Tag and method of making same

Abstract

This invention relates to a deactivatable tag useable with an electronic article surveillance system and comprised of planar conductive material cut into a pair of inverse, first and second spiral conductors wrapped about each other and positioned for capacitive and inductive coupling. The invention also relates to method of making tags wherein conductors are cut from a planar web of conductive material in a continuous process in a manner that the cutting results in the formation of two spiral conductors without accompanying waste of conductive material, and thereafter positioning the conductors to provide resonant circuits. The conductors of each pair are connected by welding to provide a reliable circuit. A film of electrostatic-charge-draining material on a web of deactivatable tags prevents their premature deactivation.

Description

BACKGROUND OF THE INVENTION

1. Field of the Invention

This invention relates to the art of resonant tags used in electronic article surveillance systems and to method cf making such tags.

2. Brief Description of the Prior Art

The following patents are made of record: U.S. Pat. No. 3,240,647 to Morgan granted Mar. 15, 1966; U.S. Pat. No. 3,624,631 to Chomet granted Nov. 30, 1971; U.S. Pat. No. 3,810,147 to Lichtblau granted May 7, 1974; U.S. Pat. No. 3,913,219 to Lichtblau granted Oct. 21, 1975; U.S. Pat. No. 4,369,557 to Vanderbilt granted Jan. 25, 1983; U.S. Pat. No. 4,482,874 to Rubertus et al. granted Nov. 13, 1984; U.S. Pat. No. 4,541,559 to O'Brien granted Sept. 17, 1985; U.S. Pat. No. 4,555,414 to Hoover granted Nov. 26, 1985; U.S. Pat. No. 4,55,291 to Tait et al granted Nov. 26, 1985; U.S. Pat. No. 4,567,473 to Lichtblau granted Jan. 28, 1986; U.S. Pat. No. 4,689,636 to Tait et al granted Aug. 25, 1987; and French Pat. No. 2,412,923 to Degueldre.

SUMMARY OF THE INVENTION

This invention relates to improved, reliable methods of making tags for use in an electronic article surveillance system. This invention also relates to improved tags for use in such systems.

It has been found that although the invention according to the embodiment of FIGS. 22 through 25 has greatly decreased the incidence of premature deactivation of a series of connected deactivatable tags during manufacturing, further improvement can be attained by eliminating electrostatic charges on the tag web in accordance with the present invention. It was also found that in spite of the improvement resulting from the invention according to the embodiment of FIG. 22 through 25, premature deactivation occurred when the tag web was printed on commercially available printers which typically generate electrostatic charges. In that such charges are passed to the tag web by the printer, and such charges remain in the tag web, it has happened that tags are deactivated through interaction of the deactivator and the resonant circuit on each tag. The present invention helps obviate this problem during printing on the tag web in a printer or other static-producing handling device.

In accordance with a specific embodiment of the invention, there is provided a method comprising the steps of forming a longitudinally extending web of a connected series of tags by using a continuous supporting web with each tag having a detectable resonant circuit on the supporting web and a deactivator adjacent each resonant circuit, and applying a continuous longitudinally extending film of electrostatic-charge-draining material to the supporting web along the series of tags to help prevent circuit deactivation caused by electrostatic discharge, for example between any deactivator nd its respective resonant circuit. The film can take the form of a web of conductive material adhered to the tag web, or a coating or stripe of conductive material applied to the tag web, or anti-static material applied to the tag web in sufficient amount and concentration to drain off the anti-static charge that can build up in the tag web during manufacture or during printing in a tag printer. The invention also relates to a web of tags which have resonant circuits and respective deactivators in which the tag web is provided with such a film to prevent premature circuit deactivation.

BRIEF DESCRIPTION OF THE DRAWINGS

FIG. 1 is an exploded perspective view of a tag in accordance with an embodiment of the invention;

FIG. 2 is a fragmentary sectional view of the tag shown in FIG. 1;

FIG. 3 is a diagrammatic perspective view illustrating method of making a tag in accordance with the invention;

FIG. 4 is a diagrammatic top plan view showing a mask having been applied to a first adhesive coated web and showing an electrically conductive web being laminated to the masked first adhesive coated web;

FIG. 5 is a diagrammatic top plan view showing the conductive web having been cut to provide first and second pairs of conductors and showing a masked second adhesive coated web being laminated to the conductive web;

FIG. 6 is a diagrammatic top plan view showing the first coated web with the first conductors adhered thereto being separated relative to the second coated web with the second conductors adhered thereto, and showing further the first coated web having been recoated with adhesive and two webs of dielectric being laminated to the recoated first coated web, and showing the dielectric webs having been coated with adhesive;

FIG. 7 is a diagrammatic top plan view showing the second coated web with the second conductors adhered thereto having been shifted and laminated over and to the dialectic webs and to the first coated web with the first conductors to provide a composite tag web, showing the staking of the first and second conductors of each tag to provide resonant circuits for each tag, and showing slitting of the composite tag web to provide a plural series of composite tag webs;

