The present invention relates to the field of three-dimensional (3D) printing, and more specifically, to a system and a method for fabricating a 3D metal structure.
3D printing, also known as additive manufacturing (AM), refers to processes used to synthesize a three-dimensional object in which successive layers of material are formed under computer control to create an object.
In the existing additive manufacturing system, the powder bed system is widely used and commercially available, in which high power continuous wave (cw) laser or electron beam is used as an energy source. The powder bed system may print high resolution features (50-100 μm) and no support structure is required during the process. However, the build volume is restricted to the processing chamber size and scan range. Another additive manufacturing technique, the electrodeposition fabrication (EFAB) process is suitable for fabricating metal structures at micrometer scale. However, an instant mask is needed for each layer and large/complex structures may require a large number of masks, making the process prohibitively expensive
Currently, it is impossible for the commercial systems to print micro-scale or nano-scale objects.
An objective of the present application is to provide a method and a system for fabricating a 3D metal structure, in order to address at least one of the above mentioned problems.
The system and method for fabricating the 3D metal structure provided in the present application can fabricate the metal structure at nanometer level resolution with high throughout. Comparing with existing 3D printing technologies, the present method and the system provides the following distinct advantages: (1) nanometer level lateral and axial printing resolutions, (2) high throughput (˜1000 times faster), (3) pure and dense metal structures, and (4) the capability of fabricating arbitrary structures.
In a first aspect, the present application discloses a method for fabricating a three-dimensional metal structure. The method may comprise: forming one or more layers successively on a substrate, wherein each of the layers may comprise a sacrificial material or a structural material; laser machining, by a pulsed laser, each of the formed layers based on a photomask corresponding to the structure to be fabricated; and removing redundant materials from the formed layers to release the fabricated three-dimensional metal structure.
In another aspect, the present application discloses a system for fabricating a three-dimensional metal structure. The system may comprise: at least one processor; and a memory storing instructions, which when executed by the at least one processor, cause the at least one processor to perform operations comprising: forming one or more layers successively on a substrate, wherein each of the layers may comprise a sacrificial material or a structural material; laser machining, by a pulsed laser, each of the formed layers based on a photomask corresponding to the structure to be fabricated; and removing redundant materials from the formed layers to release the fabricated three-dimensional metal structure.
In still another aspect, the present application discloses a system for fabricating a three-dimensional metal structure. The system may comprise: a pulsed laser source for providing pulsed light sheets; a digital micromirror device for generating a programmable photomask; a deposition device for depositing a sacrificial material or a structural material; at least one processor; and a memory storing instructions, which when executed by the at least one processor, cause the at least one processor to perform operations, the operations comprising: depositing one of the sacrificial material and the structural material on a substrate to form a first layer; patterning the formed layer by the pulsed light sheets laser in a parallel approach, based on the photomask corresponding to the structure to be fabricated; depositing the other one of the sacrificial material and the structural material on the patterned layer to form a further layer; planarizing the deposited layer by the pulsed light sheets; repeating above steps until a final layer is formed; and removing redundant materials by an etchant from the formed layers to release the fabricated three-dimensional metal structure.
In another aspect, the present application discloses a storage medium readable by a computer encoding a computer program for execution by the computer to carry out a method for fabricating a three-dimensional metal structure, the computer program comprising: forming one or more layers successively on a substrate, wherein each of the layers may comprise a sacrificial material or a structural material; laser machining, by a pulsed laser, each of the formed layers based on a photomask corresponding to the structure to be fabricated; and removing redundant materials from the formed layers to release the fabricated three-dimensional metal structure.
Other features, objects and advantages of the present application will become more apparent from a reading of the detailed description of the non-limiting embodiments, said description being given in relation to the accompanying drawings, among which:
The present application will be further described in detail in conjunction with the accompanying drawings and embodiments. It should be understood that the specific embodiments described herein are provided to illustrate the present invention, instead of limiting the present invention. It also should be noted that only parts related to the present invention are shown in the figures for convenience of description.
