The present disclosure relates to thermal management systems or units including a phase change material (PCM) or latent heat storage material, and to methods of absorbing and releasing thermal energy using such systems or units.
Telecommunications cable operators typically run fiber cables from a central location to cable access nodes placed in specific service areas, such as neighborhoods. A coaxial cable is then used to connect the nodes to or end users' or customers' premises. Such cable access nodes can present temperature or thermal energy management challenges due to the presence of heat-generating components (such as cables and other electronic components) within the nodes. Other containers, in addition to cable access nodes, can also present temperature control or thermal management challenges, including but not limited to in the electronics and telecommunications industries.
Temperature control can be even more difficult to achieve when the relevant containers or spaces are standardized. For example, a customized node enclosure is often needed for use with each of a number of different cable technologies due to the different physical, electrical and thermal specifications required by each. Temperature control of computer hardware cases or components (such as associated with central processing units (CPUs) and/or auxiliary devices such as keyboards) can also be difficult to achieve. Temperature control or thermal management of containers, compartments, or spaces can be especially challenging as the size of electronic components decreases, leading to an increase in the total number (and often, power consumption or heat generation) of electronic components per unit volume (e.g., per unit volume within a cable access node or electronics cabinet or other enclosure).
Some previous efforts to manage the temperature of electronic components or enclosures have used traditional cooling fins to dissipate heat. Unfortunately, standard cooling fins have a certain limit in terms of the rate of heat that can be removed. Further, mechanical cooling means increase costs through maintenance and electricity. Improved units, systems, and methods for thermal energy management and temperature control are therefore desired.
In one aspect, thermal management units are described herein which, in some embodiments, offer one or more advantages compared to other units for managing or controlling thermal energy. In particular, units and systems described herein incorporate one or more phase change materials (PCMs), such as one or more PCMs having a certain phase transition temperature, latent heat, and/or phase transition type. In addition, as described further below, it is believed that such units and systems provide improved systems and methods for managing the heat and temperature of telecommunications and electronic equipment and enclosures, such as generic access nodes, telecommunications equipment disposed in such nodes, and other heat-generating or temperature-sensitive equipment that are housed in other types of containers or enclosures. In some cases, a PCM described herein is combined with or disposed or dispersed in a matrix or interconnected network of metallic struts. In such instances, the PCM can act as a passive cooling source and can extend the effective reach (in distance) of the cooling source (or heat sink), or effectively bring the heat sink “closer” to the heat or heat flux or source of heat needing to be dissipated or cooled. As described further herein, the PCM, in some preferred embodiments, has a “freezing” point or temperature (or other “low end” phase transition point or temperature) that is high enough to passively charge under normal ambient conditions (for example, above 50° C.), and a “melting” point or temperature (or other “high end” phase transition point or temperature) that is low enough to prevent overheating in the equipment by absorbing heat (for example, below 80° C.).
Moreover, in some embodiments, a unit or method described herein can provide more heat dissipation in a manner that is capable of storing heat or thermal energy and releasing it to ambient at the same time. Further, in some cases, a unit described herein can be mounted on the surfaces of the bottom and lid of an enclosure or equipment housing. Such a unit described herein is used for managing excess heat or thermal energy from electronic or telecommunications equipment or other equipment, or for maintaining a desired temperature or operating temperature range for such equipment.
In one aspect, heat and temperature management units or systems are described herein. In some embodiments, a heat and temperature management unit described herein comprises one or more metallic sheets (which may define a housing) having an interior volume. Additionally, the housing can comprise a sub-housing. The sub-housing may also have an interior volume or space, and may be formed from one or more metallic sheets or other thermally conductive materials. The sub-housing can comprise or have disposed within it a thermally conductive matrix. For instance, in some cases, the thermally conductive matrix comprises a honeycomb matrix, a metallic foam structure, or any other interconnected network of metallic struts to facilitate conduction-based heat transfer between the interior volume and PCM. In some embodiments, the PCM component is disposed within the interior matrix or foam structure. In this manner, the sub-housing and its contents can together serve as a PCM-containing component. In some cases, the PCM-containing component comprises sides walls housing the interconnected network of metallic struts and one or more mounting structures, such as fastener, connecting the PCM-containing component to the exterior housing unit.
