Patent Application
20050139064
The present invention relates to sliding material, particularly sliding material comprising fluorine plastic and binder resin for bonding the fluorine plastic, more particularly, the sliding material, which is suited for depositing on the sliding surface of a swash plate of the swash-plate compressor.
Fluorine plastic exhibits excellent low-friction property under the dry lubricating condition. However, in order to improve the wear resistance of the fluorine plastic-based sliding member, the fluorine plastic is blended with a solid lubricant such as MoS2, graphite and the like and they are bonded with base resin.
In the prior art, in order to improve the sliding properties of the fluorine-plastic based sliding material, the proportion ratio or amount, and the particle diameter of the additives, have been adjusted.
For example, it is disclosed in Japanese Unexamined Patent Publication No. 7-97517 that a sliding material, which consists of from 50 to 73% by weight of at least one of polyamide resin and polyimide resin, from 3 to 15% by weight of polytetrafluoroethylene (PTFE) resin as solid lubricant, from 20 to 30% of molybdenum disulfide (MoS2) and from 2 to 8% by weight of graphite, exhibits improved wear resistance and initial compatibility under the conditions of lubrication by graphite contained in the gray cast iron, low sliding speed of from 0.08 to 1 m/second, and relatively low load. This material is appropriate for use as the surface layer of a piston skirt.
It is disclosed in Japanese Unexamined Patent Publication No. 2000-136397 that sliding material, which contains from 10 to 40% by weight of calcined granular PTFE and from 3 to 40% by weight of graphite, the balance being a binder resin, i.e., polyimide and/or polyamide imide, exhibits improved sliding properties under the dry condition, and is appropriate as the sliding material of a wiper arm, which is operated under a low speed of 20 mm/s and relatively low load. The granular calcined PTFE is prepared by means of forming PTFE powder by suspension polymerization or emulsion polymerization, heating the resultant PTFE powder to melting temperature, i.e., calcining, and then pulverizing the calcined PTFE powder.
A swash-plate type compressor, an example of which is shown in
The prior art related to the surface treatment of a swash plate of the swash-plate type compressor includes the following.
A coating film consisting of a mixture of a solid lubricant and PEEK resin is formed on the swash plate.
The PTFE contained in the coating composition according to the prior art (2) mentioned above exhibits a low-friction effect at the sliding with shoes, under such a lubricating-oil poor sliding condition that a swash-plate type compressor mounted in a vehicle is started and driven to rotate and is lubricated only by the cooling media. Specifically, heat generation is suppressed by PTFE. On the other hand, when it is desired to rapidly cool the interior of a vehicle, the swash-plate type compressor is operated under the sliding conditions of high speed and high load. In this case, the PTFE contained in the coating composition undergoes serious peeling wear so that the surface is drastically damaged and seizure occurs.
The surface treatment according to the prior art (1) mentioned above provides the coating film consisting only of metal. There is a possibility that the swash plate subjected to this surface treatment may seize with respect to the opposite member, i.e., the shoes, under poor lubricating-oil operating conditions.
The surface treatments according the prior arts (3), (4), (6), and (7) mentioned above provide a solid-lubricant coating film on the surface of metal. This coating film may incur under such recent sliding conditions as high-speed rotation and high load a problem of peeling.
The surface coating of DLC according to the prior art (5) mentioned above may crack under the reciprocating load like the case of resin coating film.
The prior art (8) mentioned above provides a resin coating layer or a plating layer on the sintered metallic layer. Since the contact area between the resin coating layer and the sintered metal is larger than that of such layer and the non-sintered and hence non-porous metal, peeling of the resin coating layer is impaired. However, fundamentally, the peeling of the resin coating cannot be prevented, because the resin is of low strength and cannot withstand the load from the shoes.
It is, therefore, an object of the present invention to improve the sliding properties of a sliding material which is subjected to high speed and high load and is used under varying sliding conditions from the lubricating-oil free condition to the lubricating-oil condition and vice versa.
It is a particular object of the present invention to lessen the peeling wear of the sliding material containing PTFE and to modify its wear mechanism such that little wear occurs gradually and hence an improved compatible surface is formed.
In accordance the objects of the present invention, there is provided a sliding material, which comprises fluorine-plastic particles having a flat ratio of from 1.5 to 10 in terms of the average aspect ratio and binder resin.
There is also provided a sliding material, which comprises fluorine-plastic particles having a flat ratio of from 1.5 to 10 in terms of the average aspect ratio and binder resin.