It should be noted that, the embodiments of the present application and the features in the present application, on a non-conflict basis, may be combined with each other. The present application will be further described in details below in conjunction with the accompanying drawings and embodiments.
Disclosed herein are a system and a method for fabricating a 3D metal structure. According to the present application, pure and dense metal structures can be fabricated with nanometer level resolution and high throughput (˜1000 times faster).
As show in
Comparing the continuous wave or nanosecond lasers, the pulsed laser is used in the present application to substantially increase the process precision and minimize thermal damage. The pulsed light sheets generated by the pulsed laser in combination with the photomask enables the parallel laser processing in contrast to the conventional serial processes.
In an embodiment, the pulsed laser may be a ultrafast laser. In another embodiment, the pulsed laser may comprise, but not limited to a picosecond laser, a femtosecond laser or a nanosecond laser.
In an embodiment of the present application, one of the sacrificial material and the structural material may be deposited on the substrate to form a first layer of the layers and the other one of the sacrificial material and the structural material may to form a further layer of the layers. In one embodiment of the present application, the additive process may be realized by electrodeposition, in which various metals can be deposited at controlled rates, achieving submicron resolution. The custom-developed electrolyte solutions can be used to optimize the electrodeposition outcome. i.e., density and uniformity. In one embodiment, the deposited layers may be planarized by the pulsed laser based on the sub-photomask defined for planarization. That is, the planarization of each of the deposited layers may be implemented by patterning.
In an embodiment, the photomask may be a pattern defined by a spatial light modulator (SLM) required to build the 3D structure. The spatial light modulator may comprise, but not limited to, at least one of a digital micromirror device (DMD), a liquid-crystal-based SLM, a micro-electromechanical system (MEMS) mirror and acousto opto deflector (AOD). For example, the photomasks required for building the structures in
In one embodiment, the deposited sacrificial materials may be etched to remove the redundant materials by using an etchant. Chemicals can be used to selectively remove supporting metals to form the desired 3D metal structures. To release the printed nickel structures, an etchant of high copper selectivity (Copper Etch BTP, Transene) is used with an etch rate of 150 A/sec. Typical etching processes are performed at room temperature and completed in several minutes.
An embodiment in which the structural material and the sacrificial material may be deposited by electrodeposition is described in the present application. However, it is understood that the structural material and the sacrificial material may be deposited by any known methods including, but not limited to, laser sintering/melting, sputtering, e-beam evaporation or polymerization.
It is known that the steps shown in
In an embodiment of the present application, the sacrificial material may be copper and the structural material may be nickel. It is appreciated that the sacrificial and structural materials are not limited to copper and nickel as described above. The exemplary examples of the sacrificial and structural materials that can be electrodeposited may comprise: nickel, copper, gold, silver, chromium, lead and lead alloys, tin and tin alloys, tin-lead alloys, zinc and zinc alloys, iron and iron alloys, palladium, semiconductors (silicon, gallium arsenide, gallium phosphide, indium compounds, etc), organic films (electron-conductive polymers). For example, gold, silver, tin, zinc, copper and nickel etc. can be used as a structural material while any other materials from the list can be selected as the sacrificial material. In addition, the “structural materials” can be more than one material, e.g., nickel and tin, while the sacrificial material can be copper. Structures made of more structural materials are also possible, depending on the availability of metal etchants. That is, the materials mentioned above can serve as the structural material or the sacrificial material, if suitable etchants are available (only etch the sacrificial material and be compatible with the structural material). It is noted that one printed structure can contain several kinds of materials.
