This invention relates to a spectrally tunable laser module, to a method for the operation of such a laser module and to applications of such a laser module. Spectrally tunable laser modules are used primarily in the field of the analysis of gases, fluids and/or surfaces.
In the field of the analysis of gases, fluids and surfaces, laser-assisted spectroscopic measurement methods are being used in an increasingly broad range of applications. One established field of activity represents the analysis of tracer gases by means of single-mode semiconductor lasers. This field of activity utilizes the variation of the emission wavelength of the laser with electric pumping. The injection of a current pulse into the active layer of the semiconductor laser leads to a heating and thus to a shift of the laser wavelength on the order of magnitude of approximately one wave number, i.e. in the average infrared spectral range of less than one per thousand. For lightweight molecules with low widths of the spectral line and a correspondingly narrow emission characteristic of the laser, this is sufficient and can be used for the high-sensitivity chemically specific sensor technology. This method is the prior art and is designated Tunable Diode Laser Spectroscopy (TDLAS) in English.
On the other hand, heavy organic molecules with a more complex construction have spectra in the infrared spectral range with significantly broader characteristic absorption bands. The half bandwidths are typically 10 to 30 wave numbers, i.e. far above the tuning range of the conventional laser spectroscopy described above. In the prior art, such large tuning ranges require significantly more complex technologies, such as an external cavity laser (ECL), for example, or frequency mixing methods of the type that are used, for example, in an optical parametric oscillator (OPO system).
With the conventional TDLAS technology, the scanning of such a broad absorption line is not possible and thus the reliability of a measurement with regard to the chemical species and cross-sensitivities with other substances is severely limited.
To expand the tuning range of semiconductor lasers, consideration could given to operating the lasers with higher currents to achieve a greater temperature shift. The heating of the active layer of a semiconductor laser beyond the injection current has limits, however. Theoretically by means of a very high injection current, a very strong heating can be achieved, although very high currents in a semiconductor laser are generally accompanied by unsuitable spectral characteristics. The mode characteristic is generally very complex and the noise conditions are unfavorable. High currents can also cause uncontrollable local overheating in the component which can ultimately lead to its destruction. For example, in the presence of high currents in the area of the laser facets, temperatures that are higher than in the volume of the laser occur, which can lead to total failure.
The object of this invention is therefore to make available a laser module which makes it possible to significantly expand the tuning range of a laser operated with the laser module or of a laser of the laser module compared to the prior art. An additional object of the invention is to make available a laser module with which a fast and accurate control of the corresponding tuning is possible, and with which a high uniformity across the tunable range can be achieved.
The invention teaches that this object is achieved by a laser module described in claim 1. Additional advantageous embodiments of the laser module claimed by the invention are described in the dependent claims 2 to 22. This invention also describes a corresponding method for the operation of the laser module (claims 22 and 23), as well as applications (claim 24).
This invention is described below, initially in general terms. The general description is followed by one concrete exemplary embodiment. The individual features of the concrete exemplary embodiment claimed by the invention can thereby occur in the context of this invention not only in a combination of the type that occurs in the specific advantageous exemplary embodiment, but also as they are or can be realized or used in any other possible combinations in the context of the invention.
The basic teaching of this invention is to realize the laser module so that the temperature variation of the laser (and the related shift of the emission wavelength of the laser) can occur independently of the injection conditions of the laser. With a decoupling of the type claimed by the invention, compared to the heating of the laser via the injection current (as with the TDLAS technology of the prior art, for example), a significantly greater temperature shift of several 100 K becomes possible (in the following example, more than 200 K was achieved). The invention teaches that this increase is possible without introducing any additional thermal load into the active layer of the laser. This invention thereby makes available a laser module in which the temperature of the semiconductor laser located on the laser module can be varied and/or modulated very rapidly by means of the diamond submount of the laser module. A decisive aspect is thereby the adjustment of a rapid temperature increase in combination with a high temperature swing. As a result of this temperature modulation which is made possible by the invention, it becomes possible to tune the wavelength of the laser in a very short time. The laser module claimed by the invention is realized so that it is possible to modulate the temperature of the laser or of the laser chip independently of the laser current or decoupled from the injection conditions of the laser at high speed (in particular at more than 1000 K/s) and/or with a large swing (in particular more than 100 K). Thus a significantly greater tuning range is achieved than is possible with spectrally tunable lasers of the prior art. Additional advantages of this invention are described in greater detail below with reference to one exemplary embodiment.
The invention teaches that a laser module is made available that has a flat substrate base (which is preferably realized from a single material, in particular diamond), whereby this base is generally realized in the form of an oblong, flat substrate base (ratio of length to width advantageously >5) and is divided into a mounting area and a least one additional thermal conduction area adjacent to this mounting area. In the mounting area on the flat substrate base are both a heating element and a temperature sensor element.
