Styrene-based syndiotactic resin composition

FIELD OF THE INVENTION
The present invention relates to a syndiotactic, polystyrenic resin composition. More precisely, it relates to a syndiotactic, polystyrenic resin composition which can be formed into an article having improved heat resistance, an increased modulus of elasticity and greatly improved toughness, and in addition, the peeling of the surface layer of the article to be formed from the composition is retarded.
BACKGROUND OF THE INVENTION
Articles formed from a styrene-based polymer having a syndiotactic configuration (hereinafter referred to as SPS) have excellent heat resistance and chemical resistance but have poor impact resistance. Therefore, the polymer has heretofore been used in limited ranges. In order to improve the impact resistance of SPS articles, it has been proposed to add rubber-like elastic substances and other thermoplastic resins to SPS (see Japanese Patent Application Laid-Open Nos. 257950/1987, 146944/1989, 182344/1989, 279944/1989, and 64140/1990).
Concretely, a composition comprising SPS and, as a rubber-like elastic material, a component containing a styrenic compound (see Japanese Patent Application Laid-Open No. 146944/1989), and a composition comprising a mixture of SPS and a thermoplastic resin and/or a rubber-like polymer except SPS, and, as a miscibility-improving agent, a styrenic chain-containing, block or graft copolymer (see Japanese Patent Application Laid-Open No. 279944/1989) have been proposed.
These compositions contain, as a miscibility-improving agent, a polystyrenic chain-containing, block or graft polymer, in order to improve the miscibility of a rubber component with immiscible SPS and to improve the dispersibility of the rubber component and the interfacial strength between the constitutive components. However, the effect of the miscibility-improving agent therein is not satisfactory. Therefore, the articles formed from these compositions are not satisfactorily tough and the peeling of the surface layers from the articles could not be retarded sufficiently.
SUMMARY OF THE INVENTION
Given the situations, it is an object of the present invention to provide a syndiotactic, polystyrenic resin composition which can be formed into an article having an increased modulus of elasticity, high heat resistance and greatly improved toughness, and additionally having high impact resistance while retarding the peeling of the surface layer from the article.
We, the inventors of the present invention have assiduously studied so as to develop a syndiotactic, polystyrenic resin composition having the above-mentioned favorable properties and, as a result, have found that the intended object can be attained by a composition comprising a styrene-based polymer having a syndiotactic configuration and a polyolefin and, as a miscibility-improving agent for these, a particular styrene-olefin copolymer, in predetermined ratios. In addition, we have found that, when a small amount of a polyphenylene ether is added to the composition, the toughness of an article to be formed from the resulting composition can be more effectively improved. Moreover, we have further found that, when a particular styrene-based copolymer and/or a particular oil or wax are/is added thereto, the toughness of the article can be much more effectively improved. Furthermore, we have found that, when an inorganic filler, or a combination of an inorganic filler and a particular polymer having a polar group is added to the composition in predetermined ratios, the heat resistance and the modulus of elasticity of the article can be much more increased. On the basis of these findings, we have completed the present invention.
Specifically, the present invention provides;
(1) a syndiotactic, polystyrenic resin composition comprising resin components of (A) 100 parts by weight of a component composed of (a) from 10 to 98% by weight of a styrene-based polymer having a syndiotactic configuration and (b) from 2 to 90% by weight of a polyolefin, and (B) from 0.5 to 50 parts by weight of a styrene-olefin copolymer having a styrene content of from 40 to 85% by weight;
(2) a syndiotactic, polystyrenic resin composition comprising resin components of (A) 100 parts by weight of a component composed of (a) from 10 to 98% by weight of a styrene-based polymer having a syndiotactic configuration and (b) from 2 to 90% by weight of a polyolefin, (B) from 0.5 to 50 parts by weight of a styrene-olefin copolymer having a styrene content of from 40 to 85% by weight, and (C) from 0.5 to 10.0 parts by weight, relative to 100 parts by weight of the component (a) of (A), of a polyphenylene ether (having an intrinsic viscosity in chloroform at 25.degree. C of 0.4 dl/g or higher);
(3) a syndiotactic, polystyrenic resin composition of the above-mentioned (1) or (2), which further contains (D) from 0 to 200 parts by weight, relative to 100 parts by weight of the component (b) of (A), of a styrene-olefin copolymer having a styrene content of from 5 to 35% by weight;
(4) a syndiotactic, polystyrenic resin composition of the above-mentioned (1) or (2), which further contains (E) from 0 to 200 parts by weight, relative to 100 parts by weight of the component (b) of (A), of a paraffinic oil, a paraffinic wax, a mineral oil and/or a siloxanic oil; and
(5) a syndiotactic, polystyrenic resin composition of the above-mentioned (1) or (2), which further contains (D) from 0 to 200 parts by weight, relative to 100 parts by weight of the component (b) of (A), of a styrene-olefin copolymer having a styrene content of from 5 to 35% by weight, and (E) from 0 to 200 parts by weight, relative to 100 parts by weight of the component (b) of (A), of a paraffinic oil, a paraffinic wax, a mineral oil and/or a siloxanic oil.
Preferred embodiments of the present invention are;
(6) the syndiotactic, polystyrenic resin composition of any of the above-mentioned (1) to (5), which further contains (F) from 0.5 to 350 parts by weight, relative to 100 parts by weight of the resin components, of an inorganic filler, and
(7) the syndiotactic, polystyrenic resin composition of any of the above-mentioned (1) to (5), which further contains (F) from 0.5 to 350 parts by weight, relative to 100 parts by weight of the resin components, of an inorganic filler, and (G) from 0.1 to 10 parts by weight, relative to the same, of a polymer which is miscible with or has an affinity for the component (a) of (A) and which has a polar group.
DETAILED DESCRIPTION OF THE INVENTION
The resin composition of the present invention comprises, as the component (a) of (A), a styrene-based polymer having a syndiotactic configuration. The syndiotactic configuration in the styrene-based polymer as referred to herein indicates that the stereochemical structure of the polymer is syndiotactic or, that is, such that the phenyl groups or substituted phenyl groups which are in the side chains of the polymer are located alternately in opposite directions relative to the main chain of the polymer that consists of carbon-carbon bonds. The tacticity of the polymer is quantitatively determined through nuclear magnetic resonance thereof using a carbon isotope (.sup.13 C-NMR). The tacticity as determined through .sup.13 C-NMR can be represented by the proportions of the structural units as continuously connected to each other, for example, in terms of diad for two structural units, triad for three structural units and pentad for five structural units. The styrene-based polymer having a syndiotactic configuration as referred to herein includes, for example, polystyrene, poly(alkylstyrene), poly(halogenostyrene), poly(halogenoalkylstyrene), poly(alkoxystyrene), poly(vinyl benzoate), hydrogenated polymers of these, mixtures of these, and copolymers consisting essentially of these, which have generally 75% or more, preferably 85% or more of syndiotacticity of racemic diad, or have generally 30% or more, preferably 50% or more of syndiotacticity of racemic pentad. The poly(alkylstyrene) includes, for example, poly(methylstyrene), poly(ethylstyrene), poly(isopropylstyrene), poly(tert-butylstyrene), poly(phenylstyrene), poly(vinylnaphthalene), and poly(vinylstyrene). The poly(halogenostyrene) includes, for example, poly(chlorostyrene), poly(bromostyrene), and poly(fluorostyrene). The poly(halogenoalkylstyrene) includes, for example, poly(chloromethylstyrene). The poly(alkoxystyrene) includes, for example, poly(methoxystyrene), and poly(ethoxystyrene).
Of these styrene-based polymers, especially preferred are polystyrene, poly(p-methylstyrene), poly(m-methylstyrene), poly(p-tert-butylstyrene), poly(p-chlorostyrene), poly(m-chlorostyrene), poly(p-fluorostyrene), hydrogenated polystyrene, and copolymers comprising structural units of these.
The molecular weight of the styrene-based polymer for use in the present invention is not specifically defined. Preferably, however, the polymer has a weight average molecular weight of 10,000 or more, more preferably 50,000 or more. The molecular weight distribution of the polymers is not also defined. Various polymers having different molecular weights can be applied to the present invention. However, polymers having a weight average molecular weight of less than 10,000 are undesirable, since the thermal and mechanical properties of the composition, if comprising any of such polymers, and those of the articles to be formed from the composition often tend to be poor.
The styrene-based polymer having a syndiotactic configuration for use in the present invention can be obtained, for example, by polymerizing a styrenic monomer (capable of giving any of the above-mentioned styrene-based polymers) in the presence of a catalyst composed of titanium compound and a condensate to be produced from water and a trialkyl aluminium, in an inert hydrocarbon solvent or in the absence of such a solvent (see Japanese Patent Application Laid-Open No. 187708/1987). Poly(halogenoalkylstyrene)s capable of being employed in the present invention can be obtained, for example, according to the method described in Japanese Patent Application Laid-Open No. 46912/89; and hydrogenated polymers for use in the invention can be obtained, for example, according to the method described in Japanese Patent Application Laid-Open No. 178505/89.
The styrene-based polymers having a syndiotactic configuration, which shall constitute the component (a) of (A) in the composition of the present invention, can be used either singly or as combined.
The component (b) of (A) in the composition of the invention is a polyolefin, which may comprise monomer units to be derived from any of olefins and dienes such as ethylene, propylene, butylene, butene, octene, butadiene, isoprene, norbornene, norbornadiene, and cyclopentadiene. It includes any known polyolefins. Specific examples of the polyolefin are ethylene-propylene copolymer rubber (EPM), ethylene-propylene-diene copolymer rubber (EPDM), isotactic polypropylene, syndiotactic polypropylene, atactic polypropylene, block polypropylene, random polypropylene, high-density polyethylene, high-pressure-process, low-density polyethylene, linear, low-density polyethylene, cyclic polyolefins, and copolymers to be obtained from two or more monomers constituting these polymers. Of these, preferred are EPM, EPDM, polypropylene and polyethylene.
The polyolefins that shall constitute the component (b) can be used either singly or as combined.
In the composition of the present invention, the component (A) comprises from 10 to 98% by weight, preferably from 20 to 95% by weight, more preferably from 30 to 90% by weight of the above-mentioned component (a), and from 2 to 90% by weight, preferably from 5 to 80% by weight, more preferably from 10 to 70% by weight of the above-mentioned component (b). If the amount of the component (a) of (A) is less than the above-mentioned range, the composition will lose the characteristics of the syndiotactic polystyrene, and the modulus of elasticity and the heat resistance of the article to be formed from the composition will be noticeably lowered. If, on the other hand, it is more than the range, the toughness of the article could not be satisfactorily improved.
The composition of the present invention comprises from 0.5 to 50 parts by weight, relative to 100 parts by weight of the component (A), of the component (B) which is a styrene-olefin copolymer having a styrene content of from 40 to 85% by weight. The component (B) acts as a miscibility-improving agent for the components (a) and (b) that constitute the component (A). The block copolymer of the component (B) must have a styrene content of from 40 to 85% by weight. Preferably, the copolymer has a melt viscosity of 1200 Pa.multidot.sec or less at a temperature of 300.degree. C. and at a shearing rate of 100 sec.sup.-1.
If the styrene content of the copolymer is outside the defined range, the copolymer of the component (B) could not sufficiently function as a miscibility-improving agent for the components (a) and (b). If so, the toughness of the article to be formed from the composition is low, the peeling of the surface layer from the article could not be satisfactorily retarded, and therefore the objects of the present invention could not be attained satisfactorily. In view of its miscibility-improving function, the styrene content of the copolymer of the component (B) is preferably from 45 to 80% by weight, more preferably from 50 to 75% by weight. If, on the other hand, the melt viscosity of the copolymer (this is a parameter of the molecular weight of the copolymer) is more than 1200 Pa.multidot.sec, the copolymer could not sufficiently function as a miscibility-improving agent for the components (a) and (b) and, as a result, the objects of the present invention could not be attained.