FIG. 8 is a vertically exploded view showing the first and second coated webs with the first and second conductors that result from cutting the electrically conductive web spirally;

FIG. 9 is a top plan view showing the first and second coated webs shifted by a distance equal to the width of one conductor spiral plus the width of one conductor;

FIG. 10 is a top plan view of two tags with the dielectric web shown in phantom lines;

FIG. 11 is a fragmentary perspective view which, when taken together with the preceding figures of the drawings, illustrates an improved method of making deactivatable tags;

FIG. 12 is a fragmentary top plan view taken along line 12--12 of FIG. 11;

FIG. 13 is a sectional view taken along line 13--13 of FIG. 12;

FIG. 14 is a fragmentary perspective view similar to FIG. 1, but showing one embodiment of structure for deactivating the tag;

FIG. 15 is a fragmentary top plan view of the tag shown in FIG. 14;

FIG. 16 is a fragmentary perspective view which, taken together with FIGS. 1 through 10, illustrated an alternative improved method of making deactivatable tags;

FIG. 17 is a fragmentary top plan view taken along line 17--17 of FIG. 16;

FIG. 18 is a sectional view taken along line 18--18 of FIG. 17;

FIG. 19 is a fragmentary perspective view similar to FIG. 14 but sowing another embodiment of structure for deactivating the tag;

FIG. 20 is a fragmentary top plan view of the tag shown in FIG. 19;

FIG. 21 is a sectional view similar to FIG. 18 but showing an alternative structure for deactivating the tag;

FIG. 22 is a top plan view of an alternative cut pattern for the web of conductive material corresponding generally to D in FIG. 5;

FIG. 23 is a top plan view of the alternative cut pattern with one-half of the conductive material removed and corresponding generally to G in FIG. 6;

FIG. 24 is a diagrammatic perspective view showing the manner in which the webs of deactivating material are cut into stripe or strips;

FIG. 25 is a top plan view of a pair of longitudinally spaced resonant circuits with separate respective deactivator strips;

FIG. 26 is a fragmentary, diagrammatic, perspective view showing the portion of a tag making process which incorporates the present invention;

FIG. 27 is a top plan view similar to FIG. 25, but incorporating the invention also illustrated in FIG. 26;

FIG. 28 is a sectional view taken generally along line 28--28 of FIG. 27;

FIG. 29 is a fragmentary perspective view showing an alternative arrangement for welding the spiral conductors to each other;

FIG. 30 is a sectional view taken generally along 30--30 of FIG. 29;

FIG. 31 is a fragmentary perspective view showing a portion of FIG. 3 modified in accordance with one embodiment of the invention;

FIG. 32 is a bottom plan view of the tag web in accordance with the invention;

FIG. 33 is a fragmentary perspective view showing a portion of FIG. 3 modified in accordance with another embodiment of the invention; and

FIG. 34 is a fragmentary perspective view showing a portion of FIG. 26 modified in accordance with yet another embodiment of the invention.

DESCRIPTION OF THE PREFERRED EMBODIMENTS

Referring initially to FIG. 1, there is shown an exploded view of a tag generally indicated at 19. The tag 19 is shown to include a sheet 20T having pressure sensitive adhesive 21 and 22 on opposite faces thereof. A mask 23 in a spiral pattern covers a portion of the adhesive 21 and a release sheet 24T is releasably adhered to the adhesive 22. The mask 23 renders the adhesive 21 which it covers non-tacky or substantially so. A conductor spiral indicated generally at 25 includes a spiral conductor 26 having a number of turns. The conductor 26 is of substantially the same width throughout its length except for a connector bar 27 at the outer end portion of the conductor spiral 26. There is a sheet of dielectric 28T over and adhered to the conductor spiral 25 and the underlying sheet 20T by means of adhesive 29. A conductor spiral generally indicated at 30 includes a spiral conductor 31 having a number of turns. The conductor 31 is adhered to adhesive 29 on the dielectric 28T. The conductor 31 is substantially the same width throughout its length except for a connector bar 32 at the outer end portion of the conductor spiral 30. The conductor spirals 25 and 30 are generally aligned in face-to-face relationship except for portions 33 which are not face-to-face with the conductor 26 and except for portions 35 which are not face-to-face with the conductor 31. A sheet 37T has a coating of a pressure sensitive adhesive 38 masked off in a spiral pattern 39. The exposed adhesive 38' is aligned with the conductor spiral 30. Adhesive is shown in FIG. 1 by heavy stippling and the masking is shown in FIG. 1 by light stippling with cross-hatching. The connector bars 27 and 32 are electrically connected, as for example by staking 90. It should be noted that the staking 90 occurs where connector bars 27 and 32 are separated only by adhesive 29. There is no paper, film or the like between tee connector bars 27 and 32. Accordingly, the staking disclosed in the present application is reliable.

