The present invention concerns surface removal from inorganic non-metallic structures, in particular concrete structures, primarily though not exclusively for the purpose of removing radioactive contamination contained in surface layers.
In the nuclear industry surfaces of concrete structures may become contaminated with radionuclides. Common contaminants include uranium oxide, plutonium oxide, strontium-90, caesium-137 and cobalt-60. Typically this contamination is only present in a surface layer of concrete. Such layers may be around 1 to 4 mm thick. By removal of such a surface layer the degree of contamination of a surface and of the structure as a whole may be greatly reduced. However, simple mechanical methods are unsuitable for use where a potential for contamination makes it desirable for an operator to be remote from a surface to be operated upon.
Various techniques are known for the surface removal of concrete, stone and similar surfaces. One such method is the heat treatment of a surface such as to degrade that surface and release a surface layer.
JP 3002595 describes the removal of a concrete surface layer by crushing due to the heat generated by the use of microwaves to irradiate a contaminated surface layer.
EP-A-0653762 describes a method of modifying concrete using a laser by a method of ejecting surface chips, thus causing surface removal, using a laser scanned across a surface in a raster scan is disclosed. In such methods energy from laser light causes surface chips to break away due to generation of steam or thermal stresses below the surface thus effecting surface removal. This latter phenomenon of ejecting surface chips or flakes is known in the art as laser scabbling.
However, it has been found that some surfaces, including some types of concrete having aggregate therein, whilst successfully scabbling on a first scan, may fail to do so on areas which are adjacent a first scanned track.
According to a first aspect of the present invention there is provided a method of treating a surface for the removal of a surface portion thereof, the method comprising the steps of: producing a beam of laser light and obscuring a low power density part of the laser beam before irradiating a surface location with the laser light so as to remove the surface portion.
According to a second aspect of the present invention there is provided an apparatus for treating a surface for the removal of a surface portion thereof, the apparatus comprising a laser source for producing a laser beam for irradiating a surface location with laser light so as to remove the surface portion wherein a low power density part of the laser beam is obscured and does not impinge upon the surface.
The low power density part of the laser beam that is obscured may be a part below a threshold power density for surface removal. The surface removal may be substantially by scabbling. A high power density portion of a laser beam may be a portion above a threshold power density for causing scabbling.
The laser beam for use in the invention may have an uneven radiation power density across the beam. The laser beam may be alternatively described as laser light or laser radiation.
In a first embodiment of the invention the laser light may be obscured by a shadow mask. A shadow mask is a means whereby a portion of laser light incident upon the mask is substantially adsorbed by the mask or at least prevents that light from impinging upon the surface location. The shadow mask may adsorb all of a low power density portion of a laser beam.
In a second embodiment of the invention the laser light may be obscured by a reflective mask. A reflective mask is a means whereby a portion of laser light incident upon the mask is substantially reflected by the mask. The portion of laser light reflected by the mask may comprise most of a low power density portion of the laser beam. The reflection may redirect one portion of low power density laser light to another region of low power density laser light so as to create an additional higher power density portion of the laser beam.
The part of laser light reflected by the mask may comprise substantially all of a low power density part of the laser beam. The reflection may redirect the low power density laser light to a high power density portion of the laser beam.
Effectively, the method and apparatus according to the present invention may prevent laser light, which is below a threshold power density for causing scabbling to be incident alone on a surface to be treated. Thus, such low power density laser light may be either adsorbed before reaching the surface; intensified by reflection to combine with another low power density portion of the laser beam to form a portion which is above a threshold level to cause scabbling; or, redirected by reflection to combine with a portion of the laser beam which is already above a threshold to cause scabbling.
