(1) Field of the Invention
The present invention relates to a solid-state imaging element having a photoelectric conversion element which is formed on a semiconductor substrate and an optical element which is formed on the photoelectric conversion element, and particularly to a solid-state imaging element that uses a photonic crystal as an optical element, and to a solid-state imaging device including a plurality of solid-state imaging elements.
(2) Description of the Related Art
Conventionally, a variety of techniques for enhancing light condensing efficiency of solid-state imaging elements have been suggested. For example, a solid-state imaging element 30 as shown in
In addition, other various techniques concerning solid-state imaging elements (or solid-state imaging devices) have been suggested (See, for example, Japanese Laid-Open Patent Application Publication No. 2003-133536 (Conventional art 1) and Japanese Laid-Open Patent Application Publication No. 2001-44401 (Conventional art 2)).
The solid-state imaging device disclosed in the conventional art 1 has a structure for shading light of a predetermined wavelength range from a region surrounding a window on a photoelectric converter by providing in that region a photonic crystal having a waveguide structure. Therefore, this solid-state imaging device allows efficient light condensing while preventing the light from being incident to the peripheral region of the photoelectric converter without using a shading layer made of metal or the like.
Furthermore, in the solid-state image pickup element disclosed in the conventional art 2, a tapered reflection film having a light reflecting characteristic is formed on a photoelectric conversion part. Transparent films, whose refractive indices are higher in the center than in the vicinity of the photoelectric conversion part, are formed on the photoelectric conversion part which is surrounded by the reflection film. As a result, the light incident to the solid-state image pickup element is condensed efficiently to the photoelectric conversion part, and thus the light condensing is improved.
However, all these above-mentioned conventional solid-state imaging elements (or solid-state imaging devices) use a plurality of elements for light condensing and color separation, so it is impossible to enhance light condensing beyond certain limits due to reflection loss and coupling loss between respective elements. This is a problem that causes an obstacle to miniaturization of a solid-state imaging element for increasing the number of pixels in every unit area.
There is another problem in the above conventional art. Since a color filter has to be provided separately, and the resins and pigments that make up the color filter are mere fractions of the size of the solid-state imaging element, color separation becomes more difficult as the solid-state imaging element becomes smaller.
There is still another problem. In a solid-state imaging device that is a set of the solid-state imaging elements 30, light is incident almost perpendicularly upon the solid-state imaging element 30 around the center of the device, whereas it is incident obliquely upon the solid-state imaging element 30 on the periphery of the device. However, it is difficult to form the microlens 21 for the solid-state imaging element 30 around the center of the device separately from the microlens 21 for the element 30 on the periphery thereof (namely, to control the forming of each microlens 21 in consideration of the position of each solid-state imaging element 30 in the device) because the microlens 21 is formed by reflow process, and thus the light condensing on the periphery of the solid-state imaging device is lower than that in the center thereof.
Furthermore, since the solid-state imaging device as disclosed in the conventional art 1 employs a method of obtaining each of RGB color signals of the light using a mirror, it is difficult to enhance light condensing beyond certain limits.
An object of the present invention, in view of the above problems, is to provide a miniature solid-state imaging element with low loss and efficient light condensing, a solid-state imaging device including such solid-state imaging elements and a method for fabricating them.
In order to achieve the above-mentioned object, the solid-state imaging element according to the present invention is a solid-state imaging element having a photoelectric conversion element and an optical element which is formed on the photoelectric conversion element, wherein the optical element has a refractive index periodic structure for a predetermined refractive index, the refractive index periodic structure being made up of at least two types of light-transparent materials with different refractive indices which are stacked in layers, and the refractive index periodic structure has a periodic structure along a stacking direction of multiple layers and a periodic structure along an in-plane direction of concentric similar shapes.
As described above, since the solid-state imaging element according to the present invention allows a single-piece optical element having a refractive index periodic structure to realize color separation and light condensing at the same time, it solves reflection loss and coupling loss caused by use of multiple elements. As a result, a miniature solid-state imaging element with extremely low loss and efficient light condensing can be realized.
