Photovoltaic layer systems for the direct conversion of sunlight into electrical energy are well known. They are commonly referred to as “solar cells”, with the term “thin-film solar cells” referring to layer systems with small thicknesses of only a few microns that require carrier substrates for adequate mechanical stability. Known carrier substrates include inorganic glass, plastics (polymers), or metals, in particular, metal alloys, and can, depending on the respective layer thickness and the specific material properties, be designed as rigid plates or flexible films.
In view of the technological handling quality and efficiency, thin-film solar cells with a semiconductor layer of amorphous, micromorphous, or polycrystalline silicon, cadmium telluride (CdTe), gallium-arsenide (GaAs), or a chalcopyrite compound, in particular copper-indium/gallium-disulfur/diselenide, abbreviated by the formula Cu(In,Ga)(S,Se)2, have proved advantageous. In particular, copper-indium-diselenide (CuInSe2 or CIS) is distinguished by a particularly high absorption coefficient due to its band gap adapted to the spectrum of sunlight.
Typically, with individual solar cells, it is possible to obtain only voltage levels of less than 1 volt. In order to obtain a technically useful output voltage, many solar cells are connected to one another in series in a solar module. For this, thin-film solar modules offer the particular advantage that the solar cells can already be connected in series in an integrated form during production of the films. Thin-film solar modules have already been described many times in the patent literature. Reference is made merely by way of example to the printed publications DE 4324318 C1 and EP 2200097 A1.
In the so-called “substrate configuration”, to produce the solar cell, the various layers are applied directly on a substrate that is adhesively bonded to a front-side transparent cover layer to form a weather-resistant laminate. The layer structure between the substrate and the cover layer comprises a back electrode, a front electrode, and a semiconductor layer. Typically, the voltage terminals of the solar cell laminate are guided over the back electrode layer by means of metal strips to the back of the substrate. There, junction boxes are situated that electrically contact the metal strips, for example, via contact clamps.
In practice, for the most part, multiple solar modules are connected in series to the junction boxes by connection cables to form a module string. Typically, each solar module is connected to a freewheeling diode or bypass diode antiparallel to the solar cells, which, in the normal operating state, in which the solar module delivers current, is reverse biased. On the other hand, damage to the solar module can be prevented if, for example, no current is delivered because of shadowing or a module defect, since the current delivered by the other solar modules can flow via the freewheeling diode.
The international patent application WO 2009/134939 A2 describes a solar module, in which a plurality of junction boxes, which have, in each case, a bypass diode, are electrically connected to each other. The two external junction boxes have, in each case, a connection cable for connection to other solar modules. An electrical connection of the junction boxes to each other is done with flat electrical leads in the interior of the solar module. The junction boxes are contacted on their underside, with which they are installed on the back side of the solar module. The German published application DE 102009041968 A1 presents a solar module with junction boxes installed on the underside, which have in each case a bypass diode. Contacting of the junction boxes is done on their underside. An electrical connection of the junction boxes to each other is done by a strip conductor in the interior of the solar module.
In contrast, the object of the present invention consists in advantageously improving conventional solar modules, wherein, in particular, automated manufacture should be simplified and production costs should be reduced. These and other objects are accomplished according to the proposal of the invention by a solar module and a method for production thereof with the characteristics of the coordinated claims. Advantageous embodiments of the invention are indicated by the characteristics of the subclaims.
According to the invention, a solar module having a plurality of solar cells connected in series for photovoltaic power generation is presented. The solar module is preferably a thin-film solar module with thin-film solar cells connected in an integrated form. In particular, the semiconductor layer is made of a chalcopyrite compound which can be, for example, a semiconductor from the group copper-indium/gallium disulfur/diselenide (Cu(In,Ga)(S,Se)2), for example, copper indium diselenide (CuInSe2 or CIS) or or related compounds.