In one particularly advantageous embodiment of the invention which is described in greater detail below, in the thermal conduction area there are a plurality of notches or saw cuts that run all the way through the substrate base perpendicularly to the plane of the surface, so that a meandering thermal resistance element is realized in this thermal conducting area. It is particularly advantageous for a laser module claimed by the invention to have two adjacent thermal conducting areas on two opposite sides of a central mounting area, in each of which thermal conducting areas a meandering thermal resistance element of this type is formed. One or two contact surface areas are therefore advantageously adjacent to the end or ends of the flat substrate basis farther from the mounting area in the respective thermal conducting area(s). A contact surface area of this type, which is advantageously also realized in the form of part of the flat substrate base, can then be used as a contact surface with an external heat sink. If, like the mounting area, it is realized in the form of a part of the flat substrate base, a contact surface area of this type advantageously has the same thermal conductivity as the mounting area.
It is particularly advantageous if a material is selected for the flat substrate base that has a thermal conductivity of greater than 1,000 W/(K*m). Diamond is particularly well suited for this purpose.
As a result of the particularly advantageous combination of such a material with high thermal conductivity with the division claimed by the invention into a mounting area (in which both the heating element and the temperature sensor element are located and in which the laser is also then bonded) and the neighboring thermal conduction area(s) as well, as the advantageous realization of corresponding notched areas or thermal resistance elements in the thermal conductivity area(s), not only can a very high thermal homogeneity be achieved in the area of the contact surface of the laser (mounting area); but the temperature variation can also be controlled very quickly, so that the laser can be very rapidly tuned across the desired spectral range. For this purpose, in particular the heating element, the temperature sensor element and the laser are advantageously located as close as possible to one another in the mounting area of the flat substrate.
The invention is described in greater detail below with reference to the special exemplary embodiment illustrated in the accompanying
a shows a view V of the front surface and the a view R of the rear surface of the substrate base 1 with the temperature sensor element mounted (in the laser module illustrated in
b shows the corresponding module from
The segments B1 and C1 on one hand and the segments B2 and C2 on the other hand are thus located on opposite sides of the mounting area A (all the above mentioned segments in a line). It is also possible, of course, to locate the segments C1 and B1, for example, not offset by 180° with respect to the segments B2 and C2, but at a 90° angle (arrangement in the shape of an “L” with the mounting area A at the articulation point of the “L”). As described in greater detail below, the illustrated laser module or its substrate base is made of a material that has high thermal conductivity (diamond), in which the thermally conducting areas B next to the mounting area A are realized with reduced thermal conductivity. In the vicinity of the mounting surface A, the heating element and the temperature sensor element are then located by means of front-side and/or back-side metallizations. Likewise, in the area A, a laser bond metallization is provided so that the semiconductor laser is also brought into contact with the substrate base in the area A. In the contact surface areas C, the substrate base is realized so that it has the same thermal conductivity as in mounting area A. In these areas C, heat sinks (e.g. copper bodies or similar bodies, including liquid-driven heat sinks or similar bodies are possible, as the technician skilled in the art will be aware. In the area A in which both the laser mounting surface as well as the laser, the heating element and the temperature sensor are located, the flat substrate base is prepared to that it is homogeneous and unstructured, which results in high thermal conductivity. With the diamond module with dimensions 3×13 mm2 and a thickness of 0.1 mm used in this example, the non-contacting surface B (10×3 mm3) has a thermal capacity of 5.5×10−3J/K (at 300 K). The value for the heat sink W should be higher by at least a factor of 10. The factor 20 has been selected here (results in 0.1 J/K for the heat sink W).
