Claims
- 1. A silver halide photographic material comprising a support having thereon at least one light-sensitive silver halide emulsion layer containing silver halide grains, wherein a silver chloride content of the silver halide grains contained in said light-sensitive silver halide emulsion layer is at least 30 mol %, and a silver iodide content of said silver halide grains is from 0 to not higher than 2 mol %; wherein said emulsion contains from 1.times.10.sup.-9 to 1.times.10.sup.-6 mol per mol of silver of a rhodium compound; and wherein said silver halide grains have been selenium-sensitized and sulfur sensitized.
- 2. The silver halide photographic material as in claim 1, wherein said light-sensitive silver halide emulsion contains at least one compound selected from the group consisting of an iron compound, a rhenium compound, a ruthenium compound and a osmium compound, in an amount greater than zero but not greater than 1.times.10.sup.-3 mol, per mol of silver.
- 3. The silver halide photographic material as in claim 1, wherein the silver halide grains have been selenium-sensitized by a selenium compound represented by formula (VI-a) or (VI-b): ##STR49## wherein Z.sub.11 and Z.sub.12 may be the same or different and each represents an alkyl group, an alkenyl group, an aralkyl group, an aryl group, a heterocyclic group, --NR.sub.11 (R.sub.12), --OR.sub.13 or --SR.sub.14 ; and wherein R.sub.11 and R.sub.12 may be the same or different and each represents a hydrogen atom, an acyl group, an alkyl group, an aryl group or a heterocyclic group; R.sub.13 and R.sub.14 may be the same or different and each represents an alkyl group, an aryl group or a heterocyclic group; ##STR50## wherein Z.sub.23, Z.sub.24 and Z.sub.25 may the same or different and each represents an aliphatic group, an aromatic group, a heterocyclic group, --OR.sub.27, --NR.sub.28 (R.sub.29), --SR.sub.30, --SeR.sub.31, a halogen atom or a hydrogen atom; R.sub.27, R.sub.30 and R.sub.31 each represents an aliphatic group, an aromatic group, a heterocyclic group, a hydrogen atom or a cation; R.sub.28 and R.sub.29 each represents an aliphatic group, an aromatic group, a heterocyclic group or a hydrogen atom.
- 4. The silver halide photographic material as in claim 3, wherein the alkyl group represented by R.sub.11, R.sub.12, R.sub.13 and R.sub.14, is an aralkyl group.
- 5. The silver halide photographic material as in claim 1, wherein the silver halide grains have been sensitized by using at least 1.times.10.sup.-8 mol per mol silver halide of a selenium sensitizing agent.
- 6. The silver halide photographic material as in claim 1, wherein the silver halide emulsion contains at least one polyhydroxybenzene compound represented by formula (VII-a), (VII-b) or (VII-c): ##STR51## wherein X.sub.0 and Y.sub.0 each represents --H, --OH, a halogen atom, --OM wherein M is an alkali metal ion, an alkyl group, a phenyl group, an amino group, a carbonyl group, a sulfone group, a carboxyl group, an alkyl ether group, an alkyl thioether group or a phenylthioether group.
- 7. The silver halide photographic material as in claim 6, wherein the alkyl group represented by X.sub.0 and Y.sub.0 is a sulfonated alkyl group, a carboxyalkyl group or a hydroxyalkyl group, wherein the phenyl group represented by X.sub.0 and Y.sub.0 is a sulfonated phenyl group, a carboxyphenyl group, a hydroxyphenyl group, or an alkylphenyl group, and wherein the amino group represented by X.sub.0 and Y.sub.0 is a sulfonated amino group, or a carboxyamino group, and wherein the carbonyl represented by X.sub.0 and Y.sub.0 is a sulfonated carbonyl group.
- 8. The silver halide photographic material as in claim 1, wherein the silver halide grains have a cubic form or a plate form and have a mean grain size of 0.01 to 0.4 .mu.m.
Priority Claims (6)
Number |
Date |
Country |
Kind |
3-116573 |
Apr 1991 |
JPX |
|
3-116611 |
Apr 1991 |
JPX |
|
3-121798 |
Apr 1991 |
JPX |
|
3-124655 |
Apr 1991 |
JPX |
|
3-131590 |
May 1991 |
JPX |
|
3-189532 |
Jul 1991 |
JPX |
|
Parent Case Info
This is a Continuation of application Ser. No. 08/243,003 filed May 16, 1994, now abandoned, which is a Continuation of application Ser. No. 07/871,749 filed Apr. 21, 1992 and now abandoned.
US Referenced Citations (7)
Foreign Referenced Citations (10)
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0132806 |
Feb 1985 |
EPX |
0330401 |
Aug 1989 |
EPX |
0336426 |
Oct 1989 |
EPX |
0421452 |
Apr 1991 |
EPX |
457298 |
Nov 1991 |
EPX |
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DEX |
2632202 |
Feb 1977 |
DEX |
1170937 |
Jul 1989 |
JPX |
1154236 |
Jun 1969 |
GBX |
1527435 |
Oct 1978 |
GBX |
Continuations (2)
|
Number |
Date |
Country |
Parent |
243003 |
May 1994 |
|
Parent |
871749 |
Apr 1992 |
|