With reference to FIG. 3, there is shown diagrammatically a method for making the tag 19 shown in FIGS. 11 and 2. A roll 40 is shown to be comprised of a composite web 41 having a web 20 with a full-gum or continuous coatings of pressure sensitive adhesive 21 and 22 on opposite faces thereof. The web 20 is "double-faced" with adhesive. A release liner or web 42 is releasably adhered to the upper side of the web 20 by the pressure sensitive adhesive 21, and the underside of the web 20 has a release liner or web 24 releasably adhered to the pressure sensitive adhesive 22. As shown, the release liner 42 is delaminated from the web 20 to expose the adhesive 21. The adhesive coated web 20 together with the release liner 24 pass partially about a sandpaper roll 43 and between a pattern roll 44 and a back-up roll 45 were mask patterns 23 are applied onto the adhesive 21 to provide longitudinally recurring adhesive patterns 21'. Masking material from a fountain 46 is applied to the pattern roll 44. With reference to FIG. 4, the portion marked A represents the portion of the web 20 immediately upstream of the pattern roll 44. The portion marked B shows the mask patterns 23 printed by the roll 44. The patterns 23 are represented by cross-hatching in FIG. 4. With reference to FIG. 3, the web 20 now passes through a dryer 47 where the mask patterns 23 are dried or cured. The adhesive 21 is rendered non-tacky at the mask patterns 23. A web 49 of planar, electrically conductive material such as copper or aluminum from a roll 48 is laminated onto th coated web 20 as they pass between laminating rolls 50 and 50'. Reference character C in FIG. 4 denotes the line where lamination of the webs 20 and 49 occurs. With reference to FIG. 3, the laminated webs 20 and 49 now pass between a cutting roll 51 having cutting blades 52 and a back-up roll 53. The blades 52 cut completely through the conductive material web 49 but preferably do not cut into the web 20. The lades 52 cut the web 49 into a plurality of series of patterns 25 and 30 best shown in the portion marked D in FIG. 5. With reference again to FIG. 3, there is shown a roll 54 comprised of a composite web 55 having a web 37 with a full-gum or continuous coating of pressure sensitive adhesive 38 and a release liner 56 releasably adhered to the adhesive 38 on the web 37. The release liner 56 is separated from the web 37 and the web 37 passes about a sandpaper roll 57. From there the web 37 passes between a pattern roll 58 and a back-up roll 59 where mask patterns 39 are applied onto the adhesive 38 to render the adhesive 38 non-tacky at the mask patterns 39 to provide longitudinally recurring adhesive patterns 38' (FIG. 1). Masking material from a fountain 60 is applied to the pattern roll 58. The masking material of which the patterns 23 and 39 are comprised is a commercially available printable adhesive deadener such as sold under the name "Aqua Super adhesive Deadener by Environmental Inks" and Coating Corp, Morganton N.C. From there the web 37 passes partially about a roll 61 and through a dryer 62 where the mask patterns 39 are dried or cured. The adhesive 38 is rendered non-tacky at the mask patterns 39. From there the webs 20, 49 and 37 pass between laminating rolls 63 and 64. FIG. 5 shows that lamination occurs along line E where the web 37 meets the web 49. When thus laminated, each adhesive pattern 21' registers only with an overlying conductor spiral 25 and each adhesive pattern 38' registers only with an underlying conductor spiral 30.

The webs 20, 37 and 49 pass successively partially about rolls 65 and 66 and from there the web 37 delaminates from the web 20 and passes partially about a roll 67. At the place of delamination, the web 49 separates into two webs of conductor spirals 25 and 30. As shown in FIG. 6, delamination occurs along the line marked F. When delamination occurs, the conductor spirals 30 adhere to the adhesive patterns 38' on the web 37, and the conductor spirals 25 adhere to the adhesive patterns 21' on the web 20. Thus, the conductor spirals 30 extend in one web and the spirals 25 extend in another web. The web 20 passes partially about rolls 68, 69 and 70 and from there pass between an adhesive coating roll 71 and a back-up roll 72. Adhesive 29 from a fountain 73 is applied to the roll 71 which in turn applies a uniform or continuous coating of adhesive 29 to the web 20 and over conductive spirals 25. The portion marked G in FIG. 6 shows the portion of the web 20 and conductor spirals 25 between the spaced rolls 66 and 72. The portion marked H shows the portion of the web 20 between the spaced rolls 72 and 74. With reference to FIG. 3, the web 20 passes through a dryer 75 where the adhesive 29 is dried. A plurality, specifically two laterally spaced dialectric webs 28a and 28b wound in rolls 76 and 77 are laminated to the web 20 as the webs 20, 28a and 28b pass between the rolls 74 and 74'. This laminating occurs along reference line I indicated in FIG. 6. With reference to FIG. 3, the web 20 with the conductor spirals 25 and the dialectric webs 28a and 28b pass about rolls 78 an 79 and pass between an adhesive applicator roll 80 and a back-up roll 81. The roll 80 applies adhesive 29' received from a fountain 83 to the webs 28a and 28b and to the portions of the web 20 not covered thereby. From there, the webs 20, 28a and 28b pass through a dryer 84 and partially about a roll 85.

