This application is based upon and claims the benefit of priority from Japanese Patent Application No. 2012-139011, filed on Jun. 20, 2012; the entire contents of which are incorporated herein by reference.
Embodiments described herein relate generally to a semiconductor memory device and a method for manufacturing the same.
A memory device of a three-dimensional structure is proposed in which a memory hole is formed in a stacked body in which an electrode film functioning as the control gate of a memory cell and an insulating film are alternately stacked in plural, and a silicon body serving as a channel is provided on the side wall of the memory hole via a charge storage film.
In such a three-dimensionally stacked memory, the electric potential of the channel body is controlled by the control of a vertical select transistor provided above the memory cell.
According to one embodiment, a semiconductor memory device includes a substrate, a plurality of electrode films, a plurality of first insulating films, a second insulating film, a select gate, a channel body, and a memory film. The electrode films are provided on the substrate. The first insulating films are each provided between adjacent ones of the electrode films. The second insulating film is provided on an uppermost electrode film out of the electrode films and including a film with a higher dielectric constant than silicon oxide. The select gate is provided directly on the second insulating film. The channel body extends in a stacking direction in a stacked body including the electrode films, the first insulating films, the second insulating film, and the select gate. The memory film is provided between a side wall of the channel body and each of the electrode films and includes a charge storage film. The memory film includes a block film, the charge storage film, and a tunnel film sequentially provided from a side of the electrode films. The second insulating film includes at least the block film of the memory film.
Various embodiments will be described hereinafter with reference to the accompanying drawings.
In the drawings, identical components are marked with the same reference numerals.
In
The memory cell array 1 includes a plurality of memory strings MS. One memory string MS is formed in a U-shaped configuration including a pair of columnar portions CL extending in the Z direction and a joining portion JP joining the lower ends of the pair of columnar portions CL.
As shown in
An insulating film 41 is provided on the back gate BG. The electrode film WL and the insulating film 25 are alternately stacked in plural on the insulating film 41. Although four electrode films WL, for example, are illustrated in
The insulating film 25 is provided between upper and lower electrode films WL adjacent in the Z direction. The insulating film 25 is provided also on the uppermost electrode film WL.
The electrode film WL is a polysilicon film doped with, for example, boron as an impurity (a first silicon film), and has an electrical conductivity sufficient to function as the gate electrode of a memory cell.
The insulating film 25 includes at least part of a memory film 30, and includes a film with a higher dielectric constant than silicon oxide, as described later.
A drain-side select gate SGD is provided in the upper end portion of one of the pair of columnar portions CL of the U-shaped memory string MS, and a source-side select gate SGS is provided in the upper end portion of the other of the pair of columnar portions CL.
The drain-side select gate SGD and the source-side select gate SGS are provided on the uppermost electrode film WL via the insulating film 25. The drain-side select gate SGD and the source-side select gate SGS are provided directly on the insulating film 25 via no other film with the insulating film 25.
In the following description, the drain-side select gate SGD and the source-side select gate SGS may not be distinguished, and may be collectively referred to as a select gate SG.
The drain-side select gate SGD and the source-side select gate SGS are a polysilicon film doped with, for example, boron as an impurity similarly to the electrode film WL, and have an electrical conductivity sufficient to function as the gate electrode of a select transistor. The thickness of the drain-side select gate SGD and the thickness of the source-side select gate SGS are thicker than the thickness of each of the electrode films WL.
The drain-side select gate SGD and the source-side select gate SGS are divided in the Y direction by an insulating separation film 48. The stacked body under the drain-side select gate SGD and the stacked body under the source-side select gate SGS are divided in the Y direction by an insulating separation film 45.
A source line SL shown in
The memory string MS includes a channel body 20 provided in a U-shaped memory hole formed in the stacked body including the insulating film 47, the select gate SG, the plurality of insulating films 25, the plurality of electrode films WL, the insulating film 41, and the back gate BG.
The channel body 20 includes a pair of columnar portions CL extending in the Z direction in the stacked body mentioned above and a joining portion JP joining the lower ends of the pair of columnar portions CL in the back gate BG.
