Embodiments of the present invention can be more easily understood and further advantages and uses thereof more readily apparent, when considered in view of the description of the preferred embodiments and the following figures in which:
a-2d are illustrations of the fabrication of a device using a lift-off process according to one embodiment;
a-3d are illustrations of the fabrication of a device using a lift-off process according to one embodiment; and
a is a diagram illustrating a device according to one embodiment;
b is a diagram illustrating a system comprising the device of
In accordance with common practice, the various described features are not drawn to scale but are drawn to emphasize features relevant to the present invention. Reference characters denote like elements throughout figures and text.
In the following detailed description, reference is made to the accompanying drawings that form a part hereof, and in which is shown by way of specific illustrative embodiments in which the invention may be practiced. These embodiments are described in sufficient detail to enable those skilled in the art to practice the invention, and it is to be understood that other embodiments may be utilized and that logical, mechanical and electrical changes may be made without departing from the scope of the present invention. The following detailed description is, therefore, not to be taken in a limiting sense.
Ambient light sensors, proximity sensors, and other optical sensing applications use high performance optical filters that have tailored spectrum response. For example, an optical filter coating can be used to achieve a sensor that has a true human eye response. To achieve the desired spectrum response, optical filters in the form of dielectric mirrors are created by stacking layers of dielectric films patterned on top of a substrate. The dielectric films are applied by sputtering, deposition or evaporation methods. This is followed by patterning of the stacked dielectric films using a lift-off process. One or more embodiments of the present invention disclosed herein combine the use of an undercut sacrificial layer with a protective layer to create physical gaps in optical coatings of the dielectric film. These gaps, as explained in detail below, are readily utilized to release the sacrificial layer from the substrate, substantially simplifying the lift-off process for optical coatings. A protective layer, as referred to herein, is a non-photoresist material that can be deposited on top of a sacrificial layer of photoresist material at a sufficiently low temperature so as to avoid causing reflow of the photoresist material used in the sacrificial layer. Examples of such a non-photoresist material would include an Oxide (such as SiO2) but can also include other materials such as, but not necessarily limited to, SiON, SiN, Si3N4, Si, as well as some metal layers such as Ti, TiN, TiW, Al, Ni, and Au. Also as further discussed below, for some applications a protective layer is formed from an initial few layers of optical coating material applied such that the sacrificial layer does not reach a temperature that will cause it to flow.
A first sacrificial layer 104 is applied in a pattern over those regions of the substrate 102 where an optical coating is not desired. The pattern leaves exposed those regions of substrate 102 where an optical coating is desired. In one embodiment, the first sacrificial layer 104 is a layer of photoresist applied using masking with a spin or sputtering process, for example. At the high temperatures used to deposit optical coatings (125 Celsius, for example) photoresist will begin to flow. A benefit of the protected-resist lift-off process illustrated by
Instead, a second sacrificial layer 106 of material is applied over the first sacrificial layer 104. In one embodiment, the second sacrificial layer comprises a low temperature deposited oxide or other non-photoresist protective layer material as discusses above. The second sacrificial layer 106 performs two functions. First, it provides a protective layer that thermally shields the first sacrificial layer 104 during application of the optical coating 108. Doing so, it increases the thermal budget so that the first sacrificial layer 104 will maintain its profile for a longer period of time. Second, it permits further lateral undercutting of the first sacrificial layer 104 prior to application of the optical coating 108. As used herein, the term undercutting refers to the partial removal of sacrificial material. For example, in one embodiment, undercutting of first sacrificial layer 104 comprises removal of approximately 1 μm around the edges of first sacrificial layer 104. This lateral undercutting of first sacrificial layer 104 produces an open void or gap (shown at 107 between the second sacrificial layer 106 and the substrate 102) that will remain open to expose the sidewalls 109 of the first sacrificial layer 104 even after the optical coating 108 is applied.
In one embodiment, after the second sacrificial layer 106 is applied, a masking layer is applied over the second sacrificial layer 106 and a pattern is etched into the masking layer to expose the region of substrate 102 having sensor 103 onto which the optical coating 108 is applied. This also exposes sidewalls of the first sacrificial layer 104 to permit the lateral undercutting. Once the pattern is developed through to expose sensor 103 and the first bottom layer 104, the masking layer is removed.