The styrene-olefin copolymer of the component (B) includes, for example, styrene-butadiene random copolymer, hydrogenated styrene-butadiene random copolymer, styrene-isoprene random copolymer, hydrogenated styrene-isoprene random copolymer, styrene-butadiene block copolymer (SBR), hydrogenated styrene-butadiene block copolymer (SEB, SEBC), styrene-butadiene-styrene block copolymer (SBS), hydrogenated styrene-butadiene-styrene block copolymer (SEBS), styrene-isoprene block copolymer (SIR), hydrogenated styrene-isoprene block copolymer (SEP), styrene-isoprene-styrene block copolymer (SIS), hydrogenated styrene-isoprene-styrene block copolymer (SEPS), styrene-ethylene copolymer, styrene-propylene copolymer, ethylene-styrene graft copolymer, propylene-styrene graft copolymer, EPM-styrene graft copolymer, EPDM-styrene graft copolymer, and their modificates. Of these, preferred are styrene-olefin diblock copolymers and styrene-olefin triblock copolymers, which include, for example, styrene-butadiene block copolymer (SEB, SEBC), styrene-butadiene-styrene block copolymer (SBS), hydrogenated styrene-butadiene-styrene block copolymer (SEBS), styrene-isoprene block copolymer (SIR), hydrogenated styrene-isoprene block copolymer (SEP), styrene-isoprene-styrene block copolymer (SIS), hydrogenated styrene-isoprene-styrene block copolymer (SEPS) and their modificates.
The olefin moiety of the component (B) is preferably compatible with the component (b) of (A). The component (B) may comprise one or more such styrene-olefin copolymers.
The composition of the present invention shall comprise from 0.5 to 50 parts by weight, relative to 100 parts by weight of the component (A), of the component (B). If the content of the component (B) is less than 0.5 parts by weight, the miscibility-improving effect of the component (B) is insufficient. If so, therefore, the toughness of the article to be formed from the composition could not be improved satisfactorily and the peeling of the surface layer from the article could not be sufficiently retarded. However, even if the content is more than 50 parts by weight, any more improvement in the toughness of the article and in the retardation of the peeling of the surface layer from the article could not be expected. Therefore, if too much amount of the component (B) over the defined range is added to the composition of the invention, such is unfavorable since the cost of the composition is increased. In view of the toughness and other properties of the article to be formed from the composition and of the intended object of retarding the peeling of the surface layer from the article, the content of the component (B) is preferably from 1 to 40 parts by weight, more preferably from 3 to 30 parts by weight.
If desired, the resin composition of the present invention may optionally contain, as the third component (C), a polyphenylene ether. Polyphenylene ethers are known, for which, for example, referred to are U.S. Pat. Nos. 3,306,874, 3,306,875, 3,257,357 and 3,257,358. Concretely, homopolymers or copolymers of polyphenylene ethers for use in the present invention can be produced from one or more phenolic compounds as substituted at two or three positions thereof, through oxidative coupling in the presence of a copper-amine complex. The copper-amine complex to be used may be derived from primary, secondary and tertiary amines. Suitable examples of polyphenylene ethers for use in the present invention include poly(2,3-dimethyl-6-ethyl-1,4-phenylene ether); poly(2-methyl-6-chloromethyl-1,4-phenylene ether); poly(2-methyl-6-hydroxyethyl-1,4-phenylene ether); poly(2-methyl-6-n-butyl-1,4-phenylene ether); poly(2-ethyl-6-isopropyl-1,4-phenylene ether); poly(2-ethyl-6-n-propyl-1,4-phenylene ether); poly(2,3,6-trimethyl-1,4-phenylene ether); poly[2-(4'-methylphenyl)-1,4-phenylene ether]; poly(2-bromo-6-phenyl-1,4-phenylene ether); poly(2-methyl-6-phenyl-1,4-phenylene ether); poly(2-phenyl-1,4-phenylene ether); poly(2-chloro-1,4-phenylene ether); poly(2-methyl-1,4-phenylene ether); poly(2-chloro-6-ethyl-1,4-phenylene ether); poly(2-chloro-6-bromo-1,4-phenylene ether); poly(2,6-di-n-propyl-1,4-phenylene ether); poly(2-methyl-6-isopropyl-1,4-phenylene ether); poly(2-chloro-6-methyl-1,4-phenylene ether); poly(2-methyl-6-ethyl-1,4-phenylene ether); poly(2,6-dibromo-1,4-phenylene ether); poly(2,6-dichloro-1,4-phenylene ether); poly(2,6-diethyl-1,4-phenylene ether); and poly(2,6-dimethyl-1,4-phenylene ether). In addition to these homopolymers, also employable are copolymers to be derived from two or more phenolic compounds such as those to be used in producing the homopolymers. Moreover, also employable are graft copolymers and block copolymers composed of aromatic vinyl compounds such as polystyrene, and polyphenylene ethers such as those mentioned above. Of those, especially preferred is poly(2,6-dimethyl-1,4-phenylene ether).
In view of its effect of improving the impact resistance of the article to be formed from the composition of the invention, it is desirable that the polyphenylene ether of the component (C) has an intrinsic viscosity of 0.4 dl/g or more, preferably 0.5 dl/g or more, as measured in chloroform at 25.degree. C. The content of the component (C) in the composition of the invention shall be from 0.5 to 10 parts by weight, relative to 100 parts by weight of the component weight, the impact strength of the article to be formed from the composition could not be improved satisfactorily. However, if it is more than 10 parts by weight, the shapability or moldability of the composition will be worsened. Preferably, the content of the component (C) is from 1.0 to 5.0 parts by weight relative to 100 parts by weight of the component (a) of (A).
In order to further improve the toughness of the article to be formed from the resin composition of the invention, the composition may contain, if desired, a fourth component (D) of a styrene-olefin copolymer having a styrene content of from 5 to 35% by weight. The component (D) must be a styrene-olefin copolymer having high miscibility with or a strong affinity for the component (b) of (A). Therefore, the styrene content of the copolymer must be from 5 to 35% by weight. If its styrene content does not fall within the defined range, the copolymer would not be effective in improving the toughness of the article to be formed from the composition of the invention.
The styrene-olefin copolymer for the component (D) differs from that for the component (B) only in the styrene content. Therefore, for the copolymers for the component (D), those for the component (B) shall be referred to except for the styrene content. Of these, preferred for the component (D) are styrene-olefin diblock copolymers and styrene-olefin triblock copolymers. Concretely, preferred examples of the copolymers for the component (D) include styrene-butadiene block copolymer (SBR), hydrogenated styrene-butadiene block copolymer (SEB, SEBC), styrene-butadiene-styrene block copolymer (SBS), hydrogenated styrene-butadiene-styrene block copolymer (SEBS), styrene-isoprene block copolymer (SIR), hydrogenated styrene-isoprene block copolymer (SEP), styrene-isoprene-styrene block copolymer (SIS), hydrogenated styrene-isoprene-styrene block copolymer (SEPS), and their modificates.
The component (D) may comprise one or more such copolymers, either singly or as combined.
The composition of the present invention may comprise from 0 to 200 parts by weight, relative to 100 parts by weight of the component (b) of (A), of the component (D). Even if the content of the component (D) is more than 200 parts by weight, the toughness of the article to be formed from the composition could not be improved so much. Therefore, the addition of such a large amount of the component (D) to the composition is unfavorable in view of the cost of the composition. Preferably, the content of the component (D) in the composition is from 1 to 150 parts by weight, more preferably from 5 to 150 parts by weight.
In order to improve the fluidity of the resin composition of the invention and the toughness of the article to be formed from the composition, still another component (E) of a paraffinic oil, a paraffinic wax, a mineral oil or a siloxanic oil may be added to the composition, if desired. The component (E) must be highly miscible with or have a strong affinity for the component (b) of (A). If not, the toughness of the article to be formed from the composition of the invention could not be improved.
The component (E) of a paraffinic oil, a paraffinic wax, a mineral oil or a siloxanic oil includes, for example, polyethylenic oligomers, polyethylenic waxes, polyolefinic oligomers, polyolefinic waxes, heavy cycloparaffins, mineral oils, fatty acid esters, esters of aliphatic, dibasic acids, phthalates, aromatic carboxylates, phosphates, polydimethylsiloxanes, dimethylsiloxane-diphenylsiloxane copolymers, and polymethylphenylsiloxanes. Of these, preferred are polyethylenic oligomers, polyethylenic waxes, mineral oils, polydimethylsiloxanes, dimethylsiloxane-diphenylsiloxane copolymers, and polymethylphenylsiloxanes.
The component (E) may comprise one or more such compounds, either singly or as combined.
The composition of the present invention may comprise from 0 to 200 parts by weight, relative to 100 parts by weight of the component (b) of (A), of the component (E). Even if the content of the component (E) is more than 200 parts by weight, any further effect of the component (E) of improving the toughness of the article to be formed from the composition could not be expected, but rather the modulus of elasticity of the article would be unfavorably lowered. Preferably, the content of the component (E) is from 1 to 150 parts by weight, more preferably from 5 to 100 parts by weight.
If desired, the composition of the present invention may comprise both the component (D) and the component (E). The combination of the component (D) and the component (E) is preferred to the single use of either the component (D) or the component (E), since the former produces higher improvement in the toughness of the article to be formed from the composition of the invention. If desired, the component (D) and/or the component (E) may be previously mixed with the component (b) of (A).
In order to much more increase the modulus of elasticity and the heat resistance of the article to be formed from the resin composition of the invention, it is advantageous to incorporate still another component (F) of an inorganic filler into the composition. Various forms of inorganic fillers can be employed herein, including, for example, fibrous, granular and powdery ones. Fibrous fillers include, for example, glass fibers, carbon fibers and whiskers. The form or shape of the fibrous filler includes, for example, clothes, mats, bound and cut fibers, short fibers, filaments and whiskers. The bound and cut fibers preferably have a length of from 0.05 to 50 mm and a diameter of from 5 to 20 .mu.m.
Examples of granular or powdery fillers include talc, carbon black, graphite, titanium dioxide, silica, mica, calcium carbonate, calcium sulfate, barium carbonate, magnesium carbonate, magnesium sulfate, barium sulfate, hydroxysulfates, tin hydroxide, alumina, kaolin, silicon carbide, metal powders, glass powder, glass flakes, and glass beads. Of these, preferred are glass fillers, such as glass powder, glass flakes, glass beads, glass filaments, glass fibers, glass rovings, and glass mats.
It is desirable that the inorganic filler is surface-treated. For the surface treatment, used is a coupling agent, by which the adhesiveness of the filler to resins is improved. The coupling agent can be selected from any known silane coupling agents, titanium coupling agents and others. Above all, especially preferably used are aminosilanes and epoxysilanes such as .gamma.-aminopropyltrimethoxysilane, N-.beta.-(aminoethyl)-.gamma.-aminopropyltrimethoxysilane, .gamma.-glycidoxypropyltrimethoxysilane, and .beta.-(3,4-epoxycyclohexyl)ethyltrimethoxysilane; and also isopropyl tri(N-amidoethyl, aminoethyl)titanate.
The means of surface-treating the filler with any of such coupling agents is not specifically defined, and any known methods can be employed for the surface treatment. For example, employable are a sizing method where a solution or suspension of a coupling agent is applied to a filler as a so-called sizing agent, and also a dry-mixing method, a spraying method, an integral-blending method and a dry-concentrating method where a Henschel mixer, a super mixer, a V-shaped mixer or the like is used. Any of these methods may be selected, depending on the shape of the filler to be surface-treated. Of these, preferably employed are a sizing method, a dry-mixing method and a spraying method.
