows may include embodiments in which the first and second features are formed in direct contact, and may also include embodiments in which additional features may be formed interposing the first and second features, such that the first and second features may not be in direct contact. Various features may be arbitrarily drawn in different scales for simplicity and clarity.
Further, spatially relative terms, such as “beneath,” “below,” “lower,” “above,” “upper” and the like, may be used herein for ease of description to describe one element or feature's relationship to another element(s) or feature(s) as illustrated in the figures. The spatially relative terms are intended to encompass different orientations of the device in use or operation in addition to the orientation depicted in the figures. The apparatus may be otherwise oriented (rotated 90 degrees or at other orientations) and the spatially relative descriptors used herein may likewise be interpreted accordingly. In addition, the term “made of” may mean either “comprising” or “consisting of.”
As shown in
A portion of the insulation layer 110 may be between the substrate 105 and first hard mask layer 180. The first hard mask layer 180 may include silicon oxide, silicon nitride, silicon carbide, silicon oxynitride, aluminum oxide, aluminum nitride, aluminum fluoride, titanium nitride, tantalum oxide, magnesium fluoride, titanium silicon nitride, or other suitable hard mask materials.
The insulation layer 110 may be formed as part of a shallow trench isolation (STI) operation. The insulation layer 110 may include one or more layers of insulating material. Each layer of insulating material may include, for example, silicon oxide, silicon dioxide, silicon nitride, silicon oxynitride (SiON), silicon oxycarbonitride (SiOCN), fluorine-doped silicate glass (FSG), or a low-k dielectric material. The insulation layer 110 may be formed using a chemical vapor deposition (CVD) operation, such as a low pressure chemical vapor deposition (LPCVD) operation, a plasma-enhanced chemical vapor deposition (PECVD) operation, a flowable chemical vapor deposition operation, a molecular layer deposition (MLD) operation, and combinations thereof, among others. In some embodiments, the insulation layer 110 is formed by forming trenches/recesses in a bulk substrate material, forming insulation material (e.g., using a CVD operation) within and over the trenches/recesses, and performing a chemical mechanical polishing (CMP) operation on the insulation material to form the insulation layer 110 within the trenches/recesses.
In
The floating gates 115 may include conductive material. In some embodiments, the floating gates 115 include polysilicon, doped polysilicon, or combinations thereof. In some embodiments, the floating gates 115, when formed, are implanted with a p-type or an n-type impurity, followed by an anneal operation to activate the implanted impurity.
In
The first etch stop layer 125 may be disposed over the control gates 120. A thickness TESL of the first etch stop layer 125 may be between about 4 nm and about 8 nm. The first etch stop layer 125 may include silicon oxide, silicon nitride, silicon carbide, silicon oxynitride, aluminum oxide, aluminum nitride, aluminum fluoride, titanium nitride, tantalum oxide, magnesium fluoride, titanium silicon nitride, or other suitable etch-stop materials. The resist protective oxide layer 130 may be disposed over the first etch stop layer 125. A thickness TRPO of the resist protective oxide layer 130 may be between about 35 nm and about 55 nm. A width WRPO of the resist protective oxide layer 130 may be between about 160 nm and about 240 nm.
The control gates 120 may include conductive material. In some embodiments, the control gates 120 include polysilicon, doped polysilicon, or combinations thereof. In some embodiments, the control gates 120, when formed, are implanted with a p-type or an n-type impurity, followed by an anneal operation to activate the implanted impurity.
In
In
In the common source site, in some embodiments, the implantation operation followed by the oxidation operation results in a non-uniform thickness in different portions of the insulation layer 110. In these embodiments, the dopants implanted into the substrate 105 via the implantation operation (e.g., high voltage ion implantation operation) damages the substrate 105, and performing the oxidation operation on the damaged substrate results in the non-uniform thickness of the insulation layer 110. In
In some embodiments, prior to performing the implantation and oxidation operations, etching operation(s) (e.g., wet etching operation(s)) are performed. The etching operation(s) may etch portions of the first spacer layers 135 and second hard mask layer 185.
In
In
In some embodiments, the wordlines 150 are utilized to allow accessing of the flash memory cell whose cross-sectional views are shown in
In
In
In
In
As shown in
On the common source site, a patterning operation and an etching operation may be performed to etch the interlayer dielectric layer 145, second etch stop layer 140, insulation layer 110, and substrate 105 in order to form an opening exposing the substrate 105 in which the second contact 175 is subsequently formed. In some embodiments, the second contact 175 is surrounded by and in contact with the interlayer dielectric layer 145, second etch stop layer 140, insulation layer 110, and substrate 105. The substrate 105 may be doped with phosphorus, arsenic, fluorine, or combination thereof. The etching operation for the control gate site and common source site may utilize fluorocarbon-based etch gases, such as CF4 gas and C4F6 gas. In some cases, additive gases such as H2, O2, N2, and/or Ar are added to the etch gases.