In some cases, depending on the Pores Per Inch (PPI) and relative density needed, the interconnected network of metallic struts of the PCM-containing component can comprise or be formed from one or more thermally conductive materials. Any material operable to facilitate heat transfer from the computing equipment to the PCM can be used. Some non-limiting examples of materials include a thermally conductive metal or mixture or alloy of metals (such as aluminum or copper. A composite material may also be used. In some cases, a thermally conductive component described herein is formed from carbon (e.g., carbon fiber, such as carbon fiber coated with boron nitride and copper particles) or silicon carbide (SiC). In some cases, 2-30% of relative density (relative to an identical non-porous alloy) is desired. Additionally, in some embodiments, a number of 5-100 PPI is used.
The equipment housing can be for cable access node, temperature-sensitive unit, telecommunication equipment, computing-related equipment, mechanical equipment, electrical equipment, or any equipment with a localized heat flux zone. Thus, in some embodiments, the system described herein can be used to manage heat or control temperature in automobiles, batteries, electronics, munitions, or computing context.
The PCM-containing component, in some cases, is designed to maintain a specific desired temperature (as described further below) inside the equipment housing. This temperature can be based on the phase transition temperature of the PCM used in the unit. In some embodiments, the metallic sheet structure serves as a housing structure for the PCM component and the interior honeycomb or foam structure. The honeycomb or foam structure can operate to conduct heat and facilitate heat transfer between the computing (or other heat-generating) equipment and the interior volume (PCM component), and from the PCM component to the ambient outside and the external environment. Any amount of PCM not inconsistent with the objectives of the present disclosure may be used. In some cases, for example, 1-3 lbs. of PCM per PCM-containing component (metallic sheet structure or sub-housing) is desired. Moreover, a number of (e.g., 1-20) PCM-containing components (metallic sheet structure or sub-housing and other interior components) may be needed depending on the size of the equipment housing.
In some cases, depending on the density and shape of the honeycomb or metallic foam or other thermally conductive material, at least 50% of the interior volume of the thermally conductive material is occupied by the PCM. In other embodiments, a range of 50% or greater of the interior volume of the thermally conductive material is occupied by the PCM. It is known that certain applications may operate with lower than 50% of the interior volume consisting of PCM, however, such applications are based upon goals of temperature control and are consistent with the disclosure herein.
Any PCM not inconsistent with the objectives of the present disclosure can be used. In some cases, for instance, a PCM comprises one or more of the following a salt hydrate; a fatty acid (e.g., having a C4 to C28 aliphatic hydrocarbon tail, which can be saturated or unsaturated, linear or branched, where a chemical species described as a “Cn” species (e.g., a “C4” species or a “C28” species) is a species of the identified type that includes exactly “n” carbon atoms; thus, a C4 to C28 aliphatic hydrocarbon tail refers to a hydrocarbon tail that includes between 4 and 28 carbon atoms); an alkyl ester of a fatty acid (such as a C2 to C6 ester alkyl backbone or a C6 to C12 ester alkyl backbone or a C12 to C28 ester alkyl backbone); a fatty alcohol (such as a fatty alcohol having a C4 to C28 aliphatic hydrocarbon tail); a fatty carbonate ester, sulfonate, or phosphonate (such as a C4 to C28 alkyl carbonate ester, sulfonate, or phosphonate); a paraffin; a polymeric material (such as a polymeric material). In some cases, the PCM is a PCM solder under the trade name BioPCM®, available from Phase Change Energy Solutions (Asheboro, N.C.), such as BioPCM-(−8), BioPCM-(−6), BioPCM-(−4), BioPCM-(−2), BioPCM-4, BioPCM-6, BioPCM 08, BioPCM-Q12, BioPCM-Q15, BioPCM-Q18, BioPCM-Q20, BioPCM-Q21, BioPCM-Q23, BioPCM-Q25, BioPCM-Q27, BioPCM-Q30, BioPCM-Q32, BioPCM-Q35, BioPCM-Q37, BioPCM-Q42, BioPCM-Q49, BioPCM-55, BioPCM-60, BioPCM-62, BioPCM-65, BioPCM-69, and others.
It is further to be understood that a PCM described herein can comprise a plurality of differing PCMs, including differing PCMs of differing types. Any mixture or combination of differing PCMs not inconsistent with the objectives of the present disclosure may be used. In some embodiments, for example, a thermal energy management unit or system comprises one or more fatty acids and one or more fatty alcohols. Further, as described above, a plurality of differing PCMs, in some cases, is selected based on a desired phase transition temperature and/or latent heat of the mixture of PCMs.