The web 37 which had been separated from the web 20 is laminated at the nip of laminating rolls 86 and 87 along a line marked J in FIG. 7 to provide a composite tag web generally indicated at 88. The webs 20, 28a, 28b and 37 are laminated between rolls 86 and 87 after the conductor spirals 30 have been shifted longitudinally with respect to the conductor spirals 25 so that each conductor spiral 30 is aligned or registered with an underlying conductor spiral 25. The shifting can be equal to the pitch of one conductor spiral pattern as indicated at p (FIG. 9) plus the width w of one conductor, or by odd multiples of the pitch p plus the width w of one conductor. Thus, each pair of conductor spirals 25 and 30 is capable of making a resonant circuit detectable by an appropriate article surveillance circuit.

FIG. 8 shows the web 20 and the web 37 rotated apart by 180.degree.. FIG. 9 shows the web 20 and the web 37 rotated apart by 180.degree. and as having been shifted with respect to each other so that the conductor spirals 25 and 30 are aligned. As best shown in FIG. 10, the dialectric 28a terminates short of stakes 90 resulting from the staking operation. By this arrangement the stakes 90 do not pass through the dielectric 28a (or 28). FIG. 10 shows the conductor spirals 25 and 30 substantially entirely overlapped or aligned with each other, except as indicated at 35 for the conductor spiral 25 and as indicated at 33 for the conductor spiral 30. Each circuit is completed by staking the conductor bars 27 and 32 to each other as indicated at 90 or by other suitable means. The staking 90 is performed by four spiked wheels 89 which make four stake lines 90 in the composite web 88. The spiked wheels 89 pierce through the conductor bars 27 and 32 and thus bring the conductor bars 27 and 32 into electrically coupled relationship. The web composite 88 is slit into a plurality of narrow webs 91 and 92 by slitter knife 93 and excess material 94 is trimmed by slitter knives 95. The webs 91 and 92 are next cut through up to but not into the release liner 24 by knives on a cutter roll 96, unless it is desired to cut the tags T into separated tags in which event the web 88 is completely severed transversely. As shown, the webs 91 and 92 continue on and pass about respective rolls 97 and 98 and are wound into rolls 99 and 100. As shown in FIG. 7, the staking 90 takes place along a line marked K and the slitting takes place along a line marked L.

The sheet 37T, the dialectric 28T, the sheet 20T and the sheet 24T are respectively provided by cutting the web 37, the web 28a (or 28b), the web 20 and the web 24.

FIG. 11 is essentially a duplicate of a portion of FIG. 3, but a pair of coating and drying stations generally indicated at 111 and 112 where respective coatings 113 and 114 in the form of continuous stripes are printed and dried. The coating 113 is conductive and is applied directly onto the pressure sensitive adhesive 38 on the web 37. The coatings 114 are wider than the respective coatings 113 which they cover to assure electrical isolation, as best shown in FIGS. 12 and 13. The coatings 114 are composed of a normally non-conductive activatable material. The remainder of the process is the same as the process taught in connection with FIGS. 1 through 10.

With reference to FIGS. 14 and 15, there is shown a fragment of the finished tag 37T' with the coatings 113 and 114 having been severed as the tag 37T' is severed from the tag web as indicated at 113T and 114T respectively. As shown the coating 113T is of constant width and thickness throughout its length and the coating 114T is of constant width and thickness but is wider than the coating 113T. The coating 113T which is conductive is thus electrically isolated from the conductor spiral 30. The coatings 113T and 114T comprise an activatable connection AC which can be activated by subjecting the tag to a high level of energy above that for causing the resonant circuit to be detected at an interrogation zone.

FIG. 16 is essentially a duplicate of a portion of FIG. 3, but a pair of webs 118 and 119 are adhered to the adhesive 38 on the web 37. The webs 118 and 119 are wound onto spaced reels 120 and 121. The webs 118 and 119 pass from the reels 120 and 121 partially about a roll 122. The webs 118 and 119 are spaced apart from each other and from the side edges of the web 37. The webs 118 and 119 are identical in construction, and each includes a thin layer of conductive material 123 such as copper or aluminum on a layer of paper 123', a high temperature, normally non-conductive, activatable, conductor-containing layer 124, and a low temperature, normally non-conductive, activatable, conductor-containing layer 125. The layers 124 and 125 contain conductors such as metal particles or encapsulated carbon. The layer 125 bonds readily when heated, so a drum heater 115 is positioned downstream of the roll 67 (FIGS. 3 and 16) and upstream of the rolls 86 and 87 (FIG. 3). The heated circuits 30, heat the layer 125 and a bond is formed between the circuits 30 and the layer 125. Rolls 116 and 117 (FIG. 16) guide the web 37 about the drum heater 115. The heating of the layer 125 has some tendency to break down the normally non-conductive nature of the layer 125, but this is not serious because the layer 124 is not broken down or activated by heat from the drum heater 115.

