All patents, patent applications and publications cited herein are hereby incorporated by reference in their entirety in order to more fully describe the state of the art as known to those skilled therein as of the date of the invention described herein.
Actuators have come a long way since the invention of rotary motors, which set the foundation for robotics and marks the dawn of the age of automation and industrialization. The drastic improvement in performance of hard actuators nowadays is only matched by the large number of emerging soft actuators, which demonstrate functionalities tantamount to or more expansive than that of their hard counterparts. The most common mode of hard actuation-torsion, however, has very few realizations in soft actuator designs.
Robots or machines capable of complex movements often require many actuators working in synchrony. Such systems are potentially difficult to control. One way of reducing the complexity in control is to have parallel actuation in the system, where one or a few inputs can result in many outputs working synchronously in a desired way. For hard machines, parallel actuation can be realized through gears and levers in high precision. In soft machines, however, the counter parts of such parallel actuation systems are rare or non-existent.
A new class of soft actuators that use buckling as a mechanism for actuation and methods of using the same for actuation are provided. In one aspect, a rotation center having a center of mass; a plurality of bucklable, elastic structural components each comprising a wall defining an axis along its longest dimension, the wall connected to the rotation center in a way that the axis is offset from the center of mass in a predetermined direction; and a plurality of cells each disposed between two adjacent bucklable, elastic structural components and configured for connection with a fluid inflation or deflation source; wherein upon the deflation of the cell, the bucklable, elastic structural components are configured to buckle in the predetermined direction. The shape of the cell is in principle not restricted and any shape or size of the cell is contemplated.
The soft actuator as described herein has excellent scaling capabilities, allowing easy realization of parallel actuation, e.g., using a single input or multiple inputs such as the input of pressure or vacuum to enable multiple outputs to generate synchronous movements. Thus, the soft actuator or actuating device comprising a plurality of the soft actuators can trigger multiple actuations occurring in parallel.
In certain embodiments, soft actuators that are pneumatically powered as described herein can be easily fabricated and may provide delicate object-handling capabilities and enable sophisticated movement with the simple input of pressure. In certain embodiments, the soft buckling actuator generates forces, e.g., torque or rotational forces, as fluid is pumped in and out of the actuator's cell(s). The forces generated by the soft actuator may enable the development of robotic elements (e.g., robotic swimmers, grippers, or walkers) and synchronized parallel actuation of attached objects (e.g., puzzle pieces or focus tracking mirror array).
As used herein, “soft actuator” refers to an actuator with at least one portion of its body being soft. As used herein, “soft body” refers to the body of the soft actuator or a portion of the soft actuator that is soft and may be involved in the actuation movement of the soft actuator. However, the soft actuator or soft body, as used herein, may have one or more portions of its body being hard or may be connected with a hard body part.
In one aspect, a soft actuator is described, a soft actuator is described, including:
In any one of embodiments described herein, all of the bucklable, elastic structural components are configured to bend clockwise.
In any one of embodiments described herein, all of the bucklable, elastic structural components are configured to bend counter-clockwise.
In any one of embodiments described herein, the two or more bucklable, elastic structural components are located symmetrically around the rotation center.
In any one of embodiments described herein, the soft actuator comprises 3, 4, 5, 6, 7, 8, or more bucklable, elastic structural components.
In any one of embodiments described herein, the wall defines the wall of the cells.
In any one of embodiments described herein, the bucklable, elastic structural component is configured to buckle upon the deflation of the cell and return to its original position when the deflated cell is re-inflated.
In any one of embodiments described herein, the soft actuator further includes two or more secondary structural components structurally linked to the cell, wherein the secondary structural component is stiffer than the bucklable, elastic structural component and configured not to buckle before the bucklable, elastic structural component upon the deflation of the cell.
In any one of embodiments described herein, the bucklable, elastic structural component and the secondary structural component are two of the walls of the cell.
In any one of embodiments described herein, the bucklable, elastic structural component is in the form of a pillar, level, beam or in an arc shape, a star sharp, or a diamond shape.
In any one of embodiments described herein, the cell is in the shape of a rod, sphere, slit, triangular prisms, square prisms, or cylinder.
In any one of embodiments described herein, the soft actuator comprises two or more cells connected to each other and configured for connection to the fluid inflation or deflation source but are otherwise isolated from the outside atmosphere.
In any one of embodiments described herein, the cell is connected to a fluid chamber configured for connection with the fluid inflation or deflation source.
