STRETCHABLE/CONFORMABLE ELECTRONIC AND OPTOELECTRONIC CIRCUITS, METHODS, AND APPLICATIONS

Abstract

A fabrication method for stretchable/conformable electronic and optoelectronic circuits and the resulting circuits. The method may utilize a variety of electronic materials including, but not limited to Silicon, GaAs, InSb, Pb Se, CdTe, organic semiconductors, metal oxide semiconductors and related alloys or hybrid combinations of the aforementioned materials. While a wide range of fabricated electronic/optoelectronic devices, circuits, and systems could be manufactured using the embodied technology, a hemispherical image sensor is an exemplary advantageous optoelectronic device that is enabled by this technology. Other applications include but are not limited to wearable electronics, flexible devices for the internet-of-things, and advanced imaging systems.

Description

FIELD OF THE INVENTION

Aspects and embodiments of the invention pertain to flexible electronic and optoelectronic circuits, methods for fabricating said flexible electronic and optoelectronic circuits, and applications thereof including but not limited to wearable electronics, flexible devices for the internet-of-things, advanced imaging systems, biometric sensor systems, and microprocessors; more particularly to stretchable/conformable electronic and optoelectronic circuits, methods for fabricating said stretchable/conformable electronic and optoelectronic circuits, and applications thereof; most particularly to stretchable/conformable focal plane arrays (FPAs), methods for fabricating said stretchable/conformable FPAs, and applications thereof.

BACKGROUND

Flexible electronic circuits are desirable for a wide range of applications. Conventional electronic materials (Silicon, GaAs, InP, InSb, HgCdTe, GaN, and related materials) are inherently rigid and the desire for flexible electronics has motivated development of novel electronic materials that are inherently flexible and stretchable, such as metal oxides, organic semiconductors, metallic inks, and ultra-thin crystalline semiconductors lifted off of a wafer. A variety of flexible electronics have been demonstrated with such materials, but these novel materials suffer from inferior optical and electronic characteristics compared to conventional crystalline materials on a wafer. This inferior performance imposes limitations to the performance and functionality of devices based on these materials. As a result, the trend in flexible electronic devices is to use rigid, wafer based circuits bonded onto flexible or stretchable substrates to provide semi-rigid (or semi-flexible) devices. For example, there is a relatively mature industry using the equivalent of flexible PCB boards that get populated with rigid wafer based circuits; in this example, the circuits are not flexible but they are attached to a flexible carrier. If these rigid circuits are small compared to the desired curvatures, this can be a satisfactory approach. For complex circuits or large area circuits, such as sensor arrays designed for monitoring some physiological response over a sizeable region of the human body, this approach requires assembly of a large number of small circuits in order to retain a semblance of flexibility and this approach becomes impractical. Similarly, this is impractical for devices needing to bend with large curvatures or otherwise require truly flexible electronic circuits.

A method has been demonstrated to permanently deform a silicon-based electronic circuit to a curved surface by thinning the wafer and applying high pressure to mold the wafer, but this is limited to very shallow curvatures due to the rigid and brittle nature of the silicon wafer.

There have been demonstrations to transfer wafer-based devices or circuits to flexible substrates using a variety of techniques to release them from the wafer; these approaches suffer severe limitations (including lack of stretchability, low device density, and/or incompatibility with conventional device structures) that make them impractical for many applications.

A method to transform a silicon wafer-based circuit into a stretchable circuit has been demonstrated where the wafer is made stretchable by etching through the wafer leaving small silicon islands mechanically connected by narrow silicon bridges. This approach requires routing electrical interconnections over these silicon bridges, precluding the ability to provide high-density interconnections required for complex circuits. This approach also suffers from low density of active circuit area as much of the footprint is consumed by the silicon bridges/interconnects. Such an approach does not appear practical or useful for complex circuits.

In view of these and other shortcomings appreciated by those skilled in the art, the inventor has recognized beneficial and advantageous solutions realized and enabled by the embodied invention. These solutions are in the form of stretchable/conformable electronic or optoelectronic circuits and methods for fabricating such stretchable/conformable electronic or optoelectronic circuits.