With reference to FIGS. 19 and 20, there is shown a fragment of a finished tag 37T" with the webs 118 and 119 having been severed so as to be coextensive with the tag 37T" and is indicated at 118T. The web strip or stripe 118T includes the paper layer 123', the conductive layer or conductor 123 and the normally non-conductive layers 124 and 125. The layers 123, 124 and 125 are shown to be of the same width and comprise an activatable connection AC. Both coatings 124 and 125 electrically isolate the conductor 123 form the conductor spiral 30. In other respects the tag 37T" is identical to the tag 37T and is made by the same process as depicted for example in FIG. 3.

The embodiment of FIG. 21 is identical to the embodiment of FIGS. 16 through 20 except that instead of the webs 118 and 119 there are a pair of webs comprised of flat bands, one of which is shown in FIG. 21 and is depicted at 118'. The band 118' is comprise of a web or band conductor 126 of a conductive material such as copper enclosed in a thin coating of a non-conductive material 127. The band 118' comprises an activatable connection AC. As seen in FIG. 21, the upper surface of the coating 127 electrically isolates the conductor 126 from the conductor spiral 30. The band 118' is processed according to one specific embodiment, by starting with coated motor winding wire, Specification No. 8046 obtained from the Belden Company, Geneva, Ill. 60134 U.S.A. and having a diameter of about 0.004 inch with an insulating coating of about 0.0055, flattening the wire between a pair of rolls into a thin band having a thickness of 0.0006 inch. Thus processed, the insulating coating is weakened to a degree which breaks down when the resulting tag is subjected to a sufficiently high energy level signal. The coating 118' is thus termed a "breakdown coating" because it acts as an insulator when the tag is subjected to an interrogation signal at a first energy level but no longer acts as an electrical insulator when subjected to a sufficiently higher energy level signal. The conductor 126 accordingly acts to short out the inductor 30 at the higher energy level signal.

The embodiments depicted in FIGS. 11 through 20 and described in connection therewith enable the tag 37T' or 37T" to be detected in an interrogation zone when subjected to a radio frequency signal at or near the resonant frequency of the resonant circuit. By sufficiently increasing the energy level of the signal, the normally non-conductive coating 114 (or 114T), or 124 and 125 becomes conductive to alter the response of the resonant circuit. This is accomplished in a specific embodiment by using a normally non-conductive coating to provide an open short-circuit between different portions of the conductor spiral 30.

When the tag is subjected to a high level of energy, in the embodiments of FIGS. 11 through 15, and 16 through 20 the normally non-conductive coating becomes conductive and shorts out the inductor. Thus, the resonant circuit is no longer able to resonate at tee proper frequency and is unable to be detected by the receiver in the interrogation zone.

While the illustrated embodiments disclose the activatable connection AC provided by an additional conductor as extending across all the turns of the conductor spiral 30 and by a normally non-conductive material or breakdown insulation electrically isolating the conductor from the conductor spiral 30 and also extending across all of the turns of the conductor spiral 30, the invention is not to be considered limited thereby.

By way of example, not limitation, examples of the various coatings are stated below:

I. For the embodiment of FIGS. 11 through 15

A. Examples of the normally non-conductive coating 114 are:

______________________________________Example 1 Parts by Weight______________________________________cellulose acetate (C.A.)powder (E-398-3) 60acetone 300Mixing procedure: Solvate C.A. powder inacetone with stirring.C.A/copper dispersion 15above C.A. solution (16% T.S.)copper 8620 powder 2.5Mixing procedure: Add copper powder toC.A. solution with adequate stirring toeffect a smooth metallic dispersion.Example 2acrylvid B-48N 30(45% in toluene)acetone 20isopropanol 3Above solution (25% T.S.) 10copper 8620 powder 5Mixing procedure: disperse copper powderinto B-48N solution (Percent copper powderis 60-70% on dry weight basis.)______________________________________

B. Examples of the conductive coating 113 are:

______________________________________Example 1 Parts by Weight______________________________________acryloid B-67 acrylic 25(45% in naptha)naptha 16silflake #237 metal powder 42Mixing procedure: add metal powder tosolvent and wet out. Add solvated acrylicand stir well to disperse. Mix or shakewell prior to use. (75% to 85% conductivemetal on dry weight basis.)Example 2acryloid NAD-10 10(40% in naptha)silflake #237 metal powder 20Mixing procedure: Add metal powder toacrylic dispersion with stirring.Example 3S & V aqueous foil ink 5OFG 11525 (37% T.S.)silflake #237 metal powder 8Mixing procedure: Add metal powder toaqueous dispersion slowly with adequateagitation to effect a smooth metallicdispersion.______________________________________ II. For the embodiment of FIGS. 16 through 20

