Patent Application
20140098836
The present invention relates to a temperature indicating paint.
Known irreversible temperature indicating paints change colour at one or more known temperatures. These colour changes indicate the temperature to which different parts of a component or components have been subjected. The paint can be applied to components such as turbine blades, turbine vanes and combustors of gas turbine engines.
The paint helps determination of the temperatures to which different regions of the component reached during the test. Advantageously, the paint can produce a temperature profile over the whole surface of the component, rather than at discrete points if for example thermocouples were used.
One known irreversible temperature indicating paint is described in U.S. 2010/0276642 and comprises sodium alumino sulpho silicate, nickel antimony titanate and a binder. The paint undergoes colour change at 520-560° C., 950-990° C., 1000-1040° C. and 1160-1200° C. However, the final colour of such a paint is generally dependent on both the temperature it is subjected to and the time period over which it is held at a raised temperature. This time dependence introduces errors when the time-temperature history of the component is not well known. Further, a requirement for a fixed, generally short, thermal excursion reduces the flexibility of how such paints can be used.
Another known temperature indicating paint is described in GB A 2204874 and comprises one or more of silver, gold, platinum, copper, nickel, chromium, titanium and silicon dispersed in 10 to 70 wt % solvent and resin. This type of paint tends to have just one change of colour or finish, but the change is substantially independent of the time period over which the component is held at a raised temperature. Thus the paint can provide one isotherm on the component e.g. from which the colour change of the first type of temperature indicating paint can be calibrated. However, as the paint exhibits only one isotherm, the information gained from use of the paint is relatively low. Further, such paints are unsuitable for components with uniform temperature distributions (which may not traverse the isotherm).
There is a need for a further type of temperature indicating paint which addresses at least some of the shortcomings noted above.
Accordingly, the present invention provides in a first aspect a temperature indicating paint which is spreadable onto a surface of an article, the paint including particles of an alloy of two or more metals, the particles varying in relative composition of the metals such that particles having different compositions have different melting points or melting ranges.
Advantageously, each composition can denote respective solidus and liquidus points. When applied as a coating to an article and then exposed to temperature, those particles whose solidus points are above the maximum temperature at a given location will remain completely unmelted, while those particles whose solidus points are below the maximum temperature at the location will begin to melt and lose their shape. Those particles whose liquidus points are below the maximum temperature at a given location will be completely melted and will lose their shape. Thus identifying the particles that have remained partially or fully unmelted and determining the lowest melting point of those particles allows the maximum temperature at a given location to be determined. Repeating the procedure at other locations then allows a 2-D map of maximum temperatures across the article to be derived. Time dependence in the maximum temperature determination is expected to be weak or non-existent.
The paint may have any one or, to the extent that they are compatible, any combination of the following optional features.
Typically, the paint includes a matrix for the particles. For example, the matrix can include components such as inert fillers to reduce interactions between particles in the paint.
Conveniently, the particles having different compositions may be distinguishable from each other by spectroscopy, e.g. energy dispersive X-ray spectroscopy, auger electron spectroscopy, X-ray photoelectron spectroscopy or wavelength dispersive X-ray spectroscopy. Such spectroscopic techniques can be combined with e.g. secondary electron microscopy to identify the unmelted particles.
The alloy may be an alloy of just two metals.
Preferably, the particles provide a continuous distribution of compositions and a corresponding continuous distribution of solidus and liquidus points. For example, one end point of the composition distribution may have a lower melting point than the other end point of the composition distribution, and the alloy may have continuously increasing solidus and liquidus lines between the end points. In this way, each composition can have a unique melting range.
The melting ranges of the particles may be at least 500° C., and preferably at least 800° C. or 900° C. The melting points of the particles may be at most 1400° C., and preferably at most 1300° C. or 1200° C. These temperature limits can provide a range of particle melting points which are suitable for investigating maximum temperatures in gas turbine engines.
