The present application relates to a semiconductor power device, especially relates to a semiconductor power device with an interlayer in the buffer layer.
Due to the demand of the semiconductor power device used for switch in high frequency, group III-V semiconductor materials, such as GaN, recently used for power device operated in high frequency develops rapidly. Because group III-V semiconductor materials are capable of forming a two-dimensional electron gas (2DEG) due to the piezoelectric effect in the junction, group III-V semiconductor materials with 2DEG has the advantages of outputting high electrical current concentration, low switching losing, and operating in high voltage with the characteristics of the high mobility of the electrons, high electrons concentration of 2DEG, and the low electrical resistance of GaN. Thus, group III-V semiconductor materials are suitable for power device.
Common power device comprises Bipolar Junction Transistor (BJT) and Field Effect Transistor (FET), wherein BJT turns on and off by controlling the bias voltage of the two pn-junctions thereof and has certain ratio of the output current to the input current, which is current gain. FET turns on and off by controlling the input signal to change the electrical field thereof and therefore the characteristic of the tunnel. Both BJT and FET have the breakdown voltage and leakage current issues when they adopt group III-V semiconductor materials to improve switch speed and efficiency. Especially, due to the lattice mismatch between the substrate and the following growth epitaxial material, the epitaxial quality such as the dislocation concentration of the epitaxial layer, significantly influences the value of the breakdown voltage and leakage current of BJT or FET.
A semiconductor power device, comprising: a substrate; a first semiconductor layer with a first lattice constant formed on the substrate, wherein the first semiconductor layer comprises a first group III element; a first grading layer formed on the first semiconductor layer and comprising a first portion; a second semiconductor layer with a second lattice constant formed on the first grading layer, wherein the second semiconductor layer comprises a second group III element; and a first interlayer formed in the first grading layer and adjacent to the first portion of the first grading layer, wherein a composition of the first interlayer is different from that of the first portion, and the first grading layer comprises the first group III element and the second group III element, and concentrations of both the first group III element and the second group III element in the first grading layer are gradually changed.
Exemplary embodiments of the present application will be described in detail with reference to the accompanying drawings hereafter. The following embodiments are given by way of illustration to help those skilled in the art fully understand the spirit of the present application. Hence, it should be noted that the present application is not limited to the embodiments herein and can be realized by various forms. Further, the drawings are not precise scale and components may be exaggerated in view of width, height, length, etc. Herein, the similar or identical reference numerals will denote the similar or identical components throughout the drawings.
The material of the substrate 2 can be Sapphire, GaN, AlN or Si. In other embodiment, a portion of the substrate 2 can be removed to shorten the leakage current path of the semiconductor power device for reducing the leakage current when forming the semiconductor power device. The semiconductor layer 4 is formed on the substrate 2 as a buffer layer for reducing the lattice constant difference between the substrate 2 and the following growth epitaxial stack. In the embodiment, the material of the semiconductor layer 4 is AlN and formed on the [111] surface of the substrate 2 formed of GaN. The first grading layer 6 formed on the semiconductor layer 4 comprises the first part 106, the second part 107, and the first interlayer 8 wherein the first layer 8 can be amorphous material, and the first part 106 and the second part 107 can be semiconductor material. Specifically, the first layer 8 comprises SiN, which can be amorphous material, and the first part 106 and the second part 107 are formed of AlGaN, which can be semiconductor material. In other words, the first part 106 and the second part 107 comprising group III-V elements are separated by the first layer 8 which comprises the composition of the group III-V elements different from that of the first part 106 or the second part 107. In other embodiment, the first layer 8 can cover a portion of the first part 106, which means that a portion of the first part 106 and the second part 107 contact directly without the first interlayer 8 therebetween. In that case, the first layer 8 is a patterned structure, which is periodic, semi-periodic or aperiodic, formed on the first part 106. The first part 106 and the second part 107 comprise the same characteristic of gradual change, which means the Al concentration of AlGaN of the first part 106 or the second part 107 decreases along the direction away from the substrate 2 and the Ga concentration of AlGaN of the first part 106 or the second part 107 increases along the direction away from the substrate 2. In other words, the concentration of Ga of the second part 107 is higher than that of the first part 106, and the Al concentration of the first part 106 is higher than that of the second part 107. From the energy bandgap point of view, the first part 106 has higher energy bandgap than that of the second part 107, and the bandgap decreases along the direction away from the substrate 2. Specifically, in the embodiment, the chemical formula of the AlGaN of the first part 106 can be Alx1Gay1N, and that of the second part 107 can be Alx2Gay2N, wherein 0<x2≦x1≦1 and 0<y1≦y2≦1. That is, the first part 106 and the second part 107 comprise different composition ratio of AlGaN in different position.