Further, in some embodiments, one or more properties of a PCM described herein can be modified by the inclusion of one or more additives. Such an additive described herein can be mixed with a PCM and/or disposed in a unit described herein. In some embodiments, an additive comprises a thermal conductivity modulator. A thermal conductivity modulator, in some embodiments, increases the thermal conductivity of the PCM. In some embodiments, a thermal conductivity modulator comprises carbon, including graphitic carbon. In some embodiments, a thermal conductivity modulator comprises carbon black and/or carbon nanoparticles. Carbon nanoparticles, in some embodiments, comprise carbon nanotubes and/or fullerenes. In some embodiments, a thermal conductivity modulator comprises a graphitic matrix structure. In other embodiments, a thermal conductivity modulator comprises an ionic liquid. In some embodiments, a thermal conductivity modulator comprises a metal, including a pure metal or a combination, mixture, or alloy of metals. Any metal not inconsistent with the objectives of the present disclosure may be used. In some embodiments, a metal comprises a transition metal, such as silver or copper. In some embodiments, a metal comprises an element from Group 13 or Group 14 of the periodic table. In some embodiments, a metal comprises aluminum, or aluminum alloys such as 1050A, 6060, 6063. Additionally, composite materials may be used such as copper-tungsten pseudo alloy, silicon carbide in an aluminum matrix, diamond in copper silver alloy matrix, and e-material such as beryllium oxide in beryllium matrix. In some embodiments, a thermal conductivity modulator comprises a metallic filler dispersed within a matrix formed by the PCM. In some embodiments, a thermal conductivity modulator comprises a metal matrix structure or cage-like structure, a metal tube, a metal plate, and/or metal shavings. Further, in some embodiments, a thermal conductivity modulator comprises a metal oxide. Any metal oxide not inconsistent with the objectives of the present disclosure may be used. In some embodiments, a metal oxide comprises a transition metal oxide. In some embodiments, a metal oxide comprises alumina.
In other embodiments, an additive comprises a nucleating agent. A nucleating agent has a surface charge that is opposite to the partial charge of the chemical moiety of the polymer. Nucleating agents accelerate the rate of crystallization, and a melting point that is greater than the melting point of the melt processible polymer. A nucleating agent, in some embodiments, can help avoid subcooling, particularly for PCMs comprising finely distributed phases, such as fatty alcohols, paraffinic alcohols, amines, and paraffins. Any nucleating agent not inconsistent with the objectives of the present disclosure may be used.
Additionally, in some embodiments, the PCM component changes phase from a first phase to a second phase by exposing the phase change material to an ambient temperature below a phase change (or transition) temperature of the phase change material. Further, in a method or unit or system described herein includes reverting the phase change material to the first phase due to the heat produced by the computing (or other heat-generating) equipment inside the equipment housing. During this process, the temperature of the computing equipment can be maintained at or below the PCM temperature. Further, this process is not only applicable to computing but includes all types of mechanical and electrical equipment in which the controlling of operating temperatures and parameters is required.
It should further be noted that the various components of systems and units described herein (for example, the PCM-containing components, including sub-housings and thermally conductive matrices, and PCMs) can have any physical dimensions not inconsistent with the objectives of the present disclosure. For example, in some cases, the PCM-containing component (including a sub-housing, a thermally conductive matrix disposed in the sub-housing, and a PCM disposed in the matrix) is a relatively thin or sheet-like component, when compared to the dimensions of the equipment housing in which it is disposed.
These and other implementations are described in more detail in the drawings and detailed description which follows.
Many aspects of the present disclosure will be better understood with reference to the following drawings. The components in the drawings are not necessarily to scale, with emphasis instead being placed upon clearly illustrating the principles of the disclosure. Moreover, in the drawings, like reference numerals designate corresponding parts throughout the several views. It should be recognized that these implementations and embodiments are merely illustrative of the principles of the present disclosure.
Implementations and embodiments described herein can be understood more readily by reference to the following detailed description, example embodiments, and drawings. In the following discussion, a general description of the system and its components and apparatuses is provided, along with a discussion of the methods and operations of the same. It will be known to those of skill in the art that multiple configurations of the equipment housing may be applied to achieve the results of the thermal management unit, and that the embodiments disclosed herein are but a few examples of preferred configurations and methods for using the same. We continue our discussion with the example embodiment of a thermal management unit according to
In
The nature of PCM, and the applications thereof, allows for a variety of configurations and is an improvement over the prior art of metallic fins and heat exchangers. It is important to note, and reiterate, that any PCM not inconsistent with the objectives of the present disclosure can be used. As a synopsis, PCM is a substance which can release or absorb sufficient energy at a phase transition to provide useful heating and cooling properties, typically, by either melting and solidifying at a phase change temperature. The phase change transition may also include non-classical states of matter, such as forming a crystalline structure. There are several classes of PCM that are applicable to the present disclosure; organic, or carbon containing materials, derived from petroleum, plants, or animals; inorganic, namely salt hydrates; and eutectic, a mixture of both organic and inorganic components.