The coupling agent can be combined with a film-forming substance for glass. The film-forming substance to be combined is not specifically defined but includes, for example, polyester-type, polyether-type, urethane-type, epoxy-type, acryl-type and vinyl acetate-type polymers.
One or more inorganic fillers can be used for the component (F), either singly or as combined. The content of the component (F) to be in the composition of the present invention shall be from 0.5 to 350 parts by weight relative to 100 parts by weight of 1 the resin component comprising the component (A) and the component (B), 2 the resin component comprising the component (A), the component (B) and the component (C), 3 the resin component comprising the component (A), the component (B), the component (C) and the component (D), 4 the resin component comprising the component (A), the component (B), the component (C) and the component (E), 5 the resin component comprising the component (A), the component (B), the component (C), the component (D) and the component (E), 6 the resin component comprising the component (A), the component (B) and the component (D), 7 the resin component comprising the component (A), the component (B) and the component (E), or 8 the resin component comprising the component (A), the component (B), the component (D) and the component (E). If the content is less than 0.5 parts by weight, the effect of the filler could not be attained. However, if it is more than 350 parts by weight, the dispersibility of the filler in the composition is worsened so that the composition is disadvantageously difficult to shape or mold. Preferably, the content of the inorganic filler is from 5 to 200 parts by weight, more preferably from 10 to 150 parts by weight.
In order to improve the adhesiveness of the inorganic filler to the resin components constituting the composition of the present invention, it is desirable to add, along with the inorganic filler for the component (F), still another component (G) of a polymer which is miscible with or has an affinity for the styrene-based polymer having a syndiotactic configuration for the component (a) of (A) and which has a polar group, to the composition.
The polymer which is miscible with or has an affinity for the component (a) of (A), as referred to herein, is a polymer having therein a polymeric chain that is miscible with or has an affinity for the component (a) of (A). The polymer of this type includes, for example, polymers having, in the main chain, the block chain or the graft chain, any of syndiotactic polystyrene, atactic polystyrene, isotactic polystyrene, styrenic copolymer, polyphenylene ether, polyvinyl methyl ether and the like. The polar group which the polymer shall have is not specifically defined, and may be any and every group capable of improving the adhesiveness of the inorganic filler for the component (F) to the resin components constituting the composition of the invention. Examples of the polar group include residues of acid anhydrides, carboxylic acids, carboxylates, carboxylic acid chlorides, carboxylic acid amides, salts of carboxylic acids, sulfonic acids, sulfonates, sulfonic acid chlorides, sulfonic acid amides, or salts of sulfonic acids; and also epoxy groups, amino groups, imido groups and oxazoline groups.
Specific examples of the component (G) include styrene-maleic anhydride copolymer (SMA), styrene-glycidyl methacrylate copolymer, terminal carboxylic acid-modified polystyrene, terminal epoxy-modified polystyrene, terminal oxazoline-modified polystyrene, terminal amino-modified polystyrene, sulfonated polystyrene, styrene-based ionomer, styrene-methyl methacrylate graft polymer, (styrene-glycidyl methacrylate)-methyl methacrylate graft polymer, acid-modified acryl-styrene graft polymer, (styrene-glycidyl methacrylate)-styrene graft polymer, polybutylene terephthalate-polystyrene graft polymer; as well as modified, styrene-based polymers such as maleic anhydride-modified syndiotactic polystyrene, fumaric acid-modified syndiotactic polystyrene, glycidyl methacrylate-modified syndiotactic polystyrene, and amine-modified syndiotactic polystyrene; and also modified polyphenylene ether-based polymers such as (styrene-maleic anhydride)-polyphenylene ether graft polymer, maleic anhydride-modified polyphenylene ether, fumaric acid-modified polyphenylene ether, glycidyl methacrylate-modified polyphenylene ether, and amine-modified polyphenylene ether. Of these, especially preferred are modified syndiotactic polystyrenes and modified polyphenylene ethers. These can be used either singly or as combined.
The polar group content of the polymer is preferably from 0.01 to 20% by weight, more preferably from 0.05 to 10% by weight. If the content is less than 0.01% by weight, a large amount of the polymer for the component (G) must be added to the composition in order to attain the intended adhesiveness of the inorganic filler to the resin components constituting the composition. Such is unfavorable, since the mechanical properties, the heat resistance and the shapability of the composition are often lowered. If, on the other hand, the content is more than 20% by weight, the miscibility of the polymer with the component (a) of (A) would be lowered and such is also unfavorable.
Modified syndiotactic polystyrenes are preferably used for the component (G), which are referred to below. SPS to be modified is not specifically defined. Any of the polymers as referred to for the component (a) of (A) can be used to obtain modified polymers. In view of the miscibility of the modified polymers with the component (a) of (A), preferably used are styrene homopolymers or styrene-substituted styrene copolymers. For the latter copolymers, the compositional proportions of the constitutive monomers are not specifically defined. However, the content of the substituted styrene units in the copolymers is preferably 50 mol % or less. If it is more than 50 mol %, the miscibility of the modified copolymers with the component (a) of (A) would be lowered and such is unfavorable. The substituted styrene includes, for example, alkylstyrenes such as methylstyrene, ethylstyrene, isopropylstyrene, tert-butylstyrene, and vinylstyrene; halogenostyrenes such as chlorostyrene, bromostyrene, and fluorostyrene; halogenoalkylstyrenes such as chloromethylstyrene; and alkoxystyrenes such as methoxystyrene, and ethoxystyrene. These substituted styrenes can be used either singly or as combined.
As the modifying agent to be used for modifying SPS such as that mentioned hereinabove, employable is a compound having both an ethylenic double bond and a polar group in one molecule. The compound includes, for example, maleic acids such as maleic anhydride, maleic acid, maleates, maleimide and its N-substituted derivatives, and salts of maleic acid; fumaric acids such as fumaric acid, fumarates, and salts of fumaric acid; itaconic acids such as itaconic anhydride, itaconic acid, itaconates, and salts of itaconic acid; acrylic acids such as acrylic acid, acrylates, acrylic acid amides, and salts of acrylic acid; and methacrylic acids such as methacrylic acid, methacrylates, methacrylic acid amides, salts of methacrylic acid, and glycidyl methacrylate. Of these, especially preferred are maleic anhydride, fumaric acid, fumarates and glycidyl methacrylate. The modifying agent can comprise one or more such compounds either singly or as combined.
To obtain modified SPS, for example, SPS such as that mentioned above is reacted with a modifying agent such as that mentioned above, in the presence or absence of a solvent or any other resin. The modification is not specifically defined but can be conducted in accordance with any known methods. For example, employable are a method of melting, kneading and reacting the components at a temperature falling between 150.degree. C. and 350.degree. C., using, for example, a roll mill, a Bambury mixer or an extruder, and a method of reacting the components under heat in a solvent such as benzene, toluene or xylene. In order to promote the reaction, it is effective to add to the reaction system, a radical-generating agent such as benzoyl peroxide, di-t-butyl peroxide, dicumyl peroxide, t-butyl peroxybenzoate, azobisisobutyronitrile, azobisisovaleronitrile, or 2,3-diphenyl-2,3-dimethylbutane. One preferred method for the modification is to melt and knead the component in the presence of such a radical-generating agent. During the modification, if desired, any other resin can be added to the reaction system.
Of the modified SPS thus obtained, especially preferred are maleic anhydride-modified SPS, fumaric acid-modified SPS and fumarate-modified SPS.
Modified polyphenylene ethers are also preferably used for the component (G), which can be obtained by modifying known polyphenylene ethers with a modifying agent. The polyphenylene ethers to be modified are not specifically defined, and any of the polymers as referred to hereinabove for the component (C) can be used. Above all, preferred is poly(2,6-dimethyl-1,4-phenylene ether).
The modifying agents usable for the modification of polyphenylene ethers may be the same as those referred to hereinabove for the modification of SPS. In particular, preferably used are maleic anhydride, fumaric acid, fumarates and glycidyl methacrylate. One or more such modifying agents can be used either singly or as combined. The modification of polyphenylene ethers can be conducted in the same manner as that mentioned hereinabove for the modification of SPS.
Of the modified polyphenylene ethers thus obtained, especially preferred are maleic anhydride-modified polyphenylene ether, fumaric acid-modified polyphenylene ether, and fumarate-modified polyphenylene ether.
The composition of the present invention may comprise one or more polymers having a polar group for the component (G), either singly or as combined. The content of the component (G) to be in the composition shall be from 0.1 to 10 parts by weight relative to 100 parts by weight of 1 the resin component comprising the component (A) and the component (B), 2 the resin component comprising the component (A), the component (B) and the component (C), 3 the resin component comprising the component (A), the component (B), the component (C) and the component (D), 4 the resin component comprising the component (A), the component (B), the component (C) and the component (E), 5 the resin component comprising the component (A), the component (B), the component (C), the component (D) and the component (E), 6 the resin component comprising the component (A), the component (B) and the component (D), 7 the resin component comprising the component (A), the component (B) and the component (E), or 8 the resin component comprising the component (A), the component (B), the component (D) and the component (E). If the content is less than 0.1 parts by weight, the adhesiveness of the inorganic filler to the resin components could not be satisfactorily improved. However, if it is more than 10 parts by weight, the heat resistance and the shapability of the composition would be lowered. In view of the adhesiveness of the inorganic filler to the resin components and of the heat resistance and the shapability of the composition, the content of the component (G) in the composition is preferably from 0.5 to 8 parts by weight, more preferably from 1 to 5 parts by weight.
The resin composition of the present invention may optionally contain, if desired, any known additives, such as a nucleating agent, an antioxidant, a plasticizer, a flame retardant, a flame retardant aid, a release agent, a pigment, carbon black, an antistatic agent, and other rubber components and thermoplastic resins, provided that such additives do not detract from the objects of the present invention.
The nucleating agent includes, for example, metal salts of carboxylic acids, such as aluminium di(p-tert-butylbenzoate); metal salts of phosphoric acid such as sodium methylenebis(2,4-di-t-butylphenol) acid phosphate; and also talc and phthalocyanine derivatives. The antioxidant can be selected from any known phosphorus-containing, phenolic, or sulfur-containing antioxidants. The plasticizer can be selected from any known ones, including, for example, polyethylene glycol, polyamide oligomers, ethylenebis-stearoamide, and polyethylene oligomers.
The flame retardant can be selected from any known ones, including, for example, brominated polymers such as brominated polystyrenes, brominated syndiotactic polystyrenes, and brominated polyphenylene ethers; and brominated aromatic compounds such as brominated diphenylalkanes, and brominated diphenyl ethers. The flame retardant aid can be selected from any known ones, including, for example, antimony compounds such as antimony trioxide. The release agent can be selected from any known ones, including, for example, polyethylene waxes, silicone oils, long-chain carboxylic acids, and metal salts of long-chain carboxylic acids. One or more such additives can be used either singly or as combined.
Specific examples of rubber-like elastic materials which can be added to the composition of the present invention include natural rubber, polybutadiene, polyisoprene, polyisobutylene, neoprene, polysulfide rubber, Thiokol rubber, acrylic rubber, urethane rubber, silicone rubber, epichlorohydrin rubber, and also core/shell type, granular, elastic rubber substances, such as butadiene-acrylonitrile-styrene core/shell rubber (ABS), methyl methacrylate-butadiene-styrene core/shell rubber (MBS), methyl methacrylate-butyl acrylate-styrene core/shell rubber (MAS), octyl acrylate-butadiene-styrene core/shell rubber (MABS), alkyl acrylate-butadiene-acrylonitrile-styrene core/shell rubber (AABS), butadiene-styrene core/shell rubber (SBR), methyl methacrylate-butyl acrylate-siloxane and other siloxane-containing core/shell rubbers, as well as modificates to be obtained by modifying these rubbers. One or more such rubber-like elastic materials can be used either singly or as combined.