In a second aspect, the present invention provides the use of the paint according to the first aspect for painting the surface of an article. For example, the article may be a gas turbine engine component such as a turbine blade or vane, turbine disc, or combustor.
In a third aspect, the present invention provides an article having a surface painted with the paint according to the first aspect. Again, the article may be a gas turbine engine component such as a turbine blade or vane, turbine disc, or combustor
In a fourth aspect, the present invention provides a method of producing the paint according to the first aspect, the method including the steps of:
sputtering a substrate with two metals or metal alloys having different compositions such that a sputtered deposit is formed on the substrate, the sputtering conditions being selected such that the deposit varies in relative composition of the two metals or metal alloys from point to point,
grinding the deposit to produce particles varying in relative composition, and
combining the particles with a suitable matrix to produce the paint.
In a fifth aspect, the present invention provides a method of producing the paint according to the first aspect, the method including the steps of:
precipitating particles of the alloy from a solution containing chemical precursors of the alloy, the precipitation conditions (e.g. precursor concentration) varying such that the precipitated particles correspondingly vary in relative composition of the two or more metals, and
combining the precipitated particles with a suitable matrix to produce the paint.
For example, the precipitation conditions may vary over time. Alternatively, the precipitation conditions may vary between batches of the solution.
In a sixth aspect, the present invention provides a method of determining the maximum temperature experienced by the article of the third aspect, the method including the steps of:
exposing the article to temperatures at which at least some of the particles in the paint may melt, either partially or completely,
examining the surface of the article at one or more locations for partially or completely unmelted particles, and
measuring the compositions of the partially or completely unmelted particles to determine the maximum temperature to which the article was exposed at the one or more locations.
The examining and measuring steps can be performed at a plurality of locations to build up a 2-D map of the maximum temperature to which the article was exposed.
The examining step may be performed using electron microscopy, e.g. using secondary electron microscopy.
The measuring step may be performed by spectroscopy, e.g. energy dispersive X-ray spectroscopy, auger electron spectroscopy, X-ray photoelectron spectroscopy, wavelength dispersive X-ray spectroscopy.
Embodiments of the invention will now be described by way of example with reference to the accompanying drawings in which:
A temperature indicating paint according to the present invention includes particles of an alloy of two or more metals. The particles vary in relative composition of the metals such that particles having different compositions have different melting ranges. The temperature indicating paint may include a number of different alloys each of a different metal and composition.
The particles may be produced as a powder by a variety of means. For example, well known methods developed for powder metallurgy include spray atomisation, electrolysis and chemical precipitation from solution. Varying the concentration of the powder precursors can then produce the variation in the alloy composition of the resulting powder.
However, an alternative approach is to sputter the metals onto a substrate with a suitable geometry and then grind up the resulting deposit. For example, one possible sputtering arrangement involves positioning sputtering targets of two different metals or metal alloys roughly equidistantly from and at opposite ends of a substrate. This then can produce a gradual change in composition of the deposited metals/alloys across the substrate. The positions of the targets and substrate can be adjusted to achieve the required range of composition on the substrate.
Having produced the powder, the paint is formed by combining the powder with a suitable matrix, which may include components such as inert fillers to reduce interactions between particles in the paint.
Another alternative approach to forming alloy compositions for the temperature indicating paint is to form a number of discrete alloy compositions and mix the compositions together. Thus there may be formed a paint comprising particles of a first composition and particles of a second composition and where each composition has a different melting point or range. The first and second compositions may be of the same metals, but could also be formed of different metals. The number of discrete particle alloy compositions and the specific composition of each particle may be tailored to the particular application for identification of desired temperature points, range or ranges that a component is subjected.
In use, hot working gases force against the blades to rotate the rotor and drive a compressor in known fashion. In service and during testing, it is desirable to know the temperatures and temperature gradients experience by the component. Here at least one blade is coated with a temperature indicating paint as described herein. Only a patch of temperature indicating paint 26 is shown, but in other cases all of the aerofoil may be coated or all of the blade can be coated as well as parts of the disc.