To be more specific, the second part 107 comprises more Ga and less Al than the first part 106. In another embodiment, the compositions of AIGaN of the first part 106 and the second part 107 in the neighboring region can be the same. In other words, Alx1Gay1N of some portion of the first part 106 and Alx2Gay2N of some portion of the second part 107 can have the characteristics of x2=x1 and y1=y2. Since the Al concentration decreases along the direction away from the substrate 2 and the concentration of Ga increases along the direction away from the substrate 2 in both the first part 106 and the second part 107, if they have regions having the same compositions, such regions should be t closest to each other in the first part 106 and the second part 107. In other words, where the first part 106 and the second part 107 directly contact the first interlayer 8 should have the same chemical composition. In the embodiment, the second part 107 has larger lattice constant than that of the first part 106, and the lattice constants of the first part 106 and the second part 107 are between the lattice constants of the tunnel layer 10 and the semiconductor layer 4. In the embodiment, the first part 106 and the second part 107 of the first grading layer 6 comprise AIGaN. In other embodiment, the first part 106 and the second part 107 can also comprise AlInGaN.
As above mentioned, by forming the first interlayer 8 having the composition of group III-V materials different from those of adjacent semiconductor layers , the defects occurring in the adjacent the semiconductor layer, such as the first part 106, are barred by the first interlayer 8 from extending to the second part 107 so the defect density of the epitaxial layers is decreased effectively, the quality of the epitaxial layers is improved, and the issues of the leakage current and breakdown voltage of the power device made of the epitaxial layers are further improved. The stack of the tunnel layer 10 and the electron supplying layer 12 are formed on the first grading layer 6. In the embodiment, the tunnel layer 10 is made of GaN, and the electron supplying layer 12 is made of AIGaN. A portion of the tunnel layer 10 is doped with carbon and another portion of the tunnel layer 10 is undoped with carbon, of which the portion undoped with carbon is adjacent to the electron supplying layer 12, whereas the portion doped with carbon is far away from the electron supplying layer 12. The thickness of the portion of the tunnel layer 10 undoped with carbon is about 10˜1000 nm, and preferably can be between 50˜150 nm. The piezoelectric effect and polarization caused by the different lattice constants of the tunnel layer 10 and the electron supplying layer form the two-dimensional electron gas (2DEG) in the portion of the tunnel layer 10 undpoed with carbon. Since the tunnel layer 10 and the electron supplying layer 12 are the combination of GaN and AIGaN, the heterostructure formed of GaN and AIGaN has higher electron mobility and high concentration of electron carriers, which make the device formed of thereof having high power and high efficiency. And, the heterostructure of GaN/AIGaN not only provides higher electron mobility and high concentration of electron carriers, but also the power device formed of thereof is capable of working with high frequency in high voltage and high temperature. In the embodiment, the defects from the difference of lattice constants between the semiconductor layer 4 and the tunnel layer 10 can be reduced by setting the first grading layer 6 therebetween. In other words, the difference of lattice constants between the semiconductor layer 4 and the first part 106 is larger than that between the second part 107 and tunnel layer 10. Therefore, comparing with the larger lattice constant difference of the tunnel layer 10 directly formed on the semiconductor layer 4, the existence of the first grading layer 6 is able to prevent two epitaxial layers from continuously growing epitaxial layers having substantially different lattice constants so the quality of epitaxial growth is improved. As the aforementioned, the defects occurring in the first part 106 during the growth thereof are barred by the first interlayer 8 of the first grading layer 6 from extending to the second part 107 for improving the quality of the epitaxial stacking layers. In the embodiment, the tunnel layer 10 and the electron supplying layer 12 are formed of undoped semiconductor materials. In other embodiment, the tunnel layer 10 further comprises a secondary electron supplying layer (not shown in the figures) between the tunnel layer 10 and the first grading layer 6, and the material of the secondary electron supplying layer can be GaN doped with carbon or comprise same AIGaN as that of the electron supplying layer 12. The difference of lattice constants between the secondary electron supplying layer and the tunnel layer 10 can increase the effect of piezoelectric polarization and spontaneous polarization for increasing the concentration of the 2DEG in the tunnel layer 10.