In any one of embodiments described herein, the soft actuator includes two or more cells configured for connection with the same fluid inflation or deflation source.
In any one of embodiments described herein, the soft actuator comprises two or more cells and at least two of the cells are connected to different fluid inflation or deflation sources.
In any one of embodiments described herein, the soft actuator further includes fluid inflation or deflation source, wherein the source is a gas pump, a gas vacuum, or a gas pump and vacuum.
In any one of embodiments described herein, the soft actuator further comprises a hard body portion.
In any one of embodiments described herein, the soft actuator is a robotic grabber, a robotic walker, or a robotic swimmer.
In another aspect, an actuating device comprising a combination of two or more soft actuators each according to any one of the embodiments disclosed herein is described.
In any one of embodiments described herein, each of the soft actuator is configured for connection with the same fluid or vacuum source or at least two of the soft actuators are configured for connection with different fluid or vacuum sources capable of being activated independently.
In any one of embodiments described herein, the actuating device is an actuating array and each of the soft actuator is configured for connection with the same fluid or vacuum source.
In yet another aspect, a method of actuation is described, including:
providing the soft actuator of any one of embodiments disclosed herein; and
In yet another aspect, a method of actuation is described, including:
In any one of embodiments described herein, the cells of the plurality of the soft actuators are deflated or over-inflated simultaneously or independently.
It is contemplated that any embodiment disclosed herein may be properly combined with any other embodiment disclosed herein. The combination of any two or more embodiments disclosed herein is expressly contemplated.
Unless otherwise defined, used or characterized herein, terms that are used herein (including technical and scientific terms) are to be interpreted as having a meaning that is consistent with their accepted meaning in the context of the relevant art and are not to be interpreted in an idealized or overly formal sense unless expressly so defined herein.
Although the terms, first, second, third, etc., may be used herein to describe various elements, these elements are not to be limited by these terms. These terms are simply used to distinguish one element from another. Thus, a first element, discussed below, could be termed a second element without departing from the teachings of the exemplary embodiments. Spatially relative terms, such as “above,” “below,” “left,” “right,” “in front,” “behind,” and the like, may be used herein for ease of description to describe the relationship of one element to another element, as illustrated in the figures. It will be understood that the spatially relative terms, as well as the illustrated configurations, are intended to encompass different orientations of the apparatus in use or operation in addition to the orientations described herein and depicted in the figures. For example, if the apparatus in the figures is turned over, elements described as “below” or “beneath” other elements or features would then be oriented “above” the other elements or features. Thus, the exemplary term, “above,” may encompass both an orientation of above and below. The apparatus may be otherwise oriented (e.g., rotated 90 degrees or at other orientations) and the spatially relative descriptors used herein interpreted accordingly. Further still, in this disclosure, when an element is referred to as being “linked to,” “on,” “connected to,” “coupled to,” “in contact with,” etc., another element, it may be directly linked to, on, connected to, coupled to, or in contact with the other element or intervening elements may be present unless otherwise specified.
The terminology used herein is for the purpose of describing particular embodiments and is not intended to be limiting of exemplary embodiments. As used herein, singular forms, such as “a” and “an,” are intended to include the plural forms as well, unless the context indicates otherwise. Additionally, the terms, “includes,” “including,” “comprises” and “comprising,” specify the presence of the stated elements or steps but do not preclude the presence or addition of one or more other elements or steps.
The invention is described with reference to the following figures, which are presented for the purpose of illustration only and are not intended to be limiting. In the Drawings:
In one aspect, a soft actuator is described, including: a rotation center having a center of mass; a plurality of bucklable, elastic structural components each comprising a wall defining an axis along its longest dimension, the wall connected to the rotation center in a way that the axis is offset from the center of mass in a predetermined direction; and a plurality of cells each disposed between two adjacent bucklable, elastic structural components and configured for connection with a fluid inflation or deflation source; wherein upon the deflation of the cell, the bucklable, elastic structural components are configured to buckle in the predetermined direction. In other embodiments, all of the axes of the bucklable, elastic structural components are configured to bend counter-clockwise.
As used herein, “structurally linked” refers to the scenario in which two structural components are connected directly or indirectly through an additional structural components. As a result, the movement of one of the two structurally linked components will result in the movement of the other component.