A. Examples of the low temperature coating 125 are:

______________________________________Example 1 Parts by Weight______________________________________acryloid NAD-10 dispersion 10(30% T. Solids)naptha 2copper 8620 copper powder 5Mixing procedure: wet copper powder withNaptha and disperse completely. Add NAD-10dispersion slowly with stirring. Mix wellor shake before use.Example 2polyester resin 28(K-1979)ethanol 10isopropanol 10ethyl acetate 20above polyester solution 10copper 8620 powder 2.5Mixing procedure: add copper powder topolyester solution while stirring to effecta smooth metallic dispersion.(48% copper powder on dry basis)______________________________________

B. Examples of the high temperature coating 124 are:

______________________________________Example 1cellulose acetate butyrate 40(C.A.B.)(551-0.2)toluene 115Ethyl Alcohol 21Above C.A.B. solution 10(22.7%)toluene 2copper 8620 copper powder 5Mixing procedure: wet copper powder withsolvent and add C.A.B. solution withstirring.Example 2acryloid B-48N 30(45% in toluene)acetone 20isopropanol 3Above solution (25% T.S.) 10copper 8620 copper powder 5(Dry weight basis - copperis 60-70% )Mixing procedure: add copper powder toabove solution with proper agitation toeffect a smooth metallic dispersion.______________________________________ The materials used in the above examples are obtainable from the following suppliers: Acryloid AND-10, Acryloid B-48N and Acryloid B-67, Rohm & Hass, Philadelphia, Pa.; Cellulose Acetate E-398-3) and Cellulose Acetate Butyrate (551-0.2), Eastman Chemical Products, Inc., Kingsport, Tenn.; Copper 8620, U.S. Bronze, Flemington, N.J.; Silflake #237, Handy & Harmo, Fairfield, Conn.; Krumbhaar K-1979, Lawter International, Inc., Northbrook, Ill.; Aqueous foil ink OFG 11525, Sinclair & Valentine, St. Paul, Minn.

FIGS. 22 through 25 depict an improved method over embodiment of FIGS. 11 through 15, over the embodiment of FIGS. 16 through 20, and over the embodiment of FIG. 21. The method of the embodiment of FIGS. 22 through 25 relates to the formation of longitudinally spaced deactivatable resonant circuits arranged in a web. The longitudinal spacing of the resonant circuits assures that electrostatic charge that can prematurely deactivate one resonant circuit in the web cannot arc longitudinally to the other resonant circuits in the web to cause their premature deactivation. Where possible, the same reference character will be used in the embodiment of FIGS. 22 through 25 as in the embodiment of FIGS. 16 through 20 to designate components having the same general construction and function, but increased by 200. It will be appreciated that reference is also made to FIGS. 3, 5 and 6.

With reference initially to FIG. 22, web 249 of planar, electrically conductive material is cut in patterns of conductor spirals 400 and 401. The cut patterns include lateral or transverse lines of complete severing 402. The conductor spirals 400 and 401 are generally similar to the conductor spirals 25 and 30, however, inspection of FIG. 5 will indicate that all conductor spirals 25 and 30 are in very close proximity to each other in the longitudinal direction, being spaced only by knife cuts themselves. In addition, spirals 25 are connected to each other and spirals 30 are connected to each other. In contrast, in the embodiment of FIGS. 22 through 25, only the conductor spirals 400 and 401 between adjacent lines of complete severing 402 are connected to each other. In the method of FIGS. 22 through 25, reference may be had to FIG. 3 which shows that the conductor spiral webs 20 and 37 are separated as they pass partly about roll 66, thereafter dielectric material webs 28a and 28b are applied, the webs 20 and 37 are shifted longitudinally by the pitch of one conductor spiral 400 (or 401) plus the width of one conductor, and thereafter the webs 20 and 37 ar re-laminated as they pass between rolls 86 and 87.

As is evident from FIG. 23, once the we of resonant circuits 401 is stripped away, the resultant web 220 has pairs of resonant circuits 401 that are longitudinally spaced apart. In like manner, the pairs of resonant circuits 400 in the stripped away web (corresponding to the web 37 in FIG. 3), are also spaced apart longitudinally.