The channel body 20 is provided in the U-shaped memory hole via a memory film 30. The channel body 20 is, for example, a silicon film. As shown in
Although
The memory film 30 includes a block film 31, a charge storage film 32, and a tunnel film 33. The block film 31, the charge storage film 32, and the tunnel film 33 are provided in this order from the electrode film WL side between each electrode film WL and the channel body 20. The block film 31 is in contact with each electrode film WL, the tunnel film 33 is in contact with the channel body 20, and the charge storage film 32 is provided between the block film 31 and the tunnel film 33.
The channel body 20 functions as a channel in a memory cell (transistor), the electrode film WL functions as the control gate of the memory cell, and the charge storage film 32 functions as a data memory layer that stores a charge injected from the channel body 20. That is, a memory cell with a structure in which the control gate surrounds the periphery of the channel is formed at the intersection between the channel body 20 and each electrode film WL.
The semiconductor memory device of the embodiment is a nonvolatile semiconductor memory device that can perform the erasing and writing of data electrically in a free manner and can retain the memory content even when the power is turned off.
The memory cell is, for example, a charge trap memory cell. The charge storage film 32 includes a large number of trap sites that trap a charge, and is a silicon nitride film, for example.
The tunnel film 33 is, for example, a silicon oxide film, and forms a potential barrier when a charge is injected from the channel body 20 into the charge storage film 32 or when the charge stored in the charge storage film 32 is diffused to the channel body 20. The tunnel film 33 is, for example, a silicon oxide film.
The block film 31 prevents the charge stored in the charge storage film 32 from diffusing to the electrode film WL. The block film 31 is, for example, a silicon nitride film or an aluminum oxide (alumina) film.
The insulating film 25 between electrode films WL and the insulating film 25 between the uppermost electrode film WL and the select gate SG are formed in the same process as the memory film 30 as described later.
Therefore, the insulating film 25 between electrode films WL and the insulating film 25 between the uppermost electrode film WL and the select gate SG include at least part of the memory film 30, and the insulating film 25 between electrode films WL and the insulating film 25 between the uppermost electrode film WL and the select gate SG have the same stacked film structure of a plurality of films.
In the example shown in
The drain-side select gate SGD, the channel body 20, and the memory film 30 between them constitute a drain-side select transistor STD (shown in
The source-side select gate SGS, the channel body 20, and the memory film 30 between them constitute a source-side select transistor STS (shown in
The back gate BG, and the channel body 20 and the memory film 30 provided in the back gate BG constitute a back gate transistor BGT (shown in
The memory cell using each electrode film WL as the control gate is provided in plural between the drain-side select transistor STD and the back gate transistor BGT. Similarly, the memory cell using each electrode film WL as the control gate is provided in plural also between the back gate transistor BGT and the source-side select transistor STS.
The plurality of memory cells, the drain-side select transistor STD, the back gate transistor BGT, and the source-side select transistor STS are connected in series via the channel body 20, and constitute one U-shaped memory string MS. The memory string MS is arranged in plural in the X direction and the Y direction; thus, a plurality of memory cells MC are provided three-dimensionally in the X direction, the Y direction, and the Z direction.
Next, a method for manufacturing a semiconductor memory device of the embodiment is described with reference to
As shown in
A resist 94 provided with openings 94a by patterning is formed on the back gate BG, and etching using the resist 94 as a mask is performed to form a plurality of trenches 81 in the back gate BG as shown in
As shown in
The sacrifice film 82 is etched back, and the upper surface of the protruding portion of the back gate BG between a trench 81 and a trench 81 is exposed as shown in
The electrode film WL as the first silicon film and a non-doped silicon film 42 as a second silicon film are alternately stacked in plural on the insulating film 41. Here, “non-doped” means that an impurity for providing electrical conductivity is not intentionally added to the silicon film and impurities are not substantially contained other than the elements resulting from the source gas in the film-formation.
The non-doped silicon film 42 is finally replaced with the insulating film 25 shown in
The electrode film WL is a polysilicon film doped with, for example, boron (B) as an impurity (the first silicon film). The uppermost layer in the stacked body including the plurality of electrode films WL and the plurality of non-doped silicon films 42 is the non-doped silicon film 42.