At least two problems have been found in the prior art with surface removal by scabbling using a laser. Both problems are associated with a non-uniform power distribution, for example, quasi-Gaussian, across a laser beam spot, in particular with the presence of lower power density parts of an incident beam of laser light on the surface to be treated. The part of a beam of laser light incident upon a surface that is above a critical energy or threshold power density for effecting scabbling gives rise to scabbling from the surface. However, a, usually peripheral part of an incident laser beam which is below the threshold power density, i.e. a part not subjecting a surface portion on which it is incident to a power density above a critical value, does not give rise to surface removal by scabbling. However, such a surface portion, and adjacent similarly un-scabbled areas, may be sufficiently affected by heating from the power of the incident laser beam that a number of processes may occur in the surface portion, such as relaxation, dehydration and chemical change. These processes can result in the affected surface no longer being amenable to subsequent surface removal by scabbling from incident laser light, even when that light is above the threshold power density for scabbling. That is at least when laser light is used in a manner whereby surface removal is otherwise effected by scabbling, i.e. the ejection of surface chips.
Furthermore a non-uniform power distribution across a laser beam incident upon a surface may result in differential surface removal by scabbling between surface portions where a highest and a lower energy, both of which are above the threshold power density, are incident. For this reason a channel with sloping sides may be formed in a surface by a scanned laser beam impinging perpendicular to a surface. A further, adjacent, scanned track, by such a perpendicular beam may result in laser light impinging upon a sloping surface portion resulting in a lower incident power density. The sloping sides may therefore cause an otherwise sufficient energy intensity, per unit area, i.e. power density to become insufficient, i.e. to fall below a threshold power density or to scabble less surface material. As a result a whole surface when scabbled using laser light may be uneven.
The term average power density, may be termed power density, energy intensity or average energy intensity, and is measured in watts (i.e. Joules per second) per square centimetre.
In addition, scabbling processes using lasers may cause explosive detachment of surface portions of a material being treated, as in the scabbling of concrete. To overcome shrapnel damage to the laser and associated optics, laser beams may be focussed through a relatively very small aperture, through which air may also be ejected under pressure so as to prevent ingress of debris. Such focussing may serve to increase the divergence of a laser beam, due to the surface to be treated being remote from the focus, and induce or increase a spread of power density within a spot of incident laser light.
The method and apparatus of the invention have been found to overcome or ameliorate the known problem of areas adjacent to a laser scabbled area resisting removal by scabbling on treatment with laser light of a power density with which the adjacent area was scabbled. In addition a surface modified according to the method of the invention can be more even than when treated in a known manner.
Masks of the invention may comprise an aperture. The aperture may be used for permitting a high power density part of a laser beam to pass through. Masks of the invention may be tubular. Masks of the invention may be circular in cross-section. Masks of the invention may be cylindrical. Masks of the invention may comprise one or more component parts. Masks of the invention may be of adjustable size. Masks of the invention may comprise an adjustable aperture.
Any aperture of a mask of the invention may have the same cross section as a part of the laser beam above a threshold power density for scabbling. A laser beam being focussed may change in cross section with distance. Any aperture of a mask of the invention may be the same shape as the shape of a given length of a part of the laser beam. The relevant given length of laser beam for determining shape may be the laser beam at the point or region respectively at which the shadow mask is placed.
Use of the method of the invention may comprise the steps of irradiating a surface, adjusting a mask aperture size to adsorb a part of the laser beam below a threshold power density for scabbling and irradiating a surface to cause scabbling.
Masks of the invention may comprise a high temperature resistant material. Masks of the invention may comprise metal or ceramic or combinations of metal and ceramic.
Shadow masks of the first aspect of the invention may comprise a non-reflective surface. The non-reflective surface may be black.
Reflective masks of the invention may preferably comprise a metal. The metal may be aluminium, steel, tungsten or stainless steel. Reflective masks of the invention may comprise a polished surface for causing reflection. Reflective masks of the invention may comprise a glass mirror. Reflective masks of the invention may include a non-reflective portion that may act as a shadow mask. The non-reflective portion of a reflective mask may be an end portion of the mask adjacent to the laser head.
