Claims
- 1. A silver halide photographic light-sensitive material comprising a support and, provided thereon, a silver halide emulsion layer, containing silver bromochloride grains having a silver bromide content of 0.01 to 2 mol % and having a (100) face, and a crown ether having a 18-membered ring condensed with at least one aromatic ring, wherein said silver halide grains satisfy the following inequality:
- 15.ltoreq.K
- wherein K is defined to be (intensity of a diffraction line attributed to a (200) face)/(intensity of a diffraction line attributed to a (222) face), said intensity being measured by an X-ray diffraction method.
- 2. The material of claim 1, wherein said silver halide emulsion further contains in an amount of 2.times.10.sup.-8 to 1.times.10.sup.-2 mol per mol of silver a red-sensitive sensitizing dye represented by the following Formula (I) or (II): ##STR16## wherein R.sub.1, R.sub.2, R.sub.3, and R.sub.4 independently represent an alkyl group, an alkenyl group or an aryl group; L.sub.1, L.sub.2, L.sub.3, L.sub.4 and L.sub.5 independently represent a methine group; Z.sub.1, Z.sub.2, Z.sub.3, and Z.sub.4 independently represent an atom or atomic group necessary to form a 5- or 6-membered heterocyclic ring; Z.sub.5 represents a hydrocabon atomic group necessary to form a 6-membered ring; m.sub.1, m.sub.2, m.sub.3, and m.sub.4 independently represent 0 or 1; n represents 0 or 1; X.sup.- represents an anion; and Y.sub.1 and Y.sub.2 independently represent 0 or 1.
- 3. The material of claim 2 wherein said red-sensitive sensitizing dye is one represented by the following Formula (III) or (IV): ##STR17## wherein Y.sup.1, Y.sup.2, Y.sup.3, and Y.sup.4 independently represent an oxygen atom, a sulfur atom or a selenium atom; A.sup.1, A.sup.2, A.sup.3, A.sup.4, B.sup.1, B.sup.2, B.sup.3, B.sup.4, C.sup.1, C.sup.2, C.sup.3, C.sup.4, D.sup.1, D.sup.2, D.sup.3, and D.sup.4 independently represent a hydrogen atom, a halogen atom, an alkyl group, an alkoxy group, a phenyl group, a cyano group, a nitro group or an alkoxycarbonyl group, provided that at least one of A.sup.1 and B.sup.1, B.sup.1 and C.sup.1, C.sup.1 and D.sup.1, A.sup.2 and B.sup.2, B.sup.2 and C.sup.2, C.sup.2 and D.sup.2, A.sup.3 and B.sup.3, B.sup.3 and C.sup.3, C.sup.3 and D.sup.3, A.sup.4 and B.sup.4, B.sup.4 and C.sup.4, and C.sup.4 and D.sup.4 may combine to form a benzene ring; R.sup.5 and R.sup.6 independently represent methyl, ethyl, propyl, butyl, or trifluoromethyl groups; R.sup.1, R.sup.2, R.sup.3, and R.sup.4 independently represent an alkyl group, an alkenyl group or an aryl group; L.sup.1, L.sup.2, L.sup.3, L.sup.4 and L.sup.5 independently represent a methine group; n.sup.1 represents 0 or 1; X.sup.- represents an anion; and Y.sup.1 and Y.sup.2 independently represent 0 or 1.
- 4. The material of claim 1, wherein said silver halide emulsion layer contains the crown ether in an amount of 1.times.10.sup.-6 to 1.times.10.sup.-1 mol per mol of silver.
- 5. The material of claim 1, wherein said silver halide grains are cubic or tetradecahedral.
- 6. A silver halide photographic light-sensitive material comprising a support and provided thereon, a blue sensitive silver halide emulsion layer, a green sensitive silver halide emulsion layer and a red sensitive silver halide emulsion layer, each layer containing silver bromochloride grains having a (100) face and satisfying the following inequality:
- 15.ltoreq.K
- wherein K is defined to be (intensity of a diffraction line attributed to a (200) face)/(intensity of a diffraction line attributed to a (222) face), said intensity being measured by an X-ray diffraction method, and said red sensitive layer containing a crown ether having a 18-membered ring condensed with at least one aromatic ring in an amount of 1.times.10.sup.-6 to 1.times.10.sup.-1 mol per mol of silver and a red-sensitive sensitizing dye in an amount of 2.times.10.sup.-8 to 1.times.10.sup.-2 mol per mol of silver, said red sensitive dye being represented by the following Formula (I) or (II): ##STR18## wherein R.sub.1, R.sub.2, R.sub.3, and R.sub.4 independently represent an alkyl group, an alkenyl group or an aryl group; L.sub.1, L.sub.2, L.sub.3, L.sub.4 and L.sub.5 independently represent a methine group; Z.sub.1, Z.sub.2, Z.sub.3, and Z.sub.4 independently represent an atom or atomic group necessary to form a 5- or 6-membered heterocyclic ring; Z.sub.5 represents a hydrocabon atomic group necessary to form a 6-membered ring; m.sub.1, m.sub.2, m.sub.3, and m.sub.4 independently represent 0 or 1; n represents 0 or 1; X.sup.- represents an anion; and Y.sub.1 and Y.sub.2 independently represent 0 or 1.
- 7. The material of claim 6, wherein said silver bromochloride grains have a silver bromide content of 0.01 to 2 mol %.
Priority Claims (1)
Number |
Date |
Country |
Kind |
2-020272 |
Feb 1993 |
JPX |
|
Parent Case Info
This application is a continuation of application Ser. No. 08/185,481, filed Jan. 21, 1994.
US Referenced Citations (2)
Number |
Name |
Date |
Kind |
5147770 |
Waki et al. |
Sep 1992 |
|
5246828 |
Okuyama et al. |
Sep 1993 |
|
Foreign Referenced Citations (1)
Number |
Date |
Country |
509810 |
Oct 1992 |
EPX |
Continuations (1)
|
Number |
Date |
Country |
Parent |
185481 |
Jan 1994 |
|