Any known thermoplastic resins, for example, as selected from polystyrene resins such as polystyrene, HIPS, ABS, and AS; polyester resins such as polycarbonates, polyarylates, polyethylene terephthalate, and polybutylene terephthalate; polyamide resins such as polyamide 6, polyamide 66, polyamide 46, polyamide 12, and aromatic polyamides; and PPS, can be added to the composition of the present invention. One or more such thermoplastic resins can be used either singly or as combined.
The method for preparing the resin composition of the present invention is not specifically defined. The composition can be prepared by any known methods. For example, the components (a) and (b) of (A), the component (B) and optionally the component (C), the component (D), the component (E), the component (F), the component (G) and other various additives are melted and kneaded, using a ribbon blender, a Henschel mixer, a Bambury mixer, a drum tumbler, a single-screw extruder, a twin-screw extruder, a co-kneader, a multi-screw extruder or the like mixing device, to obtain a resin composition of the present invention.
The resin composition of the present invention can be shaped into articles having excellent physical properties, and the method for shaping it is not defined. For example, the composition can be shaped into various articles through injection molding, into sheets or films through extrusion molding, into containers or trays through extrusion molding combined with thermal molding, into monoaxially or biaxially stretched films or sheets through extrusion molding combined with stretching, or into fibrous articles through spinning.

The present invention is described in more detail hereinunder with reference to the following examples, which, however, are not intended to restrict the scope of the invention. The physical properties of the samples as obtained in the following examples were determined according to the methods mentioned below.
(1) Izod impact strength (with notch):
This was obtained in accordance with JIS K-7110.
(2) Tensile elongation:
This was obtained in accordance with JIS K-7113.
(3) Surface layer peeling resistance:
Each sample was visually observed and ranked in three, as follows:
A: Very good
B: Good
C: Not good
PRODUCTION EXAMPLE 1
Production of SPS
1.0 liter of pure styrene and 1 mmol of triethyl aluminium were put into a 2-liter reactor and heated at 80.degree. C. Next, 16.5 ml of a pre-mixed catalyst (comprising 90 .mu.mols of pentamethylcyclopentadienyl titanium trimethoxide, 90 .mu.mols of dimethylanilinium tetrakis(pentafluorophenyl)borate, 29.1 mmols of toluene and 1.8 mmols of triisobutyl aluminium) was added thereto, and the monomer was polymerized at 80.degree. C. for 5 hours. After the polymerization, the product was washed plural times with methanol and dried. Thus was obtained 380 g of a polymer.
The weight average molecular weight of the polymer was measured through gel permeation chromatography at 130.degree. C. using a solvent of 1,2,4-trichlorobenzene, to be 300,000. The ratio of weight average molecular weight/number average molecular weight of the polymer was 2.70. It was confirmed that the polymer obtained herein is SPS from the results of the measurement of its melting point and the .sup.13 C-NMR analysis thereof.
PRODUCTION EXAMPLE 2
Production of Maleic Anhydride-Modified SPS
One kg of SPS as produced in Production Example 1, 30 g of maleic anhydride and 10 g of a radical-generating agent of cumene hydroxyperoxide were dry-blended, then melted and kneaded through a 30-mm twin-screw extruder at a screw revolution of 200 rpm and at a temperature of 300.degree. C. The strands thus extruded out were cooled and then pelletized to obtain pellets of a maleic anhydride-modified SPS.
To measure the degree of modification of the product, one g of the modified SPS was dissolved in ethylbenzene, then re-precipitated in methanol and collected. The thus-collected polymer was subjected to Soxhlet extraction using methanol and then dried. The degree of modification of the polymer was obtained from the intensity of the carbonyl absorption in its IR spectrum and from its titration, to be 1.04% by weight.
PRODUCTION EXAMPLE 3
Production of Fumaric Acid-Modified Polyphenylene Ether
One kg of polyphenylene ether (having an intrinsic viscosity of 0.45 dl/g in chloroform at 25.degree. C.), 30 g of fumaric acid and 20 g of a radical-generating agent of 2,3-dimethyl-2,3-diphenylbutane (produced by Nippon Oils & Fats Co., Ltd. under the trade name of "Nofmer BC") were dry-blended, then melted and extruded through a 30-mm twin-screw extruder at a screw revolution of 200 rpm and at a temperature of 300.degree. C. The temperature of the resin being extruded was about 330.degree. C. The strands thus extruded out were cooled and then pelletized to obtain pellets of a fumaric acid-modified polyphenylene ether. To measure the degree of modification of the product, one g of the modified polyphenylene ether was dissolved in ethylbenzene, then reprecipitated in methanol and collected. The thus-collected polymer was subjected to Soxhlet extraction using methanol and then dried. The degree of modification of the polymer was obtained from the intensity of the carbonyl absorption in its IR spectrum and from its titration, to be 1.6% by weight.
EXAMPLE 1
50 parts by weight of the syndiotactic polystyrene as prepared in Production Example 1 (having a weight average molecular weight of 300,000 and a ratio of weight average molecular weight/number average molecular weight of 2.70) (this corresponds to the component (a) of (A)), 50 parts by weight of EPM (produced by Japan Synthetic Rubber Co., Ltd. under the trade name of "EP-07P") (this corresponds to the component (b) of (A)), and, relative to 100 parts by weight of the sum of these two, 30 parts by weight of SEBS (produced by Asahi Chemical Industry Co., Ltd. under the trade name of "Tuftec H-1081") (this corresponds to the component (B)), 0.5 parts by weight of a nucleating agent of sodium methylenebis(2,4-di-t-butylphenol) acid phosphate (produced by Asahi Denka Co., Ltd. under the trade name of "NA-11"), 0.1 parts by weight of an antioxidant of (2,6-di-t-butyl-4-methylphenyl)pentaerythritol diphosphite (produced by Asahi Denka Co., Ltd. under the trade name of "PEP-36"), and 0.1 parts by weight of tetrakis(methylene-3-(3',5'-di-t-butyl-4'-hydroxyphenyl)) propionate (produced by Adeka Argus Co., Ltd. under the trade name of "MARK AO 60") were dry-blended in a Henschel mixer, then melted, kneaded and pelletized through a twin-screw extruder. The pellets thus obtained were molded through injection molding to obtain test pieces for an Izod impact test and a tensile elongation test. These test pieces were tested to measure their Izod impact strength and tensile elongation. The results obtained are shown in Table 1 below.
EXAMPLES 2 to 43, COMPARATIVE EXAMPLES 1 to 30
The same process as in Example 1 was repeated except that the components (a) of (A), (b) of (A), (B), (C), (D) and (E) as shown in Table 1 below were used herein. The results obtained are shown in Table 1.
As is known from Table 1, the samples comprising the component (B) having a higher styrene content had much more increased impact strength and elongation than those comprising the component (B) having a lower styrene content. It is also known therefrom that the samples containing the component (C), the component (D) and the component (E) had more increased impact strength and elongation than those not containing them.
EXAMPLE 44
50 parts by weight of the syndiotactic polystyrene as prepared in Production Example 1 (having a weight average molecular weight of 300,000 and a ratio of weight average molecular weight/number average molecular weight of 2.70) (this corresponds to the component (a) of (A)), 50 parts by weight of EPM (produced by Japan Synthetic Rubber Co., Ltd. under the trade name of "EP-07P") (this corresponds to the component (b) of (A)), and, relative to 100 parts by weight of the sum of these two, 30 parts by weight of SEBS (produced by Asahi Chemical Industry Co., Ltd. under the trade name of "Tuftec H-1081") (this corresponds to the component (B)), 0.5 parts by weight of a nucleating agent of sodium methylenebis(2,4-di-t-butylphenol) acid phosphate (produced by Asahi Denka Co., Ltd. under the trade name of "NA-11"), 0.1 parts by weight of an antioxidant of (2,6-di-t-butyl-4-methylphenyl)pentaerythritol diphosphite (produced by Asahi Denka Co., Ltd. under the trade name of "PEP-36"), and 0.1 parts by weight of tetrakis(methylene-3-(3',5'-di-t-butyl-4'-hydroxyphenyl)) propionate (produced by Adeka Argus Co., Ltd. under the trade name of "MARK AO 60") were dry-blended in a Henschel mixer, then melted, kneaded and pelletized through a twin-screw extruder while adding thereto 55.7 parts by weight of glass fibers (produced by Asahi Fiber Glass Co., Ltd. under the trade name of "FT-712" -10 .mu.m/3 mm) (this corresponds to the component (F)).
The pellets thus obtained were molded through injection molding to obtain test pieces for an Izod impact test and a tensile elongation test. These test pieces were tested to measure their Izod impact strength and tensile elongation. The results obtained are shown in Table 2 below.
EXAMPLES 45 to 96, COMPARATIVE EXAMPLES 3 to 70
The same process as in Example 44 was repeated except that the components (a) of (A), (b) of (A), (B), (C), (D), (E), (F) and (G) as shown in Table 2 below were used herein. The results obtained are shown in Table 2.
As is known from Table 2 where all the samples tested contained the inorganic filler of the component (F), the samples comprising the component (B) having a higher styrene content had much more increased impact strength and elongation than those comprising the component (B) having a lower styrene content. It is also known therefrom that the samples containing the component (C), the component (D), the component (E) and the component (G) had more increased impact strength and elongation than those not containing them.
As has been described hereinabove, the impact-resistant, polystyrenic resin composition of the present invention has good shapability and can be formed into articles having high heat resistance, high impact strength, high tensile elongation, and a high modulus of elasticity. Without being limited by the means of shaping it, the composition of the present invention can be shaped into articles having such good physical properties. For example, the impact-resistant, polystyrenic resin composition of the present invention can be molded into various articles through injection molding, into sheets and films through extrusion molding, into containers or trays through extrusion molding combined with thermal molding, into monoaxially or biaxially stretched films or sheets through extrusion molding combined with stretching, or into fibrous articles through spinning.