The solar cells are typically situated between a first substrate and a second substrate frequently implemented as a cover layer (e.g., cover plate), wherein the two substrates can, for example, contain inorganic glass, polymers, or metal alloys, and, depending on layer thickness and material characteristics, can be designed as rigid plates or flexible films.
The solar module has two (resulting) voltage terminals of opposite polarity, which are in each case guided by a connecting lead to a module outside (i.e., module outside surface) or substrate outside (i.e., substrate outside surface). The two connecting leads are in each case electrically connected on the module outside to a separate connection device, with each connection device situated in a separate connection housing (e.g., junction box or connection box) such that the solar module has two connection housings, in which in each case a connection device is arranged. The two connection housings are in each case fastened on the module outside or module outside surface, onto which the two resulting voltage terminals are guided by the connecting leads.
In the context of the present invention, the term “module outside” means an outward side (i.e., outside surface) of the solar module. The module outside is, at the same time, an outward side (i.e., outside surface) of a substrate (first or second substrate).
In the solar module, the two connecting leads are electrically connected for this purpose to an electrode layer, for example, a back electrode layer, of the connected solar cells. Thus, the two connecting leads are electrically connected to each other by the solar cells connected in series. On the other hand, the two connecting leads end in each case in a separate connection housing. The two connection housings serve for connecting the solar module to an electrical load, in particular for the connection in series of the solar module to other solar modules.
The two connecting leads of the solar module are electrically connected to each other with the interposition of at least one freewheeling or bypass diode connected antiparallel to the solar cells. The freewheeling diode is preferably arranged in one of the two connection housings. Protection of the solar module in the absence of current generation, for example, as a result of shadowing, is obtained by means of the freewheeling diode.
According to the invention, the two connecting leads or the two connection devices, to which the connecting leads are electrically connected, are electrically connected to each other by a ribbon cable arranged between the two connection housings, which is fastened on the module outside (i.e., outside surface of the module) or the substrate outside (i.e., outside surface of the substrate). The ribbon cable is thus not situated in the interior of the solar module (i.e., between the two substrates), but, instead, is arranged on the outside surface of the solar module facing the surroundings.
The ribbon cable enables, in a particularly advantageous manner, a technically less complex integration of the electrical connection between the two connecting leads in an automated process sequence. Since the ribbon cable has a defined geometry, it can be gripped by an automated gripping element in a simple manner for fastening onto the module outside (i.e., outside surface of the module). In addition, a particularly simple and reliable automated fastening of the ribbon cable, for example, by means of adhesive bonding, onto the typically glass module outside or outside surface of the module, is enabled. In contrast to this, an electrical connection of the two connecting leads with a connection cable with a round cross-section would cause significant problems in automation since the geometry of such a connection cable is not defined, and complex and cost-intensive position detection means (e.g., optical sensors) would have to be provided in order to bring the gripping element into position. In addition, the fastening of a connection cable on a glass module outside or outside surface of a module is, due to the relatively small contact surface (for example, by gluing) can be achieved only with significant effort, without being able to rule out the possibility that such fastening would not withstand the high mechanical loads in practice over the long-term. If, on the other hand, such a connection cable were connected only to the two connection housings, the risk would always exist that the connection cable could be misused as a carrying handle.
As a matter of fact, for the first time, with the ribbon cable fastened on the module outside, a simple automation of the electrical connection of the two connecting leads with the interposition of the freewheeling diode can be achieved, by which means time and cost can be saved in industrial series production.
In an advantageous embodiment of the solar module according to the invention, the ribbon cable is surrounded, at least between the two connection housings, by a sheath made of an electrically insulating material. Here, it can be advantageous for the end sections of the ribbon cable arranged inside the associated connection housing to be free for simple electrical contacting. The electrically insulating sheath is situated at least in a section of the ribbon cable that extends from one connection housing to the other connection housing. In particular, the insulating sheathing can even extend into the two connection housings. The ribbon cable is electrically insulated relative to the external surroundings by the sheath.