Masks for use in the invention may be coated. The coating may be partial. Coatings may include coatings to adsorb laser light so as to for a shadow mask part and coatings to reflect laser light so as to form a reflective mask part.
When using the method and apparatus of the invention the laser beam impinging upon a surface portion may typically be moved over the surface, either continuously or discontinuously so as to treat a whole surface area by causing scabbling. Any suitable method for moving the laser beam relative to the surface being treated may be used including moving the laser, moving the object to be scabbled, moving a conduit (such as a fibre-optic cable) or optical methods such as mirrors and the like.
A laser light source for use in the invention may typically be of total power from 0.5 kW to 4 kW.
A threshold power density for surface removal by scabbling for concrete may typically be in the range of 50 W/cm2 to 80 W/cm2, depending upon the surface to be treated, i.e. a value of 70 W/cm2 or thereabouts.
The average power density found in the method of the invention to produce optimum scabbling results for a Portland cement based concrete surface is of the order of 100 W/cm2, based upon sequential spotting of laser light using a 70 mm diameter spot, and a treatment time of 15-20 seconds per spot with a 3 kW YAG laser. The average power density used will increase when using smaller spots, and may be nearly double for a 40 mm diameter spot using an equivalent laser. The optimum average power density for a spot of laser light represents a trade off between the area of a laser beam above a threshold power for scabbling, removal rate and removal efficacy (e.g. no melting or the leaving of adjacent areas potentially resistant to scabbling) among other factors.
The power of the laser, the size of the incident spot of laser light and the residence time of a spot of laser light are interrelated and for any given surface will be optimised so as to achieve most effective surface removal. The interrelationships of the above factors are governed by established physical laws known to the person skilled in the art.
A suitable laser source may be a Yttrium Aluminium Garnet (YAG) laser. Laser light sources for use in the invention may have a non-uniform power density in cross-section.
It has been found that concrete removal depths of about 1 mm to 30 mm may be achieved in one pass of laser light according to the method of the invention. However, this depth will generally not be consistent across the whole treatment spot, typically showing a crater type geometry particularly with deeper scabbling.
The laser beam may be transmitted to a delivery head by means of a fibre optic cable.
A delivery head for projecting a laser beam onto a surface to be treated may comprise focussing optics to focus the beam through a focal point. The optics may include means for changing the direction of the laser light through a right angle, for example. The beam and any optics may be shrouded up to the focal point. The shroud may be frusto-conical. After the focal point the beam may diverge before impinging upon a surface to be treated. In one embodiment of the method of the present invention the surface to be treated may be 270 mm from the focal point when optics of focal length 120 mm are used giving a spot of incident laser light of around 70 mm on the surface to be treated. If the surface to be treated is 153 mm from the focal point a spot size of around 40 mm will impinge on the surface to be treated. Larger spot sizes are preferred as they give more reproducible results.
Suitable laser equipment for practising the invention is supplied by TRUMPF GmbH and Co. KG. of Stuttgart, Germany. The laser may be guided by a robotic arm.
The laser beam may effect surface removal by the effects of thermal shock. The method of the invention may give no or negligible surface removal by melting or vaporisation of the surface being treated.
The method may comprise a step of wetting the surface to be treated before irradiation with the laser beam.
The method may comprise a step of coating the surface to be treated before irradiation with laser light. Examples of suitable coatings are described in EP 0 653 762 A1.
The presence of radionuclides may affect the nature of the scabbling process and the adsorbtion of incident laser radiation.
The method of the invention will typically be used for decontamination in conjunction with fume extraction and other subsidiary protective processes to prevent the spread of any contamination, particularly where radioactivity is involved.
The surface for treatment according to the method of the invention may be an inorganic non-metallic surface such as a concrete, i.e. a cement, e.g. a Portland cement matrix having aggregate therein. The surface may alternatively comprise a natural stone such as limestone, for example.