TABLE 1-1__________________________________________________________________________Composition(a) of ASPSProduct (b) of A BObtained in Polyolefin Miscibility-Improving AgentExample and Production Amount Styrene AmountComparative Example 1 Added Content AddedExample wt. pts. Compound Grade wt. pts. Compound Grade wt. % wt. pts.__________________________________________________________________________Example 1 50 EPM EP07P 50 SEBS H1081 60 30Example 2 80 EPM EP07P 20 SEBS H1081 60 20Example 3 80 EPM EP07P 20 SEBS H1081 60 10Example 4 80 EPM EP07P 20 SEBS H1081 60 5Example 5 80 EPM EP07P 20 SEBS H1081 60 5Example 6 82 EPM EP07P 18 SEBS H1081 60 5Example 7 89 EPM EP07P 11 SEBS H1081 60 5Example 8 82 EPM EP07P 18 SEBS H1081 60 5Example 9 89 EPM EP07P 11 SEBS H1081 60 5Example 10 82 EPM EP07P 18 SEBS H1081 60 5Example 11 89 EPM EP07P 11 SEBS H1081 60 5Example 12 83 EPM EP07P 17 SEBS H1081 60 5Example 13 83 EPM EP07P 17 SEBS H1081 60 5Example 14 80 EPM EP07P 20 SEPS Septon 2104 65 5Example 15 80 EPM EP07P 20 SEBC HSB576 45 5Comparative 50 EPM EP07P 50 SEBS H1041 30 30Example 1Comparative 80 EPM EP07P 20 SEBS H1041 30 20Example 2Comparative 80 EPM EP07P 20 SEBS H1041 30 10Example 3__________________________________________________________________________
TABLE 1-2__________________________________________________________________________Composition DC Styrene-Olefin EPPE Copolymer with Low Styrene Content Oil, WaxExample and 0.55 dl/g, Styrene Amount AmountComparative CHCl.sub.3, 25.degree. C. Content Added AddedExample wt. pts. Compound Grade wt. % wt. pts. Compound Grade wt. pts.__________________________________________________________________________Example 1 0 -- -- -- 0 -- -- 0Example 2 0 -- -- -- 0 -- -- 0Example 3 0 -- -- -- 0 -- -- 0Example 4 0 -- -- -- 0 -- -- 0Example 5 4 -- -- -- 0 -- -- 0Example 6 4 SEBS Septon 8006 30 2 -- -- 0Example 7 4 SEBS Septon 8006 30 10 -- -- 0Example 8 4 -- -- -- 0 paraffin oil PW380 2Example 9 4 -- -- -- 0 paraffin oil PW380 10Example 10 4 -- -- -- 0 silicone oil SH200 2Example 11 4 -- -- -- 0 silicone oil SH200 10Example 12 4 SEBS Septon 8006 30 2 paraffin oil PW380 2Example 13 4 SEBS Septon 8006 30 2 silicone oil SH200 2Example 14 0 -- -- -- 0 -- -- 0Example 15 0 -- -- -- 0 -- -- 0Comparative 0 -- -- -- 0 -- -- 0Example 1Comparative 0 -- -- -- 0 -- -- 0Example 2Comparative 0 -- -- -- 0 -- -- 0Example 3__________________________________________________________________________
TABLE 1-3__________________________________________________________________________Composition Physical PropertiesF Peeling ResistanceInorganic Filler G Physical Properties Resistance to PeelingGF Polar Group- Izod Impact of Surface LayerAsahi Fiber's Containing Polymer Strength Tensile Visual ObservationExample and F1712 Amount (with notches) Elongation A: Very GoodComparative 10 .mu.m .times. 3 mm Added According to JIS According to B: GoodExample wt. pts. Compound wt. pts. K-7110 kJ/m.sup.2 JIS K-7113 % C: Not Good__________________________________________________________________________Example 1 0 -- 0 22.1 25.9 AExample 2 0 -- 0 13.6 19.4 AExample 3 0 -- 0 10.8 16.8 AExample 4 0 -- 0 9.0 12.0 AExample 5 0 -- 0 11.0 16.0 AExample 6 0 -- 0 12.7 18.2 AExample 7 0 -- 0 15.8 23.4 AExample 8 0 -- 0 13.0 20.6 AExample 9 0 -- 0 15.1 25.5 AExample 10 0 -- 0 12.8 20.0 AExample 11 0 -- 0 15.3 24.9 AExample 12 0 -- 0 16.1 26.3 AExample 13 0 -- 0 15.9 26.8 AExample 14 0 -- 0 9.4 12.1 AExample 15 0 -- 0 8.9 10.9 BComparative 0 -- 0 7.1 9.8 CExample 1Comparative 0 -- 0 3.3 3.4 CExample 2Comparative 0 -- 0 2.4 2.5 CExample 3__________________________________________________________________________
TABLE 1-4__________________________________________________________________________Composition(a) of ASPSProduct (b) of A BObtained in Polyolefin Miscibility-Improving AgentExample and Production Amount Styrene AmountComparative Example 1 Added Content AddedExample wt. pts. Compound Grade wt. pts. Compound Grade wt. % wt. pts.__________________________________________________________________________Comparative 80 EPM EP07P 20 SEBS H1041 30 5Example 4Comparative 80 EPM EP07P 20 SEBS H1041 30 5Example 5Comparative 80 EPM EP07P 20 SEPS Septon 2002 30 5Example 6Example 16 50 EPDM EP181SP 50 SEBS H1081 60 30Example 17 80 EPDM EP181SP 20 SEBS H1081 60 20Example 18 80 EPDM EP181SP 20 SEBS H1081 60 10Example 19 80 EPDM EP181SP 20 SEBS H1081 60 5Example 20 80 EPDM EP181SP 20 SEBS H1081 60 5Example 21 80 EPDM EP181SP 20 SEPS Septon 2002 65 5Example 22 80 EPDM EP181SP 20 SEBC HSB576 45 5Comparative 50 EPDM EP181SP 50 SEBS H1041 30 30Example 7Comparative 80 EPDM EP181SP 20 SEBS H1041 30 20Example 8Comparative 80 EPDM EP181SP 20 SEBS H1041 30 10Example 9Comparative 80 EPDM EP181SP 20 SEBS H1041 30 5Example 10Comparative 80 EPDM EP181SP 20 SEBS H1041 30 5Example 11Comparative 80 EPDM EP181SP 20 SEPS Septon 2002 30 5Example 12Example 23 50 b-PP E185G 50 SEBS H1081 60 30Example 24 80 b-PP E185G 20 SEBS H1081 60 20__________________________________________________________________________
TABLE 1-5__________________________________________________________________________Composition DC Styrene-Olefin EPPE Copolymer with Low Styrene Content Oil, WaxExample and 0.55 dl/g, Styrene Amount AmountComparative CHCl.sub.3, 25.degree. C. Content Added AddedExample wt. pts. Compound Grade wt. % wt. pts. Compound Grade wt. pts.__________________________________________________________________________Comparative 0 -- -- -- 0 -- -- 0Example 4Comparative 4 -- -- -- 0 -- -- 0Example 5Comparative 0 -- -- -- 0 -- -- 0Example 6Example 16 0 -- -- -- 0 -- -- 0Example 17 0 -- -- -- 0 -- -- 0Example 18 0 -- -- -- 0 -- -- 0Example 19 0 -- -- -- 0 -- -- 0Example 20 4 -- -- -- 0 -- -- 0Example 21 0 -- -- -- 0 -- -- 0Example 22 0 -- -- -- 0 -- -- 0Comparative 0 -- -- -- 0 -- -- 0Example 7Comparative 0 -- -- -- 0 -- -- 0Example 8Comparative 0 -- -- -- 0 -- -- 0Example 9Comparative 0 -- -- -- 0 -- -- 0Example 10Comparative 4 -- -- -- 0 -- -- 0Example 11Comparative 0 -- -- -- 0 -- -- 0Example 12Example 23 0 -- -- -- 0 -- -- 0Example 24 0 -- -- -- 0 -- -- 0__________________________________________________________________________
TABLE 1-6__________________________________________________________________________Composition Physical PropertiesF Peeling ResistanceInorganic Filler G Physical Properties Resistance to PeelingGF Polar Group- Izod Impact of Surface LayerAsahi Fiber's Containing Polymer Strength Tensile Visual ObservationExample and F1712 Amount (with notches) Elongation A: Very GoodComparative 10 .mu.m .times. 3 mm Added According to JIS According to B: GoodExample wt. pts. Compound wt. pts. K-7110 kJ/m.sup.2 JIS K-7113 % C: Not Good__________________________________________________________________________Comparative 0 -- 0 1.9 1.5 CExample 4Comparative 0 -- 0 2.3 1.9 CExample 5Comparative 0 -- 0 1.9 1.8 CExample 6Example 16 0 -- 0 25.5 27.1 AExample 17 0 -- 0 14.2 20.3 AExample 18 0 -- 0 11.5 17.8 AExample 19 0 -- 0 9.1 13.3 AExample 20 0 -- 0 12.0 17.0 AExample 21 0 -- 0 8.8 13.0 AExample 22 0 -- 0 8.5 11.9 BComparative 0 -- 0 7.5 9.4 CExample 7Comparative 0 -- 0 3.2 3.6 CExample 8Comparative 0 -- 0 2.6 2.3 CExample 9Comparative 0 -- 0 2.2 1.8 CExample 10Comparative 0 -- 0 2.4 2.2 CExample 11Comparative 0 -- 0 1.9 2.0 CExample 12Example 23 0 -- 0 16.0 16.1 AExample 24 0 -- 0 8.0 11.0 A__________________________________________________________________________
TABLE 1-7__________________________________________________________________________Composition(a) of ASPSProduct (b) of A BObtained in Polyolefin Miscibility-Improving AgentExample and Production Amount Styrene AmountComparative Example 1 Added Content AddedExample wt. pts. Compound Grade wt. pts. Compound Grade wt. % wt. pts.__________________________________________________________________________Example 25 80 b-PP E185G 20 SEBS H1081 60 10Example 26 80 b-PP E185G 20 SEBS H1081 60 5Example 27 80 b-PP E185G 20 SEBS H1081 60 5Example 28 80 b-PP E185G 20 SEPS Septon 2104 65 5Example 29 80 b-PP E185G 20 SEBC HBS576 45 5Comparative 50 b-PP E185G 50 SEPS H1041 30 30Example 13Comparative 80 b-PP E185G 20 SEBS H1041 30 20Example 14Comparative 80 b-PP E185G 20 SEBS H1041 30 10Example 15Comparative 80 b-PP E185G 20 SEBS H1041 30 5Example 16Comparative 80 b-PP E185G 20 SEBS H1041 30 5Example 17Comparative 80 b-PP E185G 20 SEPS Septon 2002 30 5Example 18Example 30 50 LLDPE LO134N 50 SEBS H1081 60 30Example 31 80 LLDPE LO134N 20 SEBS H1081 60 20Example 32 80 LLDPE LO134N 20 SEBS H1081 60 10Example 33 80 LLDPE LO134N 20 SEBS H1081 60 5Example 34 80 LLDPE LO134N 20 SEBS H1081 60 5Example 35 80 LLDPE LOl34N 20 SEPS Septon 2104 65 5Example 36 80 LLDPE LO134N 20 SEBC HSB576 45 5__________________________________________________________________________
TABLE 1-8__________________________________________________________________________Composition DC Styrene-Olefin EPPE Copolymer with Low Styrene Content Oil, WaxExample and 0.55 dl/g, Styrene Amount AmountComparative CHCl.sub.3, 25.degree. C. Content Added AddedExample wt. pts. Compound Grade wt. % wt. pts. Compound Grade wt. pts.__________________________________________________________________________Example 25 0 -- -- -- 0 -- -- 0Example 26 0 -- -- -- 0 -- -- 0Example 27 4 -- -- -- 0 -- -- 0Example 28 0 -- -- -- 0 -- -- 0Example 29 0 -- -- -- 0 -- -- 0Comparative 0 -- -- -- 0 -- -- 0Example 13Comparative 0 -- -- -- 0 -- -- 0Example 14Comparative 0 -- -- -- 0 -- -- 0Example 15Comparative 0 -- -- -- 0 -- -- 0Example 16Comparative 4 -- -- -- 0 -- -- 0Example 17Comparative 0 -- -- -- 0 -- -- 0Example 18Example 30 0 -- -- -- 0 -- -- 0Example 31 0 -- -- -- 0 -- -- 0Example 32 0 -- -- -- 0 -- -- 0Example 33 0 -- -- -- 0 -- -- 0Example 34 4 -- -- -- 0 -- -- 0Example 35 0 -- -- -- 0 -- -- 0Example 36 0 -- -- -- 0 -- -- 0__________________________________________________________________________