As
In the embodiment, the second interlayer 9 of the second grading layer 7 is formed of the same amorphous material, such as SiN, as that of the first interlayer 8 of the first grading layer 6. In other embodiment, other grading layer can be further formed on the second grading layer 7, wherein the grading layer has or do not have an interlayer. After forming multiple grading layers, the tunnel layer 10 and the electron supplying layer 12 are formed on thereof. In the embodiment, the third part 108 and the fourth part 109 of the second grading layer 7 have larger lattice constant than that of the first part 106 and the second part 107 of the first grading layer 6.
And, the lattice constants of the first part 106, the second part 107, the third part 108 and the fourth part 109 are between the lattice constants of the tunnel layer 10 and the semiconductor layer 4. In the embodiment, the first grading layer 6 and the second grading layer 7 comprise AIGaN. In other embodiment, the first grading layer 6 and the second grading layer 7 can also comprise AlInGaN.
In abovementioned embodiment, the semiconductor layer 4 formed of AlN is formed by importing trimethylaluminum and ammonia into a reaction chamber. Namely, the flow rate of trimethylaluminum is about 220 sccm and the flow rate of ammonia is about 1000 sccm for forming the semiconductor layer 4 formed of AlN with a thickness of 150 nm. The materials of the first grading layer 6 and the second grading layer 7 comprise group III-V semiconductor materials, such as AlGaN, wherein the Al concentration can be between 20% and 80%. In the embodiment, the first grading layer 6 and the second grading layer 7 are the grading layers formed of AIGaN which is formed by importing trimethylaluminum, trimethylgallium and ammonia into a reaction chamber. Furthermore, the compositions of these grading layers can be gradually changed by adjusting the ratio of these gases. Specifically, the first grading layer 6 and the second grading layer 7 with different compositions are formed by importing trimethylaluminum, ammonia and trimethylgallium, of which the ratio is about between 30:1:1000 and 65:25:4000, wherein the flow rate of trimethylaluminum is about 65˜300 sccm, the flow rate of trimethylgallium is about 10˜25 sccm, and the flow rate of ammonia is about 1000˜4000 sccm. In the embodiment, the tunnel layer 10 is formed of GaN, which is grown by metal organic vapor deposition with ammonia and trimethylgallium, wherein the ratio of trimethylgallium to ammonia to be imported into the chamber is about 60:1, the flow rate of trimethylgallium is about 130 sccm and the flow rate of ammonia is about 6000 sccm, and the thickness of the tunnel layer 10 is between 25 nm and 3000 nm. A portion of the tunnel layer 10 is doped with carbon and another portion of the tunnel layer 10 is undoped with carbon, wherein the portion undoped with carbon is far away from the second grading layer 7 and the portion doped with carbon is adjacent to the second grading layer 7. The thickness of the portion of the tunnel layer 10 undoped with carbon is about 10˜1000 nm, and preferably can be between 50˜150 nm. In the embodiment, the flow rate of the gases imported into the reaction chamber and the ratio of the gases can be adjusted based on the requirement.