As used herein, the term “buckle” refers to the phenomenon in which a structural component of the soft actuator bends, crumples or collapses, in response to a compressive or tensile force on this component. In some cases “buckling” occurs when the cell of the soft actuator is deflated, as deflation (but not limited to) of structures lead to overall or local compression and compressive forces. In other instances “buckling” occurs when the cell of the soft actuator is inflated, as inflation of the structures leads to overall or local tension and tensile forces. Thus, the bucklable, elastic structural component is an elastic structural component of the soft actuator that bends or collapses when the cell of the soft actuator is deflated or unbend when the cell is inflated under a compressive or tensile force applied across the bucklable structural element, it will buckle (it may resist a compression and maintain its shape to some extent before buckling).
The soft actuator body contains one or more cells inside the soft body. As used herein, the term “cell” refers to an enclosed space within the soft body of the soft actuator which is configured for connection with an external fluid inflation and/or deflation source. In some embodiments, the cell is in the form of a rod, slit, triangular prisms, square prisms, cylinder or an oval cross-section shape. However, the cell can have any other form or shape. In certain embodiments, other than the connection with an external fluid inflation and/or deflation source, the cell is isolated from the outside atmosphere. In certain embodiments, two or more cells are connected to each other. The soft body or portions thereof define the boundaries, e.g., walls, of the cell. In certain embodiments, the bucklable, elastic structural component makes up at least one of the boundaries, e.g., walls, of the cell. In certain embodiments, the bucklable, elastic structural component and the secondary structural component (described further below) make up two or more boundaries, e.g., walls, of the cell.
When the cell collapses during deflation or expands during re-inflation, the bucklable, elastic structural component is subjected to forces as a result of the cell's collapse or expansion and therefore buckles. In certain embodiments, this buckling results in a change in the shape and/or size of the soft actuator's body and generates a force, e.g., torque or rotational forces, which can be utilized for actuation. The expansion or compression forces as a result of the cell inflation or deflation do not act uniformly over the entire soft body in that some areas of the soft body will deform more than other areas. This will generate a non-uniform response from the soft body which causes one region and not another to collapse or buckle (or one region to deform to a greater extent than another regions) and gives rise to the rotational movement. Therefore, as described herein, buckling of the bucklable, elastic structural component can be used as a mechanism for actuation.
In some embodiments, a soft actuator is described, including: a soft body defining one or more cells inside the soft body each configured for connection with a fluid inflation or deflation source; a rotation center within the soft body; and two or more bucklable, elastic structural components within the soft body and structurally linked to the rotation center and configured to buckle upon the deflation or inflation of the cell to generate a force to cause the rotation center to rotate. In these embodiments, upon the deflation or inflation of the cell, the bucklable, elastic structural component deforms as a result of the positive or negative pressure exerted on it by the cell's changed shape. The deformation, i.e., buckling, of the bucklable, elastic structural component forces the rotation center to rotate.
In certain embodiments, the rotating soft actuator can be described with reference to
An enlarged view of the square rotator is shown in
While the structural components shown in
As shown in
The bucklable, elastic structural component can be in any form or shape. In some specific embodiments, the bucklable, elastic structural component is in the form of a pillar, beam, or column. In certain embodiments, the bucklable, elastic structural component has a high aspect ratio and is in the form of a pillar, a level, a beam, or is a wall of a cell or part thereof. In certain embodiments, those pillars/levers/beams that buckle have higher aspect ratio than those that maintain their shapes, thanks to Euler's buckling formula. For example, any shape that has two ends to which a compressive force can be applied and possibly collapse the structure, such as: an arc shape, a star shape (pick any two ends), a diamond shape with a hole in the middle, etc.
In some embodiments, the bucklable, elastic structural component has a high aspect ratio. As used herein, aspect ratio refers to the ratios of the long dimension to the short dimension of an object or particles. An aspect ratio of more than one is generally referred to as high aspect ratios. In certain embodiments, the bucklable, elastic structure component has an aspect ratio of more than 1:1, 2:1, 3:1, 4:1, 5:1, 10:1, or 20:1, or in the range denoted by any two values described herein. Other suitable high aspect ratios are contemplated. In certain embodiments, the bucklable, elastic structure component with a high aspect ratio may buckle in the direction perpendicular to its long dimension.
In certain embodiments, the bucklable, elastic structural component is directly neighboring or adjacent to the cell. Thus, when the cell collapses or over-inflates, as a result of pressure, the bucklable, elastic structural component buckles and generates a force (e.g., a torsional or rotational force) for actuation. In one particular embodiment, the bucklable, elastic structural component(s) surround the cell.