Flexible circuits or devices (without the ability to stretch) only allow bending in one direction at a time; whereas a circuit or device that can conform to complex shapes requires stretching. Thus, as used herein, the terms ‘stretchable,’ ‘conformable’ as applied to the embodied electronic or optoelectronic circuits and methods provide one or more degrees of freedom beyond those provided by ‘flexible’ electronic or optoelectronic circuits as known in the art. For example, a 2D (rectangular, x by y) ‘flexible’ electronic circuit can assume planar and non-planar topologies wherein the x- and y-dimensions will change in shape/contour but not in magnitude; whereas, the x- and/or y-dimensions of a 2D (rectangular, x by y) ‘stretchable/conformable’ electronic circuit may be elongated/stretched (e.g., by up to 50% as necessary to conform to a hemispherical surface).

SUMMARY

An aspect of the invention is a stretchable, conformable, or deformable electronic or optoelectronic circuit comprised of a wafer-based circuit and a stretchable backplane that is monolithically integrated with the circuit. The wafer-based circuit is made stretchable by etching, dicing, cleaving, or otherwise segmenting the wafer into two or more small (e.g. <1 mm wide) segments. These segments are affixed and electrically interconnected through the stretchable backplane. The lateral dimensions of the wafer segments are sized to provide flexibility and stretchability suitable for the circuit to conform to the desired curvatures and topologies. The monolithically integrated backplane allows formation of high-density and highly-interconnected circuits suitable for a wide range of applications.

In various non-limiting embodiments, the stretchable circuit may include, alone or in various combinations as one skilled in the art would understand, the following limitations, features, characteristics and/or elements:

• Silicon-based circuit fabricated using conventional CMOS fabrication technology.
• Wafer-based circuit with dedicated sacrificial regions that will be etched to segment wafer into small pieces.
• An integrated circuit containing basic circuit elements including transistors, resistors, capacitors, inductors, and/or transducers including photodetectors, bolometers, acoustic sensors, microphones, accelerometers, gyroscopes, chemical sensors, pressure sensors, temperature sensors, voltage sensors, capacitance sensors, etc.
• A hybrid circuit containing non-silicon based devices (such as lead-salt or other infrared photodetectors) in conjunction with silicon-based devices.
• Short-range interconnects fabricated using conventional BEOL (back end of line) metallization techniques to provide interconnection on a single wafer segment.
• Through-silicon-vias (TSVs) routing signals through the wafer.
• Polymer backplane that provides long-range interconnections between wafer segments and/or connection to other circuits or external electronics.
• Stretchable polymer backplane that can be stretched one or many times; for example, a thermo-formable polymer may be used to permanently deform the circuit into a desired shape, while an elastomeric polymer may be used to provide permanent stretchability.
• A polymer backplane that is monolithically integrated onto the wafer after completion of BEOL processing.
• Multilayered interconnects embedded in, on or beneath the polymer backplane.

An aspect of the invention is a method for fabricating a stretchable/conformable or deformable electronic or optoelectronic circuit. The method utilizes a stretchable/conformable or deformable polymer backplane that mechanically holds segments of a circuit, electrically interconnects the circuit, and may provide interface to external electronics that are not part of the stretchable, conformable or deformable circuit. This backplane may be monolithically integrated onto the front or back of a wafer-based circuit or in-between two wafer based circuits before the wafer is segmented into pieces to facilitate stretching, conforming or deforming. Additionally, or alternatively, wafer based circuits may be bonded onto the stretchable polymer backplane.

In an exemplary, non-limiting embodiment the method includes the steps of: (1) design and fabrication of a circuit on wafer with provision for sacrificial regions that will be used to etch/segment the wafer and designated interconnect points that will be used to electrically interface with the rest of the circuit through a polymer backplane. If the circuit components are fabricated on the frontside of the wafer in relation to a polymer backplane that will be fabricated on the backside of the wafer, the designated interconnect points may be located on the backside of the wafer and be connected to the circuit on the frontside of the wafer using through-silicon-vias (TSVs) to route signals through the thickness of the wafer allowing interconnection at the backside of the wafer. (2) A stretchable, conformable or deformable polymer backplane with interconnects is fabricated on the backside of the wafer, for example, using the steps below:

