Claims
- 1. A silver halide color photographic material having a yellow-coupler-containing silver halide emulsion layer, a magenta-coupler-containing silver halide emulsion layer, and a cyan-coupler-containing silver halide emulsion layer, which respective layers are different in color sensitivity from each other, and non-photosensitive hydrophilic colloid layers, on a reflective support; which comprises (i) a reflective support prepared by laminating at least the surface to be emulsion-coated of a base support, which has been subjected to surface treatment by machine calendering, with a composition prepared by mixing and dispersing a white pigment into a water-resistant resin whose major component is a polyester obtained by polycondensation of a dicarboxylic acid and a diol, (ii) a silver halide emulsion of at least one emulsion layer comprising silver halide grains having a silver chloride content of 90 mol % or more, (iii) at least one non-photosensitive layer containing at least one color-mix inhibitor having a molecular weight of 350 or more, and (iv) a yellow coupler having a relative coupling rate of 0.20 or over;
- wherein the base support is a paper support;
- wherein the resin-containing composition is subjected to a surface treatment after being laminated on the base support, and then an undercoat layer is coated thereon.
- 2. The silver halide color photographic material as claimed in claim 1, wherein the polyester on the reflective support is a polyester whose major component is a polyethylene terephthalate.
- 3. The silver halide color photographic material as claimed in claim 1, wherein the dicarboxylic acid is selected from the group consisting of terephthalic acid, isophthalic acid, and naphthalenedicarboxylic acid.
- 4. The silver halide color photographic material as claimed in claim 1, wherein the reflective support is prepared by covering at least the surface to be emulsion-coated of the support with a resin composition obtained by mixing and dispersing a white pigment into a polyester synthesized by polycondensation of mixed dicarboxylic acids of terephthalic acid and isophthalic acid and a diol.
- 5. The silver halide color photographic material as claimed in claim 4, wherein the molar ratio of terephthalic acid and isophthalic acid is 9/1 to 2/8.
- 6. The silver halide color photographic material as claimed in claim 1, wherein the reflective support is prepared by covering at least the surface to be emulsion-coated of the support with a resin composition obtained by mixing and dispersing a white pigment into a polyester synthesized by polycondensation of mixed dicarboxylic acids of terephthalic acid and naphthalenedicarboxylic acid and a diol.
- 7. The silver halide color photographic material as claimed in claim 6, wherein the molar ratio of terephthalic acid and naphthalenedicarboxylic acid is 9/1 to 2/8.
- 8. The silver halide color photographic material as claimed in claim 1, wherein the diol component is selected from the group consisting of ethylene glycol, butylene glycol, neopentyl glycol, triethylene glycol, butanediol, hexylene glycol, an adduct of bisphenol A with ethylene oxide, and 1,4-dihydroxymethylcyclohexane.
- 9. The silver halide color photographic material as claimed in claim 8, wherein the diol component is ethylene glycol.
- 10. The silver halide color photographic material as claimed in claim 1, wherein the white pigment is selected from the group consisting of titanium oxide, barium sulfate, lithopone, aluminum oxide, calcium carbonate, silicon oxide, antimony trioxide, titanium phosphate, zinc oxide, white lead, zirconium oxide, a finely divided powder of a polystyrene and a finely divided power of a styrene/divinylbenzene copolymer.
- 11. The silver halide color photographic material as claimed in claim 1, wherein the mixing weight ratio of the white pigment to the water-resistant resist resin is from 5/95 to 70/30.
- 12. The silver halide color photographic material as claimed in claim 1, wherein the white pigment is titanium dioxide, and the weight ratio of the white pigment to the resin that is mixed with said white pigment, which resin's major component is a polyester, is from 5/95 to 70/30.
- 13. The silver halide color photographic material as claimed in claim 1, wherein the color-mix inhibitor having a molecular weight of 350 or more is represented by the following formula (I): ##STR13## wherein X.sub.1, X.sub.2, X.sub.3, R.sub.1, and R.sub.2 each represent a hydrogen atom or a substituent, and at least one of X.sub.1, X.sub.2, and X.sub.3 represents a hydroxyl group or a sulfonamido group, provided that X.sub.1, X.sub.2, X.sub.3, R.sub.1, and R.sub.2 are selected such that the molecular weight of the compound is 350 or more, the substituents in the ortho-positions relative to each other may bond together to form a ring, and any of X.sub.1, X.sub.2, X.sub.3, R.sub.1, and R.sub.2 may be bonded to a polymer chain or may be bonded to a compound represented by formula (I) to form a dimer or a higher polymer.
- 14. The silver halide color photographic material as claimed in claim 1, wherein at least two intermediate layers, each arranged between silver halide emulsion layers, contain at least one color-mix inhibitor, and the total amount of the at least one color-mix inhibitor contained in the at least two intermediate layers is 0.05 to 0.5 g/m.sup.2.
- 15. The silver halide color photographic material as claimed in claim 1, wherein the amount of yellow coupler is 0.002 to 0.5 mol per mol of the photosensitive silver halide in the same layer.
- 16. A method for forming a color image, which comprises exposing a color photographic material as claimed in claim 1 to light in a scanning exposure method with the exposure time being 10.sup.-4 sec or less per picture element, and then color-development processing said exposed color photographic material.
Priority Claims (1)
Number |
Date |
Country |
Kind |
4-343424 |
Nov 1992 |
JPX |
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Parent Case Info
This is a Continuation of application Ser. No. 08/159,253 filed Nov. 30, 1993now abandoned.
US Referenced Citations (5)
Number |
Name |
Date |
Kind |
4732845 |
Keiji et al. |
Mar 1988 |
|
4980274 |
Tai et al. |
Dec 1990 |
|
5270158 |
Nakatsugawa et al. |
Dec 1993 |
|
5273867 |
Shibuya et al. |
Dec 1993 |
|
5288599 |
Takahashi et al. |
Feb 1994 |
|
Foreign Referenced Citations (3)
Number |
Date |
Country |
69070 |
Jan 1983 |
EPX |
98072 |
Jan 1984 |
EPX |
507489 |
Oct 1992 |
EPX |
Continuations (1)
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Number |
Date |
Country |
Parent |
159253 |
Nov 1993 |
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