In certain embodiments, the bucklable, elastic structural component neighbors the cell, (e.g., the bucklable, elastic structural component is one of the walls of the cell), or the bucklable, elastic structural component is connected to one or more intermediate structural elements which are directly neighboring or adjacent to the cell. The intermediate structural element may be made from a material which is not bucklable or less bucklable than the bucklable, elastic structural component. Alternatively, the additional structural element can be thicker and/or shorter than the bucklable, elastic structural component and thus will not buckle or will not buckle first. Alternatively, the additional structural element can be positioned so that no substantial anisotropic compressive force is applied under contraction of cells (such as a rotation center: although it's subject to compression, the compression comes evenly from all directions, thus unable to buckle the center)
The soft actuator includes one or more secondary structural components structurally linked to the cell. As noted above, the secondary structural component does not buckle upon the deflation or inflation of the cell, or is designed not to buckle first. The secondary structural component can be directly neighboring or adjacent to the cell or connected to one or more intermediate structural elements which are directly neighboring or adjacent to the cell. In certain embodiments, the secondary structural component does not buckle when the bucklable, elastic structural component buckles as a result of the deflation or over-inflation of the cell. In certain embodiments, the secondary structural component is made from a non-elastic material or a material that is less elastic than the material of the bucklable, elastic structural component. In other embodiments, the secondary structural component is made from a material the same as or similar to the material of the bucklable, elastic structural component but is thicker and/or shorter and thus is more resistant to pressure. As a result, when the cell is deflated or re-inflated, the secondary structural component does not buckle and the bucklable, elastic structural component buckles to generate a force for actuation. The secondary structural component can be in any form or shape, e.g., a pillar, a column, a disk, a sphere, a cube, a prism, or any polyhedron or smooth 3D shape in general.
The rotating portion of the soft actuator's body can be any part of the soft actuator. Other configurations for the cell, the rotating portion of the soft actuator's body, and the bucklable, elastic structural component are contemplated.
Buckling of materials is often considered an undesired behavior as it often results in permanent altered states of the materials that degrade their original functions. The reversible buckling of elastomeric materials as described herein, however, is free of such problems, and enables the development of a new class of actuators that utilize buckling for actuations as described herein. Thus, in some embodiments, the bucklable, elastic structural component buckles upon the deflation of the cell and returns to its un-buckled state upon re-inflation of the cell. In other embodiments, the bucklable, elastic structural component is configured to buckle upon the over-inflation of the cell which generates a pressure above the atmosphere pressure and returns to its original position/state when the over-inflated cell is deflated.
As described herein, the aspect ratio of the cell may also contribute to the predetermined actuation pattern. A non-limiting example is described earlier and in
In some embodiments, all structural elements may be made from one or more elastomers. Any elastomer known in the art may be used. In some embodiments, some structural elements may be made from hard materials. Any known elastic material can be used to make the bucklable, elastic structural component. In some embodiments, the material for making the bucklable, elastic structural component is an elastic polymer. Any elastic polymer known in the art can be used. Non-limiting examples of the elastic polymer include natural rubber, silicone rubbers, polyurethane rubbers, isoprene rubber, butadiene rubber, butyl rubber, styrene-butadiene rubber, nitrile rubber, ethylene propylene rubber, epichlorohydrin rubber, polyacrylic rubber, fluorosilicone Rubber, fluoroelastomers, perfluoroelastomers, polyether block amides, chlorosulfonated polyethylene, ethylene-vinyl acetate, thermoplastic elastomers, proteins resilin and elastin, polysulfide rubber, elastolefin, etc. In some embodiments, the material to make the bucklable, elastic structural component is Ecoflex, Elastosil, PDMS, 3D printed soft materials, or another material that is elastic and air tight. Any rigid materials known in the art may be used, as long as they can establish mechanical connection with the soft material used.
In some embodiments, the soft actuator comprises more than one cell connected to each other and to the optionally external fluid inflation or deflation source but otherwise isolated from the outside atmosphere. In certain embodiments, the cells are connected to the same optionally external fluid inflation or deflation source. In other embodiments, the cells are connected to different optionally external fluid inflation or deflation source and can be inflated or deflated (and thus actuated) independent of each other. Thus, the cells can be separate from one another, providing more degrees of freedom of actuation. For example, in certain specific embodiments, two buckling actuators (each with connected cells) can be glued (e.g., with elastomer) side to side, center to center, or any other ways of physical attachments, thus providing two actuating units separately-controllable.