• Applying and patterning a thick photoresist to expose the designated interconnect points;
• Electroplating a metal, such as copper, to form ˜20 μm tall contact pillars and stripping the photoresist;
• Coating wafer surface with a fluid polymer layer such as an uncured and uncrosslinked PDMS (such as Dow Corning Sylgard 184) allowing the polymer to flow in between contact pillars;
• Vacuum degassing to remove air bubbles;
• Flattening and planarizing the polymer by applying pressure from above using a non-stick planar surface such as a Teflon coated silicon wafer;
• Crosslinking the PDMS by curing at room temperature or elevated temperature such as 100° C.;
• Dry (plasma), wet (chemical) or mechanical (lapping) to clean and expose contact pillars of any residual PDMS;
• Evaporating metal over the surface of the crosslinked polymer and exposed contact pillars;
• Patterning photoresist to define the first interconnect pattern;
• Etching away unwanted metal, effectively transferring the pattern into the metal;
• Stripping photoresist;
• Repeat the above steps to pattern multiple interconnect layers separated by PDMS;
• Last, a thick PDMS layer may be applied on top of the interconnect layers to provide additional polymer thickness for improved handling and stretchability;

(3) After completion of the polymer backplane and interconnects, the wafer will be segmented, for example, by etching through the wafer with a deep reactive ion etch such as the Bosch process. Once the wafer has been segmented the circuit becomes flexible, stretchable, conformable and/or deformable according to the mechanical properties of the polymer backplane.

In various non-limiting embodiments, the method may include, alone or in various combinations as one skilled in the art would understand, the following steps, limitations, features, characteristics and/or elements:

• An elastomeric polymer backplane formed, for example, using PDMS;
• A thermo-formable polymer backplane formed, for example, using polyethylene terephthatlate (PET) or glycol-modified PET (PETg);
• Melting a cross-linked polymer for wafer coating then cooling to re-crosslink the polymer;
• Chemically cured and cross-linked polymers;
• More than one polymer type to achieve desired mechanical, electrical, optical, and/or thermal properties;
• Etching polymer to expose designated interconnect points at any level of a single or multilayer interconnected backplane;
• Lift-off patterning of metal interconnects;
• Ink-jet printing of metal interconnects from stretchable and/or nanoparticle metallic inks;
• Screen printing of metal interconnects;
• Metal patterns designated for thermal management to facilitate heat transport to/from the circuit through the polymer backplane;
• Metal patterns designated for ground planes;
• Metal-to-polymer adhesion layers such as evaporated titanium before metal deposition;
• Polymer-to-wafer adhesion promotion, such as oxide etching, surface roughening via argon-plasma etching, or surface functionalization via oxygen-plasma etching;
• Wafer thinning to facilitate narrow segmentation etch widths and small pitch TSVs;
• Thermoforming or otherwise molding the final circuit into a desired shape; and
• Bonding the circuit to a rigid carrier such as a metal, plastic or glass mold or panel, for example, using an epoxy or other adhesive.

BRIEF DESCRIPTION OF THE DRAWINGS

One or more aspects of the present invention are particularly pointed out and distinctly claimed as examples in the claims at the conclusion of the specification. The foregoing and other objects, features, and advantages of the invention are apparent from the following description taken in conjunction with the accompanying drawings in which:

FIG. 1A is a schematic representation of an illustrative embodiment of the fabrication process steps of a stretchable/conformable electronic or optoelectronic circuit;

FIG. 1B is an additional schematic representation of the illustrative embodiment of the fabrication process steps of the stretchable/conformable electronic or optoelectronic circuit of FIG. 1A;

FIG. 2A is a schematic representation of an illustrative embodiment of three interconnected layers prior to etching the Si wafer;

FIG. 2B is a schematic representation of the three interconnected layers of FIG. 2A after etching the Si wafer;

FIG. 3 is a schematic representation of an illustrative embodiment of dimensions and array of PbSe pixels on Si of the stretchable/conformable electronic or optoelectronic circuit at step 5 of FIG. 1B;

FIG. 4 is a schematic representation of an illustrative embodiment of dimensions and array of PbSe pixels on isolated Si of the stretchable/conformable electronic or optoelectronic circuit at step 6 of FIG. 1B;

FIG. 5A is a schematic representation of a stretchable/conformable electronic or optoelectronic circuit of FIG. 4 stretched over and conformed to a hemispherical lens to form an image;

FIG. 5B is an exemplary embodiment of metal patterns defined on flat PETg and thermoformed into a spherical cap;

FIG. 6 is a schematic representation of a mold incorporated into the stretchable/conformable electronic or optoelectronic circuit;

FIG. 7A is a schematic representation of another illustrative embodiment of a fabrication process steps of a stretchable/conformable electronic or optoelectronic circuit;

FIG. 7B is an additional schematic representation of the illustrative embodiment of the fabrication process steps of a stretchable/conformable electronic or optoelectronic circuit in FIG. 7A; and

FIG. 8 is a schematic representation of the lens assembly and stretchable FPA components comprising a HFPA.