In some embodiments, a patterning operation includes depositing a resist film (e.g., photoresist), exposing a portion(s) of the resist film (e.g., using an optical lithography tool or electron beam writer), and developing the exposed portion(s) of the resist film to form a resist pattern for an etching operation. The etching operation may include dry etching operations, wet-etching operations, and combinations thereof. For example, a dry etching operation may implement an oxygen-containing gas, fluorine-containing gas (e.g., tetrafluoromethane (CF4), sulfur tetrafluoride (SF6), difluoromethane (CH2F2), fluoroform (CHF3), and/or hexafluoroethane (C2F6)), chlorine-containing compound (e.g., Cl2, chloroform (CHCl3), carbon tetrachloride (CCl4), and/or boron trichloride (BCl3)), bromine-containing compound (e.g., hydrogen bromide (HBr) and/or bromoform (CHBR3)), and iodine-containing gas, other suitable gases and/or plasmas, and/or combinations thereof.
In some embodiments, the method of manufacturing the flash memory cell as provided in
Furthermore, in some embodiments, the etching operation to etch the control gates 120, first etch stop layer 125, resist protective oxide layer 130, and insulation layer 110 exposes a surface of the control gates 120. On the control gate site, in some cases where the control gates 120 are formed of silicon or polysilicon, a nickel silicide (NiSi) is formed on the surface of the exposed silicon or polysilicon, and the first contact 155 is in contact with the NiSi. On the common source site, in some cases where the substrate 105 is formed of silicon or includes silicon, a nickel silicide (NiSi) is formed on the surface of the exposed substrate, and the second contact 175 is in contact with the NiSi. In contrast, in
It will be understood that not all advantages have been necessarily discussed herein, no particular advantage is required for all embodiments or examples, and other embodiments or examples may offer different advantages.
In accordance with one aspect of the present disclosure, a memory device includes a substrate. An insulation layer is disposed in a recess in the substrate. A first gate structure is disposed over the substrate and the insulation layer. A first etch stop layer is disposed over the first gate structure. A first oxide layer is disposed over the first etch stop layer. A second etch stop layer is disposed over the first oxide layer. A first contact material is surrounded by and in contact with the first gate structure, first etch stop layer, second etch stop layer, and first oxide layer.
In accordance with one aspect of the present disclosure, in a method of manufacturing a memory device, a first gate structure is formed over an insulation material and a substrate. A first etch stop layer is formed over the first gate structure. A first oxide layer is formed over the first etch stop layer. A first spacer layer is deposited over the first oxide layer. A first etching operation is performed to etch the first spacer layer. A second etch stop layer is deposited over the first oxide layer. A second etching operation is performed to etch the second etch stop layer and first etch stop layer. A first contact structure is formed such that the first contact structure is in contact with the first gate structure, first oxide layer, first etch stop layer, and second etch stop layer.
In accordance with one aspect of the present disclosure, a memory device includes a substrate. A first oxide layer is disposed over the substrate. A wordline is disposed over the first oxide layer. A first etch stop layer is disposed over the wordline and the first oxide layer. A first gate structure is disposed over the first oxide layer. A first spacer layer is disposed between and in contact with the wordline and the first gate structure. A second spacer layer disposed between the first gate structure and the first etch stop layer. A first contact material is surrounded by and in contact with the first oxide layer and first etch stop layer.
The foregoing outlines features of several embodiments or examples so that those skilled in the art may better understand the aspects of the present disclosure. Those skilled in the art should appreciate that they may readily use the present disclosure as a basis for designing or modifying other processes and structures for carrying out the same purposes and/or achieving the same advantages of the embodiments or examples introduced herein. Those skilled in the art should also realize that such equivalent constructions do not depart from the spirit and scope of the present disclosure, and that they may make various changes, substitutions, and alterations herein without departing from the spirit and scope of the present disclosure.
This application claims the benefit of priority to U.S. Provisional Application No. 62/378,908, entitled “SEMICONDUCTOR MEMORY DEVICE AND MANUFACTURING METHOD THEREOF,” filed Aug. 24, 2016, which is incorporated herein by reference in its entirety.
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Number | Date | Country | |
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