The fluid inflation or deflation source, which is optionally external to the soft actuator, can be any apparatus that inflates and/or deflates the fluid. Non-limiting example of the fluid inflation or deflation sources include a gas pump, a gas vacuum, a gas pump and vacuum, a liquid pump, a liquid-suction pump, or a liquid pump and suction pump. In some embodiments, the one or more cells are connected directly to the fluid inflation/deflation source or via a fluid chamber. The use of any fluid, gas or liquid, is contemplated, including air, gas, water, oil, liquid metal. A non-limiting example of the gas is air. In some specific embodiments, the one or more cells are connected to a gas chamber, which may be connected to the gas inflation/deflation source. In other embodiments, the cell is connected to the gas inflation/deflation source directly. The use of other gases is contemplated.
In certain embodiments, the fluid is gas and the fluid inflation/deflation source is an optional external gas inflation/vacuum source. The external gas inflation source may be a pump, gas cylinder or balloon. The external vacuum source may be a vacuum pump. Any other gas inflation source and vacuum source known in the art are contemplated.
Thus, in some embodiments, an external deflation source, e.g., vacuum source, is used to induce a negative pressure within the cell, which allows the atmospheric pressure to apply an isotropic compressive force. Pneumatic actuation using air has the additional advantages, e.g., that the air it uses is widely available, safe to operate, transfers quickly through tubing (due to its low viscosity), lightweight, and easily controlled and monitored by regulators, valves, and sensors. In some embodiments, the cells are sealed so that it is topologically closed except for the entrance into the inflation/deflation device or the common air chamber. By connecting the cells and attaching a gas channel, e.g., a tube, to the inflation/deflation device, the cells inside the soft actuator body can be inflated and deflated through pumping air and applying vacuum. In other embodiments, an external inflation source may be used to induce a positive pressure within the cell (a gas cylinder which pumps gas into a cell), which allows the cell to expand to generate a force to cause the bucklable, elastic structural component to un-buckle (pressure reverses motion).
In another aspect, an actuating device comprising a combination of any two or more the soft actuators of any one of the embodiments described herein is described. The soft actuators can be connected to the same external fluid or vacuum source, or at least two of the soft actuators are connected to different external fluid or vacuum sources capable of being activated independently. As a result, parallel or independent actuation is achieved.
In certain embodiments, the soft actuator or actuating device is a robotic grabber, walker, or swimmer, as described herein. In certain embodiments, the soft actuator or actuating device is a puzzle actuator or a focus tracking mirror array, as described herein.
The shapes of the cells, e.g., holes, are in principle not restricted. In a particular embodiment, ellipse-shaped cells that alternate its orientation in lattice by 90 degrees or about 90 degrees (e.g., from 80-90, 85-90, 85, 86, 87, 88, 89 or 90 degrees) are used. This design restricts the actuator to rotation in a certain direction, instead of allowing it to rotate in both directions. For instance, the cells 122 in the square rotator 121 are designed to be oval-shaped so that the buckling may occurs preferentially along the shorter axis of the oval.
Planar crystal structures with different rotational symmetries have been studied by chemists. In certain embodiments, the actuating rotators with rotational symmetry are designed based on a variety of crystal geometries. In other embodiments, the actuating rotators are combined into arrays to realize parallel actuation/rotation.
The performance parameters for the actuating rotators described herein can be characterized by the mechanical properties including: i) range of motion, ii) angle vs. pressure, iii) torque vs. pressure, and/or iv) change in volume vs. pressure. Described herein are several non-limiting examples of rotational buckling actuators (i.e., actuating rotators) that each provides different mechanical (i.e., range of motion, angle vs pressure, torque vs pressure, change in volume vs pressure) behaviors.
In certain embodiments, the rotating actuator comprises 3, 4, 5, 6, 7, 8, or more bucklable, elastic structural components, e.g., pillars. In certain embodiments, the bucklable, elastic structural components are positioned symmetrically around the rotation center.
In certain embodiments, a soft bodied actuator is provided having an array of holes in a flexible, e.g., rubber or elastomeric, structure. The arrays of holes that are extended in one dimension to form cylinders, columns or rods in the soft actuator demonstrate the interesting property of “organized buckling”. When aligned in an array, the holes form rubber “pillars” that are surrounded by a number of holes, e.g., 4-6, holes when a biaxial compression is applied, the structure reduces its volume by collapsing the holes into slits through bending/buckling of the flexible walls between the holes. While doing so, the rubber “pillars” that are surrounded by holes rotate clockwise and counter-clockwise in an alternating pattern. Such motions provide the basic elements to construct torsional soft actuators or to realize parallel actuation.