The PCM (or combination of PCMs) used in a particular instance can be selected based on a relevant operational temperature range for the specific end use or application. As understood by one having ordinary skill in the art, a phase transition temperature described herein (such as a phase transition temperature of “X” ° C., where X may be 50° C., for example) may be represented as a normal distribution of temperatures centered on X° C. In addition, as understood by one having ordinary skill in the art, a PCM described herein can exhibit thermal hysteresis, such that the PCM exhibits a phase change temperature difference between the “forward” phase change and the “reverse” phase change (e.g., a solidification temperature that is different from the melting temperature). For example, in some cases, the PCM has a phase transition temperature within a range suitable for heating or cooling a telecommunications node. In other instance, the PCM has a phase transition temperature suitable for the thermal energy management of so-called waste heat. In some embodiments, the PCM has a phase transition temperature within one of the ranges of Table 1 below.
As described further herein, a particular range can be selected based on the desired application. A PCM of a thermal energy storage system described herein can either absorb or release energy using any phase transition not inconsistent with the objectives of the present disclosure. For example, the phase transition of a PCM described herein, in some embodiments, comprises a transition between a solid phase and a liquid phase of the PCM, or between a solid phase and a mesophase of the PCM. A mesophase, in some cases, is a gel phase. Thus, in some instances, a PCM undergoes a solid-to-gel transition. Further, other transitions are known and disclosed herein, such as a solid to solid, solid to crystalline, a solid to liquid, liquid to crystalline, and a liquid to liquid change, to name a few.
Moreover, in some cases, a PCM or mixture of PCMs has a phase transition enthalpy of at least about 50 kJ/kg or at least about 100 kJ/kg. In other embodiments, a PCM or mixture of PCMs has a phase transition enthalpy of at least about 150 kJ/kg, at least about 200 kJ/kg, at least about 300 kJ/kg, or at least about 350 kJ/kg. In some instances, a PCM or mixture of PCMs has a phase transition enthalpy between about 50 kJ/kg and about 350 kJ/kg, between about 100 kJ/kg and about 350 kJ/kg, between about 100 kJ/kg and about 220 kJ/kg, or between about 100 kJ/kg and about 250 kJ/kg. Several distinct advantages of PCM for cooling based applications include the thermal control ability, the high latent heat storage capacity, the small volume change in phase transformation, the high specific heat capacity, the chemical stability and lack of degradation over many cycles, the high thermal conductivity, the high density of the material, the noncorrosiveness, the nonflammable aspects, the nontoxicity, and the relatively low cost of the material.
Returning to
Turning to the example embodiment disclosed in
Turning now to
In
Turning now to
where K is thermal conductivity, Q is the amount of heat transfer, d is the distance between two isothermal planes, A is the area of the surface, and delta T is the change in difference in temperature. In some instances, a thermal conductivity of the metallic matrices is at least one order of magnitude higher than a thermal conductivity of the PCM, such as at least two orders of magnitude higher, or at least three orders of magnitude higher. Not intending to be bound by theory, a metal matrix formed from one or more materials which has a thermal conductivity one or more orders of magnitude higher than the PCM may facilitate heat absorption and/or dissipation by the PCM. The metallic matrix increases the area of the surface and the measureable benefits will be apparent to those of skill in the art.
In the example embodiment of
The equipment housing (500) is secured by the fasteners (516) and in the example embodiment the fastener is a locking fastener that is capable of locking by twisting into place. The sides of the equipment housing (500) are capable of being equipped with additional structures and the previously discussed microcontroller may be mounted to the sides of the equipment housing with probes and sensors entering the side walls or through the mounting structure.
In the example embodiment of
In
The metallic matrix may further lack the addition of Boron Nitride platelets, Boron Nitride cooling fillers are ceramic fillers that may improve thermal conductivity, these fillers are often utilized to dissipate heat. Other fillers may prove more beneficial than Boron Nitride, including compositions of silicon carbide, or other metals or alloys.
The mounting structure (704) as discussed previously, allows for differing configurations to account for a variety of applications, including mounting for extreme conditions. For example, the equipment housing and thermal management unit may be adapted to mount on the exterior of electrical or mechanical components that experience seasonal weather changes, shocks, impacts, and other conditions. The equipment housing for the thermal management unit is a versatile housing that may be certified dust and or water resistant to various standards, including Ingress Protection Codes, which is an IEC standard that classifies and rates the degree of protection provided by mechanical casings and electrical enclosures. Further, the mounting structure may be sealed with or in contact with thermal paste or other thermal conduit. Thermal paste, also known as thermal grease or thermal compound is a heat conductive compound that improves the conductivity, and is often used as a thermal interface material.
