This application is related to the following applications, all concurrently filed on the same date as the present application, including U.S. patent application Ser. No. 13/250,414, entitled “Integrated Gas Sensor”; U.S. patent application Ser. No. 13/250,432, entitled “Gas Sensor Utilizing Integrated Circuit Redistribution Layer”; U.S. patent application Ser. No. 13/250,456, entitled “Gas Sensor Having Integral Heater”; U.S. patent application Ser. No. 13/250,849, entitled “Gas Sensor Materials and Methods for Preparation Thereof”; and U.S. patent application Ser. No. 13/250,831, entitled “Methods and Materials for Forming Gas Sensor Structures” the disclosures of which are all expressly incorporated by reference herein in their entirety.
The disclosure herein relates to gas sensing, and more particularly to packages for integrated circuit (IC) gas sensor systems.
A wide variety of gas sensor types are utilized to detect gases and other ambient air conditions. For example, electrochemical sensors are well known. Such sensors may include the use of a metal or plastic can, which houses a liquid electrolyte having electrodes immersed in the liquid. An opening or gas diffusion barrier allows atmosphere to ingress and make contact with a gas-sensing electrode. Infrared sensors are also well known. Infrared sensors advantageously utilize the characteristics of gases which show differing absorption spectrum at various infrared frequencies. Further, metal oxide based gas sensors, such as sensors employing precious metal (Pt, Pd, Au, Ag)-activated SnO2, are also known. Such sensors may utilize porous metal oxides which exhibit a shift in electrical parameters when exposed to differing gases. For example, such electrical parameters may include resistance and capacitance characteristics. Such metal oxide sensors may be housed in a metal and/or plastic cylindrical can or ceramic housing with an opening provided on one end of the can to allow ingress of gas through an active charcoal filter to contact a porous metal oxide bead that is positioned within the can. Often such metal oxide based sensors utilize high operation temperatures, for example as high as 300 to 500 degrees Celsius.
The use of metal oxide based gas sensor materials in combination with integrated circuit technology to provide an integrated gas sensor has been described in U.S. Pat. No. 7,554,134, issued Jun. 30, 2009 to Cummins, and U.S. Pat. No. 8,007,167, issued Aug. 30, 2011 to Cummins, both of which are assigned to the present assignee and the disclosures of both of which are expressly incorporated by reference herein in their entirety. As described in U.S. Pat. Nos. 7,554,134 and 8,007,167 a single chip wireless gas sensor may include metal oxide sensing materials combined with a microcontroller, wireless transmit/receive circuitry, and other electrical circuits, all on a single integrated circuit.
Disclosed herein are systems and methods for packaging integrated circuit (IC) gas sensor systems which employ at least one gas sensor that is formed as part of an integrated circuit and configured to sense the presence and/or concentration of a target gas (e.g., such as carbon monoxide and/or methane) or other gas characteristics (e.g., such as humidity) that may be present in the ambient gaseous environment surrounding the packaged IC gas sensor system. In one embodiment, the disclosed systems and methods may be implemented with a IC package that includes a sensor housing having a sensor cavity defined therein for operably containing an IC gas sensor system disposed therein, and in a further exemplary embodiment, the IC package for the IC gas sensor system may be advantageously configured to be compatible with standard IC packaging techniques. In one embodiment, the IC gas sensor system may include an integrated circuit (e.g., containing a processor and memory) that has one or more gas sensor structures (e.g., electrodes, heating elements, etc.) formed thereon that are configured to sense a target gas concentration and other gas characteristics using one or more gas sensitive regions.
In addition to providing electrical contacts within the sensor cavity for purposes of interconnecting the IC gas sensor system to external circuitry, the sensor cavity of the IC package may also be configured to provide a contained gas sensing environment within which the gas sensor of the IC gas sensor system may be operated for gas sensing purposes. In this regard, the sensor housing may be provided with at least one gas entry opening therein that is contiguous with the sensor cavity for allowing entry of gas into the sensor cavity where the gas may contact one or more sensor elements (e.g., gas sensing electrodes) of the gas sensor. Electrical contacts may be provided within the sensor cavity that are configured for electrical interconnection with bonding pads of the IC gas sensor system, e.g., such as through bond wires or solder bumps. Corresponding electrical contacts (e.g., solder bumps, bonding pads, etc.) may in turn be provided on the exterior of the sensor housing that are electrically coupled to the electrical contacts provided within the sensor cavity. This configuration allows integrated circuitry of the IC gas sensor system to be interconnected to external circuitry outside the housing of the gas sensor package (i.e., via the coupled interior and exterior electrical contacts of the gas sensor package) for purposes of receiving electrical power and interchanging electrical signals with the external circuitry. Examples of such external circuitry include, but are not limited to, circuitry contained on a printed circuit board (PCB) or the like.