TABLE 1-9__________________________________________________________________________Composition Physical PropertiesF Peeling ResistanceInorganic Filler G Physical Properties Resistance to PeelingGF Polar Group- Izod Impact of Surface LayerAsahi Fiber's Containing Polymer Strength Tensile Visual ObservationExample and F1712 Amount (with notches) Elongation A: Very GoodComparative 10 .mu.m .times. 3 mm Added According to JIS According to B: GoodExample wt. pts. Compound wt. pts. K-7110 kJ/m.sup.2 JIS K-7113 % C: Not Good__________________________________________________________________________Example 25 0 -- 0 6.8 9.2 AExample 26 0 -- 0 5.9 7.2 AExample 27 0 -- 0 6.5 8.5 AExample 28 0 -- 0 5.8 7.0 AExample 29 0 -- 0 5.5 6.8 BComparative 0 -- 0 3.1 5.0 CExample 13Comparative 0 -- 0 2.8 2.4 CExample 14Comparative 0 -- 0 1.8 2.0 CExample 15Comparative 0 -- 0 1.3 1.0 CExample 16Comparative 0 -- 0 1.9 1.5 CExample 17Comparative 0 -- 0 1.2 1.0 CExample 18Example 30 0 -- 0 18.5 19.3 AExample 31 0 -- 0 10.4 13.9 AExample 32 0 -- 0 9.2 11.1 AExample 33 0 -- 0 6.4 8.9 AExample 34 0 -- 0 9.3 10.5 AExample 35 0 -- 0 5.9 8.0 AExample 36 0 -- 0 5.9 8.2 B__________________________________________________________________________
TABLE 1-10__________________________________________________________________________Composition(a) of ASPSProduct (b) of A BObtained in Polyolefin Miscibility-Improving AgentExample and Production Amount Styrene AmountComparative Example 1 Added Content AddedExample wt. pts. Compound Grade wt. pts. Compound Grade wt. % wt. pts.__________________________________________________________________________Comparative 50 LLDPE LO134N 50 SEBS H1041 30 30Example 19Comparative 80 LLDPE LO134N 20 SEBS H1041 30 20Example 20Comparative 80 LLDPE LO134N 20 SEBS H1041 30 10Example 21Comparative 80 LLDPE LO134N 20 SEBS H1041 30 5Example 22Comparative 80 LLDPE LO134N 20 SEBS H1041 30 5Example 23Comparative 80 LLDPE LO134N 20 SEPS Septon 2002 30 5Example 24Example 37 50 b-PP/EPR E185G/EP07P 25/25 SEBS H1081 60 30Example 38 80 b-PP/EPR E185G/EP07P 10/10 SEBS H1081 60 20Example 39 80 b-PP/EPR E185G/EP07P 10/10 SEBS H1081 60 10Example 40 80 b-PP/EPR E185G/EP07P 10/10 SEBS H1081 60 5Example 41 80 b-PP/EPR E185G/EP07P 10/10 SEPS H1081 60 5Example 42 80 b-PP/EPR E185G/EP07P 10/10 SEBS Septon 2104 65 5Example 43 80 b-PP/EPR E185G/EP07P 10/10 SEBC HSB576 45 5Comparative 50 b-PP/EPR E185G/EP07P 25/25 SEBS H1041 30 30Example 25Comparative 80 b-PP/EPR E185G/EP07P 10/10 SEBS H1041 30 20Example 26Comparative 80 b-PP/EPR E185G/EP07P 10/10 SEBS H1041 30 10Example 27Comparative 80 b-PP/EPR E185G/EP07P 10/10 SEBS H1041 30 5Example 28Comparative 80 b-PP/EPR E185G/EP07P 10/10 SEBS H1041 30 5Example 29Comparative 80 b-PP/EPR E185G/EP07P 10/10 SEPS Septon 2002 30 5Example 30__________________________________________________________________________
TABLE 1-11__________________________________________________________________________Composition DC Sytrene-Olefin EPPE Copolymer with Low Styrene Content Oil, WaxExample and 0.55 dl/g, Styrene Amount AmountComparative CHCl.sub.3, 25.degree. C. Content Added AddedExample wt. pts. Compound Grade wt. % wt. pts. Compound Grade wt. pts.__________________________________________________________________________Comparative 0 -- -- -- 0 -- -- 0Example 19Comparative 0 -- -- -- 0 -- -- 0Example 20Comparative 0 -- -- -- 0 -- -- 0Example 21Comparative 0 -- -- -- 0 -- -- 0Example 22Comparative 4 -- -- -- 0 -- -- 0Example 23Comparative 0 -- -- -- 0 -- -- 0Example 24Example 37 0 -- -- -- 0 -- -- 0Example 38 0 -- -- -- 0 -- -- 0Example 39 0 -- -- -- 0 -- -- 0Example 40 0 -- -- -- 0 -- -- 0Example 41 4 -- -- -- 0 -- -- 0Example 42 0 -- -- -- 0 -- -- 0Example 43 0 -- -- -- 0 -- -- 0Comparative 0 -- -- -- 0 -- -- 0Example 25Comparative 0 -- -- -- 0 -- -- 0Example 26Comparative 0 -- -- -- 0 -- -- 0Example 27Comparative 0 -- -- -- 0 -- -- 0Example 28Comparative 4 -- -- -- 0 -- -- 0Example 29Comparative 0 -- -- -- 0 -- -- 0Example 30__________________________________________________________________________
TABLE 1-12__________________________________________________________________________Composition Physical PropertiesF Peeling ResistanceInorganic Filler G Physical Properties Resistance to PeelingGF Polar Group- Izod Impact of Surface LayerAsahi Fiber's Containing Polymer Strength Tensile Visual ObservationExample and F1712 Amount (with notches) Elongation A: Very GoodComparative 10 .mu.m .times. 3 mm Added According to JIS According to B: GoodExample wt. pts. Compound wt. pts. K-7110 kJ/m.sup.2 JIS K-7113 % C: Not Good__________________________________________________________________________Comparative 0 -- 0 4.8 3.9 CExample 19Comparative 0 -- 0 3.3 3.0 CExample 20Comparative 0 -- 0 2.2 2.5 CExample 21Comparative 0 -- 0 1.8 2.1 CExample 22Comparative 0 -- 0 2.3 2.5 CExample 23Comparative 0 -- 0 1.5 2.7 CExample 24Example 37 0 -- 0 20.1 23.0 AExample 38 0 -- 0 12.0 16.3 AExample 39 0 -- 0 9.3 13.1 AExample 40 0 -- 0 8.4 11.5 AExample 41 0 -- 0 9.5 13.4 AExample 42 0 -- 0 8.5 10.9 AExample 43 0 -- 0 8.0 9.7 BComparative 0 -- 0 5.1 5.5 CExample 25Comparative 0 -- 0 3.0 3.0 CExample 26Comparative 0 -- 0 2.2 2.2 CExample 27Comparative 0 -- 0 1.8 1.3 CExample 28Comparative 0 -- 0 2.3 1.7 CExample 29Comparative 0 -- 0 1.9 1.5 CExample 30__________________________________________________________________________
TABLE 2-1__________________________________________________________________________Composition(a) of ASPSProduct (b) of A BObtained in Polyolefin Miscibility-Improving AgentExample and Production Amount Styrene AmountComparative Example 1 Added Content AddedExample wt. pts. Compound Grade wt. pts. Compound Grade wt. % wt. pts.__________________________________________________________________________Example 44 50 EPM EP07P 50 SEBS H1081 60 30Example 45 80 EPM EP07P 20 SEBS H1081 60 20Example 46 80 EPM EP07P 20 SEBS H1081 60 10Example 47 80 EPM EP07P 20 SEBS H1081 60 5Example 48 80 EPM EP07P 20 SEBS H1081 60 5Example 49 80 EPM EP07P 20 SEBS H1081 60 5Example 50 80 EPM EP07P 20 SEBS H1081 60 5Example 51 82 EPM EP07P 18 SEBS H1081 60 5Example 52 89 EPM EP07P 11 SEBS H1081 60 5Example 53 82 EPM EP07P 18 SEBS H1081 60 5Example 54 89 EPM EP07P 11 SEBS H1081 60 5Example 55 82 EPM EP07P 18 SEBS H1081 60 5Example 56 89 EPM EP07P 11 SEBS H1081 60 5Example 57 83 EPM EP07P 17 SEBS H1081 60 5Example 58 83 EPM EP07P 17 SEBS H1081 60 5Example 59 80 EPM EP07P 20 SEPS Septon 2104 65 5Example 60 80 EPM EP07P 20 SEBC HBS576 45 5Comparative 50 EPM EP07P 50 SEBS H1041 30 30Example 31__________________________________________________________________________
TABLE 2-2__________________________________________________________________________Composition DC Styrene-Olefin EPPE Copolymer with Low Styrene Content Oil, WaxExample and 0.55 dl/g, Styrene Amount AmountComparative CHCl.sub.3, 25.degree. C. Content Added AddedExample wt. pts. Compound Grade wt. % wt. pts. Compound Grade wt. pts.__________________________________________________________________________Example 44 0 -- -- -- 0 -- -- 0Example 45 0 -- -- -- 0 -- -- 0Example 46 0 -- -- -- 0 -- -- 0Example 47 0 -- -- -- 0 -- -- 0Example 48 0 -- -- -- 0 -- -- 0Example 49 0 -- -- -- 0 -- -- 0Example 50 4 -- -- -- 0 -- -- 0Example 51 4 SEBS Septon 8006 30 2 -- -- 0Example 52 4 SEBS Septon 8006 30 10 -- -- 0Example 53 4 -- -- -- 0 paraffin oil PW380 2Example 54 4 -- -- -- 0 paraffin oil PW380 10Example 55 4 -- -- -- 0 silicon oil SH200 2Example 56 4 -- -- -- 0 silicon oil SH200 10Example 57 4 SEBS Septon 8006 30 2 paraffin oil PW380 2Example 58 4 SEBS Septon 8006 30 2 silicone oil SH200 2Example 59 0 -- -- -- 0 -- -- 0Example 60 0 -- -- -- 0 -- -- 0Comparative 0 -- -- -- 0 -- -- 0Example 31__________________________________________________________________________
TABLE 2-3__________________________________________________________________________Composition Physical PropertiesF Peeling ResistanceInorganic Filler G Physical Properties Resistance to PeelingGF Polar Group- Izod Impact of Surface LayerAsahi Fiber's Containing Polymer Strength Tensile Visual ObservationExample and F1712 Amount (with notches) Elongation A: Very GoodComparative 10 .mu.m .times. 3 mm Added According to JIS According to B: GoodExample wt. pts. Compound wt. pts. K-7110 kJ/m.sup.2 JIS K-7113 % C: Not Good__________________________________________________________________________Example 44 55.7 Production 2 14.0 3.5 A Example 3Example 45 51.4 Production 2 11.5 2.8 A Example 3Example 46 47.1 Production 2 10.4 2.5 A Example 3Example 47 45.0 -- 0 7.3 2.0 AExample 48 45.0 Production 2 8.5 2.3 A Example 2Example 49 45.0 Production 2 9.4 2.4 A Example 3Example 50 46.7 Production 2 9.9 2.6 A Example 3Example 51 46.7 Production 2 11.0 2.7 A Example 3Example 52 46.7 Production 2 12.1 2.9 A Example 3Example 53 46.7 Production 2 10.9 2.8 A Example 3Example 54 46.7 Production 2 12.0 2.9 A Example 3Example 55 46.7 Production 2 11.1 2.8 A Example 3Example 56 46.7 Production 2 12.3 3.0 A Example 3Example 57 46.7 Production 2 12.1 2.9 A Example 3Example 58 46.7 Production 2 12.3 3.0 A Example 3Example 59 45.0 Production 2 9.5 2.5 A Example 3Example 60 45.0 Production 2 9.3 2.3 B Example 3Comparative 55.7 Production 2 7.5 2.5 CExample 31 Example 3__________________________________________________________________________