In the solar module according to the invention, the ribbon cable is fastened on the module outside (i.e., outside surface of the module), which, for example, is accomplished through the fact that the ribbon cable is glued to the module outside.
In another advantageous embodiment of the solar module according to the invention, the ribbon cable is covered by a cover fastened on the module outside (i.e., outside surface of the module) and made of an electrically insulating material. The cover glued for this purpose preferably on the module outside (i.e., outside surface of the module) can fulfill various functions. One function consists in protecting the ribbon cable against mechanical influences to improve long-term durability. Another function can consist in fastening the ribbon cable on the module outside. In this case, a separate fastening of the ribbon cable on the module outside can optionally be dispensed with, but also, on the other hand, provision can be made to fasten the ribbon cable itself onto the module outside in order to obtain a particularly good connection with the module outside.
In an embodiment particularly advantageous from the standpoint of mechanical stress from high temperature fluctuations, the ribbon cable is not fastened on the module outside itself, but, instead, only by way of the covering. It can be further advantageous for the ribbon cable to be electrically connected to the two connecting leads, in particular through the connection devices such that it is not set or fixed in the ribbon plane or in the ribbon direction. In this manner, thermal stresses at the customarily high temperature fluctuations to which the solar module is frequently exposed in practice can be at least substantially reduced.
The ribbon cable enables a particularly simple electrical connection of the connecting leads in the two connection housings. Preferably, the connection housings have, for this purpose, in each case, a contact element, for example, a spring contact element or a clamping contact element, electrically connected to the associated connecting lead that can be brought into electrical contact with one of the two end sections of the ribbon cable. Advantageously, the contact element is implemented so as to automatically come into electrical contact with the ribbon cable at the time of the fastening of the connection housing on the module outside, as a result of which a simple automation of the electrical contacting of the ribbon cable in the connection housings is enabled such that time and costs can be saved with automated module manufacture.
The invention further extends to a method for the automated production of a solar module having a plurality of solar cells connected in series for photovoltaic power generation, wherein the solar module has two voltage terminals of opposite polarity, which are guided in each case by a connecting lead to a module outside or outside module surface, wherein the two connecting leads are electrically connected each case to a separate connection device, wherein each connection device is situated in a separate connection housing. The method comprises the following steps: A step, wherein the two connection housings are in each case fastened to the module outside (i.e., outside surface of the module). A step, wherein the two connecting leads are electrically connected to each other with the interposition of a freewheeling diode arranged in particular in one of the two connection housings, wherein for the electrical connection of the two connecting leads, a ribbon cable arranged between the two connection housings is fastened on the module outside (i.e., outside surface of the module). For example, the ribbon cable is glued for this purpose to the module outside (i.e., outside surface the module). For example, a cover covering the ribbon cable is fastened on the module outside (i.e., outside surface of the module), wherein it is, in particular, possible for the ribbon cable to be fastened to the module outside exclusively by the cover. It can further be advantageous for contact elements to automatically be brought into electrical contact with the ribbon cable at the time of the fastening of the connection housing to the module outside.
The invention is now explained in detail using exemplary embodiments and with reference to the accompanying figures. In the figures, identical or identically functioning elements are identified by the same reference characters. They depict:
Reference is first made to
The solar module 1 comprises an electrically insulating substrate 7 (designated in the introduction to the description as “first substrate”) with a layer structure mounted thereon to form a photovoltaically active absorber layer 8. The layer structure is arranged on the light-entry front side (III) of the substrate 7. The substrate 7 is made here, for example, of glass with relatively low permeability to light, with it equally possible to use other insulating materials with adequate strength as well as inert behavior relative to the process steps performed. The layer structure comprises a back electrode layer 9 arranged on the front side (III) of the substrate 7. The back electrode layer 9 contains, for example, a layer of an opaque metal such as molybdenum and is applied on the substrate 7, for example, by cathode sputtering. The back electrode layer 9 has, for example, a layer thickness of roughly 1 μm. In another embodiment, the back electrode layer 9 comprises a layer stack of different individual layers.