As
In the abovementioned embodiment, the characteristic of gradual change of AIGaN or AlGaInN of the first grading layer 6 and the second grading layer 7 can be continuous type or discontinuous type, such as stepped type. Referring to the gradual change types A to I shown in
As
In another embodiment, the first interlayer 8 comprises a series of alternate AlxGa1-xN/AlyGa1-yN/Al2Ga1-zN layers, and |x-y|≧0.2, |y-z|≧0.2, wherein the AlxGa1-xN layer is the closest to the semiconductor layer 4 and the AlzGa1-zN layer is the farthest away from the semiconductor layer 4 among the AlxGa1-xN/AlyGa1-yN/Al2Ga1-zN layers, and the series of alternate AlxGa1-xN/AlyGa1-yN/Al2Ga1-zN layers starts from AlxGa1-zN adjacent to the first part 106. In other embodiment, the relationship of x, y, z, a and b can be x>a=b≧y>z, x>y≧a=b>z,a>x>y>z>b,x>a>b≧y>z,x>a≧y>b>z, or x>y≧a>b>z.
As
The first part 106 and the second part 107 of the first grading layer 6 respectively have a first interface 1061 and a second interface 1071 adjacent to the first interlayer 8, wherein the portion of first part 106 near the first interface 1061 is formed of AlaGai-aN, and the portion of the second part 107 near the second interface 1071 is formed of AlbGa1-bN, wherein the relationship of a and b can be a=b or a≠b. In other embodiment, the relationship of x1, y1, a and b can be x1>a=b>y1, a>x1>y1>b, or x1>a>b>y1.
The third part 108 and the fourth part 109 of the second grading layer 7 respectively have an third interface 1081 and a fourth interface 1091 adjacent to the second interlayer 9, wherein the portion of the third part 108 near the third interface 1081 is formed of AlcGa1-cN, and the portion of the fourth part 109 near the fourth interface 1091 is formed of AldGai-dN, wherein the relationship of c and d can be c=d or c≠d. In other embodiment, the relationship of x2, y2, c and d can be x2>c=d>y2, c>x2>y2>d, or x2>c>d>y2.
In another embodiment, the first interlayer 8 comprises a first series of alternating Alx1Ga1-x1N/Alz1Ga1-z1N/Alz1Ga1-z1N layers, |x1-y1|≧0.2, |y1-z1|≧0.2, wherein the Alx1Ga1-x1N layer is the closest to the semiconductor layer 4 and the Alz1Ga1-z1N layer is the farthest away from the semiconductor layer 4 among the Alx1Ga1-x1N/Alz1Ga1-z1N/Alz1Ga1-z1N layers, and the series of alternate Alx1Ga1-x1N/Alz1Ga1-z1N/Alz1Ga1-z1N layers starts from AlxiGa1-x1N adjacent to the first part 106. The second interlayer 9 comprises a second series of alternate Alx2Ga1-x2N/Aly2Ga1-y2N/Al,2Ga1-z2N layers, |x2-y2|≧0.2, |y2-z2|≧0.2, wherein the Alx2Ga1-x2N layer is the closest to the semiconductor layer 4 and the Alz2Ga1-z2N layer is the farthest away from the semiconductor layer 4 among the Alx2Ga 1-x2N/Aly2Ga1-y2N/Al,2Ga1-z2N layers, and the series of alternate Alx2Ga1-x2N/Aly2Ga1-y2/Alz2Ga1-z2N layers starts from Alx2Ga1-x2N adjacent to the third part 108. In one embodiment, the average of x1, y1 and z1 is larger than that of x2, y2 and z2. In other embodiment, the relationship of x1, y1, z1, a and b can be x1>a=b≧y1>z1, x1>y1 a=b>z1, a>x1>y1>z1>b, x1>a>b≧y1>z1, x1>a>y1>b>z1, or x1>y1 a>b>z1. The relationship of x2, y2, z2, c and d can be x2>c=d≧y2>z2, x2>y2 c=d>z2, c>x2>y2>z2>d, x2>c>d≧y2>z2, x2>c>y2>d>z2, or x2>y2 c>d>z2.
As being understood by a person skilled in the art, the foregoing preferred embodiments of the present application are illustrated of the present application rather than limiting of the present application. It is intended to cover various modifications and similar arrangements included within the spirit and scope of the appended claims, the scope of which should be accorded the broadest interpretation so as to encompass all such modifications and similar structure.
Number | Date | Country | Kind |
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102129615 | Aug 2013 | TW | national |