DESCRIPTION OF NON-LIMITING, EXEMPLARY EMBODIMENTS

An embodiment of the invention is a fabrication process to make stretchable, conformable electronic or optoelectronic devices, circuits, or systems. Initially, a custom, wafer-based circuit is designed and manufactured using conventional microelectronics fabrication processes. This circuit will be designed to have multiple segments (islands) that are electrically isolated from each other. These segments/islands may contain one or more devices or circuit elements. Flexible, stretchable, and/or deformable interconnects are then fabricated onto the wafer to provide interconnection between these isolated segments of the circuit. The interconnects may be metallic “wires” fabricated on-top and/or embedded-inside of a polymeric (i.e., plastic, rubber, etc.), thin glass, foil and/or other flexible, stretchable, conformable supporting medium. These “wires” may be printed and/or lithographically defined in conjunction with conventional microelectronics deposition methods including evaporation, sputtering, chemical vapor deposition, electroplating, lithographic patterning, and others as known in the art. The interconnects may be multilayered, allowing for formation of complex interconnection patterns. Different interconnect layers of a multilayered interconnect may be separated by one or more layers of a supporting and/or insulating medium; not all layers will necessarily need to be stretchable if they do not inhibit the flexibility and/or stretchability of the completed device, circuit, or system. The interconnects will provide a flexible handle that will give mechanical support to the wafer segments after the circuit is made stretchable/conformable. Finally, the circuit is made stretchable/conformable by mechanically isolating the wafer segments by dicing, etching-through, or otherwise partitioning the wafer. Etching may be performed all the way through the wafer or only part way through the wafer to achieve the desired flexibility (bendability) for the circuit. The resulting interconnected and stretchable/conformable circuit may be encapsulated and/or packaged and it may be integrated as the whole, or part of, a system or device. The resulting system or device may or may not be flexible, stretchable, or conformable, as such circuits may be included in rigid systems or devices to provide improved mechanical robustness and impact resistance.

FIGS. 1A-1B schematically illustrates the fabrication process steps of a stretchable/conformable electronic or optoelectronic circuit 30. (FIGS. 7A-7B show both top and side views on the fabrication steps of the stretchable/conformable electronic or optoelectronic circuit 30 of FIGS. 1A-1B). In step 1, circuitry is fabricated on a Si wafer 10 using conventional fabrication techniques (i.e., wafer based techniques such as the CMOS process). This wafer 10 is complete with electronic/optoelectronic devices 12, short-range interconnects 24 and, when necessary, through-Si-vias (TSVs) 16. The sacrificial regions 14 which will be etched are shown on either side of the Si wafer 10.

In step 2, thick metal pillars (10 μm, Cu) 18 are fabricated on designated interconnect points to extend these contacts vertically. As illustrated, these designated interconnect points may be the bottom 26 of the TSVs 16 themselves to minimize the footprint of interconnects. These pillars 18 may be fabricated by a variety of well-known metal deposition techniques including, for example, copper electroplating from a seed layer through a photoresist.

In step 3, a polymer coating 20 is applied to fill in-between the metal pillars 18. This polymer 20 may be an elastomeric material (such as PDMS), a thermo-formable material (such as PET), or other polymer that can provide the desired mechanical properties and be coated to fill between metal pillars 18. Polymer coating 20 may be performed by spin-coating, drop casting, transfer printing, injection molding, etc. Methods such as spin-coating may coat the top of the metal pillars 18 with polymer 20 and this can be removed, for example, by plasma etching to provide an electrically accessible interconnect point at the distal end 22 of the metal pillar 18.