After the stacked body shown in
Although the insulating separation film 45 is deposited also on the uppermost non-doped silicon film 42, the insulating separation film 45 on the non-doped silicon film 42 is removed and the non-doped silicon film 42 is exposed.
As shown in
The select gate SG is formed directly on the uppermost non-doped silicon film 42, and there is not a film (an insulating film such as a silicon oxide film) other than the non-doped silicon film 42 between the uppermost non-doped silicon film 42 and the select gate SG.
The back gate BG and the stacked films on the back gate BG shown in
After the stacked body of
Since all the stacked films between the insulating film 41 and the insulating film 47 are silicon films, the setting of the conditions of RIE and the shape controllability of the hole h are easy.
The bottom of the hole h reaches the sacrifice film 82, and the sacrifice film 82 is exposed at the bottom of the hole h. A pair of holes h are formed on one sacrifice film 82, with the insulating separation film 45 located between the holes h. The insulating film 47, the select gate SG, the non-doped silicon film 42, the electrode film WL, and the insulating film 41 are exposed at the side wall of the hole h.
After the hole h is formed, the sacrifice film 82 and the non-doped silicon film 42 are removed as shown in
The etching rate of the silicon film to the alkaline chemical liquid depends on the concentration of the impurity doped in the silicon film. In particular, when the concentration of boron as the impurity becomes 1×1020 (cm−3) or more, the etching rate of the silicon film decreases rapidly to become a few percent of that when the boron concentration is 1×1019 (cm−3) or less.
In the embodiment, the boron concentration of the back gate BG, the electrode film WL, and the select gate SG is 1×1021 (cm−3) to 2×1021 (cm−3). In the chemical liquid treatment using an alkaline chemical liquid, the etching selection ratio of the silicon film with a boron concentration of 1×1021 (cm−3) to 2×1021 (cm−3) to the non-doped silicon film is 1/1000 to 1/100.
Therefore, by the chemical liquid treatment mentioned above, the non-doped silicon film 42 and the sacrifice film 82, which is likewise a non-doped silicon film, are removed via the hole h. On the other hand, the back gate BG, the electrode film WL, and the select gate SG are left.
By the removal of the sacrifice film 82, the trench 81 appears which has been formed in the back gate BG in the process shown in
By the removal of the non-doped silicon film 42, a space 26 is formed between electrode films WL and between the uppermost electrode film WL and the select gate SG. The space 26 leads to the memory hole MH.
The electrode films WL and the select gate SG are supported by the insulating separation film 45, and the state where the plurality of electrode films WL and the select gate SG are stacked via the space 26 is maintained.
After the chemical liquid treatment mentioned above, as shown in
As described above with reference to
Depending on the height of the space 26 and the film thickness of each film included in the memory film 30, the space 26 may be filled up with only the block film 31; or a stacked film including the block film 31 and the charge storage film 32 or a stacked film including the block film 31, the charge storage film 32, and the tunnel film 33 may be buried as the insulating film 25 in the space 26.
In the structure of
The first block film 31a is provided on the electrode film WL side and on the select gate SG side, and the second block film 31b is provided between the first block film 31a and the charge storage film 32.
Both the first block film 31a and the second block film 31b have the function of blocking the charge stored in the charge storage film 32 from diffusing to the electrode film WL.
The second block film 31b is, for example, an aluminum oxide (alumina) film, a silicon oxide film, or a silicon oxynitride film.
For the first block film 31a, a film with a higher nitrogen concentration than the second block film 31b is used, and the first block film 31a has a higher capability of blocking the charge from diffusing to the electrode film WL than the second block film 31b. The first block film 31a is, for example, a silicon nitride film.
In both structures of
After the memory film 30 and the insulating film 25 are formed, the channel body 20 is formed on the inside of the memory film 30 in the memory hole MH.
After that, as shown in
Here,
In the comparative example, as shown in
As shown in
In the comparative example, when the hole h is formed, a stacked body in which the silicon oxide film 49 different from a silicon film exists in a middle position of the stacked silicon films is processed. Hence, the side wall of the hole h in the portion piercing the silicon oxide film 49 is formed in a tapered shape inclined with respect to the substrate surface, and the diameter of the hole h provided in the silicon oxide film 49 is likely to be smaller on the lower end side than on the upper end side.