TABLE 2-4__________________________________________________________________________Composition(a) of ASPSProduct (b) of A BObtained in Polyolefin Miscibility-Improving AgentExample and Production Amount Styrene AmountComparative Example 1 Added Content AddedExample wt. pts. Compound Grade wt. pts. Compound Grade wt. % wt. pts.__________________________________________________________________________Comparative 80 EPM EP07P 20 SEBS H1041 30 20Example 32Comparative 80 EPM EP07P 20 SEBS H1041 30 10Example 33Comparative 80 EPM EP07P 20 SEBS H1041 30 5Example 34Comparative 80 EPM EP07P 20 SEBS H1041 30 5Example 35Comparative 80 EPM EP07P 20 SEBS H1041 30 5Example 36Comparative 80 EPM EP07P 20 SEBS H1041 30 5Example 37Comparative 80 EPM EP07P 20 SEPS Septon 2002 30 5Example 38Example 61 50 EPDM EP181SP 50 SEBS H1081 60 30Example 62 80 EPDM EP181SP 20 SEBS H1081 60 20Example 63 80 EPDM EP181SP 20 SEBS H1081 60 10Example 64 80 EPDM EP181SP 20 SEBS H1081 60 5Example 65 80 EPDM EP181SP 20 SEBS H1081 60 5Example 66 80 EPDM EP181SP 20 SEBS H1081 60 5Example 67 80 EPDM EP181SP 20 SEBS H1081 60 5Example 68 80 EPDM EP181SP 20 SEPS Septon 2104 65 5Example 69 80 EPDM EP181SP 20 SEBC HSB576 45 5Comparative 50 EPDM EP181SP 50 SEBS H1041 30 30Example 39Comparative 80 EPDM EP181SP 20 SEBS H1041 30 20Example 40__________________________________________________________________________
TABLE 2-5__________________________________________________________________________Composition DC Styrene-Olefin EPPE Copolymer with Low Styrene Content Oil, WaxExample and 0.55 dl/g, Styrene Amount AmountComparative CHCl.sub.3, 25.degree. C. Content Added AddedExample wt. pts. Compound Grade wt. % wt. pts. Compound Grade wt. pts.__________________________________________________________________________Comparative 0 -- -- -- 0 -- -- 0Example 32Comparative 0 -- -- -- 0 -- -- 0Example 33Comparative 0 -- -- -- 0 -- -- 0Example 34Comparative 0 -- -- -- 0 -- -- 0Example 35Comparative 0 -- -- -- 0 -- -- 0Example 36Comparative 4 -- -- -- 0 -- -- 0Example 37Comparative 0 -- -- -- 0 -- -- 0Example 38Example 61 0 -- -- -- 0 -- -- 0Example 62 0 -- -- -- 0 -- -- 0Example 63 0 -- -- -- 0 -- -- 0Example 64 0 -- -- -- 0 -- -- 0Example 65 0 -- -- -- 0 -- -- 0Example 66 0 -- -- -- 0 -- -- 0Example 67 4 -- -- -- 0 -- -- 0Example 68 0 -- -- -- 0 -- -- 0Example 69 0 -- -- -- 0 -- -- 0Comparative 0 -- -- -- 0 -- -- 0Example 39Comparative 0 -- -- -- 0 -- -- 0Example 40__________________________________________________________________________
TABLE 2-6__________________________________________________________________________Composition Physical PropertiesF Peeling ResistanceInorganic Filler G Physical Properties Resistance to PeelingGF Polar Group- Izod Impact of Surface LayerAsahi Fiber's Containing Polymer Strength Tensile Visual ObservationExample and F1712 Amount (with notches) Elongation A: Very GoodComparative 10 .mu.m .times. 3 mm Added According to JIS According to B: GoodExample wt. pts. Compound wt. pts. K-7110 kJ/m.sup.2 JIS K-7113 % C: Not Good__________________________________________________________________________Comparative 51.4 Production 2 6.1 2.0 CExample 32 Example 3Comparative 47.1 Production 2 5.6 1.8 CExample 33 Example 3Comparative 45.0 -- 0 4.0 1.1 CExample 34Comparative 45.0 Production 2 4.9 1.4 CExample 35 Example 2Comparative 45.0 Production 2 5.2 1.6 CExample 36 Example 3Comparative 46.7 Production 2 6.0 1.8 CExample 37 Example 3Comparative 45.0 Production 2 5.3 1.5 CExample 38 Example 3Example 61 55.7 Production 2 14.2 3.7 A Example 3Example 62 51.4 Production 2 12.0 3.0 A Example 3Example 63 47.1 Production 2 10.5 2.7 A Example 3Example 64 45.0 -- 0 7.3 1.9 AExample 65 45.0 Production 2 8.7 2.2 A Example 2Example 66 45.0 Production 2 9.8 2.4 A Example 3Example 67 46.7 Production 2 10.2 2.6 A Example 3Example 68 45.0 Production 2 9.8 2.4 A Example 3Example 69 45.0 Production 2 9.3 2.4 B Example 3Comparative 55.7 Production 2 7.8 2.4 CExample 39 Example 3Comparative 51.4 Production 2 6.5 2.0 CExample 40 Example 3__________________________________________________________________________
TABLE 2-7__________________________________________________________________________Composition(a) of ASPSProduct (b) of A BObtained in Polyolefin Miscibility-Improving AgentExample and Production Amount Styrene AmountComparative Example 1 Added Content AddedExample wt. pts. Compound Grade wt. pts. Compound Grade wt. % wt. pts.__________________________________________________________________________Comparative 80 EPDM EP181SP 20 SEBS H1041 30 10Example 41Comparative 80 EPDM EP181SP 20 SEBS H1041 30 5Example 42Comparative 80 EPDM EP181SP 20 SEBS H1041 30 5Example 43Comparative 80 EPDM EP181SP 20 SEBS H1041 30 5Example 44Comparative 80 EPDM EP181SP 20 SEBS H1041 30 5Example 45Comparative 80 EPDM EP181SP 20 SEPS Septon 2002 30 5Example 46Example 70 50 b-PP E185G 50 SEBS H1081 60 30Example 71 80 b-PP E185G 20 SEBS H1081 60 20Example 72 80 b-PP E185G 20 SEBS H1081 60 10Example 73 80 b-PP E185G 20 SEBS H1081 60 5Example 74 80 b-PP E185G 20 SEBS H1081 60 5Example 75 80 b-PP E185G 20 SEBS H1081 60 5Example 76 80 b-PP E185G 20 SEBS H1081 60 5Example 77 80 b-PP E185G 20 SEPS Septon 2104 65 5Example 78 80 b-PP E185G 20 SEBC HSB576 45 5Comparative 50 b-PP E185G 50 SEBS H1041 30 30Example 47Comparative 80 b-PP E185G 20 SEBS H1041 30 20Example 48Comparative 80 b-PP E185G 20 SEBS H1041 30 10Example 49__________________________________________________________________________
TABLE 2-8__________________________________________________________________________Composition DC Styrene-Olefin EPPE Copolymer with Low Styrene Content Oil, WaxExample and 0.55 dl/g, Styrene Amount AmountComparative CHCl.sub.3, 25.degree. C. Content Added AddedExample wt. pts. Compound Grade wt. % wt. pts. Compound Grade wt. pts.__________________________________________________________________________Comparative 0 -- -- -- 0 -- -- 0Example 41Comparative 0 -- -- -- 0 -- -- 0Example 42Comparative 0 -- -- -- 0 -- -- 0Example 43Comparative 0 -- -- -- 0 -- -- 0Example 44Comparative 4 -- -- -- 0 -- -- 0Example 45Comparative 0 -- -- -- 0 -- -- 0Example 46Example 70 0 -- -- -- 0 -- -- 0Example 71 0 -- -- -- 0 -- -- 0Example 72 0 -- -- -- 0 -- -- 0Example 73 0 -- -- -- 0 -- -- 0Example 74 0 -- -- -- 0 -- -- 0Example 75 0 -- -- -- 0 -- -- 0Example 76 4 -- -- -- 0 -- -- 0Example 77 0 -- -- -- 0 -- -- 0Example 78 0 -- -- -- 0 -- -- 0Comparative 0 -- -- -- 0 -- -- 0Example 47Comparative 0 -- -- -- 0 -- -- 0Example 48Comparative 0 -- -- 0 -- -- 0Example 49__________________________________________________________________________
TABLE 2-9__________________________________________________________________________Composition Physical PropertiesF Peeling ResistanceInorganic Filler G Physical Properties Resistance to PeelingGF Polar Group- Izod Impact of Surface LayerAsahi Fiber's Containing Polymer Strength Tensile Visual ObservationExample and F1712 Amount (with notches) Elongation A: Very GoodComparative 10 .mu.m .times. 3 mm Added According to JIS According to B: GoodExample wt. pts. Compound wt. pts. K-7110 kJ/m.sup.2 JIS K-7113 % C: Not Good__________________________________________________________________________Comparative 47.1 Production 2 5.8 1.8 CExample 41 Example 3Comparative 45.0 -- 0 3.8 1.0 CExample 42Comparative 45.0 Production 2 4.5 1.3 CExample 43 Example 2Comparative 45.0 Production 2 5.0 1.5 CExample 44 Example 3Comparative 46.7 Production 2 5.2 1.6 CExample 45 Example 3Comparative 45.0 Production 2 4.5 1.1 CExample 46 Example 3Example 70 55.7 Production 2 12.0 2.9 A Example 3Example 71 51.4 Production 2 9.8 2.3 A Example 3Example 72 47.1 Production 2 8.5 2.2 A Example 3Example 73 45.0 -- 0 5.8 1.5 AExample 74 45.0 Production 2 7.1 1.7 A Example 2Example 75 45.0 Production 2 8.3 1.9 A Example 3Example 76 46.7 Production 2 8.6 2.1 A Example 3Example 77 45.0 Production 2 8.2 1.9 A Example 3Example 78 45.0 Production 2 7.9 1.8 B Example 3Comparative 55.7 Production 2 5.9 1.8 CExample 47 Example 3Comparative 51.4 Production 2 4.8 1.5 CExample 48 Example 3Comparative 47.1 Production 2 4.0 1.3 CExample 49 Example 3__________________________________________________________________________
TABLE 2-10__________________________________________________________________________Composition(a) of ASPSProduct (b) of A BObtained in Polyolefin Miscibility-Improving AgentExample and Production Amount Styrene AmountComparative Example 1 Added Content AddedExample wt. pts. Compound Grade wt. pts. Compound Grade wt. % wt. pts.__________________________________________________________________________Comparative 80 b-PP E185G 20 SEBS H1041 30 5Example 50Comparative 80 b-PP E185G 20 SEBS H1041 30 5Example 51Comparative 80 b-PP E185G 20 SEBS H1041 30 5Example 52Comparative 80 b-PP E185G 20 SEBS H1041 30 5Example 53Comparative 80 b-PP E185G 20 SEPS Septon 2002 30 5Example 54Example 79 50 LLDPE L0134N 50 SEBS H1081 60 30Example 80 80 LLDPE L0134N 20 SEBS H1081 60 20Example 81 80 LLDPE L0134N 20 SEBS H1081 60 10Example 82 80 LLDPE L0134N 20 SEBS H1081 60 5Example 83 80 LLDPE L0134N 20 SEBS H1081 60 5Example 84 80 LLDPE L0134N 20 SEBS H1081 60 5Example 85 80 LLDPE L0134N 20 SEBS H1081 60 5Example 86 80 LLDPE L0134N 20 SEPS Septon 2104 65 5Example 87 80 LLDPE L0134N 20 SEBC HSB576 45 5Comparative 50 LLDPE L0134N 50 SEBS H1041 30 30Example 55Compatative 80 LLDPE L0134N 20 SEBS H1041 30 20Example 56Comparative 80 LLDPE L0134N 20 SEBS H1041 30 10Examples 57Comparative 80 LLDPE L0134N 20 SEBS H1041 30 5Example 58__________________________________________________________________________
