Sliding member and process for formation of its coating layer

Abstract

An object of the present invention is that in a sliding member whose substrate is improved in sliding characteristics by a coating layer comprising a solid lubricant, the coating layer is obtained as one having a low coefficient of friction and an excellent wear resistance. In the present invention, the coating layer 7 has a structure formed by laminating solid lubricant plate crystal grains 3, and contains not more than 10 mass % of a resin for binder 8 for bonding the solid lubricant plate crystal grains 3, and the lubricant plate crystal grains have a crystal structure formed by piling (00l) planes (wherein l is an integer of not less than 1) in parallel, the index of orientation of the (00l) planes being not less than 90% at least on the sliding surface.

Description

BRIEF DESCRIPTION OF THE DRAWINGS

FIG. 1 is a schematic cross-sectional view showing the laminar structure of solid lubricant plate crystal grains in a coating layer.

FIG. 2 is a partially sectional view of a plain bearing.

FIG. 3 is a cross-sectional view of an adhering apparatus.

FIG. 4 is a side view of a plain bearing.

FIG. 5 is a cross-sectional view of a bimetal.

FIG. 6 is a schematic illustration showing the laminated state of plate crystals of solid lubricant plate crystal grains.

FIG. 7 is a diagram showing the crystal structure of molybdenum disulfide.

FIG. 8 is a graph showing the result of an X-ray diffraction intensity test on the coating layer of a specimen of a working example.

FIG. 9 is a graph showing the result of an X-ray diffraction intensity test on the coating layer of a specimen of a comparative example.

Claims

1. A sliding member comprising a substrate and a coating layer having a sliding surface and adhered to the surface of the substrate, wherein said coating layer is formed by laminating solid lubricant plate crystal grains and contains not more than 10 mass % of a resin for binder for bonding the solid lubricant plate crystal grains, andsaid solid lubricant plate crystal grains have a crystal structure formed by piling (00l) planes (wherein l is an integer of not less than 1) in parallel, the index of orientation of the (00l) planes being not less than 90% at least on said sliding surface.

2. A sliding member according to claim 1, wherein said solid lubricant plate crystal grains are composed of not less than one compound selected from molybdenum disulfide, graphite, tungsten disulfide, boron nitride and molybdenum trioxide.

3. A sliding member according to claim 1, wherein said resin for binder is contained in said coating layer in a proportion of 2 to 7 mass %.

4. A sliding member according to claim 1, wherein said resin for binder is composed of a thermoplastic resin or a thermosetting resin.

5. A process for forming the coating layer of a sliding member according to claim 1, which comprises subjecting the solid lubricant plate crystal grains having a crystal structure formed by piling (00l) planes in parallel, to free adhesion to adhesion media together with powder of the resin for binder,sliding the adhesion media having the solid lubricant plate crystal grains and the powder of the resin for binder subjected to the free adhesion to the adhesion media, on the surface of the substrate while applying a pressure to the substrate surface, to adhere the solid lubricant plate crystal grains to the substrate surface with rubbing, together with the powder of the resin for binder so that the (00l) planes of the solid lubricant plate crystal grains may be parallel to the substrate surface,sliding the above-mentioned adhesion media on the surfaces of the solid lubricant plate crystal grains adhered to the substrate surface, under pressure to adhere the solid lubricant plate crystal grains adhered freely to the adhesion media, to the surfaces of the solid lubricant plate crystal grains adhered to the substrate surface, together with the powder of the resin for binder to effect laminating, andinfiltrating the powder of the resin for binder into the spaces among the above-mentioned solid lubricant plate crystal grains by allowing the powder to assume a semi-molten state or a molten state by heating the substrate and/or generating frictional heat by adjustment of the sliding speed of the adhesion media, at the time of the adhesion of the above-mentioned solid lubricant plate crystal grains and the powder of the resin for binder.

6. A process for forming the coating layer of a sliding member according to claim 5, wherein the powder of said resin for binder is composed of powder of a thermosetting resin, and said resin for binder is infiltrated into the spaces among the above-mentioned solid lubricant plate crystal grains and then heated to be cured.