The photovoltaically active absorber layer 8, whose band gap is preferably capable of absorbing the greatest possible fraction of sunlight, is deposited on the back electrode layer 9. The photovoltaically active absorber layer 8 contains a p-doped semiconductor layer 10, for example, a p-conductive chalcopyrite semiconductor, such as a compound from the group copper indium diselenide (CuInSe2), in particular Cu(In,Ga)(S,Se)2. The semiconductor layer 10 has, for example, a layer thickness of 500 nm to 5 μm and, in particular, of roughly 2 μm. A buffer layer 11, which contains here, for example, a single layer of cadmium sulfide (CdS) and a single layer of intrinsic zinc oxide (i-ZnO), is deposited on the semiconductor layer 10. A front electrode layer 12 is applied on the buffer layer 11, for example, by vapor deposition. The front electrode layer 12 is transparent (“window layer”) to radiation in the spectral range sensitive for the semiconductor layer 11, to ensure only a slight fluctuation of the incident sunlight. The transparent front electrode layer 12 can, in general, be referred to as a TCO layer (TCO=transparent conductive oxide and is based on a doped metal oxide, for example, n-conductive, aluminum-doped zinc oxide (AZO). A pn-heterojunction, i.e., a sequence of layers of the opposing conductor type, is formed by the front electrode layer 12, the buffer layer 11, and the semiconductor layer 10. The layer thickness of the front electrode layer 12 is, for example, 300 nm.
The layer system is divided using methods known per se for production of a (thin-film) solar module 1 into individual photovoltaically active regions, i.e., solar cells 2. The division is carried out by incisions 13 using a suitable patterning technology such as laser writing and machining, for example, by drossing or scratching. The individual solar cells 2 are connected to each other in series via an electrode region 14 of the back electrode layer 9.
The solar module 1 has, for example, 100 solar cells 2 connected in series and a open-circuit voltage of 56 V. In the example depicted here, both the resultant positive (+) and the resultant negative (−) voltage terminal of the solar module 1 are guided over the back electrode layer 9 and electrically contacted there, as is explained in detail below.
For protection against environmental influences, an intermediate layer 15, which contains, for example, polyvinyl butyral (PVB) or ethylene vinyl acetate (EVA), is applied on the front electrode layer 12. The thickness of the intermediate layer 15 is, for example, 0.76 mm. In addition, the layer structure composed of substrate 7, back electrode layer 9, and photovoltaically active absorber layer 8 is sealed over the intermediate layer 15 with a cover pane 16 (designated in the introduction to the description as “second substrate”), which is glued to its back side (II). The cover pane 16 is transparent to sunlight and contains, for example, hardened, extra-white, low-iron glass. The cover pane 16 has, for example, an area of 1.6 m×0.7 m. The solar cells 2 can be irradiated by light incident on the front side (I) of the cover pane 16, which is indicated in
It is also expedient for the edge region between substrate 7 and cover plate 16 to be sealed circumferentially with an edge sealing 34 as a vapor diffusion barrier, preferably with a plastic material, for example, poly isobutylene, to protect the corrosion sensitive photovoltaically active absorber layer 8 against atmospheric oxygen and moisture. The edge sealing 34 is discernible in
In the solar module 1, the two resultant voltage terminals (+, −) are guided by two connecting leads 17 onto the back side (IV) or back surface of the substrate 7, which are illustrated in
Reference is now made to
According to this figure, the connecting lead 17 comprises a strip-shaped metal foil 30, for example, made of aluminum, with a thickness of, for example, 0.1 mm and a width of, for example, 20 mm. The metal foil 30 is glued (here, for example, on one side) to an insulating film 31 made from an electrically insulating material, for example, polyimide, with the insulating film 31 arranged on the outward side, i.e., on the side of the foil lead 17 facing away from the substrate 7. In an alternative embodiment, the connecting lead 17 comprises a tinned copper strip. It would be equally possible for the strip-shaped metal foil 30 to be bonded on both sides to an insulating film 31. The insulating film 31 is, for example, glued onto the metal foil 30. It is also conceivable to laminate the metal foil 30 into two insulating films 31.