A temperature gradient toward the heat sink or toward the contact surface areas C can now be established by means of the areas B with reduced thermal conductivity. In the areas B, the thermal conductivity is reduced in a controlled manner by means of notches (saw cuts) cut into the material of the substrate base 1. The module once again has the maximum thermal conductivity in the area of the contact surfaces C which create the contact with the heat sink. In this case, diamond is used as the materials for the substrate base 1 as described above, although other materials such as SiC or AlN can also be used (see also table in
A temperature sensor element 5 in the form of a C-shaped metallization is installed in the mounting area A on the upper side of the module shown in
On the reverse side R opposite to the front side V shown here (see
Each of the two thermal conduction areas B1 and B2 is then realized as follows: Viewed in the longitudinal direction L, notches are introduced into the substrate base 1 in alternation (i.e. alternating from both lateral edges, in this figure therefore from the top longitudinal narrow side and the bottom longitudinal narrow side). These notches (e.g. the notches E1 and E2) are thereby cut all the way through the thickness (perpendicular to the plane of the paper) of the substrate (e.g. they are cut all the way through the substrate layer). Viewed in the longitudinal direction, neighboring notches E1, E2 are thereby separated by the distance d. The notch length, i.e. its depth viewed in the direction of the width BR, is 1. The length 1 is hereby significantly greater than the distance d, and the ratio here is approximately V2=1/d=4. Because the width BR of the substrate 1 is only insignificantly greater than 1 (here approximately 1.25*1) and because six notches E were made in each of the areas B1 and B2, a meandering thermal resistance element is thereby formed (resistance elements 4a and 4b) in each of the areas B1 and B2. The essential feature in this case is therefore on one hand that the above mentioned ratio V2=1/d has a minimum value and that neighboring segments are cut in respectively from both sides (viewed in the longitudinal direction L) so that the above mentioned meandering path results for the thermal conduction, i.e. the path of is significantly longer than the dimension of the areas B1 and B2 viewed in the longitudinal direction. The geometry described above is hereby realized so that in the illustrated case the ratio V1=WA/WB of the thermal conductivity WA of the mounting area A and the thermal conductivity WB of a thermally conducting area B1, B2 is approximately 30.
Also decisive is the compact, integrated arrangement of the elements 5 to 8 in the mounting area A. The decisive variables in this regard are the two ratios v3 and v4 as follows. Let AH be the average dimension of the heating element in the surface plane (if the heating element 2 can be considered in a first approximation to be square, it corresponds to the length of one side of the square). Let AT be the corresponding average dimension of the temperature sensor element (if this element has, for example, the approximate shape of a circle in the surface plane, this dimension equals the diameter of the circle). If we the take the average of these two dimensional values AHT and place it in a ratio to the distance aHT between the heating element and the temperature sensor element, the two elements 2, 5 must be arranged so that the ratio v3=aHT/AHT is as small as possible. The distance is hereby defined as the distance between the (geometric) centers of gravity of the two elements 2, 5 in the surface plane. V3 is approximately 0.8 here. Likewise, the ratio v4=aHL/AHL can be defined from the distance aHL between the heating element on the one hand and the laser bond metallization 8 (or the laser) on the other hand and by the correspondingly determined average dimension AHL of the heating element and of the laser bond metallization (or of the laser). The distance is here again defined by means of the centers of gravity and in the surface plane. This value should also be selected so that it is as small as possible (here it is approximately 0.5).
On the upper side of the substrate base 1, a gold metallization (laser bond metallization 8) is therefore applied in the center A and is used for the mounting of a semiconductor laser by means of soldering (see also
b is a detail, although it shows only the mounting area A with the thermally conductive areas B1 and B2 located alongside it. The contact areas C1 and C2 are here concealed by the heat sinks (copper bodies) W1 and W2. The figure also shows the bonded laser. The lateral copper contact surfaces of the heat sinks W1, W2 form the contact of the laser to the heat sinks.
The optimum overall performance of the laser module is achieved by using diamond as the material for the flat substrate base 1. The use of diamond is advantageous primarily for the rapid temperature equalization in the mounting area A between the heating element 2, the flat substrate base 1 and temperature sensor element 5, on account of the high thermal conductivity. Defined temperature variations can therefore be achieved very quickly. Using the diamond module claimed by the invention, rates of more than 2,500 K/s can be achieved with temperature swings between 77 K and 300 K (see also
c) shows the intensity curve of the laser emission. As expected, the laser intensity is reduced by slightly less than one-half during the change from 77 K to room temperature. The slight oscillations of the intensity are the result of variations of the mode distribution as a result of the shift of the laser wavelength.
In the operation of the module described here, note should be taken of the different thermal expansion rates of the materials used. The thermal expansion rate of diamond is less than that of the III-V semiconductor of the laser used in the illustrated example (see
Load tests with an active laser assembly were performed in the operating mode described above. When a 2000 μm×1000 μm laser chip was used, on which a 8 μm×2000 μm quantum cascade laser (QC laser) was located, 10,000 temperature cycles could be performed between 77 K and 300 K the laser, which was in constant operation throughout, did not suffer any damage.
The invention teaches a novel concept which makes possible the expansion of the spectral tuning range of semiconductor lasers in optical spectroscopy. A QC laser constructed on the diamond module is operated at 180 K and 120 K alternately. The period of the complete heating and cooling cycle is 1 s. As illustrated in the emission characteristic shown in
Finally,
Number | Date | Country | Kind |
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10 2007 039 219.4 | Aug 2007 | DE | national |
Filing Document | Filing Date | Country | Kind | 371c Date |
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PCT/EP2008/006703 | 8/14/2008 | WO | 00 | 5/3/2010 |