In an embodiment of the present application, the photomask may be a programmable photomask generated by a digital micromirror device (DMD). Selected patterns are programmed to the DMD and the number of pulses can be precisely controlled by the DMD. The flatness of each layer may be adjusted by controlling a pixel refreshing rate, i.e., gray scale control of the digital micromirror device. For example, during the planarization step in
The method for fabricating the 3D metal structure has been described as above. Hereinafter, a system for fabricating a 3D metal structure will be described with reference to
Referring to
The system may include a laser source (laser amplifier), a power control device, a high reflectance mirror (HR), a beam homogenizer, an image generation device, an optical device, a process observation device, and an electrodeposition device. In an embodiment, the laser source may be a regenerative femtosecond Ti: sapphire laser amplifier, for example, Spectra-Physics, Spitfire Pro 4.0 W; 800 nm, 100 fs. The diameter of the laser beam is approximately 10 mm with an M2 value less than 1.3. The power control device may include a half wave plate (HWP) and a polarized beam splitter (PBS). The beam homogenizer (e.g., AdlOptica GmbH, piShaper_TisHP) may be used to convert the laser beam from a Gaussian profile to a flattop profile.
The image generation device may be a 2-D programmable digital device, e.g., a digital micromirror device (DMD). The DMD (e.g., DLP4500, Texas Instruments) contains millions of fast-switching micromirrors that has a bandwidth of 4.2-32.5 kHz. The optical device for guiding the laser beam from the laser source may include a concave mirror (CM), a half mirror (HM), and an objective lens (e.g., Nikon S Plan Fluor ELWD 40×). It is appreciated that the components of the optical device are not limited this, and other components for relaying laser beams may also be used. The concave mirror (CM) and the objective lens together form a 4-f system, enabling the pattern projection from the DMD to the focal plane of the objective lens. The process observation device may include a dichroic mirror (DM), a light source (a lamp), and a charge coupled device (CCD). The light source (an epi-illumination light source) and the CCD with a standard zoom lens (Canon EF 70-200 mm, f/4L IS) may be used for in situ process monitoring by reflectance through the long-pass dichroic mirror and the half mirror.
A sample to be fabricated may be mounted on a precision XYZ stage and connected to the negative side of a DC power supply which provides a stable current. The electrodeposition device may include three chambers which are filled with custom-developed solutions, e.g., the nickel electrolyte solutions, water, and custom-developed copper electrolyte solutions, respectively. In an embodiment, water cleaning is needed between alternate electrodeposition steps because electrolyte solutions may be polluted by other metal ions. By properly controlling the XYZ stage, the processes of electrodeposition can be fully automated.
As shown in
Further referring to
The thickness of the deposited metal layer is related to the current density and deposition time. The deposition rate can be estimated by an equation as below, derided from Faraday's Law:
where t represents deposition time; n represents the electron number; ρ represents the metal density; F represents the Faraday's contract; Aωt represents the relative atomic mass; I represents the current; S represents the deposition area; and h represents the deposition thickness.
For the micro metal printing, 4 A/dm2 is a proper current density for both the copper and nickel depositions.
Then, the relationship between the deposition thickness and deposition time for the copper and nickel is established as below:
The power supply may be used to provide steady currents so that the deposition layers can be precisely controlled via deposition time with high axial resolution, e.g., 10s nanometers. During the electrodeposition process, agitation is needed to provide sufficient metal ions near the cathode. Proper temperatures for copper and nickel deposition are 25° C. and 55° C. respectively.
Next, some exemplary examples according to embodiments of the present application will be illustrated and described with reference to
In an embodiment, the structural material may be deposited on the substrate and the structures can be fabricated without the need of sacrificial material by parallel femtosecond laser machining. Example 1 is illustrated to demonstrate the arbitrary patterning ability of the system of the embodiment according to the present application. In this example, a processing area is set to be 100×60 μm2 so that each DMD pixel corresponds to an area of 76×76 nm2. That is, the patterning resolution is only limited by the optical system instead of DMD pixels. The laser power used in the example 1 is 48 mW, i.e. 48 μJ/pulse, which is measured by a power meter (Coherent LabMax-TOP), several millimeters away from the focal plane of the objective lens. Selected patterns are programmed to the DMD and number of pulses is precisely controlled by the DMD. Two results fabricated in the Example 1 are shown in
Specifically, 30 pulses are fired to the nickel substrate/layer, i.e., the entire laser machining process is completed within 30 milliseconds (i.e., 30 pulses). In this example, a dry objective lens is used, so that some small particles are scattered on the substrate surface during the machining process. These particles may be removed and cleared up by firing a single laser pulse. Alternately, these particles may be removed by using water/oil immersion objective lenses and the system resolution may also be improved due to the higher numerical aperture (NA) of the water/oil lenses. With the dry objective lens, the system of the present application can achieve ˜800 nm resolution, which is close to the diffraction limited resolution. Higher resolution can be achieved by using the femtosecond laser with shorter wavelengths, e.g. 400 nm and 266 nm. Large processing areas can be achieved by (1) increasing the laser power or (2) stitching the patterns sequentially. Analyzed by a white light interferometer, the ablation depth increases quasi-linearly with increasing laser power and increasing pulse numbers. In this example, small particles scattered on the substrate surface during the machining process may be removed by using a single laser pulse from the pulsed laser or by using a water/oil-immersion objective lens.