In addition, the solid-state imaging device according to the present invention is a solid-state imaging device comprising a plurality of solid-state imaging elements which are arranged in a two-dimensional plane, wherein each of the solid-state imaging elements has a photoelectric conversion element and an optical element which is formed on the photoelectric conversion element, the optical element has a refractive index periodic structure for a predetermined refractive index, the refractive index periodic structure being made up of at least two types of light-transparent materials with different refractive indices which are stacked in layers, and the refractive index periodic structure has a periodic structure along a stacking direction of multiple layers and a periodic structure along an in-plane direction of concentric similar shapes.
As described above, since the solid-state imaging device includes a plurality of solid-state imaging elements which are arranged in a two-dimensional plane, it is also possible to realize a solid-state imaging device with low loss and efficient light condensing as a whole.
Since the solid-state imaging device of the present invention is fabricated using a multi-layer forming technique used for fabricating semiconductors (such as lithography and etching) for forming a tubular optical element (photonic crystal) having a refractive index periodic structure, it is possible to easily realize the refractive index periodic structure for detecting one of the RGB color signals or the optimum refractive index periodic structure dependent upon the position of the solid-state imaging element in the device.
There is another method for fabricating the solid-state imaging device of the present invention. To be more specifically, autocloning is used for forming, on a base having concentric similar shapes in the in-plane direction, an optical element (photonic crystal) having a refractive index periodic structure with the vertical sectional profile being a series of triangles. This optical element (photonic crystal) with the triangular vertical sectional profile has the same function as the tubular optical element (photonic crystal).
As mentioned above, the solid-state imaging device of the present invention realizes not only low loss and efficient light condensing but also miniaturization of the device. Therefore, this solid-state imaging device is applicable in a wide variety of areas, and thus the practical value thereof is extremely high.
As further information about technical background to this application, the disclosure of Japanese Patent Application No. 2003-192175 filed on Jul. 4, 2003 including specification, drawings and claims is incorporated herein by reference in its entirety.
These and other objects, advantages and features of the invention will become apparent from the following description thereof taken in conjunction with the accompanying drawings that illustrate a specific embodiment of the invention. In the Drawings:
The embodiments of the present invention will be explained below with reference to the drawings.
The photonic crystal is used for making color separation of the incident light and the light condensing all at once. It has a periodic structure of refractive indices in the stacking direction, like a multi-layer filter. To be more specific, the photonic crystal has an 11-layer structure as a whole. It includes low refractive layers 1 made of low refractive material (1c in the solid-state imaging element 11c, for example) as the odd-numbered layers including the top layer and high refractive layers 2 made of high refractive material (2c in the solid-state imaging element 11c, for example) as the even-numbered layers including the second layer from the top, which are stacked alternately. Note that the sixth layer from the top, which is made of the high refractive material, is a “stacking-fault” resonator 6 (6c in the solid-state imaging element 11c, for example).
As materials for a photonic crystal, for example, SiO2, Al2O3 or the like as a low refractive material and TiO2, Ta2O5 or the like as a high refractive material can be used. Note that it is desirable that these materials are transparent in the visible region to avoid absorption loss. When SiO2 and Ta2O5 are used, the SiO2 film thickness is 217 [m], whereas the Ta2O5 film thickness is 141 [m] (where the thickness of the “stacking-fault” resonator is 282 [m]).
In the in-plane direction of the photonic crystal, three cavities are provided concentrically for one solid-state imaging element. In other words, a central opening and two doughnut-shaped openings on the top layer penetrate the photonic crystal vertically down to the bottom layer. Both the diameters of the central openings and the widths of the doughnut-shaped openings of the photonic crystals are 180 [m] for the solid-state imaging element 11a, 210 [m] for 11b, and 250 [m] for 11c, respectively (where the pitches between the doughnut-shaped openings are all 600 [m]).
The transmission wavelength of the photonic crystal is determined by the thicknesses and the refractive indices of the low refractive layers 1 and the high refractive layers 2 in the stacking direction. Various periods of concentric openings as mentioned above cause various effective refractive indices, and thus cause transmission wavelengths to vary from element to element. As a result, the photonic crystals with various transmission wavelengths in the solid-state imaging elements 11a, 11b and 11c allow, as a whole, separation of incident light into RGB colors (wavelength filtering function). In addition, the in-plane directional periodic structure of refractive index of this photonic crystal brings about a light condensing function.
Note that the structures of the solid-state imaging elements 11a, 11b and 11c are not limited to those mentioned above.
