Claims
- 1. A silver halide photographic light-sensitive material comprising
- (a) a support,
- (b) a silver halide photographic emulsion layer provided on a first side of said support,
- (c) a protective layer provided on said emulsion layer, and
- (d) a backing layer on a second side of said support opposite said first side,
- wherein an outermost layer of said first side or said second side contains a fluorine-containing anionic surfactant and a fluorine-containing cationic surfactant, and said outermost layer of said second side contains a compound represented by Formula A or B:
- Formula A RCOOM
- wherein R is an aliphatic hydrocarbon group and M is a cation,
- Formula B R.sub.1 --CO--O--X--O--CO--R.sub.2
- wherein R.sub.1 and R.sub.2 each represent an aliphatic hydrocarbon group and X is a divalent bonding group.
- 2. The material of claim 1, wherein said fluorine-containing anionic surfactant is a compound represented by the following Formula (FA): ##STR13## wherein Cf represents a group having at least three fluorine atoms and at least two carbon atoms; and Y represents --COOM, --SO.sub.3 M, --OSO.sub.3 M, or --P(.dbd.O)(OM).sub.2 wherein M represents a hydrogen atom, an alkali metal or a quaternary ammonium group.
- 3. The material of claim 1, wherein said fluorine-containing anionic surfactant is a compound represented by the following Formula (FA'): ##STR14## wherein Rf represents a fluorine-containing alkyl group having 3 to 30 carbon atoms or a fluorinated aryl group having 6 to 30 carbon atoms; D represents a divalent bonding group having 1 to 12 carbon atoms and at least one selected from the group consisting of --O--, --COO--, --CON(R.sub.1)-- and --SO.sub.2 N(R.sub.1)-- wherein R.sub.1 represents an alkyl group having 1 to 5 carbon atoms; and Y represents --COOM, --SO.sub.3 M, --OSO.sub.3 M or --P(.dbd.O)(OM).sub.2 wherein M represents a hydrogen atom, an alkali metal or a quaternary ammonium group.
- 4. The material of claim 1, wherein the content of said compound is 1 to 500 mg per square meter of the light-sensitive material.
- 5. The material of claim 1, wherein the content of said compound is 5 to 100 mg per square meter of the light-sensitive material.
- 6. The material of claim 1, wherein said fluorine-containing cationic surfactant is a compound represented by the following Formula (FK):
- Formula (FK) Rh--T--X.sup.+ Z.sup.-
- wherein Rh represents a fluorine-containing hydrocarbon group having 3 to 20 carbon atoms; T represents a divalent bonding group; X represents a cation; and Z represent a counter anion.
- 7. The material of claim 1, wherein the total content of said fluorine-containing anionic surfactant and said fluorine-containing cationic surfactant is 0.1 to 1000 mg per square meter of the light-sensitive material.
- 8. The material of claim 1, wherein the total content of said fluorine-containing anionic surfactant and said fluorine-containing cationic surfactant is 1.0 to 150 mg per square meter of the light-sensitive material.
- 9. The material of claim 1, wherein said M in formula (A) represents Na, K, Li, Ca, Sr, Ba, HN(R.sub.2).sub.3 or N(R.sub.2).sub.4 wherein R.sub.2 represents an alkyl group having 1 to 18 carbon atoms.
- 10. The material of claim 1, wherein said R.sub.1 and R.sub.2 in formula (B) each represent an aliphatic hydrocarbon group having 12 to 70 carbon atoms.
- 11. The material of claim 1 wherein a mol ratio of said fluorine-containing anionic surfactant to said fluorine-containing cationic surfactant is 1:10 to 10:1.
- 12. The material of claim 11 wherein said mol ratio is 3:7 to 7:3.
- 13. The material of claim 1 wherein said outermost layer on said first side is said protective layer.
- 14. The material of claim 1 wherein said outermost layer on said second side of said support is an outermost layer of said backing layer.
Priority Claims (1)
Number |
Date |
Country |
Kind |
4-025337 |
Feb 1992 |
JPX |
|
Parent Case Info
This application is a continuation of application Ser. No. 08/012,721, filed Feb. 3, 1993, now abandoned.
US Referenced Citations (1)
Number |
Name |
Date |
Kind |
5075209 |
Sasaki |
Dec 1991 |
|
Foreign Referenced Citations (3)
Number |
Date |
Country |
395107 |
Oct 1990 |
EPX |
2260812 |
Sep 1975 |
FRX |
2012978 |
Aug 1979 |
GBX |
Continuations (1)
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Number |
Date |
Country |
Parent |
12721 |
Feb 1993 |
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