The paint is applied to a component, such as a turbine blade or vane, turbine disc, or combustor, and run in an engine. The surface of the component may be pretreated to improve keying of the paint, which can be brushed or sprayed onto the component. Stoving of the paint may be required before the test to bond the paint to the component.
After the test, the paint can be removed from the component for subsequent analysis, for example by peeling off the paint using adhesive tape, or by detaching a removable part of the component itself. Alternatively, the paint on smaller components (such as high pressure turbine blades etc) may be analysed in situ on the component and/or after the component is removed from the engine.
At a given location on the component, particles in the paint with compositions having a solidus point below the maximum temperature reached in this location will have begun to melt and flow, partially losing their original particle shape, while those particles with compositions having a solidus point above the maximum reached will still remain as discrete, unmelted particles. At the same given location on the component, particles in the paint with compositions having a liquidus point below the maximum temperature reached in this location will have completely melted and flowed, losing their original particle shape and/or texture and/or lustre or other measurable parameter such as composition and radiance.
Referring to
Areas of temperature indicating paint 26 are given the reference numbers 26A, 26B, 26C and 26D and are generally subject to different temperatures. The temperature indicating paint 26 comprises particles of alloys or in some cases pure metals. The alloy composition or single metal varies such that there may be two or more different alloy compositions or single metal particles within the paint. In this example, the temperature indicating paint 26 comprises four different particle types each having different compositions for alloys and therefore four different liquidus and solidus points. The four types or compositions of particles are dispersed throughout the paint 26 and are referred to as alloys W, X, Y and Z. Alloy compositions W, X, Y and Z have increasingly high liquidus and solidus points, such that composition Z has the highest melting point.
After being run in a gas turbine engine, in area 26A, the highest temperature zone, particles having compositions W, X and Y have completely melted, particles having composition Z having a solidus point below the maximum temperature reached in this area will have begun to melt (or partially melted) and flow, partially losing their original particle shape.
In area 26B, the second highest temperature zone, particles having compositions W and X have completely melted, particles having compositions Y having a solidus point below the maximum temperature reached in this area will have begun to melt (or partially melted) and flow, partially losing their original particle shape, while those particles with compositions Z having a solidus point above the maximum reached will still remain as discrete, unmelted particles.
In third highest temperature-exposed area 26C, particles having composition W have completely melted, particles having composition X having a solidus point below the maximum temperature reached in this area will have begun to melt (or partially melted) and flow, partially losing their original particle shape, while those particles with compositions Y and Z having a solidus point above the maximum reached will still remain as discrete, unmelted particles.
In fourth highest temperature-exposed area 26D, particles having composition W having a solidus point below the maximum temperature reached in this area will have begun to melt (or partially melted) and flow, partially losing their original particle shape, while those particles with compositions X, Y and Z having a solidus point above the maximum reached will still remain as discrete, completely unmelted particles.
Thus, for example, by examining the temperature indicating paint 26 using electron microscopy and measuring the particles using spectroscopy it is possible to determine isotherms (34-38), temperature gradients and maximum temperatures experienced by the blade. This method can therefore be used at a plurality of locations to build up a two-dimensional or graphical map of the temperature to which the article was exposed and particularly illustrate maximum temperature location(s).
While the invention has been described in conjunction with the exemplary embodiments described above, many equivalent modifications and variations will be apparent to those skilled in the art when given this disclosure. Accordingly, the exemplary embodiments of the invention set forth above are considered to be illustrative and not limiting. Various changes to the described embodiments may be made without departing from the spirit and scope of the invention.
All references referred to above are hereby incorporated by reference.
| Number | Date | Country | Kind |
|---|---|---|---|
| 1109533.8 | Jun 2011 | GB | national |
| Filing Document | Filing Date | Country | Kind | 371c Date |
|---|---|---|---|---|
| PCT/EP2012/060100 | 5/30/2012 | WO | 00 | 11/18/2013 |