Those portions of optical coating 108 applied over the second sacrificial layer 106 are removed when the first sacrificial layer 104 is removed during the lift-off process. Those portions of optical coating 108 applied to the exposed optical sensor 103 will remain to function as an optical filter (show generally at 110). In order to perform the lift-off process, an etchant or solvent solution is applied which enters into the gaps 107 to attack and destroy sacrificial layer 104. Those portions of the second sacrificial layer 106 and the optical coating 108 supported by the first sacrificial layer 104 will rinse or break away in this process.
Rather than being a uniform layer of material, an optical coating actually comprises multiple dielectric layers individually applied over several hours. For example, a finished optical coating 108 may comprise 70 layers of deposited dielectric films. In one embodiment, the thickness of each layer is on the order of 100 nm. Because gaps 107 provide a well defined break, the lift-off procedure applied in the embodiment of
The specific compositions and combinations of these multiple dielectric layers dictate the refraction index of the optical filter 110. Such stacks of various dielectric films are generally referred to as dielectric mirrors. Selection of dielectric material will depend both on the wavelengths of light to be filtered from reaching sensor 103. For example, in one embodiment, optical filter 110 comprises a dielectric mirror of alternating silicon and silicon-dioxide layers.
a-2d are block diagrams illustrating another embodiment of a process using a two-step application of optical coating material. Referring first to
A first sacrificial layer 204 is applied in a pattern over those regions of the substrate 202 where the optical coating is not desired. In one embodiment, the first sacrificial layer 204 is a patterned layer of photoresist applied using masking with a spin or sputtering process, for example. First sacrificial layer 204 forms a pattern that permits the deposition of dielectric material on the regions of substrate 202 where optical filters are needed. For example, in one embodiment, first sacrificial layer 204 forms a pattern leaving optical sensor 203 exposed so that an optical coating can be deposited.
As mentioned above, deposition of optical coatings typically is performed over several hours at high temperatures (125 Celsius, for example) that will cause photoresist material to flow. The optical film material is applied as multiple interleaved dielectric layers that form a stack of films referred to as a dielectric mirror. By alternating materials with different dielectric characteristics, a dielectric mirror having the desired refraction index to pass certain wavelengths of light is produced. Such dielectric mirrors thus function as optical filters for optical devices such as optical sensor 203. In the embodiment of
As illustrated in
When the first optical coating 206 is applied, a slight non-conformity of sputtered films will result in a thinner layer of optical film material (shown generally at 208) on the sidewalls 209 of first sacrificial layer 204. Applying an ultra sonic rinse will break down these areas of relatively thin optical film exposing the sidewalls 209 of first sacrificial layer 204, shown in
Next, as illustrated in
Referring to
Because gaps 207 provide a well defined break, the lift-off procedure applied to remove the first sacrificial layer 204 does not distort edges of the layers of deposited dielectric films forming optical filter 210. Instead, the dielectric layers forming optical filter 210 are substantially flat across optical filter 110 because they have not been deformed by the lift-off process. This is described further with respect to
a-3d are block diagrams illustrating another embodiment of a process for providing an optical filter for an optical sensor using a double-coating lift-off process of one embodiment of the present invention. Referring first to
A first sacrificial layer 304 is applied to cover those regions of the substrate 302 where the optical coating is not desired. In one embodiment, the first sacrificial layer 304 is a patterned layer of photoresist applied using masking with a spin or sputtering process, for example. The first sacrificial layer 304 forms a pattern that permits the deposition of dielectric material on the regions of substrate 302 where optical filters are needed. For example, in one embodiment first sacrificial layer 304 forms a pattern leaving optical sensor 303 exposed so that an optical coating can be deposited. In addition, in this embodiment an etching process is applied that provides a negatively angled re-entrant profile on the sidewalls 309 of the first sacrificial layer 304. That is, sidewalls 309 have a re-entrantly sloped profile, which is wider at the top than at the bottom. In one embodiment, the slope of each of the sidewalls 309 is less than 88 degrees from a normal (i.e. a vertical 90 degree) slope. As with the embodiment of
Because the sidewalls 309 were provided with a negatively angled re-entrant profile, application of the first optical coating 306 will not result in a coating of optical film material on the sidewalls 309. That is, the profile of sidewalls 309 will prevent the optical film material from being deposited on the re-entrant slope of the photoresist sidewalls.