In one exemplary embodiment, one or more selected filter materials (e.g., such as activated carbon in the form of activated carbon cloth or a permeable cartridge of powdered activated carbon) may be optionally provided in a gas entry path between the gas entry opening in the sensor housing and the sensor cavity defined within the housing. Such filter material/s may be provided for purposes of filtering out contaminants other than the target gas present in the ambient gas that may interfere with accurate gas sensing measurements by the gas sensor and/or that may adversely affect components of the IC gas sensor system. Optional appropriate sensor component/s (e.g., such as electrodes) may be present to monitor the status of the filter material/s. For example, electrical resistance of an activated carbon filter material may drop as the filter material becomes saturated with trapped contaminants that are removed from the ambient gas that enters the sensor cavity through the filter material. Accordingly, spaced-apart electrodes may be provided to monitor the resistance of the filter materials so that appropriate action (e.g., alarm or sensor shut-down) may be taken when a predetermined drop in electrical resistance across the filter material indicates that the amount of contaminant saturation in the filter material has reached an undesired level and/or indicates onset of filter saturation. In one exemplary embodiment, a microcontroller component of the gas sensor system may be configured to monitor the status (e.g., resistance) of the filter material, and to take the appropriate action upon detection of undesired contaminant saturation level.
In one respect, disclosed herein is 1. A packaged integrated circuit gas sensor system, including: an integrated circuit package having a sensor cavity and a separate filter cavity defined therein; an integrated circuit gas sensor system disposed within the sensor cavity; and at least one filter material disposed within the filter cavity. The filter cavity may be in fluid communication with an ambient gaseous atmosphere outside the package, and the filter cavity may be in fluid communication with the sensor cavity to form a gas entry path through the filter material between the outside ambient gaseous atmosphere and the sensor cavity defined within the package. The sensor cavity is sealed from the outside ambient gaseous atmosphere except for the gas entry path through the filter material.
In another respect, disclosed herein is a method for packaging an integrated gas sensor system, the method including: providing an integrated circuit package having a sensor cavity and a separate filter cavity defined therein; disposing an integrated circuit gas sensor system within the sensor cavity; disposing at least one filter material within the filter cavity; and sealing the integrated circuit from an ambient gaseous atmosphere outside the package except for a gas entry path through the filter material. The filter cavity of the so formed package may be in fluid communication with the ambient gaseous atmosphere outside the package, and the filter cavity may be in fluid communication with the sensor cavity to form the gas entry path through the filter material between the outside ambient gaseous atmosphere and the sensor cavity defined within the package.
In another respect, disclosed herein is a method for sensing at least one target gas, including providing a packaged integrated circuit gas sensor system that includes an integrated circuit package having a sensor cavity and a separate filter cavity defined therein, the filter cavity being in fluid communication with an ambient gaseous atmosphere outside the package, the sensor cavity being sealed from the outside ambient gaseous atmosphere except for a gas entry path through the filter cavity, an integrated circuit gas sensor system disposed within the sensor cavity, and at least one filter material disposed within the filter cavity. The method may further include allowing gas from the outside ambient gaseous atmosphere to enter the sensor cavity via the gas entry path through the filter material disposed in the filter cavity to filter out one or more contaminants other than the target gas from the entered gas; and using the integrated circuit gas sensor system to sense one or more characteristics of the target gas that enters the sensor cavity via the gas entry path through the filter material.
