Patent Application
20150107297
The present invention relates to a method to liquefy natural gas from a transmission gas pipeline. The described process was developed to efficiently produce liquid natural gas (LNG).
LNG is a natural gas that has been cooled to a cryogenic condition to condense methane, the natural gas main component. A temperature of approximately −161 C is required to produce and keep natural gas in a liquid state at standard atmospheric pressure. Liquefaction reduces the volume by approximately 600 times thus making it more economical to transport over great distances versus traditional pipelines. At present, LNG is primarily transported across continents thus making it available throughout the world. LNG is also produced in small scale liquefaction plants to supply peak saving demands, as well as to make available natural gas to regions that need it but where it is not economical or technically feasible to build pipelines.
There are differences in liquefaction selection processes for large versus small LNG plants. For large plants, the main criteria is minimization of capital cost whereas the minimization of energy consumption is left as a second objective. These two objectives can also go together; thus an optimization of the efficiency of the plant may involve a reduction in the investment of the equipment. On the other hand, a higher efficiency can result in an increase in LNG production, so the efficiency factor has a significant impact on the plant economics. In small to medium LNG plants, it is not the efficiency, but other factors such as simplicity, modularization, ease of maintenance, operation and installation that have an higher criteria when selecting a liquefaction technology. The direct consequence of these different selection criteria is that liquefaction technologies for small to medium scale applications are not the same as the ones that are used in large LNG plants.
The two main groups of liquefaction technologies are the mixed refrigerant technologies and expansion based technologies. The mixed refrigerant technologies are “condensing type” processes, where the refrigerant used for the liquefaction makes use of its latent heat of vaporization to cool the natural gas. The expansion based technologies are processes where the refrigerant is always in gas phase and only makes use of its sensible heat to cool the natural gas.
The following mixed refrigerant technologies are the most representative processes in the industry: PRICO (Poly Refrigerated Integrated Cycle Operation) is licensed by Black and Veatch and it consists of one cycle of mixed refrigerant (a mixture of methane, ethane, propane, butane, nitrogen and sometimes isopentane), the advantages claimed by the licensor are operating flexibility, modular design and reduced refrigerant inventory. The AP-M (Air Products) is licensed by APCI, is a single mixed refrigerant that is vaporized at two different levels of pressure. The dual pressure cycle is more efficient than the single pressure cycle, resulting in smaller heat exchangers and compressor. The LiMuM (Linde Multistage Mixed Refrigerant) is licensed by Linde and consists of a spiral wound heat exchanger and one 3-stage single mixed refrigeration loop for the pre-cooling, liquefaction and sub-cooling of the natural gas. This process allows for high capacity throughput. PCMR (Pre-cooled Mixed Refrigerant) is licensed by Kryopak and consists of a pre-cooling stage (ammonia or propane cycle) followed by a single mixed refrigerant cycle, where the mixed refrigerant is a mixture of nitrogen, methane, ethane, propane and butanes, this process is used primarily in small plants. OSMR (Optimized Single Mixed Refrigerant) is licensed by LNG Limited, the process is a single mixed refrigerant process complemented with a standard package ammonia absorption process. The utilization of an ammonia process improves the efficiency of the process and an increase in LNG output compared to traditional single mixed refrigerant processes. In all of the above mixed refrigerant technologies, the main differences between them are the composition of the mixed refrigerant (although the refrigerants are the same i.e.; nitrogen, methane, ethane, etc.), the metallurgy of the heat exchangers, the orientation of the equipment and the operations set points. In all the mixed refrigerants processes, the objective of innovation is to increase efficiency, reducing capital and operating costs.
The expansion based technologies have various processes based on the use of nitrogen as a refrigerant to liquefy natural gas, the N2 expansion cycle. Some of these processes use a single cycle, others use a dual expansion cycle and in other cases a pre-cooling cycle is added to improve efficiency. Several licensors i.e., APCI, Hamworthy, BHP Petroleum Pty, Mustang Engineering and Kanfa Oregon offer the N2 expansion cycles processes, and they differ by proprietary process arrangement. In all these processes, the cooling is provided by an external refrigeration plant using nitrogen expanders. The Niche LNG process is licensed by CB&I Lummus, consists of two cycles: one cycle uses methane as a refrigerant and the other uses nitrogen. The methane provides cooling at moderate and warm levels while the nitrogen cycle provides refrigeration at the lowest temperature level. The OCX process is licensed by Mustang Engineering and is based on the use of the inlet gas as a refrigerant in an open refrigerant cycle with turbo-expanders, there are variations such as OCX-R which adds a closed loop propane refrigerant to the OCX process and OCX-Angle which incorporates LPG recovery.
As demonstrated, presently there are many variations and processes to liquefy LNG. All of the processes operate based on the expansion of low boiling fluids be it through expanders or JT valves, be it closed or open cycle, the difference between them is in the process efficiencies which result in lower capital and operating costs per unit of LNG produced.
What is required is an alternative method to liquefy gas, such as LNG.
According to one aspect, there is provided a method for liquefying gas where a gas stream is passed through a gas expansion turbine. The method involves pre-treating the gas stream in a pre-treater to remove impurities, and then passing the gas stream through a first flow path of a first heat exchanger to lower a temperature of the gas stream. The gas stream is then passed through the gas expansion turbine to lower a pressure of the gas stream and further decrease the temperature of the gas stream. The gas stream is then passed into a primary separator to separate the gas stream into a liquid stream and a cold gas stream. The liquid stream is collected. Selected quantities of the cold gas stream are passed through a second flow path of the first heat exchanger whereby a heat exchange takes place to cool the gas stream flowing through the first flow path to maintain the temperature of the gas stream entering the gas expansion turbine at a temperature which promotes the production of liquids.