The exposed sidewalls 309 are further undercut (on the order of 1-10 micron) to produce gaps 307 between the first optical coating 306 and substrate 302. In one embodiment, a wet etch is applied to achieve the undercut and produce gaps 307.
Next, as illustrated in
Referring to
In one embodiment, an ultrasonic rinse is applied through gaps 307 to laterally etch and completely remove the sacrificial layer 304 in order to “lift-off” the optical coatings 306 and 312 present on top of the sacrificial layer 304. In another embodiment, an etchant or solvent solution is applied which enters into the gaps 307 to attack and destroy sacrificial layer 304. Those portions of the first and second optical coatings 306 and 312 supported by the first sacrificial layer 304 will rinse or break away in this process. Those portions of the first and second optical coatings 306 and 312 applied to the exposed substrate 302 will remain. For example, those portions of the first and second optical coatings 306 and 312 applied to the exposed optical sensor 303 will remain to function as an optical filter (show generally at 310) for optical sensor 303.
Because gaps 307 provide a well defined break, the lift-off procedure applied to remove the first sacrificial layer 304 does not distort edges of the layers of deposited dielectric films forming optical filter 310. Instead, the dielectric layers forming optical filter 310 have horizontal surfaces that are substantially flat parallel planes across optical filter 310 because they have not been deformed by the lift-off process. This is described further with respect to
The method proceeds to 420 with depositing a protective layer over at least part of the first sacrificial layer. In one embodiment, the protective layer comprises a second sacrificial layer such as described with respect to
In the case where the protective layer comprises a second sacrificial layer, the material of the protective layer is applied over the first sacrificial layer. In one embodiment, the second sacrificial layer comprises a low temperature deposited oxide or other non-photoresist protective layer as discussed above. The second sacrificial layer performs two functions. First, it thermally shields the first sacrificial layer during subsequent application of the optical coating, providing sufficient thermal budget so that the first sacrificial layer will maintain its profile when the optical coating is applied. Second, it permits further lateral undercutting of the first sacrificial layer (described in block 430 below) prior to application of the optical coating. In one embodiment, after the second sacrificial layer is applied, a masking layer is applied and a pattern is etched into the masking layer to expose the region of the substrate onto which the optical coating is applied. This etching also exposes sidewalls of the first sacrificial layer to permit the lateral undercutting.
In the case where the protective layer comprises a first optical coating, the first optical coating is deposited over the first sacrificial layer and over the exposed regions of the substrate. The first optical coating comprises a sufficiently small number of dielectric layers such that when they are applied, the first sacrificial layer does not reach a temperature that will cause it to flow and lose its profile. In one embodiment, the initial layer of optical coating comprises 2-4 layers of dielectric material, each layer on the order of 100 nanometers thick. In addition, the first optical coating is applied to a total thickness that less than the thickness of the first sacrificial layer. For example, in one embodiment the first sacrificial layer comprises a photoresist layer of 1-10 micrometers while the first optical coating is between 200-400 nanometers in thickness. When the profiles of the sidewalls of the first sacrificial layer are provided with a negatively angled re-entrant profile, the sidewalls will remain free from material after depositing the first optical coating. Otherwise, where depositing of the first optical coating results in a thin coating of material on the sidewalls, an ultrasonic rinse or other process, as mentioned above with respect to
The method proceeds to 430 with partially removing the first sacrificial layer to form at least one gap between the protective layer and the substrate. The lateral undercutting produces an open void or gap that will remain open to expose the sidewalls of the first sacrificial layer even after subsequent optical coatings are applied. In one embodiment, the gap is on the order of a few micron wide.