The cells can have any desired geometry. In certain embodiments, the soft-bodied actuator includes holes having a round cross-section shape. In certain embodiments, the soft-bodied actuator includes holes having an ellipsoid cross-section. In certain embodiments, the ellipse shaped holes are arranged in alternating orientations, that is, the longer diameter of the ellipsoid cross section alternates between orientations. When the biaxial compression is applied on an array of cells, e.g., holes, in rubber with circular shaped holes, however, the holes are equally prone to collapse vertically and horizontally. Thus the material cannot decide whether to rotate left or right upon application of pressure. This bifurcation is undesirable for a reliable actuator design. In some embodiments, ellipse-shaped holes in alternation orientations are included in the soft actuator. Once under vacuum and compressed, the holes are predisposed to collapse along the short axis of the ellipse, thus eliminating the bifurcation.
A practical approach to biaxial decomposition is to induce a negative pressure within the structure, which allows the atmospheric pressure to apply an isotropic compressive force. Pneumatic actuation has the additional advantages in that the air it uses is widely available, safe to operate, transfers quickly through tubing (due to its low viscosity), lightweight, and easily controlled and monitored by regulators, valves, and sensors. Therefore, the holes are sealed at one end by adding an additional layer of rubber on top of the array of holes. The structure is now topologically closed except for the entrance into the common air chamber. By connecting the holes—now chambers—and attaching a tube to the common air chamber, the body can be inflated and deflated through pumping air and applying vacuum. This actuator buckles and un-buckles through control of the pressure of the air inlet.
In some embodiments, an array of the soft actuators is described, comprising a plurality of any of the soft actuators described herein. In certain embodiments, the array comprises a plurality of the actuating rotators described herein and the cell/pillars are arranged so that adjacent rotation centers can rotate in concert or against one another, or in a predetermined pattern.
In some embodiments, an example of the rotating actuator array is described with reference to
In certain embodiments, the soft actuator further includes a hard body portion. The soft buckling actuator can include both soft and hard components to perform useful functions. The soft buckling actuator is a promising new element one can use in making soft machines or soft and hard hybrid machines.
Soft machines have potential for use in locomotion since they are lightweight and able to adapt to their environment.
Each unit in the buckling actuator is capable of individual torsional actuation; however that motion is simultaneous with and linked to the motion of the units in the array. Thus, multiple parallel actuations are possible. For example, each cell in a buckling array can be equipped with a reflecting surface (see schematics shown in
In some embodiments, the soft buckling actuators, e.g., rotating actuators, are created by replica-molding (
Inspired by various crystallographic space groups, we built structures consisting of more than one output.
Since CAD assisted molding is a scalable method of fabrication, structures consisting of more than one output can be built.
In some embodiments, buckling actuators actuated using pressures above the atmospheric pressure are described (
Speed of actuation is based on the change in volume needed for actuation, and the flow rate of gas being transferred in and out of the structure. For a given flow rate, smaller structures can actuate at a frequency faster than larger structures.
In another aspect, a method of actuation is described, including: providing the soft actuator or the actuating device of any one of embodiments described herein; and deflating the cells or over-inflating the cells of the plurality of the soft actuators to cause the bucklable, elastic structural component to buckle and to generate a force available for actuation. In the embodiments where the soft actuator includes a plurality of the cells, the cells can be deflated or over-inflated simultaneously or independently.
While for purposes of illustration a preferred embodiments of this invention has been shown and described, other forms thereof will become apparent to those skilled in the art upon reference to this disclosure and, therefore, it should be understood that any such departure from the specific embodiments shown and described are intended to fall within the spirit and scope of this invention.
The foregoing and other features and advantages of various aspects of the invention(s) will be apparent from the following, more-particular description of various concepts and specific embodiments within the broader bounds of the invention(s). Various aspects of the subject matter introduced above and discussed in greater detail below may be implemented in any of numerous ways, as the subject matter is not limited to any particular manner of implementation. Examples of specific implementations and applications are provided primarily for illustrative purposes.
The present application claims priority to U.S. Provisional Application 61/979,267, filed Apr.14, 2014, and to U.S. Provisional Application 62/025,766, filed Jul. 17, 2014, the contents of which are hereby incorporated by reference herein in their entirety.
This invention was made with support from the United States government under Grant No. DMR-0820484 awarded by the National Science Foundation, and Grant No. DE-SC0000989 awarded by the Department of Energy. The United States government has certain rights to this invention.
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