TABLE 2-11__________________________________________________________________________Composition DC Styrene-Olefin EPPE Copolymer with Low Styrene Content Oil, WaxExample and 0.55 dl/g, Styrene Amount AmountComparative CHCl.sub.3, 25.degree. C. Content Added AddedExample wt. pts. Compound Grade wt. % wt. pts. Compound Grade wt. pts.__________________________________________________________________________Comparative 0 -- -- -- 0 -- -- 0Example 50Comparative 0 -- -- -- 0 -- -- 0Example 51Comparative 0 -- -- -- 0 -- -- 0Example 52Comparative 4 -- -- -- 0 -- -- 0Example 53Comparative 0 -- -- -- 0 -- -- 0Example 54Example 79 0 -- -- -- 0 -- -- 0Example 80 0 -- -- -- 0 -- -- 0Example 81 0 -- -- -- 0 -- -- 0Example 82 0 -- -- -- 0 -- -- 0Example 83 0 -- -- -- 0 -- -- 0Example 84 0 -- -- -- 0 -- -- 0Example 85 4 -- -- -- 0 -- -- 0Example 86 0 -- -- -- 0 -- -- 0Example 87 0 -- -- -- 0 -- -- 0Comparative 0 -- -- -- 0 -- -- 0Example 55Comparative 0 -- -- -- 0 -- -- 0Example 56Comparative 0 -- -- -- 0 -- -- 0Example 57Comparative 0 -- -- -- 0 -- -- 0Example 58__________________________________________________________________________
TABLE 2-12__________________________________________________________________________Composition Physical PropertiesF Peeling ResistanceInorganic Filler G Physical Properties Resistance to PeelingGF Polar Group- Izod Impact of Surface LayerAsahi Fiber's Containing Polymer Strength Tensile Visual ObservationExample and F1712 Amount (with notches) Elongation A: Very GoodComparative 10 .mu.m .times. 3 mm Added According to JIS According to B: GoodExample wt. pts. Compound wt. pts. K-7110 kJ/m.sup.2 JIS K-7113 % C: Not Good__________________________________________________________________________Comparative 45.0 -- 0 2.9 0.9 CExample 50Comparative 45.0 Production 2 3.5 1.0 CExample 51 Example 2Comparative 45.0 Production 2 3.9 1.1 CExample 52 Example 3Comparative 46.7 Production 2 4.1 1.2 CExample 53 Example 3Comparative 45.0 Production 2 3.8 1.0 CExample 54 Example 3Example 79 55.7 Production 2 13.0 2.9 A Example 3Example 80 51.4 Production 2 10.5 2.4 A Example 3Example 81 47.1 Production 2 9.4 2.1 A Example 3Example 82 45.0 -- 0 6.0 1.5 AExample 83 45.0 Production 2 7.5 1.8 A Example 2Example 84 45.0 Production 2 8.6 1.9 A Example 3Example 85 46.7 Production 2 9.1 2.1 A Example 3Example 86 45.0 Production 2 8.7 1.8 A Example 3Example 87 45.0 Production 2 8.5 2.0 B Example 3Comparative 55.7 Production 2 6.8 1.8 CExample 55 Example 3Comparative 51.4 Production 2 5.0 1.5 CExample 56 Example 3Comparative 47.1 Production 2 4.6 1.3 CExample 57 Example 3Comparative 45.0 -- 0 3.0 0.8 CExample 58__________________________________________________________________________
TABLE 2-13__________________________________________________________________________Composition(a) of ASPSProduct (b) of A BObtained in Polyolefin Miscibility-Improving AgentExample and Production Amount Styrene AmountComparative Example 1 Added Content AddedExample wt. pts. Compound Grade wt. pts. Compound Grade wt. % wt. pts.__________________________________________________________________________Comparative 80 LLDPE L0134N 20 SEBS H1041 30 5Example 59Comparative 80 LLDPE L0134N 20 SEBS H1041 30 5Example 60Comparative 80 LLDPE L0134N 20 SEBS H1041 30 5Example 61Comparative 80 LLDPE L0134N 20 SEPS Septon 2002 30 5Example 62Example 88 50 b-PP/EPR E185G/EP07P 25/25 SEBS H1081 60 30Example 89 80 b-PP/EPR E185G/EP07P 10/10 SEBS H1081 60 20Example 90 80 b-PP/EPR E185G/EP07P 10/10 SEBS H1081 60 10Example 91 80 b-PP/EPR E185G/EP07P 10/10 SEBS H1081 60 5Example 92 80 b-PP/EPR E185G/EP07P 10/10 SEBS H1081 60 5Example 93 80 b-PP/EPR E185G/EP07P 10/10 SEBS H1081 60 5Example 94 80 b-PP/EPR E185G/EP07P 10/10 SEBS H1081 60 5Example 95 80 b-PP/EPR E185G/EP07P 10/10 SEPS Septon 2104 65 5Example 96 80 b-PP/EPR E185G/EP07P 10/10 SEBC HBS576 45 5Comparative 50 b-PP/EPR E185G/EP07P 25/25 SEBS H1041 30 30Example 63Comparative 80 b-PP/EPR E185G/EP07P 10/10 SEBS H1041 30 20Example 64Comparative 80 b-PP/EPR E185G/EP07P 10/10 SEBS H1041 30 10Example 65Comparative 80 b-PP/EPR E185G/EP07P 10/10 SEBS H1041 30 5Example 66Comparative 80 b-PP/EPR E185G/EP07P 10/10 SEBS H1041 30 5Example 67Comparative 80 b-PP/EPR E185G/EP07P 10/10 SEBS H1041 30 5Example 68Comparative 80 b-PP/EPR E185G/EP07P 10/10 SEBS H1041 30 5Example 69Comparative 80 b-PP/EPR E185G/EP07P 10/10 SEPS Septon 2002 30 5Example 70__________________________________________________________________________
TABLE 2-14__________________________________________________________________________Composition DC Styrene-Olefin EPPE Copolymer with Low Styrene Content Oil, WaxExample and 0.55 dl/g, Styrene Amount AmountComparative CHCl.sub.3, 25.degree. C. Content Added AddedExample wt. pts. Compound Grade wt. % wt. pts. Compound Grade wt. pts.__________________________________________________________________________Comparative 0 -- -- -- 0 -- -- 0Example 59Comparative 0 -- -- -- 0 -- -- 0Example 60Comparative 4 -- -- -- 0 -- -- 0Example 61Comparative 0 -- -- -- 0 -- -- 0Example 62Example 88 0 -- -- -- 0 -- -- 0Example 89 0 -- -- -- 0 -- -- 0Example 90 0 -- -- -- 0 -- -- 0Example 91 0 -- -- -- 0 -- -- 0Example 92 0 -- -- -- 0 -- -- 0Example 93 0 -- -- -- 0 -- -- 0Example 94 4 -- -- -- 0 -- -- 0Example 95 0 -- -- -- 0 -- -- 0Example 96 0 -- -- -- 0 -- -- 0Comparative 0 -- -- -- 0 -- -- 0Example 63Comparative 0 -- -- -- 0 -- -- 0Example 64Comparative 0 -- -- -- 0 -- -- 0Example 65Comparative 0 -- -- -- 0 -- -- 0Example 66Comparative 0 -- -- -- 0 -- -- 0Example 67Comparative 0 -- -- -- 0 -- -- 0Example 68Comparative 4 -- -- -- 0 -- -- 0Example 69Comparative 0 -- -- -- 0 -- -- 0Example 70__________________________________________________________________________
TABLE 2-15__________________________________________________________________________Composition Physical PropertiesF Peeling ResistanceInorganic Filler G Physical Properties Resistance to PeelingGF Polar Group- Izod Impact of Surface LayerAsahi Fiber's Containing Polymer Strength Tensile Visual ObservationExample and F1712 Amount (with notches) Elongation A: Very GoodComparative 10 .mu.m .times. 3 mm Added According to JIS According to B: GoodExample wt. pts. Compound wt. pts. K-7110 kJ/m.sup.2 JIS K-7113 % C: Not Good__________________________________________________________________________Comparative 45.0 Production 2 3.6 1.1 CExample 59 Example 2Comparative 45.0 Production 2 3.9 1.3 CExample 60 Example 3Comparative 46.7 Production 2 4.2 1.4 CExample 61 Example 3Comparative 45.0 Production 2 4.0 1.2 CExample 62 Example 3Example 88 55.7 Production 2 13.3 3.1 A Example 3Example 89 51.4 Production 2 10.9 2.5 A Example 3Example 90 47.1 Production 2 9.8 2.3 A Example 3Example 91 45.0 -- 0 6.7 1.7 AExample 92 45.0 Production 2 8.0 1.9 A Example 2Example 93 45.0 Production 2 9.1 2.1 A Example 3Example 94 46.7 Production 2 9.5 2.3 A Example 3Example 95 45.0 Production 2 9.3 2.0 A Example 3Example 96 45.0 Production 2 9.0 2.2 B Example 3Comparative 55.7 Production 2 7.2 2.1 CExample 63 Example 3Comparative 51.4 Production 2 5.7 1.7 CExample 64 Example 3Comparative 47.1 Production 2 5.0 1.5 CExample 65 Example 3Comparative 45.0 -- 0 3.3 0.9 CExample 66Comparative 45.0 Production 2 4.0 1.2 CExample 67 Example 2Comparative 45.0 Production 2 4.3 1.3 CExample 68 Example 3Comparative 46.7 Production 2 4.5 1.5 CExample 69 Example 3Comparative 45.0 Production 2 4.3 1.4 CExample 70 Example 3__________________________________________________________________________
Notes:
SPS: Obtained in Production Example 1.
EP07P: EPR produced by Japan Synthetic Rubber Co., Ltd.
EP181SP: EPDM produced by Japan Synthetic Rubber Co., Ltd.
E-185G: b-PP produced by Idemitsu Petrochemical Co., Ltd.
L0134N: LLDPE produced by Idemitsu Petrochemical Co., Ltd.
Tuftec H1081: SEBS produced by Asahi Chemical Industry Co., Ltd.
Tuftec H1041: SEBS produced by Asahi Chemical Industry Co., Ltd.
Septon 2104: SEPS produced by Kuraray Co., Ltd.
Septon 2002: SEPS produced by Kuraray Co., Ltd.
Septon 8006: SEBS produced by Kuraray Co., Ltd.
Dynaron HBS576: SEBC produced by Japan Synthetic Rubber Co., Ltd.
PPE: Poly(2,6-dimethyl-1,4-phenylene ether) having an intrinsic viscosity of 0.55 dl/g in chloroform at 25.degree. C.
PW 380: Paraffin oil produced by Idemitsu Kosan Co., Ltd.
SH 200: Silicone oil produced by Toray Dow Corning Silicone Co., Ltd.
FT 712: Glass fiber having a length of 3 mm and a diameter of 10 .mu.m, produced by Asahi Fiber Glass Co., Ltd.
As has been described in detail hereinabove, the syndiotactic polystyrenic resin composition of the present invention can be formed into articles having good heat resistance, a high modulus of elasticity and greatly improved toughness. In addition, the articles are advantageous in that their surface layers are hardly peeled.
Therefore, the resin composition of the present invention is favorably used in forming various materials for industrial use, for example, electric and electronic materials (e.g., connectors, substrates for printed circuits), industrial construction materials, car parts (e.g., connectors to be mounted on cars, wheel caps, cylinder head covers), household appliances, various machine parts, pipes, sheets, trays, films, etc.
While the invention has been described in detail and with reference to specific embodiments thereof, it will be apparent to one skilled in the art that various changes and modifications can be made therein without departing from the spirit and scope thereof.

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Number	Date	Country
0 324 398	Jul 1989	EPX
0 639 616	Feb 1995	EPX
WO 9101352	Jul 1991	WOX

	Number	Date	Country
Parent	059019	Apr 1998
Parent	711271	Sep 1996

Styrene-based syndiotactic resin composition

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