The method proceeds to 440 with depositing a thin film, such as an optical coating, over the protective layer and the one or more regions of the substrate exposed through the first sacrificial layer, wherein the optical coating deposited over the protective layer is separated by the at least one gap from the optical coating deposited over the one or more regions of the substrate expose through the first sacrificial layer.
The method proceeds to 450 with removing the first sacrificial layer. In one embodiment, an ultrasonic rinse is applied through the gaps to laterally etch and completely remove the first sacrificial layer, in order to “lift-off” the optical coatings present on top of the photoresist. In another embodiment, an etchant or solvent solution is applied which enters into the gaps to attack and destroy the first sacrificial layer. Subsequent layers that were applied on top of, and supported by, the first sacrificial layer will rinse or break away during this part of the process. Optical coatings applied on top of the exposed substrate will remain. For example, layers of optical coatings applied to an optical sensor in the exposed region of the substrate will remain to function as an optical filter for the optical sensor.
The specific compositions and combinations of the multiple dielectric layers that make up the optical coatings and the resulting optical filter will dictate the refraction index the optical filter. Selection of which optical coating materials to use will depend on the wavelengths of light to be filtered.
Because the one or more gaps provide a well defined break between optical coating material deposited over the protective layer and optical coating material deposited directly onto the substrate, the lift-off procedure performed at block 450 will not distort edges of the remaining layers of optical coating that form a optical filter on the substrate. That is, the layers of optical coating that remain on the substrate after removal of the first sacrificial layer remain substantially flat across the optical filter because they have not been deformed by the lift-off process.
For example,
In one alternate embodiment, device 600 further comprises an optical proximity sensor 620 having an optical filter 621 such as described above with respect to optical filter 510 and sensor 503. For example, where device 600 is used as a cellular phone, power resources can be conserved by turning off or otherwise reducing the intensity of display 670 when the device 600 is held to a user's ear. As such, in one embodiment, the processor 660 monitors the output of sensor 620 for changes in light levels that would indicate that ambient light to sensor 620 is being at least partially blocked. When the processor 660 determines that ambient light to sensor 620 is being at least partially blocked, the intensity of display 670 is reduced (potentially completely). In one embodiment, processor 660 makes the determination based on the output signal from sensor 620 dropping below a threshold, or based on a rate of change in the output signal. In yet another embodiment, processor 660 uses the outputs of both sensors 610 and 620 in making the determination. For example, when processor 660 detects a sudden loss of light entering proximity sensor 620, but sensor 610 does not indicate an appreciable change in ambient light conditions, the processor determines that device 600 has been placed proximate to a user's ear and reduces the intensity of display 670. Such an embodiment avoids shutoff of display 670 simply because a nearby light source is suddenly turned off, for example.
Terms of relative position as used in this application are defined based on a plane parallel to the conventional plane or working surface of a wafer or substrate, regardless of the orientation of the wafer or substrate. The term “horizontal” or “lateral” as used in this application is defined as a plane parallel to the conventional plane or working surface of a wafer or substrate, regardless of the orientation of the wafer or substrate. The term “vertical” refers to a direction perpendicular to the horizontal. Terms such as “on,” “side” (as in “sidewall”), “higher,” “lower,” “over,” “top,” and “under” are defined with respect to the conventional plane or working surface being on the top surface of the wafer or substrate, regardless of the orientation of the wafer or substrate.
Although specific embodiments have been illustrated and described herein, it will be appreciated by those of ordinary skill in the art that any arrangement, which is calculated to achieve the same purpose, may be substituted for the specific embodiment shown. Elements of each embodiment described above can be combined with each other to provide still further embodiments. This application is intended to cover any adaptations or variations of the present invention. Therefore, it is manifestly intended that this invention be limited only by the claims and the equivalents thereof.
This application claims priority to and the benefit of U.S. Provisional Application No. 61/487,353 entitled “SYSTEMS AND METHODS FOR FACILITATING LIFT-OFF PROCESSES” and filed on May 18, 2011, which in its entirety is incorporated herein by reference.
| Number | Date | Country | |
|---|---|---|---|
| 61487353 | May 2011 | US |