As further shown in
Still referring to
Sensor structures such as structures 122 and 124 of
In one exemplary embodiment, sensor structure 122 may be a planar gas sensor structure for sensing a constituent gas concentration (e.g., such as carbon monoxide and/or methane) that has two electrodes separated by a gas sensitive metal oxide material, e.g. a tin oxide (SnO2) doped with platinum and antimony such as disclosed in concurrently filed U.S. patent application Ser. No. 13/250,849, entitled “Gas Sensor Materials and Methods for Preparation Thereof”, and in concurrently filed U.S. patent application Ser. No. 13/250,831, entitled “Methods and Materials for Forming Gas Sensor Structures” the disclosure of each of which is expressly incorporated by reference in its entirety. Such a gas sensitive material exhibits a variation in electrical resistance as the amount of gas that the gas sensitive material is exposed to varies. In such a embodiment, planar interdigitated fingers of two separate conductive elements may form one gas sensing electrode while the other gas sensing electrode may be formed by a third conductive element winding between the interdigitated fingers of first two conductive elements. Applications for a packaged IC gas sensor system 100 configured for carbon monoxide detection include, but are not limited to, household or industrial carbon monoxide detectors that detect unhealthy levels of carbon monoxide in closed buildings, fire detectors that sense fire by detecting low levels of carbon monoxide, etc.
In a further exemplary embodiment, sensor structure 124 may be a planar capacitive humidity sensor positioned in close proximity to a carbon monoxide sensor structure 122, such that sensor structure 124 may be utilized to measure humidity within sensor cavity 190 for purposes of calibrating the carbon monoxide sensor structure 122 to correct for the environmental influence of humidity on sensed carbon monoxide concentration. The humidity sensor may utilize a variety of humidity sensing techniques and may be formed in a variety of manners. In one exemplary approach, sensor structure 124 may utilize two interdigitated conductors formed in a semiconductor redistribution layer (RDL) conductor layer with an overlaying humidity sensitive dielectric layer, such as a polybenzoxazole (PBO) or polyimide layer or other suitable dielectric layer, that extends down between the two conductors and over the two conductors. The capacitance between the two conductors may change as moisture ingresses into the dielectric layer, and capacitance variations may be utilized to reflect variations in the relative humidity. As so configured in this embodiment, sensor structure 124 is positioned downstream in the gas travel path from filter material 150 so that sensor structure 124 is exposed to the same environmental characteristics (e.g., environmental humidity) that affects sensor structure 122. Capacitive humidity sensing techniques may include, for example, the techniques described in U.S. Pat. No. 8,007,167 to Cummins, the disclosure of which is incorporated herein by reference in its entirety.
Further information on the aforementioned sensor embodiments may be found described in more detail in said concurrently filed U.S. patent application Ser. No. 13/250,414, entitled “Integrated Gas Sensor”, the disclosure of which is expressly incorporated herein by reference in its entirety. It will be understood that any one or more alternative types of sensor structures may be similarly positioned and coupled to an integrated circuit 120 of a packaged integrated circuit (IC) gas sensor system 100 for detecting concentrations of other types of gases and/or for detecting characteristics of a gas other than humidity. In this regard, other embodiments may include, for example, multiple gas sensors with specific materials and configuration selective to particular gases or airborne artifacts.
In the exemplary embodiment of
As shown in
It will be understood that the materials and construction of housing 102 and lid 104 of packaged IC gas sensor system 100 may be according to any suitable semiconductor package configuration. Fabrication of housing 102 for a packaged IC gas sensor system 100 may be, for example, in accordance with standard semiconductor packaging techniques and examples of suitable semiconductor packaging types that may be employed include, but are not limited to, ceramic packages, plastic packages, and combinations thereof.
In the practice of the disclosed systems and methods, any suitable type of gas permeable filter material or combination of such filter material/s 150 may be employed to fit the characteristics of a given ambient gas composition to be sensed and/or characteristics of gas sensor structure/s employed inside sensor cavity 190. For example, in the exemplary embodiment where a carbon monoxide sensor structure 122 is employed, a filter material may be activated carbon in the form of activated carbon cloth, a gas permeable cartridge of powdered activated carbon or carbon foam. Other examples of suitable filter materials include, but are not limited to, hydrophobic membranes.