The requirements, features and integers of the method of the first aspect of the invention apply mutatis mutandis to the apparatus of the second aspect of the invention and vice versa.
In order that the present invention may be more fully understood, examples will now be given by way of illustration only, with reference to the accompanying drawings, in which:
In the accompanying figures like features are denoted by like reference numerals.
A beam of laser light may be non-uniform in power density across a width of the beam. A schematic representation of power density across a laser beam is shown in
A schematic representation of laser equipment suitable for use in the method of the invention is shown in
The laser equipment may be mounted on a robotic arm for movement about a surface to be scabbled. Alternatively a robotic arm may move a laser head for emitting laser light on to a surface to be scabbled wherein the head is connected to a stationary laser source by a fibre optic cable.
The apparatus of the invention thus enables a method of conditioning laser light for the scabbling of a surface whereby the component 214 of laser light below a threshold power density is prevented from impinging upon a surface by means of a shadow mask. An area of a surface being scabbled which is modified by laser light not intense enough to give rise to scabbling but which could have otherwise affected the surface such that scabbling may be prevented by more intense laser light is, therefore, not created. Thus the efficiency of surface removal by scabbling is increased by use of the method and apparatus according to the present invention.
The mask 202 may be cooled, for example, by a water jacket if desired.
The shadow mask may alternatively be made of a ceramics material.
In practice aperture width A may not correspond exactly to the points on curves 4 and 274 where the curves intersect the line of threshold power density for causing scabbling 18. However, the shadow mask aperture will not normally be greater than the above distance, which defines the width of the laser beam, which is above the threshold power density for causing scabbling.
The effect of the reflective mask is further illustrated in
A significant benefit of this aspect of the invention is that low power density laser light is no longer lost or wasted by adsorbtion but is substantially reflected and reinforces the laser light capable of causing scabbling thus increasing the efficiency of the apparatus and providing a more effective method of scabbling a surface.
In the example, the reflective mask 302 comprises a hollow cylinder and is composed of a mass of around a kilogram of aluminium metal for use with a laser of 4 kw intensity. The diameter of the bore of the cylinder is 7 cm with wall thickness 1 cm. The bore of the reflective mask is polished to improve reflectivity. The reflective mask may be attached to the apparatus by brackets, stays or other means (not shown). The physical mass of the shadow mask enables energy to be adsorbed from the incoming laser light before any thermal degradation of the mask occurs. In addition the reflective mask is sufficiently robust so as to withstand the impact of any debris from the scabbling process. The end face 350 of the reflective mask 350 adjacent to the laser source may be made adsorbent to laser light to avoid reflection of laser light back at the apparatus. Alternatively, the reflective mask may be made of polished stainless steel or any other suitable materials such as a cylindrical mirror, for example.
It will be noted from
The dimensions of aperture 310 of the reflective mask 302 need not correspond exactly to the dimensions corresponding to the distance A between the points on incoming laser light power density curve 4 where the curve meets the line of threshold power density for scabbling 18. Instead the diameter of aperture 310 of the reflective mask 302 may be A′ a dimension greater than A. However, the reflective mask aperture 310 will not normally be significantly greater than the above distance A which defines the width of the laser beam which is above the threshold power density for scabbling before the beam impinges upon the reflective mask. It is noted that the increase in power density of the central part of the laser light 324, as depicted by curve 374, means that the points where line 18 of threshold power density for scabbling meet the curve 374 will be further apart (A′) than the corresponding distance (c.f. A) of points 22 on a graph 2 of incoming laser light before the reflective mask. The diameter of the aperture of a reflective mask may therefore be a dimension equal to the distance between the effective width of a reflectively masked laser beam, which is above a threshold power for surface removal by scabbling.
Number | Date | Country | Kind |
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0222342.8 | Sep 2002 | GB | national |
Filing Document | Filing Date | Country | Kind | 371c Date |
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PCT/GB03/04168 | 9/26/2003 | WO | 3/25/2005 |