Inductively Coupled Plasma (ICP) Etching: T. Baba, et al., Journal of Lightwave Technology vol. 17 pp. 2113-2120, 1999
(2) Electron Cyclotron Resonance (ECR) Etching: T. Tada, et al., Japanese Journal of Applied Physics, vol. 38 pp. 7253-7256, 1999
(3) Anode-coupled Reactive Ion Etching (RIE): T. Saitoh, et al., Japanese Journal of Applied Physics, vol. 39 pp. 6259-6263, 2000
As described above, since the solid-state imaging element in the present embodiment makes light condensing and color separation using only an optical element made of a photonic crystal, there occurs no reflection loss nor coupling loss due to its structure including a plurality of elements, which are the conventional problems. In addition, the present solid-state imaging element does not need a color filter. Therefore, it is possible to realize a miniature solid-state imaging element with extremely low loss and effective light condensing.
Note that in the present embodiment, the concentric pattern in the in-plane direction is a circle, regular hexagon or square, but any other polygons may be used.
Next, a solid-state imaging element in the second embodiment will be explained. This solid-state imaging element is different from that in the first embodiment in the structure of a photonic crystal and the method for fabricating it.
The photonic crystal has a periodic structure of refractive indices in the stacking direction, like a multi-layer filter. Like the solid-state imaging element in the first embodiment, the photonic crystal has an 11-layer structure as a whole. It includes low refractive layers 1c as the odd-numbered layers including the top layer and high refractive layers 2c as the even-numbered layers including the second layer from the top, which are stacked alternately. Note that the sixth layer from the top, which is made of the high refractive material, is the “stacking-fault” resonator 6c. The same materials as those in the first embodiment can be used for the low refractive layers 1c and the high refractive layers 2c. For example, when SiO2 and Ta2O5 are used, the SiO2 film thickness is 92 [m] (where the bottom layer thickness is 200 [m]), whereas the Ta2O5 film thickness is 60 [m] (where the thickness of the “stacking-fault” resonator is 120 [m]).
On the other hand, in the in-plane direction of the photonic crystal, each of the top layer through the tenth layer of the present solid-state imaging element 12c has a refractive index periodic structure by having three concentric doughnut-shaped projections, with a cross-sectional profile being a series of triangles, that form concentric circles. The eleventh layer, namely, the bottom layer will be described later.
The transmission wavelength of the photonic crystal is determined by the thicknesses and the refractive indices of the low refractive layers 1 and the high refractive layers 2 in the stacking direction. Various periods of concentric circles as mentioned above cause various effective refractive indices, and thus cause transmission wavelengths to vary from element to element. As a result, the photonic crystals with various transmission wavelengths in the solid-state imaging elements 12a, 12b and 12c as shown in
As described above, since the solid-state imaging element in the second embodiment makes light condensing and color separation using only an optical element made of a photonic crystal fabricated by autocloning, a color filter is not needed and there occurs no reflection loss nor coupling loss due to its structure including a plurality of elements. Therefore, it is possible to realize a miniature solid-state imaging element with extremely low loss and efficient light condensing. And it is also possible to make a solid-state imaging element smaller in the in-plane directional size than the conventional one.
Note that in the present embodiment, the concentric pattern in the in-plane direction is a circle, but a regular hexagon, a square or any other polygons may be used.
The present invention is not limited to the solid-state imaging elements in the above-mentioned embodiments. For example, in the first and second embodiments, the photonic crystal has a stacking structure of 11 layers, but it may have more layers. In addition, the concentric periodic structure in the in-plane direction has a pattern including 3 periods of similar shapes and a regular pitch in the first and second embodiments, but it may include 4 or more periods, and may have irregular pitches. Furthermore, a method for fabricating a photonic crystal is not limited to multi-layer fabrication technology, lithography, etching or autocloning, and any other methods may be used.
Although only some exemplary embodiments of this invention have been described in detail above, those skilled in the art will readily appreciate that many modifications are possible in the exemplary embodiments without materially departing from the novel teachings and advantages of this invention. Accordingly, all such modifications are intended to be included within the scope of this invention.
The present invention is available for solid-state imaging elements, and it is applicable particularly to CCD-type solid-state imaging devices for digital still cameras, personal digital assistants and the like.