The method will hereinafter, as applied to the natural gas. The impurities removed are carbon dioxide and water. The liquids collected are natural gas liquids.
Although beneficial results may be obtained through the use of the method, as described above, greater efficiencies can be achieved through the use of a recycle stream. The recycle stream already has impurities removed. This involves a step of compressing the cold gas stream in a compressor after the cold gas stream has passed through the first heat exchanger to create a recycled gas stream and directing the recycled gas stream into the gas stream downstream of the pre-treater and upstream of the first heat exchanger.
Passing the recycled gas stream through the compressor will unavoidably raise the temperature of the recycled gas stream. It is, therefore, preferred that a step be included of passing the recycled gas stream through a first flow path of a second heat exchanger downstream of the compressor to lower the temperature of the recycled gas stream prior to the recycled gas stream being directed into the gas stream.
In accordance with the teachings of this method, a steady state will be reached in which a ratio of the recycled gas stream entering the gas stream is maintained constant.
In a variation of the method, where the liquids one wishes to collect are Liquid Natural Gas (LNG), a further step is included of mixing a slip stream of liquid natural gas (LNG) drawn from the primary separator into the gas stream via a mixer positioned downstream of the first heat exchanger and upstream of the gas expansion turbine.
In another variation of the method, a further step may be taken of passing the gas stream through a preliminary separator positioned downstream of the mixer and upstream of the gas expansion turbine to separate natural gas liquids (NGLs) from the gas stream, collecting the NGLs and directing the gas stream to the gas expansion turbine.
An advantage of the above method is that it can operate without external power inputs, resulting in substantial savings in both capital and operating costs. The above described method was developed with a view to collecting natural gas liquids and liquefying natural gas to form Liquid Natural Gas (LNG).
These and other features of the invention will become more apparent from the following description in which reference is made to the appended drawings, the drawings are for the purpose of illustration only and are not intended to in any way limit the scope of the invention to the particular embodiment or embodiments shown, wherein:
The method will now be described with reference to
As set forth above, this method was developed with a view to liquefying natural gas to form Liquid Natural Gas (LNG). The description of application of the method to LNG should, therefore, be considered as an example.
Referring to
A main feature of this invention is the simplicity of the process which eliminates the use of external refrigeration systems. Another feature of the invention is the flexibility of the process to meet various operating conditions since the ratio of LNG production is proportional to the cold vapour stream generated and recycled. The invention also provides for a significant savings in energy when compared to other processes since it uses its recycled vapour stream as the coolant medium, the process produces its own refrigeration stream. The proposed invention can be used in any LNG production plant size.
Referring to
Referring to
The cooling of compressed recycled gas stream 23 is provided by a once through heat exchange from gas transmission line 29. The required gas coolant is routed through valve 31 and line 32 into heat exchanger 24 and the once through flow is returned to gas transmission line 29 through line 34 and valve 33.
The LNG receiver 13 accumulates the LNG produced. LNG exits receiver 13 through stream 14 to supply LNG product pump 15, where it is pumped to storage through line 16. A portion of the produced LNG is routed through line 38 to high pressure LNG pump 39. The pressurized LNG liquid stream is controlled by temperature valve 41 to a pre-set temperature through temperature transmitter 47. The controlled LNG stream 42 enters mixer 44 to cool and condense the desired natural gas liquids.
The proposed invention addresses both large and small plants in which process simplicity and ease of operation are the main components. The invention eliminates the need for refrigeration cycle plants and the use of proprietary mixed refrigerants. By simplifying the process, it reduces capital, maintenance, and operations costs.
In the preferred method, natural gas is first pre-cooled with produced cold vapor then expanded through a gas expander. The gas expander produces electricity. The expanded gas produces a vapour and a liquid stream. The vapour stream is recycled by first pre-cooling the feed gas to the expander and then recompressed, cooled and recycled. A portion of the produced LNG provides the cold energy required as a recycle stream to cool and liquefy the pre-treated natural gas stream to recover desired natural gas liquids. The proposed invention eliminates the practice and use of mixed refrigerant cycles resulting in lower capital and operating costs. The process is applicable to any LNG plant size.
It should be noted that the motive force for the compressor can be provided by an electric motor versus a gas driven engine as proposed. Moreover, the compressed vapour stream can be discharged into gas transmission line 29 rather than recycled as proposed.
In this patent document, the word “comprising” is used in its non-limiting sense to mean that items following the word are included, but items not specifically mentioned are not excluded. A reference to an element by the indefinite article “a” does not exclude the possibility that more than one of the element is present, unless the context clearly requires that there be one and only one of the elements.
The scope of the claims should not be limited by the preferred embodiments set forth in the examples, but should be given a broad purposive interpretation consistent with the description as a whole.
| Number | Date | Country | Kind |
|---|---|---|---|
| 2,772,479 | Mar 2012 | CA | national |
| Filing Document | Filing Date | Country | Kind |
|---|---|---|---|
| PCT/CA2013/050232 | 3/21/2013 | WO | 00 |