In step 4, the first interconnect layer 24 is patterned on top of the polymer layer 20 formed in step 3. This interconnect 24 will electrically connect some of the metal pillars 18 and route signals across the top of the polymer 20. This interconnect layer 24 may be fabricated by lithographic methods similar to conventional patterning on a wafer 10 (i.e., etching or lift-off techniques) using processes compatible with the mechanical, optical, thermal and chemical stability of the polymer 20. Such interconnects 24 also may be patterned using more novel techniques such as stamp transfer patterning or printing.

In step 5, steps 2-4 can be repeated one or more times to form multilayered contacts allowing the formation of complex interconnects 24 suitable for complex circuits. These interconnects 24 may connect to multiple designated interconnect points per island, may connect adjacent islands (i.e., intermediate range interconnects), may connect islands to other parts of the polymer backplane 20 or out from the local circuit (consisting of a multiplicity of Si islands) to external electronics or circuits (i.e., long range interconnects). After completion of the interconnect layers 24, additional polymer 20 may be applied to add thickness to achieve the desired mechanical properties.

In step 6, the wafer 10 is segmented into small, yet interconnected, segments 28. The segmentation may be accomplished by dicing, cleaving, etching, laser ablation, focused ion-beam milling, etc. For example, a deep reactive ion etch (DRIE) using the Bosch process is an ideal way to etch through the wafer 10 with high-aspect ratio allowing for a minimal sacrificial region 14, maximum wafer active area and high-density circuitry. Thin wafers 10 may be utilized to maximize the resolution of such etching and the density of interconnects routed through the wafer 10 with TSVs 16. After the wafer 10 is segmented, the Si islands 28 remain affixed in place by adhesion to the flexible polymer backplane 20 and/or bonding of the embedded metal pillars 18 to the Si island 28. The Si islands 28 remain electrically interconnected through the flexible polymer backplane 20. After completion of etching, the circuit 30 becomes flexible, conformable and stretchable based on the properties of the polymer backplane 20.

In step 7, the flexible, conformable and stretchable circuit 30 can be deformed to the desired shape. The minimum radius of curvature should be much larger than the width of the Si islands 28 as shown. Island 28 size can vary depending on circuit requirements, but typically is expected to be in the range of 10-1000 μm for a hemispherical imager. Similarly, the number of designated interconnect points and/or TSVs 16 can vary, but typically is expected to be in the range of 4-64 for a hemispherical imager.

FIG. 2A and FIG. 2B, respectively, illustrate three interconnect layers 32 before and after etching the Si wafer 10 to make it stretchable and conformable. In FIG. 2B, the total thickness of the three interconnect layers 32 is between about 100-200 microns. The total device 30 thickness is between about 300-800 microns. The device 30 of FIGS. 2A-2B comprises CMOS layers 12 with IR detectors 34.

FIG. 3 schematically illustrates in a perspective view the device 30 at step 5 in FIG. 1B (before wafer segmentation), further showing exemplary dimensions and an array of PbSe pixels 36 (apprx. 10 μm) on Si 10 (i.e., Si ROIC) on the interconnected PDMS backing 32 for an IR imager application. The structure shown above in FIG. 3 forms a small portion of the overall device 30 shown below.

FIG. 4 schematically illustrates in a perspective view the device 30 at step 6 in FIG. 1 (after wafer segmentation), further showing exemplary dimensions and multiple arrays of pixels 36 (e.g., apprx. 10 μm PbSe pixels) on isolated Si islands (i.e., segments) 28 on the interconnected PDMS backing 32. The structure shown above in FIG. 4 forms a small portion of the overall device 30 illustrated below in FIG. 4. The overall device 30 has spacing 38 between the Si islands 28, which provides a configuration to better facilitate deformation to a hemisphere.

Ultimately, scaling and interconnect density are a concern. This is especially true for circuit architectures that require TSV interconnects where the relatively large TSV diameter limits the density of interconnections through a wafer. The minimum TSV pitch is approaching 5 μm using thin wafers and is expected to reach ˜1 μm by the year 2020. In the context of a stretchable image sensor utilizing TSV feedthroughs, for example, an individual pixel in the sensor may require anywhere from 2-8 input/output (I/O) lines for power, control and readout; yet, advanced CMOS pixels can be smaller than 1 μm on an edge. Consequently, the footprint required for I/O may be much larger than the desired pixel footprint if pixels are directly connected with TSVs; this would lead to undesirably low imager resolution. The number of I/O lines per pixel can be reduced by including multiplexing capability in the CMOS circuitry and packing numerous pixels onto a single segment of the wafer. Pixels on a single segment can then share TSVs and interconnects across the polymer backplane allowing formation of advanced image sensors with a high density of complex pixels.

