Claims
- 1. A curable mixture comprising an epoxy resin having an average of more than one vicinal epoxy group per molecule and a curing amount of a novolac resin which results from removing at least about 25 weight percent of the 2-functional component from a novolac resin which results from reacting (1) a material having at least one aromatic hydroxyl group per molecule selected from the group consisting of (a) a substituted phenol wherein the substituent groups are hydroxyl, hydrocarbyl or hydrocarbyloxy groups having from 1 to about 9 carbon atoms, or a halogen; and (b) a mixture of said substituted phenol and phenol wherein more than about 50 molar percent of the mixture is a substituted phenol; with (2) an aldehyde.
- 2. A curable mixture of claim 1 wherein the novolac resin is that which results from removing at least about 35 weight percent of the 2-functional component from a novolac resin represented by the formula ##STR4## wherein each A is independently a divalent hydrocarbon group or a divalent hydrocarbon group substituted with any inert substituent group selected from chlorine, bromine or fluorine, said hydrocarbon having from 1 to about 14 carbon atoms; each R is independently hydrogen, a halogen atom, a hydroxyl group or a hydrocarbon group having from about 1 to about 9 carbon atoms and n has an average value of from about 0.5 to about 10; with the proviso that more than about 60 percent of the aromatic rings have at least one R group which is other than hydrogen.
- 3. A curable mixture of of claim 2 wherein the novolac resin is that which results from removing at least about 50 weight percent of the 2-functional component from a novolac resin wherein each A is independently a divalent hydrocarbon group or a divalent hydrocarbon group substituted with any inert substituent group selected from chlorine, bromine or fluorine, said hydrocarbon having from 1 to about 8 carbon atoms; and n has an average value of from about 1 to about 8; and wherein more than 70 about percent of the aromatic rings have at least one R group which is other than hydrogen.
- 4. A curable mixture of claim 3 wherein the novolac resin is that which results from removing at least about 70 weight percent of the 2-functional component from a novolac resin wherein n has an average value of from about 1.5 to about 4; and wherein more than about 85 percent of the aromatic rings have at least one R group which is other than hydrogen.
- 5. A curable mixture of claim 1, 2, 3 or 4 wherein said substituted phenol is an alkyl phenol and said aldehyde is formaldehyde.
- 6. A curable mixture of claim 5 wherein said alkyl phenol is nonylphenol or cresol.
- 7. A curable mixture of claim 6 wherein said alkyl phenol is cresol.
- 8. A curable mixture of claim 1, 2, 3 or 4 wherein said substituted phenol is a halogen substituted phenol and said aldehyde is formaldehyde.
- 9. A curable mixture of claim 8 wherein said halogen substituted phenol is chlorophenol or bromophenol.
- 10. A curable mixture comprising an epoxy resin having an average of more than one vicinal epoxy group per molecule and a curing amount of a novolac resin which results from reacting an aldehyde with a phenolic hydroxyl-containing material which is (a) a phenol substituted with at least one but not more than about three groups selected from hydrocarbyl, halogen or hydroxyl groups, or any combination thereof or (b) a mixture of a phenol substituted with at least one but not more than about three groups selected from hydrocarbyl, halogen or hydroxyl groups, or any combination thereof with phenol with the proviso that at least 50 mole percent of the mixture is a substituted phenol; wherein said novolac resin has a ratio of 2-functional component to 3-functional component of not greater than 0.7:1.
- 11. A curable mixture of claim 10 wherein said novolac resin has a ratio of 2-functional component to 3-functional component of not greater than about 0.5:1; and when said phenolic hydroxyl-containing material is a mixture of phenol and a substituted phenol, said mixture contains at least 70 mole percent substituted phenol.
- 12. A curable mixture of claim 11 wherein said novolac resin has a ratio of 2-functional component to 3-functional component of not greater than abou 0.4:1; and when said phenolic hydroxyl-containing material is a mixture of phenol and a substituted phenol, said mixture contains at least 85 mole percent substituted phenol.
- 13. A curable mixture of claim 12 wherein said novolac resin has a ratio of 2-functional component to 3-functional component of not greater than about 0.2:1.
- 14. A curable mixture of claim 10, 11, 12 or 13 wherein said substituted phenol is an alkyl phenol and said aldehyde is formaldehyde.
- 15. A curable mixture of claim 13 wherein said alkyl phenol is nonylphenol or cresol.
- 16. A curable mixture of claim 14 wherein said alkyl phenol is cresol.
- 17. A curable mixture of claim 10, 11, 12 or 13 wherein said substituted aldehyde is formaldehyde.
- 18. A curable mixture of claim 17 wherein said halogen substituted phenol is chlorophenol or bromophenol.
- 19. The product resulting from curing the curable mixture of claim 1, 2, 3, 4, 10, 11, 12 or 13.
- 20. The product resulting from curing the curable mixture of claim 5.
- 21. The product resulting from curing the curable mixture of claim 6.
- 22. The product resulting from curing the curable mixture of claim 7.
- 23. The product resulting from curing the curable mixture of claim 8.
- 24. The product resulting from curing the curable mixture of claim 14.
- 25. The product resulting from curing the curable mixture of claim 15.
- 26. The product resulting from curing the curable mixture of claim 16.
- 27. The product resulting from curing the curable mixture of claim 17.
- 28. The product resulting from curing the curable mixture of claim 18.
- 29. The cured product of claim 19 which contains a reinforcing component.
- 30. The cured product of claim 20 which contains a reinforcing component.
- 31. The cured product of claim 21 which contains a reinforcing component.
- 32. The cured product of claim 22 which contains a reinforcing component.
- 33. The cured product of claim 23 which contains a reinforcing component.
- 34. The cured product of claim 24 which contains a reinforcing component.
- 35. The cured product of claim 25 which contains a reinforcing component.
- 36. The cured product of claim 26 which contains a reinforcing component.
- 37. The cured product of claim 27 which contains a reinforcing component.
- 38. The cured product of claim 28 which contains a reinforcing component.
- 39. The product resulting from curing the curable mixture of claim 9.
- 40. The cured product of claim 39 which contains a reinforcing agent.
CROSS REFERENCE TO RELATED APPLICATION
This is a continuation-in-part of our copending application Ser. No. 690,702 filed Jan. 11, 1985, now abandoned.
US Referenced Citations (3)
Number |
Name |
Date |
Kind |
3928288 |
Walker |
Dec 1975 |
|
4611036 |
Sekyuchi et al. |
Sep 1986 |
|
4649188 |
Bertram et al. |
Mar 1987 |
|
Non-Patent Literature Citations (2)
Entry |
Lee et al; Handbook of Epoxy Resins; McGraw-Hill Book Co.; 1967, pp. 2-10, 11-14, 11-15. |
Quatrex; Dow Chemical Co.; Form No. 296-598-85. |
Continuation in Parts (1)
|
Number |
Date |
Country |
Parent |
690702 |
Jan 1985 |
|