In
There are two main types of metal foams, open cell, also known as metal sponge, which has the pores exposed, and closed cell, which traps the pores. In the present embodiment a closed cell foam is used for its properties of increasing surface space. In additional embodiments a closed cell metallic foam may be used if, for instance, a floating metallic foam structure is desired within the equipment housing (800). Additionally, metal foams come in a variety of composites and metals. Some examples of additional embodiments include silicon carbide (SiC) foam and or metallic matrix, carbon fiber composite foam. Examples of silicon carbide foam include physical characteristics such as compression strength of 200 psi, flexural strength of 400 psi, shear strength of 100 psi, with bulk thermal conductivity at 250 degrees Celsius at 3.05 BTU/ft, and a high resistance to oxidation and corrosion. Silicon carbide is known for high thermal conductivity, due in part to the surface area of foam constructs, which further facilitate transfer to/from PCM flowing through the matrix.
SiC and SiC composites are mainly processed through three different methods. However, these processing methods are often subjected to variations in order to create the desired structure or property. First, the Chemical Vapor Infiltration (CVI) method which uses a gas phase SiC precursor to first grow SiC whiskers or nanowires in a preform, using conventional techniques developed with CVD. Following the growth of the fibers, the gas is again infiltrated into the preform to densify and create the matrix phase. Generally, the densification rate is slow during CVI, thus this process creates relatively high residual porosity (10-15%). The Polymer Impregnation and Pyrolysis (PIP) method, which uses preceramic polymers (polymeric SiC precursors) to infiltrate a fibrous preform to create a SiC matrix. This method yields low stoichiometry as well as crystallinity due to the polymer-to-ceramic conversion process. Additionally, reduction also occurs during this conversion process, resulting in 10-20% residual porosity. Multiple infiltrations can be performed to compensate for the shrinkage. Lastly, the Melt Infiltration (MI) method which has several variations, including using a dispersion of SiC particulate slurry to infiltrate into the fibrous preform, or using CVI to coat carbon on the SiC fibers, followed with infiltrating liquid Si to react with the carbon to form SiC. With these methods, chemical reactivity, melt viscosity, and wetting between the two components should be considered carefully. Some issues with infiltrating melted Si is that the free Si can lower the composite's resistance to oxidation and creep. However, this technique usually yields lower residual porosity (˜5%) compared to the other two techniques due to higher densification rates
The metal foams may also apply to stiffen the equipment housing, by occupying a large interior volume the metal foam may serve to bolster the equipment housing so that it may be load bearing or capable of handling increased loads or usage such as under electrical equipment of vehicles and machines or the like. The unique strength properties of metallic foams relative to weight allow for versatile applications that can control overall temperature regulation with weight limitations.
In
In
Turning now to
The equipment housing (1102) may contain PCM that surrounds the subunit equipment housing (1104), forming a multi-stage thermal management unit. The benefits of subunits and additional equipment housing will be known to those of skill in the art. Turning now to the phase change material of a thermal energy storage system described herein, the PCM, in some preferred embodiments, is in direct physical contact with heat exchange surfaces of the heat generating component. In additional embodiments the conductive matrix is in direct contact with the heat exchange surface. For example, in some cases, as described above, the heat exchange surfaces are at least partially in contact, either through the equipment housing, or the mounting structure, or the conductive matrix with the PCM. Any PCM not inconsistent with the objectives of the present disclosure may be used in a thermal energy storage system described herein. Moreover, the PCM (or combination of PCMs) used in a particular instance can be selected based on a relevant operational temperature range for the specific end use or application
The attachment point of the equipment housing (1202) to the heat generating component (1204) may also be sealed with thermal paste or thermal grease. Such application increases the thermal conductivity and further creates a union between the equipment housing (1202) and the heat generating component (1204).
Focusing on
In
The present patent application claims the benefit and priority of U.S. Provisional Patent Application No. 62/948,721, filed on Dec. 16, 2019, titled “SYSTEMS AND METHODS FOR THERMAL MANAGEMENT AND PASSIVE COOLING OF LOCALIZED HEAT FLUX ZONES,” the contents of which is hereby incorporated by reference in its entirety.
Filing Document | Filing Date | Country | Kind |
---|---|---|---|
PCT/US2020/065274 | 12/16/2020 | WO |
Number | Date | Country | |
---|---|---|---|
62948721 | Dec 2019 | US |