The metal foil 30 of the two connecting leads 17 is electrically connected to a strip-shaped electrical conductor, a so-called “busbar” 36. The two busbars 36 contact in each case a resultant voltage terminal (+, −) of the solar module 1 (here, for example, formed by the back electrode layer 9) and extend only in the region of the plane of the back electrode layer 9. The busbars 36 thus serve for the electrical connection of the two voltage terminals to the connecting leads 17.
Each busbar 36 is implemented here, for example, as metal foil, in particular aluminum foil. The metal foil 30 of the two connecting leads 17 and the busbar 36 electrically connected thereto can be implemented in two parts and can be different from one another; in particular, they can be made of materials different from one another. However, alternatively, it is also possible for the metal foil 30 of the two connecting leads 17 and the busbar 36 electrically connected thereto to be a single part or one-piece metal foil such that the busbar 36 is merely a foil section of the metal foil 30 of the connecting lead 17.
The two busbars 36 are electrically conductively connected to the back electrode layer 9, for example, by welding, bonding, soldering, or gluing with an electrically conductive adhesive. In the case of an aluminum foil, the electrical connection to the back electrode layer 9 is preferably done by ultrasonic bonding.
In the example depicted in
The two connecting leads 17 have in each case a connection point 18 for electrical contacting, which are arranged, for example, on the back side (IV) of the substrate 7 at a distance of roughly 20 mm from its side edge (substrate edge 33), with the understanding that the connection points 18 can, in principle, be arranged at any points on the back side (IV) of the substrate 7.
The electrical contacting of the two connecting leads 17 at the contact points 18 is done in each case through a first connection device 19 in a junction box 3, which has, for this purpose, an electrical contact element, for example, a spring or clamp contact element.
The contacting of the connection points 18 of the two connecting leads 17 is done in the junction boxes 3 that are, for example, made of plastic and produced in the injection molding process. The two junction boxes 3 are fastened on the back side (IV) or outside surface of the substrate 7, for example, by gluing, which enables simple and fast automated assembly. The bonding of the junction boxes 3 to the substrate 7 can, for example, be done with an acrylic adhesive or a polyurethane adhesive. In addition to a simple and durable connection, these adhesives fulfill a sealing function and protect the electrical components contained against moisture and corrosion. The interior of the junction boxes 3 can also be filled, at least partially, with a sealant, for example, poly isobutylene, to increase the electrical breakdown resistance and to reduce the risk of penetration of moisture and the leakage currents associated therewith.
As depicted in
A freewheeling diode 6, which is connected in series to the two connecting leads 17 antiparallel to the forward current direction of the solar cells 2 of the solar module 1, is arranged in one of the two junction boxes 3. By means of the freewheeling diode 6, the solar module 1 is prevented from being damaged by pole reversal, for example, in the case of shadowing or a module defect. The electrical connection between the two connecting leads 17 or the two first connection devices 19 is illustrated schematically in
As depicted in
The ribbon cable 21 has a defined geometric shape such that it can be gripped relatively simply by a gripping element for assembly. As is discernible from the cross-section, the ribbon cable 21 comprises an electrically conductive metal strip 26 that is surrounded by an insulating sheath 23 made of an electrically insulating material, with the two end sections 22 of the metal strip 26 lying freely inside the junction boxes 3. The metal strip 26 is, for example, an aluminum strip or a tinned copper strip of a thickness of, for example, 10 to 30 μm, a width of, for example, 50 mm, and a length of, for example, 60 cm. The metal strip 26 bonded to an electrically insulating film, made, for example, of polyimide, with the electrically insulating film situated on all sides, in particular even on the side of the ribbon cable 21 turned toward the substrate 7. The ribbon cable 21 is glued with its wide surface onto the back side (IV) or back outside surface of the substrate 7 by an adhesive layer 29, which enables simple and fast automated assembly on the substrate 7. The bonding of the ribbon cable 21 can be done, for example, with an acrylic adhesive or a polyurethane adhesive. It is also conceivable to adhesively bond the ribbon cable 21 onto the substrate 7 with a two-sided adhesive strip. Depending on the manner of electrical contacting, its end sections 22 can be bonded to the substrate 7 or even be freely movable relative to the substrate 7. As a result of the large adhesive area, the ribbon cable 21 can be fastened reliably and with long-term stability on the substrate 7.