It will be understood that the particular above-described configuration of housing 102 and lid 104 of
It will be understood that the presence of filter seal 151 of
In a further embodiment, an insert component (e.g., one or more metal insert/s) may be optionally placed inside filter cavity 192 together with filter material 150 so as to suitably adjust the interior size 192 of filter cavity 192 so that the cavity 192 may easily accommodate filter materials and filter material components of differing sizes, e.g., filter material components having different thicknesses may be accommodated including those filter material components having thicknesses less than the depth of the interior of cavity 192. For example, in one exemplary embodiment, such a metal insert may be positioned between lid 104 and the top of filter material 150, e.g., in a position and configuration similar to that of optional filter seal 151 of
In a further embodiment, electrical resistance of a filter material 150 (e.g., activated carbon) may be optionally monitored over time to detect the presence of contaminant build up in the filter material. In this regard, the measured resistance across a given segment of the filter material 150 tends to drop as the filter material 150 absorbs contaminant gas molecules (e.g., such as isopropyl alcohol vapours) that are removed from the ambient gas that enters the sensor cavity 190 through the filter material 150, and as the filter material 150 becomes saturated with these trapped contaminants. A saturated filter material 150 offers no protection against contaminant gas exposure and can make a gas sensor system liable to false positive alarms.
Accordingly, as further shown in the exemplary embodiment of
In another exemplary embodiment, a microcontroller within integrated circuit 120 may be configured to apply correction factors based on measured filter material electrical resistance to the detected gas concentration values from gas sensor structure 122 and/or to output a signal to a user that is representative of the amount of filter material contamination (or remaining filter material life or capacity) based on electrical resistance correlation factors. Such correction and/or correlation factors may be maintained, for example, in a lookup table within memory of integrated circuit 120.
Further modifications and alternative embodiments of this invention will be apparent to those skilled in the art in view of this description. It will be recognized, therefore, that the present invention is not limited by these example arrangements. Accordingly, this description is to be construed as illustrative only and is for the purpose of teaching those skilled in the art the manner of carrying out the invention. It is to be understood that the forms of the invention herein shown and described are to be taken as the presently preferred embodiments. Various changes may be made in the implementations and architectures. For example, equivalent elements may be substituted for those illustrated and described herein and certain features of the invention may be utilized independently of the use of other features, all as would be apparent to one skilled in the art after having the benefit of this description of the invention.
Number | Name | Date | Kind |
---|---|---|---|
4057823 | Burkhardt et al. | Nov 1977 | A |
4580439 | Manaka | Apr 1986 | A |
4638346 | Inami et al. | Jan 1987 | A |
4649364 | Tanahashi et al. | Mar 1987 | A |
4793181 | Djorup | Dec 1988 | A |
4831381 | Hester | May 1989 | A |
4849798 | Wantanabe | Jul 1989 | A |
4876890 | Mercer et al. | Oct 1989 | A |
4931851 | Sibbald et al. | Jun 1990 | A |
5279855 | Hafele et al. | Jan 1994 | A |
5296125 | Glass et al. | Mar 1994 | A |
5357149 | Kimura | Oct 1994 | A |
5481129 | DeJong et al. | Jan 1996 | A |
5605612 | Park et al. | Feb 1997 | A |
5801428 | Felde et al. | Sep 1998 | A |