The method of the embodiment of FIGS. 22 through 25, relates to production of deactivatable tags. The illustrated arrangement for deactivating the tags utilizes the arrangement taught in the embodiment of FIGS. 16 through 20 with the exception that the deactivator webs 318 and 319 (corresponding to the deactivator webs 118 and 119 in FIG. 16 for example), are separated into longitudinally spaced deactivator strips or stripes 318' and 319'. The separation is accomplished in accordance with the specific embodiment shown in FIG. 24 by punching out portions or holes 407 of the web 238 and the deactivator webs 318 and 319. For this purpose, a diagrammatically illustrated rotary punch 403 and a rotary die 404 are used. The rotary punch 403 has punches 405 and the rotary die 404 has cooperating die holes 406. The resultant holes 407 are wider than the spacing between the resonant circuits. The holes 407 are thus registered with the margins of the longitudinally spaced resonant circuits are shown in FIG. 25. Thus, static electricity cannot arc between resonant circuits in a longitudinal direction and static electricity cannot arc between deactivator strips 318' (or 319').

The invention of the embodiments of FIGS. 26 through 28, and 29 and 30 has applicability in general to tags with resonant circuits with generally spaced but connected conductors. For example, the invention is useful in the embodiments of FIGS. 1 through 10, 11 through 13, 14 through 20, 21 and 22 through 25. The invention is not limited to applications involving a par of spiral conductors. It is useful for example in resonant circuits where at least one of the conducts is not a spiral. This type f a circuit is shown for example in U.S. Pat. No. 3,913,219. The invention is, however, illustrated with the structure according to the most preferred embodiment of FIGS. 22 through 25.

With reference initially to FIG. 26, there are illustrated several of the steps in the improved process. It is to be understood that other steps in the process are illustrated in other figures, for example FIGS. 3 and 16. It is seen in FIG. 3 that the roll 71 applies a coating of adhesive 29 fully across the web 24 and that the roll 80 applies a coating of adhesive 29' fully across the dielectric webs 28a and 28b, but also fully across the exposed portions of the web 24. This means that when the staking occurs as illustrated at 90, the spiked wheels 89 are required to pass through adhesive and also that the spiral conductors are spaced by that adhesive except where the staking occurs. By a construction not shown, and with respect to the embodiments of FIGS. 26 through 28, and 29 and 30, the roll 29 is patterned so it will not apply adhesive to the web 24 except in the path of the dielectric webs 28a and 28b. Roll 80' is identical to the roll 80 except it is patterned to apply adhesive 29' only to the upper sides of the dielectric webs 28a and 28b so that portions 24(1), 24(2) and 24(3) of the web 24 are free of adhesive. From there the web 24 and associated webs 28a and 28b pass through a drier 84 and partly around a roll 85. A fountain 500 has a roll 501 cooperating with a back-up roll 502 to deposit or print a welding material 503 onto the connector portions 400c of spiral conductors 400 in a predetermined repetitive pattern. It is preferred that two spaced spots of the welding material 503 be applied to each connector portion 400c. As shown, once the welding material 503 has been applied, the web 24 is laminated to the web 37 as they pass between rolls 504 and 505. From there the combined webs 24 and 37 pass partially around and in contact with a drum heater 506 and from there partially about rolls 507 and 508 to slitters 93 and 95. From there the tag web 89 can be acted upon by transverse cutter 96 and the resulting narrow webs rolled into portions 400 c and 401c to be welded to each other to make good electrical connection. The expression "welding" as used herein includes what is sometimes referred to as "soldering". The heater 506 heats the welding material to the temperature where it fuses to the connector portions 400 and 401 to each other but below the temperature where the resonant circuit is degraded or where the activatable connection AC causes deactivation of th resonant circuit. By way of example, not limitation, the welding material fuses at 96.degree. C. and the breakdown coating 114 for example breaks down at 103.degree. C. The welding material is comprised of 80% by weight of metal alloy and of 20% by weight of flux and is designated BI 52 PRMAA4 and sold by Multicore Solders Inc., Cantiague Rock Road, Westbury N.Y. 11590. The metal alloy contains 15% tin, 33% lead and 52% bismuth. The 20% by weight of flux comprises 10.3% resin, 8.4% glycol, 0.3% activators and 1.0% gelling agent.

In an alternative embodiment, the tags can be made as illustrated for example in FIGS. 3 and 16 except instead of applying the welding material 503, the connector portions 400C and 401C are connected by welding using localized heat to bring the temperature of the connector portions 400 and 401 to the melting point. The resulting weld is shown at 509. This can be accomplished for example by a laser beam. Laser guns 510 illustrated in FIG. 29 are operated to effect the welds 509.