Generally speaking, the ribbon cable 21 is distinguished by a very high aspect ratio (width-to-thickness ratio) such that even with a very flat embodiment, a low electrical resistance of, for example, less than 10 mΩ is realized. With a current of, for example, 3 A, this would result in a voltage loss of, for example, 30 mV, corresponding to an efficiency loss of, for example, ca. 0.06%.
The two end sections 22 of the ribbon cable 21 are situated in each case completely inside the junction boxes 3, with the insulating sheath 23 extending into the junction boxes 3. The end sections 22 of the metal strip 26 serve as connection points 24 for electrical contacting, which is shown in detail in
As is discernible from
A particular advantage of the use of the connection device implemented as a spring contact element resides in the fact that each spring contact element can be implemented such that it automatically comes into contact with the metal strip 26 or metal foil 30 by means of the (automated) assembly of the junction box 3 on the substrate 7, by which means the automated manufacture of the solar module 1 is facilitated. Alternatively, however, it would also be possible to use a clamping contact element or a contact element (e.g., wire) to be bonded by soldering, by gluing with a conductive adhesive, or by ultrasonic bonding to the metal strip 26.
If the metal strip 26 is made of aluminum, is expedient to tin the connection points 24 to improve the electrical conductivity. It is understood that the connection points 24 need not be bare metal, but, instead, can be coated with a protective layer of paint or plastic film to protect the metal contact surface against oxidation and corrosion during the production process. The protective layer can be penetrated for electrical contacting with an object, for example, a contact pin or a contact needle. It is also conceivable to manufacture the protective layer from a bondable and peelable plastic film that is removed before the actual electrical contacting.
The cover film 27 is made of an electrically insulating material, for example, plastic. As illustrated in
With the variant depicted in
The invention makes available a solar module, in particular a thin-film solar module, wherein the connecting leads for connection of the solar cells to the connection devices are electrically connected to each other in the junction boxes by a ribbon cable with the interposition of a freewheeling diode. The ribbon cable enables a technically simple to realize automated fastening onto the substrate, wherein the ribbon cable can, for example, be reliably and certainly connected to the substrate by adhesive bonding.
1 solar module
2 solar cell
3 junction boxes
4 connection cable
5 terminal connection
6 freewheeling diode
7 substrate
8 absorber layer
9 back electrode layer
10 semiconductor layer
11 buffer layer
12 front electrode layer
13 incision
14 electrode region
15 intermediate layer
16 cover pane
17 connecting lead
18 connection point
19 first connection device
20 wire
21 ribbon cable
22 end section
23 insulating sheath
24 connection point
25 second connection device
26 metal strip
27 cover film
28 film region
29 adhesive layer
30 metal foil
31 insulating film
32 module edge
33 substrate edge
34 edge sealing
35 opening
36 busbar
Number | Date | Country | Kind |
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11185732.2 | Oct 2011 | EP | regional |
Filing Document | Filing Date | Country | Kind | 371c Date |
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PCT/EP2012/070706 | 10/18/2012 | WO | 00 | 4/7/2014 |