FIG. 5A schematically illustrates a stretchable/conformable optoelectronic circuit 30 as illustrated in FIG. 4 stretched over and conformed to a hemispherical lens to form an imager 40. (FIG. 8 shows a lens assembly 46 and stretchable FPA 30 used to form a HFPA 40). FIG. 5B shows exemplary metal patterns defined on flat PETg and thermoformed into a spherical cap 40. A vacuum mold or other fixture may be used to enable the proper stretching and conformation shapes and sizes. Such a mold could be a permanent component of a finished system as schematically illustrated in FIG. 6. FIG. 6 shows front end electronics 42; a Dewar cover 44; lens assembly 46; flexible FPA 48; 3D mold, heat sink, and Dewar base 50; and TECs 52.

A contemplated embodiment of the invention utilizes a thermo-formable (i.e., non-elastomeric) polymer, such as polyethylene terephthalate (PET), for the stretchable/deformable backplane. The polymer may be applied, for example, by direct polymerization on the wafer, injection molding or other melt-based application process. After fabrication of the polymer backplane and etching of the wafer using a process similar to that shown in FIGS. 1A-1B, the circuit could then be permanently thermo-formed to the desired shape, for example, using a heated vacuum mold, enabling fabrication of semi-rigid but highly contoured circuit. The inventors have shown that interconnects fabricated on PET can survive thermos-forming to a variety of shapes using such a mechanism.

Claims

1. A method for making a stretchable/conformable electronic or optoelectronic circuit, comprising: a) fabricating circuitry on a Si wafer;b) fabricating metal pillars on designated interconnect points to extend these contacts vertically;c) applying a polymer coating to fill in-between the metal pillars;d) patterning a first interconnect layer on top of the polymer coating layer;e) repeating steps (b-d) one or more times to form multilayered contacts;f) segmenting the wafer into interconnected segments thus forming a flexible, conformable and stretchable circuit.

2. The method of claim 1, further comprising the step of: g) deforming the flexible, conformable and stretchable circuit to a desired shape.

3. The method of claim 1, wherein the step of segmenting the wafer into interconnected segments thus forming a flexible, conformable and stretchable circuit includes the step of etching through at least a portion of the wafer.

4. The method of claim 2, further comprising the step of: h) stretching the flexible, conformable and stretchable circuit over a hemispherical lens.

5. The method of claim 2, further comprising the steps of: h) applying the flexible, conformable and stretchable circuit to a mold; andwherein the desired shape is the shape of the mold.

6. The method of claim 1, wherein the metal pillars are composed of copper.

7. The method of claim 1, wherein the polymer is an elastomeric material.

8. The method of claim 1, wherein the polymer is a thermos-formable material.

9. The method of claim 1, wherein the interconnect points are composed of through-Si-vias (TSVs).

10. A stretchable, conformable, or deformable electronic or optoelectronic circuit comprised of a wafer-based circuit and a stretchable backplane that is monolithically integrated with a circuit.

11. The circuit of claim 10, further comprising one or more isolated wafer segments of the wafer-based circuit interconnected by the stretchable backplane.

12. The circuit of claim 10, wherein the stretchable backplane comprises one or more metal interconnect layers between polymer coating layers.

13. The circuit of claim 12, wherein the polymer coating is composed of at least one of an elastomeric material and a thermo-formable material.

14. The circuit of claim 12, further comprising metal pillars interconnecting the wafer based circuit and the one or more metal interconnect layers.

15. The circuit of claim 10, further comprising photodetectors on a surface of the wafer-based circuit.

16. The circuit of claim 10, further comprising a hemispherical lens layered between the stretchable backplane and the wafer-based circuit.

17. The circuit of claim 12, further comprising an array of PbSe pixels on each of the one or more isolated wafer segments.

18. The circuit of claim 10, wherein the total thickness of the stretchable, conformable, or deformable electronic or optoelectronic circuit is within the range of 300-800 microns.

19. The circuit of claim 12, wherein the polymer coating is composed of polyethylene terephthalate (PET).