5814281 | Williams et al. | Sep 1998 | A |
5878332 | Wang et al. | Mar 1999 | A |
5942372 | West et al. | Aug 1999 | A |
6017775 | Igel et al. | Jan 2000 | A |
6051854 | Vigna et al. | Apr 2000 | A |
6111280 | Gardner et al. | Aug 2000 | A |
6407449 | Takikawa et al. | Jun 2002 | B1 |
6417026 | Gotoh et al. | Jul 2002 | B2 |
6537347 | Motouji et al. | Mar 2003 | B2 |
6647782 | Toyoda | Nov 2003 | B2 |
6673644 | Gole et al. | Jan 2004 | B2 |
6690569 | Mayer et al. | Feb 2004 | B1 |
6724612 | Davis et al. | Apr 2004 | B2 |
6774613 | Becker et al. | Aug 2004 | B1 |
7554134 | Cummins | Jun 2009 | B2 |
7622080 | Enquist | Nov 2009 | B2 |
7709828 | Braithwaite et al. | May 2010 | B2 |
RE41889 | Ferrari et al. | Oct 2010 | E |
7888708 | Yazawa et al. | Feb 2011 | B2 |
7980116 | Koda et al. | Jul 2011 | B2 |
8007167 | Cummins | Aug 2011 | B2 |
20020141136 | Toyoda et al. | Oct 2002 | A1 |
20030010119 | Toyoda | Jan 2003 | A1 |
20030010988 | Franson | Jan 2003 | A1 |
20040008471 | Davis et al. | Jan 2004 | A1 |
20050097941 | Sandvik et al. | May 2005 | A1 |
20050188764 | Itakura et al. | Sep 2005 | A1 |
20050199975 | Matubara | Sep 2005 | A1 |
20080061323 | Yazawa et al. | Mar 2008 | A1 |
20090141767 | Cummins | Jun 2009 | A1 |
20090273009 | Cummins | Nov 2009 | A1 |
20090308747 | Cramer et al. | Dec 2009 | A1 |
20090324449 | Kira | Dec 2009 | A1 |
20100098593 | Trakhtenberg et al. | Apr 2010 | A1 |
20110089439 | Cummins | Apr 2011 | A1 |
20110089472 | Cummins | Apr 2011 | A1 |
20110098937 | Cummins | Apr 2011 | A1 |
20110186995 | Alvarado et al. | Aug 2011 | A1 |
20110197657 | Gole | Aug 2011 | A1 |
20110198732 | Lin et al. | Aug 2011 | A1 |
20110210446 | Liao et al. | Sep 2011 | A1 |
20110226041 | Cummins | Sep 2011 | A1 |
20120032692 | Kothari et al. | Feb 2012 | A1 |
20120113650 | Inoue | May 2012 | A1 |
Number | Date | Country |
---|---|---|
358111747 | Jul 1983 | JP |
63103957 | Oct 1986 | JP |
404361149 | Dec 1992 | JP |
2012-78089 | Apr 2012 | JP |
WO2006090433 | Aug 2006 | WO |
WO2007097025 | Aug 2007 | WO |
WO2007099933 | Sep 2007 | WO |
Entry |
---|
JPO computer-generated English language translation of Aranishi et al. JP 2012-78089 A, patent published Apr. 19, 2012. |
Speer et al., “Gas Sensor Having Integral Heater”, U.S. Appl. No. 13/250,456, filed Sep. 30, 2011, 26 pgs. |
Speer et al., “Gas Sensor Utilizing Integrated Circuit Redistribution Layer”, U.S. Appl. No. 13/250,432, filed Sep. 30, 2011, 26 pgs. |
Speer et al., “Integrated Gas Sensor”, U.S. Appl. No. 13/250,414, filed Sep. 30, 2011, 26 pgs. |
Smith et al., “Methods and Materials for Forming Gas Sensor Structures”, U.S. Appl. No. 13/250,831, filed Sep. 30, 2011, 27 pgs. |
Smith et al., “Gas Sensor Materials and Methods for Preparation Thereof”, U.S. Appl. No. 13/250,849, filed Sep. 30, 2011, 27 pgs. |
Fis, “Fis Gas Sensor, SB-500-12, for Carbon Monoxide Detection”, Mar. 2006, 2 pgs. |
Lemme, Elektronik, “CMOS-Sensoren gehort die Zukunft”, vol. 43, No. 24, Nov. 1994, 10 pgs. |
Bousse et al., “A Process for the Combined Fabrication of Ion Sensors and CMOS Circuits”, IEEE Electron Device Letters, vol. 9, No. 1, Jan. 1988, 3 pgs. |
Baltes et al., “Micromachined Thermally Based CMOS Microsensors”, Proceedings of the IEEE, vol. 86, No. 8, Aug. 1998, 19 pgs. |
Baltes et al., “The Electronic Nose in Lilliput”, Proceedings of the IEEE, vol. 35, No. 9, Sep. 1998, 4 pgs. |
McCartney et al., “A Fully Integrated Sensor Interface Chip”, Solid State Circuits Conference Esscirc, 1999, 4 pgs. |
Cratlon, “C701 802.15.4 Zigbee Ready Wireless Sensor Module”, 2004. 1 pg. |
Morris et al., “Pt(II) As an Electronically Active Surface Site in the Room Temperature CO Response of Pt Modified Gas Sensitive Resistors”, J. Physc. Chem. B, 2001, 8 pgs. |
Aqili et al., “Effect of Antimony Doping on the Structure, Electrical and Optical Properties of Tin Oxide Thin Films”, Sci. Int., 18(1), 2006, 3 pgs. |