With reference to the embodiment of FIGS. 31 and 32, FIG. 31 shows a modification of FIG. 3 in which a pair of spaced webs 600 and 601 of conductive material such as copper or aluminum are applied to the underside of the web 24. The webs 600 and 601 serve a useful purpose in connection with deactivatable tags in helping prevent their premature deactivation. The webs 600 and 601 can have adhesive thereon. As the webs 600 and 601 pass between roll 43 and a back-up roll 602 the adhesive on the webs 600 and 601 adheres the webs 600 and 601 to the underside of the liner or web 24. The web 24 is continuous and supports the webs 600 and 601 and is thus considered a support or supporting web for the webs 600 and 601. The webs 600 and 601 can be delaminated from a release liner or carrier web 603 as the webs 600 and 601 are drawn from supply roll 604. The webs 600 and 601 pass together with web 24 through the entire process and FIG. 32 shows the underside of the completed tag web or composite tag web 88'. As at least some of the guide rolls used in the process are metal and are electrically grounded, the webs 600 and 601 will prevent the deactivation of the circuits of the embodiments starting with FIG. 11. In addition, each of the narrow webs 91 and 92 resulting from slitting along centerline 605 will have either web 600 or web 601 adhered thereto so when the tags are printed upon in a properly grounded printer, the web 600 (or 601) will drain off an electrostatic charge and will prevent the deactivator or activatable connection AC from deactivating the associated resonant circuit. The conductive webs 600 and 601 are effective to prevent a destructive electrostatic charge from simultaneously deactivating a multitude of resonant circuits which can result in the electrostatic charge is not dissipated.

The embodiment of FIG. 33 accomplishes the same purpose as the embodiment of FIGS. 31 and 32 except that conductive stripes or coatings 606 and 607 are applied to the underside of the web 24 by a roll 608' which receives coating material form a fountain 608. Examples of conductive coatings are given above in I.B., Examples 1, 2 and 3 and in II.B., Examples 1 and 2. Dryers can be used to dry the coatings 606 and 607 if desired.

In the embodiment of FIG. 34, a coating roll 609, receiving coating material 610 from a suitable fountain, applies the coating 610 to the underside of the web 24 preferably across its entire width and a coating roll 611, receiving coating material 612 from a suitable fountain, applies the coating material 612 to the web 27 preferably across its entire width. The coating material 610 and 612 can be identical anti-static materials, by way of example, not limitation, a suitable transparent coating material is known as Staticide 3000 concentrate diluted in at least ten parts water for each part of concentrate, by volume. This coating material is sold by ACL, Inc., Elk Grove Village, Ill. 60007 U.S.A. The concentrate is composed of 40% isopropyl alcohol, 59% long chain fatty quaternary ammonium, and 1% floral compounds. It has a boiling point of approximately 80.degree. F., a vapor pressure @68.degree. F. of 35 mmHg., a vapor density of 2.1 compared with air being equal to 1, and a specific gravity of 0.97 compared with water being equal to 1. The diluted concentrate has a boiling point of between 180.degree. F. and 212.degree. F., a vapor pressure of approximately 18 mmHg., a vapor density of approximately 2 compared with air being equal to 1, and a specific gravity of 1 compared with water being equal to 1. It is possible that trace amount of anti-static material have been added to paper and film webs by others in the past, however one embodiment of the present invention is limited to tag webs, having resonant circuits and deactivators, to which anti-static material has been added in sufficient amount and concentration to prevent premature deactivation by interaction between any deactivator and a respective resonant circuit.

It is most preferred to apply both coatings 610 and 612. The tags T are typically completely severed by knives on a cutter roll 96 so if only the coating 612 is applied, electrostatic charge drainage may be insufficient. It is therefore, preferred that at least the supporting web 24, which is continuous, have the coating 610. In that the coating 612 is invisible and does not interfere with printing, the tags T can be printed upon.

Other embodiments and modifications of the invention will suggest themselves to those skilled in the art, and all such of these as come within the spirit of this invention are included within its scope as best defined by the appended claims.

Claims

1. A longitudinally extending tag web including a series of connected deactivatable tags usable in an electronic article surveillance system, the tag web comprising a continuous longitudinally extending supporting web, each tag having a detectable resonant circuit on the supporting web and a deactivator, and a continuous longitudinally extending web of conductive material on the supporting web along the series of tags to help prevent circuit deactivation caused by electrostatic discharge.

2. A longitudinally extending tag web including a series of connected deactivatable tags usable in an electronic article surveillance system, the tag web comprising a continuous longitudinally extending supporting web, each tag having a detectable resonant circuit on the supporting web and deactivator, and a continuous longitudinally extending film of electrostatic-charge-draining material on the supporting web along the series of tags to help prevent circuit deactivation caused by electrostatic discharge.

3. A longitudinally extending tag web including a series of connected deactivatable tags useable in an electronic article surveillance system, the tag web comprising a continuous longitudinally extending supporting web, each tag having a detectable resonant circuit on the supporting web and a deactivator, and a continuous longitudinally extending coating of conductive material on the supporting web along he series of tags to help prevent circuit deactivation caused by electronic discharge.

4. A longitudinally extending tag web including a series of connected deactivatable tags useable in an electronic article surveillance system, the tag web comprising a continuous longitudinally extending supporting web, each tag having a detectable resonant circuit on the supporting web and a deactivator, and a continuous longitudinally extending film of anti-static material on the supporting web along the series of tags to help prevent circuit deactivation caused by electrostatic discharge.