Thus, the diameter of the hole h is not equalized between the upper side and the lower side of the silicon oxide film 49, and consequently a variation in the characteristics of the memory string may be caused.
In contrast, in the embodiment, when the hole h is formed in the process shown in
In the comparative example, since the insulating film between the uppermost electrode film WL and the select gate SG is a single-layer film of the silicon oxide film 49, the film thickness of the silicon oxide film 49 sufficient to ensure the breakdown voltage between the electrode film WL and the select gate SG tends to be increased. An increase in the thickness of the insulating film between the uppermost electrode film WL and the select gate SG causes an increase in the parasitic resistance of the channel due to the increase of the distance between the channels of the select transistor and the uppermost memory cell.
On the other hand, in the embodiment, the insulating film 25 between the select gate SG and the uppermost electrode film WL includes at least part of the memory film 30 as described above, and includes a film with a higher dielectric constant than silicon oxide (e.g. a silicon nitride film). Therefore, the breakdown voltage of the insulating film 25 of the embodiment is higher than that of a single-layer film of a silicon oxide film, and the insulating film 25 of the embodiment can be made thinner than the single-layer film of a silicon oxide film.
Thus, the distance between the channels of the select transistor and the uppermost memory cell can be made shorter than in the case of the comparative example, and the parasitic resistance of the channel can be reduced.
Next,
Similarly to the embodiment described above, after trenches are formed in the back gate BG and the sacrifice film 82 is buried in the trench, as shown in
In this embodiment, the select gate SG is stacked by two separate steps. First, a first-story select gate SG1 is formed on the uppermost non-doped silicon film 42 as shown in
Next, the stacked body including the select gate SG1, the plurality of non-doped silicon films 42, the plurality of electrode films WL, and the insulating film 41 is divided by the insulating separation film 45 as shown in
After that, as shown in
That is, in this embodiment, the select gate SG is formed of the select gate SG1 and the select gate SG2 formed by two separate processes via the process of forming the insulating separation film 45.
Also in this embodiment, the select gate SG is formed on the uppermost electrode film WL via the non-doped silicon 42, and the select gate SG is formed directly on the uppermost non-doped silicon film 42. There is not an insulating film such as a silicon oxide film different from a silicon film between the uppermost non-doped silicon film 42 and the select gate SG.
The insulating film 47 is formed on the second-story select gate SG2. As shown in
Also in the embodiment, silicon films are processed from the select gate SG to the lowermost electrode film WL. Therefore, the setting of the conditions of RIE and the shape controllability of the hole h are easy, and a hole h with a uniform diameter can be formed from the select gate SG to the lowermost electrode film WL. Thus, the diameter of the columnar portion CL of the memory string can be made uniform from the select transistor to the lowermost memory cell, and desired characteristics can be obtained.
After the hole h is formed, similarly to the embodiment described above, the non-doped silicon film 42 and the sacrifice film 82 are removed via the hole h as shown in
The electrode films WL and the select gate SG are supported by the insulating separation film 45, and the state where the plurality of electrode films WL and the select gate SG are stacked via the space 26 is maintained. In the embodiment, since the upper portion of the insulating separation film 45 cuts into the lower portion of the select gate SG (the select gate SG1), the support of the select gate SG by the insulating separation film 45 is stabilized.
After the memory hole MH and the space 26 are formed, as shown in
Also in the embodiment, the insulating film 25 is formed in the space 26 shown in
Therefore, also in the embodiment, the distance between the channels of the select transistor and the uppermost memory cell can be made shorter than in the case of the comparative example, and the parasitic resistance of the channel can be reduced.
After that, as shown in
While certain embodiments have been described, these embodiments have been presented by way of example only, and are not intended to limit the scope of the inventions. Indeed, the novel embodiments described herein may be embodied in a variety of other forms; furthermore, various omissions, substitutions and changes in the form of the embodiments described herein may be made without departing from the spirit of the inventions. The accompanying claims and their equivalents are intended to cover such forms or modifications as would fall within the scope and spirit of the invention.
Number | Date | Country | Kind |
---|---|---|---|
2012-139011 | Jun 2012 | JP | national |