The fluorine plastic particle is preferably at least one selected from the group consisting of polytetrafluoroethylen (PTFE), tetrafluoroethylene perfluoroalkoxy vinyl ether copolymer(PFA), perfluoroethylene propylene tetrafluoroethylenen hexafluoropylene(FEP), ethylene-tetrafluoroethylene copolymer (ETFE), polyvinyldenefluoride (PVdF), and ethylene-chlorotrifluoroethylene copolymer (ECTFE).
In the description hereinafter, the fluorine plastic is described by referring to a representative example of PTFE.
The granular PTFE particles have smaller surface area than the flat PTFE particles. The bonding strength of the former particles with the binder is, therefore, lower than that of the latter particles. The former particles are, therefore, liable to separate from the binder, so that peeling of PTFE is induced. Contrary to this, the sliding material comprising the flat PTFE particles bonded with the binder has improved compatibility such that fluid lubrication can be realized on the surface of the sliding material.
Meanwhile, under such poor oil condition at the initial sliding period that only the cooling media lubricates, PTFE exhibits low-friction property independently upon the shape of PTFE particles. The friction between the PTFE-containing sliding material and a shoe is, therefore low during sliding. Specifically, the extremely thin surface of the PTFE particles having a thickness of few atom-layers is subject to cleavage. This process takes place even under extremely weak external force, so that satisfactorily low friction is realized.
The granular PTFE particles can be flattened by means of imparting strong shear blending. A bead mill blender, which can perform strong shear blending, was used to prepare the solid-lubricant coating-mixture, which may be referred to as the paint. The average aspect ratio of PTFE particles and the blending time of the paint were investigated. The seizure time in dependent on the average aspect ratio was also investigated.
The composition of the paint was 60% by volume of PAI, 20% by volume of PTFE, and 20% by volume of graphite for every blended mixture with the varied average aspect ratio.
The testing condition was as follows.
Testing Machine: 3 pin/disc type seizure tester
Load: 1.2 kN
Number of Revolutions: 1000 rpm
Lubricating Condition: R 134 gas
Opposite Shaft: SUJ 2 (shoe form)
As is clear from
The binder is selected from a heat-resistant resin and is preferably at least one selected from polyamide imide and polyimide. Proportion of the fluorine plastic particles is preferably from 5 to 40% by volume, more preferably from 15 to 35% by volume based on the total volume of the fluorine plastic particles and binder, or the total volume of the fluorine plastic particles, the wear-resistant additives and/or the solid lubricant, and the binder. Either of these volumes is hereinafter referred to as the total volume.
If necessary, at least one solid lubricant selected from the group consisting of MoS2 and graphite is contained in a proportion of from 2 to 20% by volume based on the total volume. The balance is from 98 to 80% by volume of the fluorine-plastic particles and the binder resin.
In addition, at least one wear resistant additive selected from the group consisting of SiO2, TiO2, SiC and Al2O3 may be contained in a proportion of from 0.1 to 5.0% by volume based on the total volume. The balance is from 99.9 to 95.0% by volume of the fluorine-plastic particles and the binder resin.
When the paint is subjected to strong shear blending, the granular PTFE contained is flattened in the paint. For example, the calcined fluorine plastic having from 2 to 20 μm of average particle diameter may be blended with the other starting materials within a bead mill developed by IPROS Corporation, and the sliding material according to the present invention may be thus prepared.
The sliding material according to the present invention can be preferably used for, for example, the sliding layer of a swash-plate type compressor and the like, which is operated under high pressure and high speed and lubricating oil supplied on the sliding surface.
The paint having the blended composition shown in Tables 1 and 2 was subjected to blending with a propeller mixing (Comparative Example, untreated PTFE) and blending with strong shear blending by means of a bead mill (Examples, flattened PTFE).
The respective components were as follows.
The prepared powder was applied on the substrate of a swash-plate to provide a coating thickness of 20 μm, and the surface of the coating was polished to form approximately 0.3 μm Rz of roughness.
The testing condition was under no lubrication of the lubricant oil and as follows.
The test results are shown in Table 1.
It is apparent from Table 1 that the inventive examples are superior to the comparative examples in view of the seizure resistance.
The test conditions was under lubrication of lubricating oil and cooling media and were as follows.
The test results are as follows.
It is apparent from Table 2 that no peeling occurs in the inventive examples.
As is described hereinabove, the present invention provides sliding material with small wear and free of peeling, when used as the sliding material on a swash plate of a swash-plate type compressor.
| Number | Date | Country | Kind |
|---|---|---|---|
| 2003-429966 | Dec 2003 | JP | national |