From the images shown in
The Example 2 is illustrated to demonstrate multi-layer 3D microstructures and will be described with reference to
The method and system of the present application can fabricate 3D metal structures having arbitrary geometries and nanometer level resolution, with high throughput. Comparing with the existing additive manufacturing systems, the system of the present application can fabricate pure and dense metal microstructures with high resolution (˜800 nm) and high throughput. The following Table 1 lists selected commercially available metal additive manufacturing systems with technical specifications. Note the feature resolution is larger than focus diameter due to heat diffusion. From table 1, it can be seen that the systems only achieve tens (>50 μm) to hundreds of micron resolution under different processing parameters.
Referring now to
As shown in
The following components are connected to the I/O interface 9005: an input portion 9006 comprising a keyboard, a mouse and the like, an output portion 9007 comprising a cathode ray tube (CRT), a liquid crystal display (LCD), a speaker and the like; the storage portion 9008 comprising a hard disk and the like; and a communication portion 9009 comprising a network interface card, such as a LAN card, a modem and the like. The communication portion 9009 performs communication process via a network, such as the Internet. A driver 9010 is also connected to the I/O interface 9005 as required. A removable medium 9011, such as a magnetic disk, an optical disk, a magneto-optical disk and a semiconductor memory, may be installed onto the driver 3010 as required, so as to install a computer program read therefrom to the storage portion 9008 as needed.
In particular, according to the embodiment of the present disclosure, the method described above with reference to
The flow charts and the block diagrams in the figures illustrate the system architectures, functions, and operations which may be achieved by the systems, devices, methods, and computer program products according to various embodiments of the present application. For this, each block of the flow charts or the block diagrams may represent a module, a program segment, or a portion of the codes which comprise one or more executable instructions for implementing the specified logical functions. It should also be noted that, in some alternative implementations, the functions denoted in the blocks may occur in a different sequence from that marked in the figures. For example, two blocks denoted in succession may be performed substantially in parallel, or in an opposite sequence, which depends on the related functions. It should also be noted that each block of the block diagrams and/or the flow charts and the combination thereof may be achieved by a specific system which is based on the hardware and performs the specified functions or operations, or by the combination of the specific hardware and the computer instructions.
The units or modules involved in the embodiments of the present application may be implemented in hardware or software. The described units or modules may also be provided in a processor. The names of these units or modules do not limit the units or modules themselves.
As another aspect, the present application further provides a computer readable storage medium, which may be a computer readable storage medium contained in the device described in the above embodiments; or a computer readable storage medium separately exists rather than being fitted into any terminal apparatus. One or more computer programs may be stored on the computer readable storage medium, and the programs are executed by one or more processors to perform the formula input method described in the present application.
The above description is only the preferred embodiments of the present application and the description of the principles of applied techniques. It will be appreciated by those skilled in the art that, the scope of the claimed solutions as disclosed in the present application are not limited to those consisted of particular combinations of features described above, but should cover other solutions formed by any combination of features from the foregoing or an equivalent thereof without departing from the inventive concepts, for example, a solution formed by replacing one or more features as discussed in the above with one or more features with similar functions disclosed (but not limited to) in the present application.